• Bulletin of the Korean Chemical Society
• /
• v.33 no.6
• /
• pp.1945-1948
• /
• 2012

Rhodamine B (RhB) and rhodamine 6G (Rh6G) were employed as catalysts for the synthesis of cyclic carbonate from carbon dioxide and epoxide. It turned out that the catalytic activity of Rh6G was nearly 29 times higher than that of RhB at 1 atm pressure, $90^{\circ}C$. Furthermore, the catalytic efficiency of RhB and Rh6G was greatly enhanced with triethylamine as co-catalyst. Under the optimized conditions, the best isolated yield (93%) of cyclic carbonate was achieved without organic solvent and metal component.

• Journal of the Korean Society of Safety
• /
• v.8 no.4
• /
• pp.16-20
• /
• 1993

The combined effect of increased pressure/temperature and the reduced material thicknesses act to increase the stress on the radiator componets. The design life of the radiator is influenced by the cyclic stresses and corrosion, which act to weaken the materials, radiator mechanical failure occurs when a tube or solder Joint ruptures, causing coolant loss or insufficient heat rejection. Therefore, in this study, through strain measurement of the tubes in copper/brass radiator, the strain distribution of the tubes in radiator as function of temperature and pressure is obtained.

• Proceedings of the KSME Conference
• /
• 2007.05a
• /
• pp.17-22
• /
• 2007

Low-cycle environmental fatigue tests of cast austenitic stainless steel CF8M at the condition of fatigue strain rate 0.04%/sec were conducted at the pressure and temperature, 15MPa, $315^{\circ}C$ of a operating pressurized water reactor. The used test rig was limited to install an extensometer at the gauge length of the cylindrical fatigue specimen inside the small autoclave. So the magnet type LVDT's were used to measure the fatigue displacement at the specimen shoulders inside the high temperature and high pressure water autoclave. However, the displacement and strain measured at the specimen shoulders is different from the one at the gauge length for the geometry and the cyclic strain hardening effect. FEM calculated the displacement and the strain of the gauge length from the data measured at the shoulders. Tensile test properties in elastic and plastic behavior of CF8M material were used in the FEM analysis. A series of low cycle fatigue tests simulating the cyclic strain hardening effect verified that the FEM calculation was well agreed with the simulated tests. The process and method developed in this study would be so useful to produce reliable environmental fatigue curves of CF8M stainless steel in pressurized water reactors.

• Transactions of the Korean Society of Mechanical Engineers A
• /
• v.32 no.2
• /
• pp.177-185
• /
• 2008

Low-cycle environmental fatigue tests of cast austenitic stainless steel CF8M at the condition of fatigue strain rate 0.04%/sec were conducted at the pressure and temperature, 15MPa, $315^{\circ}C$ of a operating pressurized water reactor (PWR). The used test rig was limited to install an extensometer at the gauge length of the cylindrical fatigue specimen inside a small autoclave. So the magnet type LVDT#s were used to measure the fatigue displacement at the specimen shoulders inside the high temperature and high pressure water autoclave. However, the displacement and strain measured at the specimen shoulders is different from the one at the gauge length for the geometry and the cyclic strain hardening effect. Displacement of the fatigue specimen gauge length calculated by FEM (finite element method) used to modify the measured displacement and fatigue life at the shoulders. A series of low cycle fatigue life tests in air and PWR conditions simulating the cyclic strain hardening effect verified that the FEM modified fatigue life was well agreed with the simulating test results. The process and method developed in this study for the environmental fatigue test inside the small sized autoclave would be so useful to produce reliable environmental fatigue curves of CF8M stainless steel in pressurized water reactors.

• Geomechanics and Engineering
• /
• v.24 no.6
• /
• pp.519-529
• /
• 2021

In coal mining activities, the abutment stress of the coal has to undergo cyclic loading and unloading, affecting the strength and seepage characteristics of coal; additionally, it can cause dynamic disasters, posing a major challenge for the safety of coal mine production. To improve the understanding of the dynamic disaster mechanism of gas outburst and rock burst coupling, triaxial devices are applied to axial pressure cyclic loading-unloading tests under different axial stress peaks and different pore pressures. The existing empirical formula is use to perform a non-linear regression fitting on the relationship between stress and permeability, and the damage rate of permeability is introduced to analyze the change in permeability. The results show that the permeability curve obtained had "memory", and the peak stress was lower than the conventional loading path. The permeability curve and the volume strain curve show a clear symmetrical relationship, being the former in the form of a negative power function. Owing to the influence of irreversible deformation, the permeability difference and the damage of permeability mainly occur in the initial stage of loading-unloading, and both decrease as the number of cycles of loading-unloading increase. At the end of the first cycle and the second cycle, the permeability decreased in the range of 5.777 - 8.421 % and 4.311-8.713 %, respectively. The permeability decreases with an increase in the axial stress peak, and the damage rate shows the opposite trend. Under the same conditions, the permeability of methane is always lower than that of helium, and it shows a V-shape change trend with increasing methane pressures, and the permeability of the specimen was 3 MPa > 1 MPa > 2 MPa.

• Journal of Energy Engineering
• /
• v.18 no.3
• /
• pp.156-162
• /
• 2009

Cylinder-pressure based combustion analysis provides a mechanism through which a combustion researcher can understand the combustion process. This paper was to identify the most significant sources of cycle-to-cycle combustion variability in a spark ignition engine at idle. To analyse the cyclic variation in the test engine, the burn parameters are determined on a cycle-to-cycle basis through analysis of the engine pressure data. The burn rate analysis program was used in the analysis of the data. Burn parameters were used to determine the variations in the input parameter-i.e., fuel, air, residual mass, and so on.

• Journal of Welding and Joining
• /
• v.16 no.2
• /
• pp.111-121
• /
• 1998

It is well recognized that a excessive temperature gradient from the junction of head to skirt in axial direction in a hot pressure vessel can cause unpredicted high thermal stress at the junction and/or in axial direction of a skirt. this thermal stress resulting from axial thermal gradient may be a major cause of unsoundness of structural integrity. In case of cyclic operation of hot pressure vessels, the thermal stress becomes one of the primary design consideration because of the possibility of fracture as a result of cyclic thermal fatigue and progressively incremental plastic deformation. To perform thermal stress analysis of the junction and cylindrical skirt of a vessel, or, at least, to inspect quantitatively the magnitude and effect of thermal stress, the temperature profile of the vessel and skirt must be known. This paper demonstrated the temperature distribution and thermal stress analysis for the junction of skirt to head using F.E. analysis. Effect of air pocket in crotch space was quantitatively investigated to minimize the temperature gradient causing the thermal stress in axial direction. Effect of the skirt height on thermal stresses was also studied. Analysis results were compared with theoretical formulas to verify th applicability to the strength calculation in design field.

• Journal of the Korean institute of surface engineering
• /
• v.28 no.1
• /
• pp.34-45
• /
• 1995

An amphiphilic nitroxide radical(2,2'6,6'-tetramethyl-4-octadecyioxy-1-piperidinyloxyl, TEMOPO) or mixture of TEMOPO and arachidic acid(Icosanoic acid, AA), was spread on water surface by the Langmuir-Blodgett(LB) method and surface pressure-area curve was measured. Such monolayer films of TEMOPO were transferred onto surfaces of photo transferable tin oxide electrodes(PTTO) by the LB method under various surface pressure with the transfer ratio of larger than 0.95 at the surface pressure higher than 15mN/m. The electrochemical effect of functional nitroxy radical monolayer onto semi-conductive electrode to electrolyte have been investigated by using LB method. Cyclic voltammetry technique was used for the electrochemical behavior measurement of TEMOPO monolayer onto the PTTO in 0.18 mo1/$dm^3$ $H_2SO_4$ solutions. The shape of voltammograms was found to change from one electrode to another. The amount of charge for the oxidation and the re-reduction of the cation to TEMOPO were evaluated from graphical integration. The amounts of charge were always smaller than those predicted from the $\pi$-$\sigma$ curves though the transfer ratio was unity. The poor reproducibility of the cyclic voltammograms was improved by the mixing with AA. Structure and arrangement of monomolecular layer on water surface and electrode were studied. Characteristics of monolayer film applied for the mediation reaction was also discussed by electrochemical method.

• Transactions of the Korean Society of Automotive Engineers
• /
• v.4 no.2
• /
• pp.221-229
• /
• 1996

The engine speed fluctuation at idle operation mainly comes from cyclic variation of combustion in SI engine. In the present study, engineering model that is representing the cyclic variation of combustion was proposed for the sub-model of the engine cycle simulation. From the observed behaviors of the mass burn rates, probability density functions for the parameters of Wiebe function were defined. The mass burn rate of each cycle is obtained by Monte Cralo perturbation method with the probability function. The simulation results shows that trends of cylinder pressure variation and imep distribution follow up with those of experimental results at idle condition.

• Journal of the Korean Society for Railway
• /
• v.9 no.3 s.34
• /
• pp.305-312
• /
• 2006

Gravel ballasted tracks are used as a basic structure for the domestic railway tracks. However, such kind of tracks has few disadvantages with service life of the structure, such as rapid deterioration of the tracks. Due to this reason, there is a need to develop low maintenance track to improve the service life of the conventional line tracks. CMP paved tacks are one of the kind of concrete tracks those were manufactured by using the prepacked concrete techniques. The purpose to develop paved tracks is to reduce the maintenance cost. The most important controlling factors to design the paved tracks are surrounding environmental condition and repeated train loading. In this study, in order to investigate the deformation characteristics such as displacement, earth pressure, strain ratio, and crack along the repeated loading cycle, cyclic loading test through real scale model was carried out.