• 제목/요약/키워드: Cyclic properties

검색결과 1,059건 처리시간 0.028초

4-Octyl-4'-(5-carboxy-pentamethylene-oxy)azobenzene과 Dilauroyl-L-${\alpha}$- Phosphayidylcholine의 혼합 LB막의 전기화학적 특성 (Electrochemical Properties of Langmuir-Blodgett Films of 4-Octyl-4'-(5-carboxy-pentamethylene-oxy)azobenzene and Dilauroyl-L-${\alpha}$-Phosphayidylcholine Mixture)

  • 김범준;민병철;박근호
    • 한국응용과학기술학회지
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    • 제19권1호
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    • pp.49-55
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    • 2002
  • We carried out this experiment to observe electrochemical properties for LB films of phospholipid(Dilauroyl-L-${\alpha}$-Phosphayidylcholine) and 4-octyl-4'-(5-carboxypentamethylene-oxy)azobenzene mixture by the cyclic voltammetry. LB films of 8A5H and 8A5H-DLPC(1:1, 2:1) were deposited by using the Langmuir-Blodgett method on the ITO glass. We determined electrochemical measurement by using cyclic voltammetry with a three-electrode system, An Ag/AgCl reference elect rode, a platinum wire counter electrode and LB film-coated ITO working electrode measured in 0.1, 0.5, and 1.0 mol/L $NaClO_{4}$ solution. A measuring range was reduced from initial potential to -1350 mV, continuously oxidized to 1650 mV and measured to the initial point. The scan rate were 50, 100, 150 and 200 mV/s. As a result, LB films of 8A5H 8A5H-DLPC appeared irreversible process caused by only the oxidation current from the cyclic voltammogram.

고강도 저합금강의 저주기 피로특성 (Low Cycle Fatigue Characteristics of High Strength Low Alloy Steel)

  • 김재훈;김덕회;이종현;조성석;전병환
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2001년도 춘계학술대회논문집A
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    • pp.169-174
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    • 2001
  • Low cycle fatigue tests are performed on high strength low alloy steels that be developed for submarine material. The relation between absorbed plastic strain energy and numbers of cycle to failure is examined in order to predict the low cycle fatigue life of structural steels by using plastic strain energy method. The cyclic properties are determined by a least square fit techniques. The life predicted by the plastic strain energy method is found to coincide with experiment data and results obtained from the Coffin-Manson method. Also the cyclic behavior of structural steels is characterized by cyclic softening with increasing number of cycle at room temperature. Especially, low cycle fatigue characteristics and microstructural changes of structural steels are investigated according to changing tempering temperatures. In the case of PFS steels, the $\varepsilon$-Cu is formed in 550C of tempering temperature and enhances the low cycle fatigue properties.

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Cyclic Co-oligomeric Ferroelectric Liquid Crystals with Fast Switching Properties, Wide SmC* Temperature Range and de Vries-type SmA*-SmC* Transition

  • Park, Seung-Beom;Cho, Tai-Yon;Yoon, Kyung-Hwan;Chang, Ji-Young;Zentel, Rudolf;Yoon, Do-Y.
    • Bulletin of the Korean Chemical Society
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    • 제32권spc8호
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    • pp.3057-3062
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    • 2011
  • We have synthesized and characterized the first cyclic co-oligomeric ferroelectric liquid crystals (FLCs) based on cyclic siloxanes and found that the co-oligomer containing two different mesogenic units exhibits $SmC^*$ mesophase over a wide temperature range from $65^{\circ}C$ to $135^{\circ}C$, much wider than those of the monomer counterparts and the cyclic homo-oligomers. The cyclic co-oligomeric liquid crystal readily filled the display cell and exhibited fast switching times in the range of 4 ms to 6 ms over the entire $SmC^*$ phase. Moreover, the practical absence of layer shrinkage, attributed to de Vries-type transition, shows an additional significant advanage for cyclic co-oligomeric FLCs in LCD applications.

A NEW CLASS OF CYCLIC CODES USING ORDERED POWER PRODUCT OF POLYNOMIALS

  • Gaur, Ankita;Sharma, Bhudev
    • Journal of applied mathematics & informatics
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    • 제32권3_4호
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    • pp.529-537
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    • 2014
  • The paper introduces a new product of polynomials defined over a field. It is a generalization of the ordinary product with inner polynomial getting non-overlapping segments obtained by multiplying with coefficients and variable with expanding powers. It has been called 'Ordered Power Product' (OPP). Considering two rings of polynomials $R_m[x]=F[x]modulox^m-1$ and $R_n[x]=F[x]modulox^n-1$, over a field F, the paper then considers the newly introduced product of the two polynomial rings. Properties and algebraic structure of the product of two rings of polynomials are studied and it is shown to be a ring. Using the new type of product of polynomials, we define a new product of two cyclic codes and devise a method of getting a cyclic code from the 'ordered power product' of two cyclic codes. Conditions for the OPP of the generators polynomials of component codes, giving a cyclic code are examined. It is shown that OPP cyclic code so obtained is more efficient than the one that can be obtained by Kronecker type of product of the same component codes.

냉간가공을 통한 중성자조사된 오스테나이트 스테인리스강의 기계적물성 모사 타당성 분석 (Feasibility Analysis of Simulation on the Mechanical Properties of Neutron Irradiated Austenitic Stainless Steels by Cold-working)

  • 김진원;김윤재
    • 한국압력기기공학회 논문집
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    • 제15권2호
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    • pp.9-18
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    • 2019
  • The objective of this study is to investigate the feasibility of simulating the mechanical properties of irradiatied austenitic stainless steels by cold-working. In this study, the tensile properties, cyclic hardening behaviors and fracture toughness of cold-worked TP316L stainless steel were compared with those of austenitic stainless steels irradiated by neutrons. It showed that cold-working can properly simulate the increase in strength and the decrease in ductility and fracture resistance of austenitic stainless steels by neutron irradiation, even though it could not perfectly simulate the microstructures of irradiated austenitic stainless steels. Also, cold-working can appropriately simulate the hardening behaviors of neutron irradiated austenitic stainless steels under monotonic and cyclic loading conditions.

Preparation and Electrochemical Properties of Carbon Cryogel for Supercapacitor

  • Song, Min-Seob;Nahm, Sahn;Oh, Young-Jei
    • 한국세라믹학회지
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    • 제45권11호
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    • pp.662-666
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    • 2008
  • Electrochemical properties of carbon cryogel electrode for the application of composite electrode materials mixed with metal oxide in supercapacitor have been studied. Carbon cryogels were synthesized by sol-gel polycondensation of resorcinol with form aldehyde, followed by a freeze drying, and then pyrolysis in an inert atmosphere. Physical properties of carbon cryogel were characterized by BET, X-ray diffraction (XRD) and scanning electron microscopy (SEM). It is found that carbon cryogel is amorphous material. The electrochemical properties of carbon cryogel were measured by cyclic voltammetry as a function of concentration of liquid electrolyte, galvanostatic charge-discharge with different scan rates and electrochemical impedance measurements. The result of cyclic voltammetry indicated that the specific capacitance value of a carbon cryogel electrode was approximately 150.2 F/g (at 5 mV/s in 6M KOH electrolyte).

$WO_{3}$$ MoO_{3}$ 이중층을 가진 전기변색 소자에 관한 연구 (Study of electrochromic cells in $WO_{3}$/$MoO_{3}$ double-layer structure)

  • 임석범;임동규;백희원;김영호;조봉희;유인종;변문기
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2000년도 하계학술대회 논문집
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    • pp.515-518
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    • 2000
  • The electrochromic properties of $WO_{3}$/$MoO_{3}$ and $MoO_{3}$/$WO_{3}$ double-layers have been systemically studied. The double-layers were made by a e-beam evaporation method and investigated by studying optical modulation, transmittance, and cyclic voltammetry. The devices exhibit good optical properties with wavelength range of 400 to 1100 nm(visible and infrared) during coloration as a function of lithium ion charge injection. It has shown that the double-layer electrochromic thin films are improved the electrochromic properties, but the electrochemical properties are less stable.

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Langmuir-Blodgett법으로 제조한 기능성 폴리이미드 초박막의 전기화학적 특성 (Electrochemical Properties of Ultrathin Film Prepared Functional Polyimide by Langmuir-Blodgett Method)

  • 박근호;민창훈;손태철
    • 한국응용과학기술학회지
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    • 제26권4호
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    • pp.400-406
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    • 2009
  • We investigated the electrochemical properties for Langmuir-Blodgett (LB) films of functionalized polyimide. LB films of polyimide monolayer were deposited by the Langmuir-Blodgett method on the indium tin oxide(ITO) glass. The electrochemical properties measured by cyclic voltammetry with a three-electrode system(an Ag/AgCl reference electrode, a platinum wire counter electrode and LB film-coated ITO working electrode) at various concentrations(0.5, 1.0, and 1.5 N) of $NaClO_4$ solution. The current of reduction and oxidation range was measured from 1650 mV to -1350 mV, continuously. The scan rates were 50, 100 and 150 mV/s, respectively. As a result, monolayer and multilayer LB films of polyimide are appeared on irreversible process caused by the oxidation current from the cyclic voltammogram.

브롬화 알킬혼합물 단분자 LB막의 전기화학적 특징 (Electrochemical Properties of Langmuir-Blodgett(LB) Monolayer Films of Alkyl Bromides Mixture)

  • 손태철;김덕술;박근호
    • 한국응용과학기술학회지
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    • 제27권2호
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    • pp.202-207
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    • 2010
  • We investigated the electrochemical properties for Langmuir-Blodgett(LB) films mixed with l-bromotetradecane(Cl4), l-bromohexadecane(Cl6), and l-bromooctadecane(Cl8). The alkyl bromides mixture was deposited by using the Langmuir-Blodgett method on the ITO glass. The electrochemical properties measured by using cyclic voltammetry with a three-electrode system(an Ag/AgCl reference electrode, a platinum wire counter electrode and LB film-coated ITO working electrode) at various concentrations(0.5, 1.0, 1.5 and 2.0 N) of $NaClO_4$ solution. A measuring range was reduced from initial potential to -1350 m V, continuously oxidized to 1650 mV. The scan rate was 100 mV/s. As a result, LB films of Cl4, Cl6, and Cl8 mixture monolayers appeared irreversible process caused by only the oxidation current from the cyclic voltammogram. The diffusivity(D) effect of LB films decreased with increasing of alkyl bromides amount.

다양한 기공 크기 및 분포를 갖는 양극 탄소의 전극 특성 (Electrode properties of various carbon anodes containing different sizes and distributions of pores)

  • 안홍주;오한준;김인기;김세경;임창성;지충수;이재봉;박광규;고영신
    • 한국결정성장학회지
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    • 제12권1호
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    • pp.42-49
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    • 2002
  • 기공 크기와 분포가 다른 세 종류의 전해용 탄소전극 즉, YBD-like grade carbon, YBD grade carbon, P2X grade carbon 전극의 전극 특성과 불소 전해특성을 비교하였다. 탄소전극의 특성 조사는 물리적 특성 및 1 mM의 $[[Fe(CN)_6]^\;{3-}/Fe(CN)_6$]$^{4-}$가 첨가된 0.5M $K_2SO_4$ 용액에서의 변전위 전류전압곡선과 한계확산전류밀도를 통하여 전기화학적 거동을 평가하고. 불소 전해특성은 $85^{\circ}C$의 KF.2HF용응염의 전기분해 시 임계전류밀도로 비교하였다. 이 결과 변.전위 전류전압곡선과 한계전류밀도에서는 적절한 기공을 함유한 P2X grade carbon 전극이, 불소 전해특성에서는 200~300$\mu$m의 기공 크기를 갖는 YBD-like grade carbon 전극이 우수한 전극 특성을 보였다. 이러한 전극 특성의 차이는 탄소전극 표면에 용도에 적합한 크기의 기공이 적절하게 분포되어 있음에 기인하였다.