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http://dx.doi.org/10.9713/kcer.2022.60.1.62

Fabrication of Graphene-modified Indium Tin Oxide Electrode Using Electrochemical Deposition Method and Its Application to Enzyme Electrode  

Wang, Xue (Department of Chemical Engineering and RIGET, Gyeongsang National University)
Shi, Ke (Department of Chemical Engineering and RIGET, Gyeongsang National University)
Kim, Chang-Joon (Department of Chemical Engineering and RIGET, Gyeongsang National University)
Publication Information
Korean Chemical Engineering Research / v.60, no.1, 2022 , pp. 62-69 More about this Journal
Abstract
Graphene has a large surface area to volume ratio and good mechanical and electrical property and biocompatibility. This study described the electrochemical deposition and reduction of graphene oxide on the surface of indium tin oxide (ITO) glass slide and electrochemical characterization of graphen-modified ITO. Cyclic voltammetry was used for the deposition and reduction of graphene oxide. The surface of graphen-coated ITO was characterized using scanning electron microscopy and energy dispesive X-ray spectroscopy. The electrodes were evaluated by performing cyclic voltammetry and electrochemical impedance spectroscopy. The number of cycles and scan rate greatly influenced on the coverage and the degree of reduction of graphene oxide, thus affecting the electrochemical properties of electrodes. Modification of ITO with graphene generated higher current with lower charge transfer resistance at the electrode-electrolyte interface. Glucose oxidase was immobilized on the graphene-modified ITO and has been found to successfully generate electrons by oxidizing glucose.
Keywords
Graphene oxide; Indium tin oxide; Electro deposition; Electro reduction; Glucose oxidase immobilization;
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