• Title/Summary/Keyword: Current decomposition

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Decomposition Properties of Trifluoroiodomethane under Discharges and Interruptions

  • Cai, Fan-Yi;Tan, Dong-Xian;Zhou, Bai-Jie;Xue, Jian;Xiao, Deng-Ming
    • Journal of Electrical Engineering and Technology
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    • v.13 no.6
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    • pp.2385-2391
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    • 2018
  • This paper is devoted to detecting decomposition characteristics of Iodotrifluoromethane ($CF_3I$) under alternating current (AC) discharges or load current interruptions. The decomposition products are measured utilizing chromatography-mass spectroscopy. It is found that less than 1% $CF_3I$ gas decomposed after several interruptions at load current of 200 A or hundred times of AC discharges. However, under interruptions at a current of 400 A, more than 95% $CF_3I$ gas decomposed into carbon tetrafluoride ($CF_4$) and hexafluoroethane ($C_2F_6$). The equilibrium compositions based on Gibbs free energy minimization of $CF_3I$ was calculated to explain the decomposition mechanism.

A STUDY ON THE GRID GENERATION FOR TWO-DIMENSIONAL FLOW USING A POTENTIAL SOLVER (포텐셜 해석자를 이용한 2차원 유동의 격자 생성 연구)

  • Lee, J.;Jung, K.
    • Journal of computational fluids engineering
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    • v.21 no.1
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    • pp.36-42
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    • 2016
  • One of the obstacles on the grid generation for complex geometries with multi-block structured grids is the domain decomposition. In this paper, the domain decomposition for two-dimensional flow is studied using the flow characteristics. The potential flow equation with the source distribution on the panel surface is solved to extract the information of the flow. The current approach is applied to a two-dimensional cylinder and Bi-NACA0012 problems. The generated grids are applied to generic flow solvers and reasonable results are obtained. It can be concluded that the current methods is useful in the domain decomposition for the multi-block structured grid.

Electrochemical oxidation of sodium dodecylbenzenesulfonate in Pt anodes with Y2O3 particles

  • Jung-Hoon Choi;Byeonggwan Lee;Ki-Rak Lee;Hyun Woo Kang;Hyeon Jin Eom;Seong-Sik Shin;Ga-Yeong Kim;Geun-Il Park;Hwan-Seo Park
    • Nuclear Engineering and Technology
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    • v.54 no.12
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    • pp.4441-4448
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    • 2022
  • The electrochemical oxidation process has been widely studied in the field of wastewater treatment for the decomposition of organic materials through oxidation using ·OH generated on the anode. Pt anode electrodes with high durability and long-term operability have a low oxygen evolution potential, making them unsuitable for electrochemical oxidation processes. Therefore, to apply Pt electrodes that are suitable for long-term operation and large-scale processes, it is necessary to develop a new method for improving the decomposition rate of organic materials. This study introduces a method to improve the decomposition rate of organic materials when using a Pt anode electrode in the electrochemical oxidation process for the treatment of organic decontamination liquid waste. Electrochemical decomposition tests were performed using sodium dodecylbenzenesulfonate (SDBS) as a representative organic material and a Pt mesh as the anode electrode. Y2O3 particles were introduced into the electrolytic cell to improve the decomposition rate. The decomposition rate significantly improved from 21% to 99%, and the current efficiency also improved. These results can be applied to the electrochemical oxidation process without additional system modification to enhance the decomposition rate and current efficiency.

Study on Factors Degrading the Accuracy of Real Beam Modal Decomposition

  • Choi, Kyuhong;Kim, Youngchan;Yun, Youngsun;Noh, Young-Chul;Jun, Changsu
    • Current Optics and Photonics
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    • v.5 no.2
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    • pp.93-100
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    • 2021
  • Three factors that degrade the accuracy of modal decomposition are extensively studied using simulated and measured beams. These include a beam size mismatch, beam center mismatch, and signal-to-noise ratio of the images. The beam size and beam center are scanned using simulated noisy beams, and the result of the modal decomposition is compared with that of real beams. Based on the suggested procedure, error functions of approximately 1-4 × 10-3 can be acquired for real beams. This study provides important information regarding the impact of the three factors on the practical modal decomposition and tolerances of a mismatch, helping estimate the achievable values of the error function in a real beam modal decomposition.

A Study on the Decomposition of DFP using Cu(II)-Chitosan Complex (Cu(II)-Chitosan Complex의 DFP 분해 반응 연구)

  • Kye, Young-Sik;Chung, Woo Yong;Kim, Dongwook;Park, Yangki;Song, Siuk;Jeong, Keunhong
    • Journal of the Korea Institute of Military Science and Technology
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    • v.15 no.5
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    • pp.699-704
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    • 2012
  • In this study, we have proposed a novel decomposition agent composed of Cu(II) and soluble chitosan for organophosphorus chemical agents. Compared to the autohydrolysis, the soluble Cu(II)-Chitosan complex hydrolyzed DFP more effectively. Results show that soluble Cu(II)-Chitosan complex enhances the hydrolysis of DFP in 4~6 folds compared to the autohydrolysis of DFP in buffer solution. This study provides the possibility of using this soluble Cu(II)-Chitosan complex as the environmental friendly decomposition agent which can substitute current DS-2 decomposition agent.

Characteristics of Copper-catalyzed Cyanide Decomposition by Electrolysis (전해법에 의한 구리함유 시안의 분해특성)

  • Lee Jin-Yeung;Yoon Ho-Sung;Kim Sung-Don;Kim Chul-Joo;Kim Joon-Soo;Han Choon;Oh Jong-Kee
    • Resources Recycling
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    • v.13 no.1
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    • pp.28-38
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    • 2004
  • The characteristics of cyanide decomposition in aqueous phase by electric oxidization have been explored in an effort to develop a process to recycle waste water. Considering current efficiency and voltage, the free cyanide decomposition experiment by electric oxidization indicated that 5 V of voltage and copper catalytic Cu/CN mole ratio 0.05 was the most appropriate condition, where current efficiency was 26%, and decomposition speed was 5.6 mM/min. High voltage and excess copper addition increased decomposition speed a little bit but not current efficiency. The experiment of free cyanide density change proves that high density cyanide is preferred because speed and current efficiency increase with density. Also, the overall decomposition reaction could be represented by the first order with respcect to cyanide with the rate constant of $1.6∼7.3${\times}$10^{-3}$ $min^{-1}$ The mass transfer coefficient of electric oxidization of cyanide came out as $2.42${\times}$10^{-5}$ $min^{-1}$ Furthermore, the Damkohler number was calculated as 5.7 in case of 7 V and it was found that the mass transfer stage was the rate determining step.

Complexity Estimation Based Work Load Balancing for a Parallel Lidar Waveform Decomposition Algorithm

  • Jung, Jin-Ha;Crawford, Melba M.;Lee, Sang-Hoon
    • Korean Journal of Remote Sensing
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    • v.25 no.6
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    • pp.547-557
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    • 2009
  • LIDAR (LIght Detection And Ranging) is an active remote sensing technology which provides 3D coordinates of the Earth's surface by performing range measurements from the sensor. Early small footprint LIDAR systems recorded multiple discrete returns from the back-scattered energy. Recent advances in LIDAR hardware now make it possible to record full digital waveforms of the returned energy. LIDAR waveform decomposition involves separating the return waveform into a mixture of components which are then used to characterize the original data. The most common statistical mixture model used for this process is the Gaussian mixture. Waveform decomposition plays an important role in LIDAR waveform processing, since the resulting components are expected to represent reflection surfaces within waveform footprints. Hence the decomposition results ultimately affect the interpretation of LIDAR waveform data. Computational requirements in the waveform decomposition process result from two factors; (1) estimation of the number of components in a mixture and the resulting parameter estimates, which are inter-related and cannot be solved separately, and (2) parameter optimization does not have a closed form solution, and thus needs to be solved iteratively. The current state-of-the-art airborne LIDAR system acquires more than 50,000 waveforms per second, so decomposing the enormous number of waveforms is challenging using traditional single processor architecture. To tackle this issue, four parallel LIDAR waveform decomposition algorithms with different work load balancing schemes - (1) no weighting, (2) a decomposition results-based linear weighting, (3) a decomposition results-based squared weighting, and (4) a decomposition time-based linear weighting - were developed and tested with varying number of processors (8-256). The results were compared in terms of efficiency. Overall, the decomposition time-based linear weighting work load balancing approach yielded the best performance among four approaches.

The Decomposition of Cyanide by the Electrodeposited Lead Dioxide Electrode (전착이산화납전극에 의한 시안염 분해)

  • Han, Man Seok;Tak, Yongsug;Lee, Choong Young;Nam, Chong Woo
    • Applied Chemistry for Engineering
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    • v.8 no.3
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    • pp.438-445
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    • 1997
  • ${\beta}-PbO_2$ electrode, which was electrodeposited on Ti madras, was prepared and for the decomposition of cyanide in electroplating wastewater. After the investigation of temperature and pH conditions for no hydrogen cyanide evolution during the decomposition of cyanide, the optimum current densities of ${\beta}-PbO_2$ electrodeposition and cyanide decomposition were determined in 500ppm NaCN solution, and durability of ${\beta}-PbO_2$ electrode was also investigated. Hydrogen cyanide was actively generated above $40^{\circ}C$ and was not evolved above pH 13. ${\beta}-PbO_2$ electrode electodeposited at $5A/dm^2$ showed the best cyanide decomposition efficiency The decompostion efficiency was about 70% at low decomposition current density ($0.08A/dm^2$), and it decreased gradually to about 10% as the decomposition current density increased up to $4A/dm^2$. The film of ${\beta}-PbO_2$ electrodeposited was corrosive at $20A/dm^2$ and was broken at $50A/dm^2$.

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Comparative Study of Field-Oriented Control in Different Coordinate Systems for DTP-PMSM

  • Zhang, Ping;Zhang, Wei;Shen, Xiaofeng
    • Journal of international Conference on Electrical Machines and Systems
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    • v.2 no.3
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    • pp.330-335
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    • 2013
  • This paper performs two kinds of Field-Oriented Control (FOC) for dual three phase permanent magnet synchronous motor (DTP-PMSM).The first is based on vector space decomposition to study the effect of current harmonics on electromechanical energy conversion. And the second presents the coupling relations between two sets of windings using two d-q transformation. And then this paper has deeply studied the differences between these two strategies, the different effect on the control of harmonic current and the reason for these differences. MATLAB-based Simulation studies of a 3KW DTP-PMSM are carried out to verify the analysis of differences between the two FOC strategies.

A study of decomposition of sulfur oxides(harmful gas) using calcium dihydroxide catalyst by plasma reactions (Ca(OH)2촉매를 이용한 플라즈마 반응에 의한 황산화물(유해가스)의 제거에 관한 연구)

  • Kim, Dayoung;Hwang, Myungwhan;Woo, Insung
    • Journal of the Korea Safety Management & Science
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    • v.16 no.2
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    • pp.237-246
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    • 2014
  • Researches on the elimination of sulfur and nitrogen oxides with catalysts and absorbents reported many problems related with elimination efficiency and complex devices. In this study, decomposition efficiency of harmful gases was investigated. It was found that the efficiency rate can be increased by moving the harmful gases together with SPCP reactor and the catalysis reactor. Calcium hydroxide($Ca(OH)_2$), CaO, and $TiO_2$ were used as catalysts. Harmful air polluting gases such as $SO_2$ were measured for the analysis of decomposition efficiency, power consumption, and voltage according to changes to the process variables including frequency, concentration, electrode material, thickness of electrode, number of electrode winding, and additives to obtain optimal process conditions and the highest decomposition efficiency. The standard sample was sulfur oxide($SO_2$). Harmful gases were eliminated by moving them through the plasma generated in the SPCP reactor and the $Ca(OH)_2$ catalysis reactor. The elimination rate and products were analyzed with the gas analyzer (Ecom-AC,Germany), FT-IR(Nicolet, Magna-IR560), and GC-(Shimazu). The results of the experiment conducted to decompose and eliminate the harmful gas $SO_2$ with the $Ca(OH)_2$ catalysis reactor and SPCP reactor show 96% decomposition efficiency at the frequency of 10 kHz. The conductivity of the standard gas increased at the frequencies higher than 20 kHz. There was a partial flow of current along the surface. As a result, the decomposition efficiency decreased. The decomposition efficiency of harmful gas $SO_2$ by the $Ca(OH)_2$ catalysis reactor and SPCP reactor was 96.0% under 300 ppm concentration, 10 kHz frequency, and decomposition power of 20 W. It was 4% higher than the application of the SPCP reactor alone. The highest decomposition efficiency, 98.0% was achieved at the concentration of 100 ppm.