• 제목/요약/키워드: Current decomposition

검색결과 281건 처리시간 0.04초

Decomposition Properties of Trifluoroiodomethane under Discharges and Interruptions

  • Cai, Fan-Yi;Tan, Dong-Xian;Zhou, Bai-Jie;Xue, Jian;Xiao, Deng-Ming
    • Journal of Electrical Engineering and Technology
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    • 제13권6호
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    • pp.2385-2391
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    • 2018
  • This paper is devoted to detecting decomposition characteristics of Iodotrifluoromethane ($CF_3I$) under alternating current (AC) discharges or load current interruptions. The decomposition products are measured utilizing chromatography-mass spectroscopy. It is found that less than 1% $CF_3I$ gas decomposed after several interruptions at load current of 200 A or hundred times of AC discharges. However, under interruptions at a current of 400 A, more than 95% $CF_3I$ gas decomposed into carbon tetrafluoride ($CF_4$) and hexafluoroethane ($C_2F_6$). The equilibrium compositions based on Gibbs free energy minimization of $CF_3I$ was calculated to explain the decomposition mechanism.

포텐셜 해석자를 이용한 2차원 유동의 격자 생성 연구 (A STUDY ON THE GRID GENERATION FOR TWO-DIMENSIONAL FLOW USING A POTENTIAL SOLVER)

  • 이재훈;정경진
    • 한국전산유체공학회지
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    • 제21권1호
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    • pp.36-42
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    • 2016
  • One of the obstacles on the grid generation for complex geometries with multi-block structured grids is the domain decomposition. In this paper, the domain decomposition for two-dimensional flow is studied using the flow characteristics. The potential flow equation with the source distribution on the panel surface is solved to extract the information of the flow. The current approach is applied to a two-dimensional cylinder and Bi-NACA0012 problems. The generated grids are applied to generic flow solvers and reasonable results are obtained. It can be concluded that the current methods is useful in the domain decomposition for the multi-block structured grid.

Electrochemical oxidation of sodium dodecylbenzenesulfonate in Pt anodes with Y2O3 particles

  • Jung-Hoon Choi;Byeonggwan Lee;Ki-Rak Lee;Hyun Woo Kang;Hyeon Jin Eom;Seong-Sik Shin;Ga-Yeong Kim;Geun-Il Park;Hwan-Seo Park
    • Nuclear Engineering and Technology
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    • 제54권12호
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    • pp.4441-4448
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    • 2022
  • The electrochemical oxidation process has been widely studied in the field of wastewater treatment for the decomposition of organic materials through oxidation using ·OH generated on the anode. Pt anode electrodes with high durability and long-term operability have a low oxygen evolution potential, making them unsuitable for electrochemical oxidation processes. Therefore, to apply Pt electrodes that are suitable for long-term operation and large-scale processes, it is necessary to develop a new method for improving the decomposition rate of organic materials. This study introduces a method to improve the decomposition rate of organic materials when using a Pt anode electrode in the electrochemical oxidation process for the treatment of organic decontamination liquid waste. Electrochemical decomposition tests were performed using sodium dodecylbenzenesulfonate (SDBS) as a representative organic material and a Pt mesh as the anode electrode. Y2O3 particles were introduced into the electrolytic cell to improve the decomposition rate. The decomposition rate significantly improved from 21% to 99%, and the current efficiency also improved. These results can be applied to the electrochemical oxidation process without additional system modification to enhance the decomposition rate and current efficiency.

Study on Factors Degrading the Accuracy of Real Beam Modal Decomposition

  • Choi, Kyuhong;Kim, Youngchan;Yun, Youngsun;Noh, Young-Chul;Jun, Changsu
    • Current Optics and Photonics
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    • 제5권2호
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    • pp.93-100
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    • 2021
  • Three factors that degrade the accuracy of modal decomposition are extensively studied using simulated and measured beams. These include a beam size mismatch, beam center mismatch, and signal-to-noise ratio of the images. The beam size and beam center are scanned using simulated noisy beams, and the result of the modal decomposition is compared with that of real beams. Based on the suggested procedure, error functions of approximately 1-4 × 10-3 can be acquired for real beams. This study provides important information regarding the impact of the three factors on the practical modal decomposition and tolerances of a mismatch, helping estimate the achievable values of the error function in a real beam modal decomposition.

Cu(II)-Chitosan Complex의 DFP 분해 반응 연구 (A Study on the Decomposition of DFP using Cu(II)-Chitosan Complex)

  • 계영식;정우영;김동욱;박양기;송시욱;정근홍
    • 한국군사과학기술학회지
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    • 제15권5호
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    • pp.699-704
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    • 2012
  • In this study, we have proposed a novel decomposition agent composed of Cu(II) and soluble chitosan for organophosphorus chemical agents. Compared to the autohydrolysis, the soluble Cu(II)-Chitosan complex hydrolyzed DFP more effectively. Results show that soluble Cu(II)-Chitosan complex enhances the hydrolysis of DFP in 4~6 folds compared to the autohydrolysis of DFP in buffer solution. This study provides the possibility of using this soluble Cu(II)-Chitosan complex as the environmental friendly decomposition agent which can substitute current DS-2 decomposition agent.

전해법에 의한 구리함유 시안의 분해특성 (Characteristics of Copper-catalyzed Cyanide Decomposition by Electrolysis)

  • 이진영;윤호성;김성돈;김철주;김준수;한춘;오종기
    • 자원리싸이클링
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    • 제13권1호
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    • pp.28-38
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    • 2004
  • 시안 함유 도금폐수의 재활용이 가능한 전기적 산화법에 의한 수용액상의 시안 성분 분해특성을 규명하기 위한 실험을 수행하였다. 전해산화에 의한 유리시안 분해실험 결과, 전류효율과 분해속도를 고려할 때 전압 5V, 구리촉매량 Cu/CN 몰비 0.05가 적정조건이었으며, 이때의 전류효율은 26%, 분해속도는 5.6 mM/min 이었으며 적정수준 이상의 전압과 구리첨가는 분해속도를 소폭 상승시키나 전류효율은 증가하지 않았다. 지지전해질의 증가는 전류밀도의 증가로 분해속도를 소폭 증가시키나 전류효율은 크게 감소하였다. 초기 유리시안 농도실험 결과, 과산화수소 산화와 유사한 결과를 나타내어 시안농도 증가시 분해속도 및 전류효율이 동시에 증가하므로 고농도 시안일수록 적절한 공정으로 판단된다. 각 변수가 총괄 반응속도에 미치는 영향을 확인하기 위하여 In($C_{CN}$ /$C_{CNo}$ )와 시간과의 관계로부터 계산한 총괄 반응속도 상수는 $1.6∼7.3${\times}$10^{-3}$ $min^{-1}$ 이었으며 시안농도에 대하여 1차 반응식을 만족하였다.

Complexity Estimation Based Work Load Balancing for a Parallel Lidar Waveform Decomposition Algorithm

  • Jung, Jin-Ha;Crawford, Melba M.;Lee, Sang-Hoon
    • 대한원격탐사학회지
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    • 제25권6호
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    • pp.547-557
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    • 2009
  • LIDAR (LIght Detection And Ranging) is an active remote sensing technology which provides 3D coordinates of the Earth's surface by performing range measurements from the sensor. Early small footprint LIDAR systems recorded multiple discrete returns from the back-scattered energy. Recent advances in LIDAR hardware now make it possible to record full digital waveforms of the returned energy. LIDAR waveform decomposition involves separating the return waveform into a mixture of components which are then used to characterize the original data. The most common statistical mixture model used for this process is the Gaussian mixture. Waveform decomposition plays an important role in LIDAR waveform processing, since the resulting components are expected to represent reflection surfaces within waveform footprints. Hence the decomposition results ultimately affect the interpretation of LIDAR waveform data. Computational requirements in the waveform decomposition process result from two factors; (1) estimation of the number of components in a mixture and the resulting parameter estimates, which are inter-related and cannot be solved separately, and (2) parameter optimization does not have a closed form solution, and thus needs to be solved iteratively. The current state-of-the-art airborne LIDAR system acquires more than 50,000 waveforms per second, so decomposing the enormous number of waveforms is challenging using traditional single processor architecture. To tackle this issue, four parallel LIDAR waveform decomposition algorithms with different work load balancing schemes - (1) no weighting, (2) a decomposition results-based linear weighting, (3) a decomposition results-based squared weighting, and (4) a decomposition time-based linear weighting - were developed and tested with varying number of processors (8-256). The results were compared in terms of efficiency. Overall, the decomposition time-based linear weighting work load balancing approach yielded the best performance among four approaches.

전착이산화납전극에 의한 시안염 분해 (The Decomposition of Cyanide by the Electrodeposited Lead Dioxide Electrode)

  • 한만석;탁용석;이충영;남종우
    • 공업화학
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    • 제8권3호
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    • pp.438-445
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    • 1997
  • 마드래스형 티타늄 기판위에 전착시킨 $\beta$형-이산화납 전극을 이용하여 도금폐수중의 시안염을 분해하기 위한 최적조건에 관하여 검토하고자 하였다. 시안분해에 알맞는 온도 및 pH를 검토한 후 500ppm NaCN을 전해질로 하여 시안분해효율이 높아질 수 있는 이산화납의 전착전류밀도와 시안의 분해전류밀도를 구하였으며, 이산화납 전극의 내구성을 조사하였다. 시안화수소의 발생은 온도 $40^{\circ}C$이상의 시안염용액에서 활발했으며 pH 13이상에서는 시안화수소가 발생하지 않았다. $5A/dm^2$의 전류밀도로 전착시킨 이산화납전극에서 최대의 시안분해효율을 나타냈다. $0.08A/dm^2$의 시안분해전류밀도에서 약 70%의 시안분해 전류효율을 보였으며 $4A/dm^2$이상에서는 약 10% 정도로 일정해지는 경향을 보였다. 이산화납 전착층은 약 $20A/dm^2$의 시안분해 전류밀도에서부터 열화가 일어났으며 약 $50A/dm^2$에서 파괴되었다.

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Comparative Study of Field-Oriented Control in Different Coordinate Systems for DTP-PMSM

  • Zhang, Ping;Zhang, Wei;Shen, Xiaofeng
    • Journal of international Conference on Electrical Machines and Systems
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    • 제2권3호
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    • pp.330-335
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    • 2013
  • This paper performs two kinds of Field-Oriented Control (FOC) for dual three phase permanent magnet synchronous motor (DTP-PMSM).The first is based on vector space decomposition to study the effect of current harmonics on electromechanical energy conversion. And the second presents the coupling relations between two sets of windings using two d-q transformation. And then this paper has deeply studied the differences between these two strategies, the different effect on the control of harmonic current and the reason for these differences. MATLAB-based Simulation studies of a 3KW DTP-PMSM are carried out to verify the analysis of differences between the two FOC strategies.

Ca(OH)2촉매를 이용한 플라즈마 반응에 의한 황산화물(유해가스)의 제거에 관한 연구 (A study of decomposition of sulfur oxides(harmful gas) using calcium dihydroxide catalyst by plasma reactions)

  • 김다영;황명환;우인성
    • 대한안전경영과학회지
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    • 제16권2호
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    • pp.237-246
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    • 2014
  • Researches on the elimination of sulfur and nitrogen oxides with catalysts and absorbents reported many problems related with elimination efficiency and complex devices. In this study, decomposition efficiency of harmful gases was investigated. It was found that the efficiency rate can be increased by moving the harmful gases together with SPCP reactor and the catalysis reactor. Calcium hydroxide($Ca(OH)_2$), CaO, and $TiO_2$ were used as catalysts. Harmful air polluting gases such as $SO_2$ were measured for the analysis of decomposition efficiency, power consumption, and voltage according to changes to the process variables including frequency, concentration, electrode material, thickness of electrode, number of electrode winding, and additives to obtain optimal process conditions and the highest decomposition efficiency. The standard sample was sulfur oxide($SO_2$). Harmful gases were eliminated by moving them through the plasma generated in the SPCP reactor and the $Ca(OH)_2$ catalysis reactor. The elimination rate and products were analyzed with the gas analyzer (Ecom-AC,Germany), FT-IR(Nicolet, Magna-IR560), and GC-(Shimazu). The results of the experiment conducted to decompose and eliminate the harmful gas $SO_2$ with the $Ca(OH)_2$ catalysis reactor and SPCP reactor show 96% decomposition efficiency at the frequency of 10 kHz. The conductivity of the standard gas increased at the frequencies higher than 20 kHz. There was a partial flow of current along the surface. As a result, the decomposition efficiency decreased. The decomposition efficiency of harmful gas $SO_2$ by the $Ca(OH)_2$ catalysis reactor and SPCP reactor was 96.0% under 300 ppm concentration, 10 kHz frequency, and decomposition power of 20 W. It was 4% higher than the application of the SPCP reactor alone. The highest decomposition efficiency, 98.0% was achieved at the concentration of 100 ppm.