• Journal of Electrochemical Science and Technology
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• 제15권3호
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• pp.427-435
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• 2024

Here we introduce a new method for characterizing the constant phase element (CPE) in electrochemical systems using cyclic voltammetry (CV), presenting an alternative to the conventional electrochemical impedance spectroscopy (EIS) approach. While CV is recognized for its diagnostic capabilities in electrochemical analysis, it traditionally encounters difficulties in accurately measuring CPE systems due to a lack of clear linearity with scan rates, unlike capacitors. Our research demonstrates a linear relationship between current and scan rate on a log-log plot, enabling the calculation of n and Y₀ values for CPE from the slopes of these linear relationships. For validation of our method, it is applied to two kinds of capacitors and the results agree with those measured by EIS. Although EIS is known to be accurate in measuring CPE systems, our alternative approach offers a timely and reasonably precise diagnostic tool, balancing between ease of use and accuracy, especially beneficial for preliminary assessments before conducting further in-depth analysis.

• 폴리머
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• 제32권2호
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• pp.125-130
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• 2008

A commercial cyclic diphosphonate ester (TPMP) and melamine (MA) was combined and added to polyamide 6 (PA6) to prepare the fire retardant PA6. An increase of the oxygen index to 28.6 as well as an improvement of the UL-94 classification to V-0 rating was observed. Cone measurements explained the rate of heat release (RHR) decreased and TGA showed the early decomposition and high solid residue due to co-addition of TPMP and MA, suggesting the occurrence of synergistic effect of TPMP and MA on fire resistance of PA6. The morphology of the char developed during combust ion showed the appearance of thick, intumescent cells on the surface of retardant PA6, which protects the underlying material from the action of the heat flux or flame and limits the diffusion of combustible volatile products towards the flame and oxygen.

• 한국인터넷방송통신학회논문지
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• 제10권6호
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• pp.263-268
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• 2010

본 논문에서는 802.11n WLAN 시스템에서 우수한 오류성능을 유지하고 시스템 용량을 개선하기 위해 순환 지연 다이버시티와 블록 대각화 프리코딩 기법을 적용한 다중 사용자 MIMO OFDM 시스템을 제안하였다. 순환 지연 다이버시티(CDD : Cyclic Delay Diversity) 기법은 주파수 다이버시티를 이용하여 OFDM 시스템의 성능을 향상시키는 기법이다. 또한 블록 대각화 프리코딩 기법은 다중 사용자 MIMO 채널 환경에서 만들어진 여러 거지 프리코딩 기법 중 하나로 특이값 분해를 이용하여 zero-forcing을 하는 간단한 방법으로 구성되어 있다. 모의실험 결과를 통해 본 논문에서 제안하는 방법이 기존의 프리코딩을 사용하지 않는 CDD MIMO-OFDM 시스템에 비하여 높은 시스템 용량 성능을 보임을 확인할 수 있다.

• Steel and Composite Structures
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• 제18권1호
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• pp.29-50
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• 2015

With a quasi-three point bending apparatus, ratcheting deformation is studied experimentally on a pressurized austenitic stainless steel Z2CND18.12N pipe under bending load and vertical displacement control, respectively. The characteristic of ratcheting behavior of straight pipe under both control methods is achieved and compared. The cyclic bending loading and internal pressure influence ratcheting behavior of pressurized straight pipe significantly under loading control and the ratcheting characteristics are also highly associated with the cyclic displacement and internal pressure under displacement control. They all affect not only the saturation of the ratcheting strain but the ratcheting strain rate. In addition, ratcheting simulation is performed by elastic-plastic finite element analysis with ANSYS in which the bilinear model, Chaboche model, Ohno-Wang model and modified Ohno-Wang model are applied. By comparison with the experimental data, it is found that the CJK model gives reasonable simulation. Ratcheting boundaries under two control modes are almost same.

• 한국응용과학기술학회지
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• 제26권4호
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• pp.451-456
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• 2009

We carried out this experiment to observe an electrochemical properties for LB films of alkyl compounds by the cyclic voltammetry. Alkyl bromides was deposited by using the Langmuir- Blodgett method on the ITO glass. We measured to an electrochemical measurement by using cyclic voltammetry with a three-electrode system(an Ag/AgCl reference electrode, a platinum wire counter electrode and LB film-coated ITO working electrode) in 0.5, 1.0, 1.5 and 2.0 N $NaClO_4$ solution. A measuring range was reduced from initial potential to -1350 mV, continuously oxidized to 1650 mV. The scan rate were 100 mV/s. As a result, an electrochemical properties of the LB films of alkyl bromides appeared irreversible process caused by only the oxidation current from the cyclic voltammogram. The diffusivity(D) effect of LB films decreased with increasing of alkyl compounds amount.

• 한국응용과학기술학회지
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• 제19권1호
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• pp.49-55
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• 2002

We carried out this experiment to observe electrochemical properties for LB films of phospholipid(Dilauroyl-L-${\alpha}$-Phosphayidylcholine) and 4-octyl-4'-(5-carboxypentamethylene-oxy)azobenzene mixture by the cyclic voltammetry. LB films of 8A5H and 8A5H-DLPC(1:1, 2:1) were deposited by using the Langmuir-Blodgett method on the ITO glass. We determined electrochemical measurement by using cyclic voltammetry with a three-electrode system, An Ag/AgCl reference elect rode, a platinum wire counter electrode and LB film-coated ITO working electrode measured in 0.1, 0.5, and 1.0 mol/L $NaClO_{4}$ solution. A measuring range was reduced from initial potential to -1350 mV, continuously oxidized to 1650 mV and measured to the initial point. The scan rate were 50, 100, 150 and 200 mV/s. As a result, LB films of 8A5H 8A5H-DLPC appeared irreversible process caused by only the oxidation current from the cyclic voltammogram.

• 대한기계학회:학술대회논문집
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• 대한기계학회 2000년도 추계학술대회논문집A
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• pp.231-237
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• 2000

A15052/AFRP laminates were developed principally to obtain a material with good fatigue strength, in which possible cracks would grow very slowly. Weight savings of more than 30% should be attainable in practice. Also, the crack bridging fibers could still was carry a significant part of the load over the crack, thus the COD and stress intensity factor was reduced at the crack tip. A15052/ AFRP laminates consists of three thin sheets of 5052-H34 aluminum alloy and two layers of [0] unidirectional aramid fiber prepreg. The cyclic-bending moment test was investigated based on applying the five kinds of bending moments. The size of the delamination zone produced between 5052-H34 aluminum alloy sheets and fiber-adhesive layers was measured from ultrasonic C-scan pictures taken around the fatigue crack. In addition, the relationship between the cyclic-bending moment and the delamination zone size was studied and the effect of fiber bridging mechanism was also considered.

• 대한전자공학회논문지
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• 제26권12호
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• pp.1947-1955
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• 1989

With the increasing complexity of cabling at sensory level in process control and manufacturing automation, field buses were introduced to replace the traditional point to point links from each sensor or acruator to its controlling equipments by a single link on which all information is transmitted seriall and multiplexed in time. In this papr, we introduce the BITBUS network as a field bus. For the service discipline of the BITBUS network, two service strategies are proposed to obtain the performance of the network. They are the equal priority cyclic service strategy and the non-equal priority cyclic service strategy. The former assigns equal priority to each node for polling and the latter assumes non-equal priority. The BITBUS network was modeled as a cyclic queueing model and it is analyzed by two methods: the Kuehn's and the Boxma's. Computer simulation was also done for the cyclic queueing model and simulation results were compared with those. Under mathematically non-analyzable environment, only the computer simulation was done. From the simulation result, in order to meet the response time requirement of 5 msec imposed by International Electrotechnical Commission when each node has the average traffic of 5000 messages/sec in manufacturing automation the number of slave nodes should be smaller than 10 at the transmission rate of 2.5 Mbps.

• 생명과학회지
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• 제16권7호
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• pp.1225-1228
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• 2006

cAMP와 복합체를 형성한 cAMP 수용성 단백질은 DNA와 결합하여 ${\sim}90$도 정도의 예리한 DNA bending을 유도한다. 그러나 이전의 논문[5]에 의하면 돌연변이 CRP:cGMP 복합체는 돌연변이 CRP:cAMP 복합체보다 아크릴아미드 겔에서 상대적으로 빠른 이동속도를 보였다. CRP와 cyclic nucleotide 존재하에서 DNA의 구조 변화를 알아보기 위하여 6가지 준비된 DNA조각들을 사용하여 몰 고리화 인자(molar cyclization factor)[13]를 측정하였다. 이들 자료를 사용하여 nonlinear regression analysis를 통하여 cGMP 존재하에서 돌연변이 CRP는 DNA bending을 형성하지 않으나 CAMP 존재하에서 나선 꼬임과 같은 DNA 구조 변화없이 DNA bending을 형성한다.

• 콘크리트학회지
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• 제7권2호
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• pp.165-174
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• 1995

정적하중은 동적하중에 비해 재하속도가 느리므로 보다 합리적인 내진설계 규준제정을 위해서는 정적 실험과 별도로 동적실험이 필요하다. 그러나 구조물의 실물크기로 동적실험을 수행하기에는 여러 가지 기계적, 경제적인 제약이 있으므로 그 크기를 축소시킨 모형실험이 일반적으로 수행되고 있다. 이 연구에서는 11개의 철근 콘크리트 보-기둥 접합부 실험체에 대해 이미 잘 알려진 상사법칙을 적용하여 길이 축척비 1 : 2 : 4로 제작하여, 재하진동수를 0.0025Hz~2.0Hz로 각각 서로 다르게 작용시켜 철근콘크리트 부재의 동적 모형실험에 대한 신뢰성을 검토하였다. 실험결과, 상사법칙에 의해 설계된 모형실험체는 원형크기 실험체의 동적거동 예측에 유용하게 사용 될 수 있음이 확인되었다.