• Title/Summary/Keyword: Current density

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Assessment of kinetics behavior of electrocoagulation process for the removal of suspended solids and metals from synthetic water

  • Singh, Hariraj;Mishra, Brijesh Kumar
    • Environmental Engineering Research
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    • v.22 no.2
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    • pp.141-148
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    • 2017
  • Globalization, industrialization, mining, and uncontrolled population growth have fostered a shortage of potable water. Therefore, it has become imperative to understand an effective and reasonable water purification technique. A renewed interest in electrocoagulation (EC) has been spurred by the search for reliable, cost-effective, water-treatment processes. This paper has elucidated a technical approach for getting rid of heavy metals and total suspended solids (TSS) from synthetic water using an aluminum electrode. The effect of operational parameters, such as current density, inter-electrode distance, operating time, and pH, were studied and evaluated for maximum efficiency. This study corroborates the correlation between current density and removal efficiency. Neutral pH and a low electrode gap have been found to aid the efficacy of the EC setup. The outcome indicates that a maximum TSS removal efficiency of 76.6% occurred at a current density of $5.3mA/cm^2$ during a contact time of 30 min. In the case of heavy metals remediation, 40 min of process time exhibited extremely reduced rates of 99%, 59.2%, and 82.1%, for Cu, Cr, and Zn, respectively. Moreover, kinetic study has also demonstrated that pollutants removal follows first-and second-order model with current density and EC time being dependent.

Effects of Current Density and Phosphoric Acid Concentration on Anodic Oxide Film of Titanium (전류밀도와 전해액의 인산농도가 Ti 양극 산화 피막에 미치는 영향)

  • Kim, Kye-Sung;Chung, Won-Sub;Shin, Heon-Cheol;Choe, Young-Son;Cho, Young-Rae
    • Korean Journal of Metals and Materials
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    • v.46 no.6
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    • pp.370-376
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    • 2008
  • The formation of anodic oxide film of titanium (Ti) was studied at a variety of electrolyte concentrations and current density to clarify their effects on morphology, microstructure and composition of Ti oxide layer. For the analysis of the Ti oxide films, a scanning electron microscopy (SEM), X-ray diffractometer (XRD), and X-ray photoelectron spectroscopy (XPS) were used. The results showed that the concentration of phosphoric acid played a crucial role in the crystalline structure of the Ti oxide layer while the current density gave a critical effect on the thickness and diameter of its pore. In particular, the crystalline anatase phase with a thickness larger than $2{\mu}m$, which is quite desirable for a dental implant application, could be readily prepared at the phosphoric acid concentration of 0.5 M and current density higher than $2.0A/dm^2$.

Improvement of Current Path by Using Ferroelectric Material in 3D NAND Flash Memory (3D NAND Flash Memory에 Ferroelectric Material을 사용한 Current Path 개선)

  • Jihwan Lee;Jaewoo Lee;Myounggon Kang
    • Journal of IKEEE
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    • v.27 no.4
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    • pp.399-404
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    • 2023
  • In this paper, we analyzed the current path in the O/N/O (Oxide/Nitride/Oxide) structure of 3D NAND Flash memory and in the O/N/F (Oxide/Nitride/Ferroelectric) structure where the blocking oxide is replaced by a ferroelectric. In the O/N/O structure, when Vread is applied, a current path is formed on the backside of the channel due to the E-fields of neighboring cells. In contrast, the O/N/F structure exhibits a current path formed on the front side due to the polarization of the ferroelectric material, causing electrons to move toward the channel front. Additionally, we performed an examination of device characteristics considering channel thickness and channel length. The analysis results showed that the front electron current density in the O/N/F structure increased by 2.8 times compared to the O/N/O structure, and the front electron current density ratio of the O/N/F structure was 17.7% higher. Therefore, the front current path is formed more effectively in the O/N/F structure than in the O/N/O structure.

Effect of Current Density and pH of Electrolyte on Anion-Exchange Membrane Fouling (전류밀도와 전해질의 pH가 음이온교환막의 막 오염에 미치는 영향)

  • Choi, Jae-Hwan
    • Journal of Korean Society of Environmental Engineers
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    • v.27 no.9
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    • pp.965-969
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    • 2005
  • Current density is an important operating parameter in the ion-exchange membrane process. We observed the effects of fouling of a Neosepta AMX anion-exchange membrane(Tokuyama Soda, Japan) in 0.02 M NaCl solution containing 100 mg/L sodium humate. Membrane fouling was analyzed by measuring the change in the electrical resistance in the under- and over-limiting current density regions. The experimental results found that membrane fouling was negligible at under-limiting current densities, but was increased significantly when an over-limiting current was supplied. After the fouling experiments, the current-voltage curves for the fouled membranes were measured. From the curves, we observed increased electric resistance and reduced limiting current density(LCD), caused by the accumulation of humic acid on the membrane surface. Furthermore, membrane fouling increased as the acidity of the electrolyte solution containing humic acid increased. This occurred because the fouling of an anion-exchange membrane is affected more by the physicochemical properties of the humic substance than by the surface charge of the humate.

Affecting of Corrosion Potential and Current Density on Variation Polarization Curves with Polyvinylchloride (I)

  • Choi, Chil-Nam;Yang, Hyo-Kyung;Jung, Oh-Jin
    • Environmental Sciences Bulletin of The Korean Environmental Sciences Society
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    • v.2 no.2
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    • pp.91-98
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    • 1998
  • In this study, we carried out the experiments for measuring the variations of corrosion potential and current density for polarization curves with polyvinylchloride. The results exhibited especially the influence affecting the corrosion potential and various conditions (temperature, day, pH, bacteria, and added salt). The second anodic current density peak and the minimum passive current density are designated $I_P/I_0,$ respectively. The value of $I_P/I_O$ is used as a measurement for the extent of degradation of the polyvinylchloride. The potentiodpnamics parameters of the corrosion were obtained using Tafel equation.

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Effects of Electroplating Current Density and Duty Cycle on Nanocrystal Size and Film Hardness

  • Sun, Yong-Bin
    • Journal of the Semiconductor & Display Technology
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    • v.14 no.1
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    • pp.67-71
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    • 2015
  • Pulse electroplating was studied to form nanocrystal structure effectively by changing plating current density and duty cycle. When both of plating current density and duty cycle were decreased from $100mA/cm^2$ and 70% to $50mA/cm^2$ and 30%, the P content in the Ni matrix was increased almost up to the composition of $Ni_3P$ compound and the grain growth after annealing was retarded as well. The as-plated hardness values ranging from 660 to 753 HV are mainly based on the formation of nanocrystal structure. On the other hand, the post-anneal hardness values ranging from 898 to 1045 HV, which are comparable to the hardness of hard Cr, are coming from how competition worked between the precipitation of $Ni_3P$ and the grain coarsening. According to the ANOVA and regression analysis, the plating current density showed more strong effect on nanocrystal size and film hardness than the duty cycle.

Performance Analysis of SOFC/MGT Hybrid System

  • Kim, Jae-Hwan;Suzuki, Kenjiro
    • Proceedings of the KSME Conference
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    • 2001.06d
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    • pp.703-707
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    • 2001
  • A performance analysis of a SOFC/MGT hybrid system has been carried out for concept design. Thermo-dynamic models for each component being able to describe electrochemical characteristics and heat and mate-rial balance are proposed. Estimated is the power capacity of a SOFC suitable for the hybrid operation with a 5kW class MGT. Effects of current density and operating pressure are also investigated. Electric efficiency showed weak dependence on operating pressure and current density. It is desirable that the SOFC operates at high current density in manufacturing cost's point of view though operating with high current density slightly decreases the electric efficiency find specific power.

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Mechanical Characteristics of Bi-2223 Wire for High-Tc Superconducting Cable (고온 초전도 케이블용 Bi-2223 선재의 기계적 특성)

  • 백승명;김영석;정순용;김상현
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.11 no.11
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    • pp.1028-1034
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    • 1998
  • Bi-2223 superconductor is known as one of the candidates for practical superconducting wires. Ag-sheathed Bi-2223 superconducting wires were fabricated using the powder-in-tube(PIT) method. When the 19-filaments wire was immersed in liquid nitrogen(77K), maximum critical current density Jc of 62 A/$mm_2$ at 0T was achieved. The critical current density has been shown to depend on the mechanical properties such as tensile stress and bending strain in Ag-sheathed Bi-2223 superconducting wires. The tensile strain for Jc degradation onset was in the range of 0.12~0.3%. In the case of 19-filaments wire, the bending strain is estimated to be smaller than 0.3% for the reasonable Jc value. The observed degradation of the critical current density due to strain effect is inevitable and can be attributed to the formation of microcracks within the superconducting core.

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Structural and Optical Properties of Porous Silicon Prepared by Electrochemical Etching

  • Lee, Jeong-Seok;Cho, Nam-Hee
    • Journal of the Korean Ceramic Society
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    • v.39 no.2
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    • pp.109-112
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    • 2002
  • The structural and optical features of Porous Silicon(PS) were investigated; the porous silicon was prepared by electrochemical etching of silicon wafers in HF solution. The morphologies and Photoluminescece(PL) features of the PS were investigated in terms of etching time, current density and aging conditions. The average pore diameter and pore depth were determined by current density and etching time, respectively. As-prepared PS exhibited the maximum PL peak at the wavelength of ∼ 450 nm. The degree of deviation from as-prepared PS during aging treatment seemed to depend on the microstructure as well as morphology of the PS. It is found that etching current density played an important role on the microstructural features of the PS.

Corrosion Characteristics with Polarization Curve of Polymers

  • Park, Chil-Nam;Jung, Oh-Jin
    • Environmental Sciences Bulletin of The Korean Environmental Sciences Society
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    • v.10 no.S_4
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    • pp.181-187
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    • 2001
  • This study was carried out to measure the variations of potential and current density with polymers. The results were particularly examined to identify the influences on potential and rate of various factors including temperature and pH. The Tafel slope for anodic dissolution was determined by the polarization effect depending on these conditions. The optimum conditions were established for each case. The second anodic current density peak and maximum current density were designated as the relative polarization sensitivity$(I_r/I_f)$. The mass transfer coefficient value$(\alpha)$ was determined with the Tafel slope for anodic dissolution based on the polarization effect with optimum conditions.

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