• Journal of Surface Science and Engineering
• /
• v.36 no.5
• /
• pp.379-385
• /
• 2003

The surface morphology, the glossiness and the hardness of Zn-Cr and Zn-Cr-X(X:Co, Mn) alloy electrodeposits were investigated by using chloride bath with EDTA additive and flow cell system. The surface morphology of Zn-Cr alloy and Zn-Cr-Mn alloy changed from fine needle shape crystalline structure to colony structure of fine granular crystallites with increasing current density in the range of 20-100 $A/dm^2$. The surface morphology of Zn-Cr-Co alloy deposited from low Co concentration bath(2.5-10 g/$\ell$) was similar to that of Zn-Cr alloy, while that of Zn-Cr-Co alloy deposited from high cobalt concentration bath was fine granular crystalline structure in the same range of current density. The glossiness of Zn-Cr and Zn-Cr-Mn alloy increased noticeably with increasing current density, while that of Zn-Cr-Mn alloy decreased with increasing Mn concentration of bath in high current density region. The glossiness of Zn-Cr-Co alloy deposited from low Co concentration bath increased with current density while that of the alloy from high Co concentration bath decreased with increasing current density. The hardness of Zn-Cr and Zn-Cr-X alloy increased noticeably with current density.

• Journal of Ocean Engineering and Technology
• /
• v.18 no.5
• /
• pp.22-28
• /
• 2004

This study constructed a 3D real-time numerical model that predicts the water quality and movement characteristics of the inner bay, considering the characteristics of the wind-driven current and density current in estuaries, generated by the river discharge from the Hyeong-san river and oceanic water of the Eastern sea. The numerical model successfully calculated the seawater circulation current of Yeong-il Bay, using the input conditions oj the real-time tidal current, river discharge, and weather conditions during March 2001. This study also observed the wind-driven current and density current in estuaries that are effected by the seawater circulation pattern of the inner bay. We investigated and analyzed each impact factor, and its relationship to the water quality of Yeong-il bay.

• Journal of Electrochemical Science and Technology
• /
• v.8 no.3
• /
• pp.197-205
• /
• 2017

Lead dioxide thin films were electrodeposited on nickel substrate from acidic lead nitrate solution. Current efficiency and thickness measurements, cyclic voltammetry, AFM, SEM, and X-ray diffraction experiments were conducted on $PbO_2$ surface to elucidate the effect of lead nitrate concentration, current density, temperature on the morphology, chemical behavior, and crystal structure. Experimental results showed that deposition efficiency was affected by the current density and solution concentration. The film thickness was independent of current density when deposition from high $Pb(NO_3)_2$ concentration, while it decreased for low concentration and high current density deposition. On the other hand, deposition temperature had negative effect on current efficiency more for lower current density deposition. Cyclic voltammetric study revealed that comparatively more ${\beta}-PbO_2$ produced compact deposits when deposition was carried out from high $Pb(NO_3)_2$ concentration. Such compact films gave lower charge discharge current density during cycling. SEM and AFM studies showed that deposition of regular-size sharp-edge grains occurred for all deposition conditions. The grain size for high temperature and low concentration $Pb(NO_3)_2$ deposition was bigger than from low temperature and high concentration deposition conditions. While cycling converted all grains into loosely adhered flappy deposit with numerous pores. X-ray diffraction measurement indicates that high concentration, high temperature, and high current density favored ${\beta}-PbO_2$ deposition while ${\alpha}-PbO_2$ converted to ${\beta}-PbO_2$ together with some unconverted $PbSO_4$ during cycling in $H_2SO_4$.

• Membrane and Water Treatment
• /
• v.1 no.1
• /
• pp.13-37
• /
• 2010

The performance of an electrodialyzer for concentrating seawater is predicted by means of a computer simulation, which includes the following five steps; Step 1 mass transport; Step 2 current density distribution; Step 3 cell voltage; Step 4 NaCl concentration in a concentrated solution and energy consumption; Step 5 limiting current density. The program is developed on the basis of the following assumption; (1) Solution leakage and electric current leakage in an electrodialyzer are negligible. (2) Direct current electric resistance of a membrane includes the electric resistance of a boundary layer formed on the desalting surface of the membrane due to concentration polarization. (3) Frequency distribution of solution velocity ratio in desalting cells is equated by the normal distribution. (4) Current density i at x distant from the inlets of desalting cells is approximated by the quadratic equation. (5) Voltage difference between the electrodes at the entrance of desalting cells is equal to the value at the exits. (6) Limiting current density of an electrodialyzer is defined as average current density applied to an electrodialyzer when current density reaches the limit of an ion exchange membrane at the outlet of a desalting cell in which linear velocity and electrolyte concentration are the least. (7) Concentrated solutions are extracted from concentrating cells to the outside of the process. The validity of the computer simulation model is demonstrated by comparing the computed results with the performance of electrodialyzers operating in salt-manufacturing plants. The model makes it possible to discuss optimum specifications and operating conditions of a practical-scale electrodialyzer.

• The Bulletin of The Korean Astronomical Society
• /
• v.41 no.1
• /
• pp.46.1-46.1
• /
• 2016

The formation process of a current sheet is important for solar flare from a viewpoint of a space weather prediction. We therefore derive the temporal development of the spatial and statistical distribution of electric current density distributed in a flare-producing active region to describe the formation of a current sheet. We derive time sequence distribution of electric current density by applying a nonlinear force-free approximation reconstruction to Active Region 12158 that produces an X1.6-class flare. The time sequence maps of photospheric vector magnetic field used for reconstruction are captured by a Helioseismic and Magnetic Imager (HMI) onboard Solar Dynamic Observatory (SDO) on 10th September, 2014. The spatial distribution of electric current density in NLFFF model well reproduce observed sigmoidal structure at the preflare phase, although a layer of high current density shrinks at the postflare phase. A double power-law profile of electric current density is found in statistical analysis. This may be expected to use an indicator of the occurrence of a solar flare.

• Journal of the Korean Society of Fisheries and Ocean Technology
• /
• v.58 no.2
• /
• pp.159-174
• /
• 2022

Flow prediction was carried out through observational survey and three dimensional multi-layered numerical diagnostic model experiment to clarify the time and spatial structure of tidal current and residual flow dominant in the sea exchange and material circulation of the waters around Geumo Islands in the southern waters of Korea. The horizontal variation of tidal current is so large that it causes asymmetric tidal mixing due to horizontal eddies and the topographical effect creating convergence and dispersion of flow direction and velocity. Due to strong tidal currents flowing northwest-southeast, counterclockwise and clockwise eddies are formed on the left and right sides of the south of Sori Island. These topographical eddies are created by horizontal turbulence and bottom friction causing nonlinear effects. Baroclinic density flows are less than 5 cm/s at coastal area in summer and the entire sea area in winter. The wind driven currents assuming summer and winter seasonal winds are also less than 5 cm/s and the current flow rate is high in winter. Density current in summer and wind driven current in winter have a relatively greater effect on the net residual flows (tidal residual current + density current + density driven current) around Geumo Islands Sea area.

• Membrane Journal
• /
• v.12 no.3
• /
• pp.171-181
• /
• 2002

The parameter which determines the plateau length of current-voltage curve for ion- exchange membranes was studied at various concentrations of NaCl and different flow rates. Moreover, the feasibility of the electrodialytic removal of 0.1 M NaCl solution at various current densities was tested by assessing the electrodialysis performance parameters such as salt removal efficiency, current efficiency, energy consumption and water dissociation. The diffusion boundary layer (DBL) thickness decreased with the NaCl concentration and flow rate of fled solution and it was observed that the plateau length of current-voltage curves was related with the DBL thickness. The removal efficiency and current efficiency were not affected significantly by the current densities even at the overlimiting current region indicating that most current were passed by electrolyte, and water dissociations are not responsible for the overlimiting current. Energy consumption increased when the current density supplied exceeded the limiting current density (LCD) values, because additional energy was necessary to overcome the plateau potential. Beyond the LCD values the energy consumption required to get a certain removal efficiency was not affected by the current density applied. The result suggests that it is allowed to operate electrodialysis processes at as high as possible current density unless water-splitting does not occur.

• Journal of Surface Science and Engineering
• /
• v.24 no.2
• /
• pp.88-95
• /
• 1991

The tin-lead alloy was electrodeposited in the low range of peak current density in order to investigate the change of composition and microstructure of them. The Pb content of alloy deposits, which was decreased with increasing average current density, was relatively lower than that of D.C. plated alloy deposit. The preferred orientation of alloy deposit was changed with increasing peak current density and the surface morphology of alloy deposits was closely related to the preferred orientation of them.

• The Transactions of the Korean Institute of Electrical Engineers C
• /
• v.55 no.5
• /
• pp.231-238
• /
• 2006

This paper analysed the induced current density inside human body of hot-line worker for 765kV double circuit transmission line according to locations of human body. Human model was composed of several organs and other parts, whose shapes were expressed by spheroids or cylinders. Organs such as the brain, heart, lungs, liver and intestines were taken into account. Applying the 3 dimensional boundary element method, we calculated induced current density in case a worker was located inside and outside a lowest phase of 765 kV transmission line in which a 60% current of maximum load flowed. As results of study, we found a maximum induced current density in all organs was less than $10mA/m^2$ when a wonder was outside. As one in brain and heart was higher than $10mA/m^2$ when a worker was inside, we propose a method for lowering current density.

• Journal of Surface Science and Engineering
• /
• v.36 no.3
• /
• pp.256-262
• /
• 2003

The current efficiency and the composition of Zn-Cr and Zn-Cr-X (X : Co, Mn) alloy electrodeposits were investigated by using chloride bath with EDTA auditive and flow cell plating system. The current efficiency of Zn-Cr alloy decreased with increasing current density, while it increased with the content of Co and Mn of the Zn-Cr-X alloy bath in high current density region. The Cr content in Zn-Cr alloy increased from 1.4-2.7 to $28wt\%$ with increasing current density and the phase structure of the alloys changed from $\eta-Zn$ through $\eta-Zn+\gamma'-ZnCr\;to\;\gamma'-ZnCr$ with Increasing Cr content of the alloys. The Co content in Zn-Cr-Co alloys increased with Co content of the bath, while Cr content of the alloy increased or decreased in low current density region $(10-75A/dm^2)$ or high current density region $(75-100A/dm^2)$, respectively. $\gamma-ZnCo$ phase was formed in the Zn-Cr-Co alloy with above $9.0wt\%$ Co. The content of Mn and Cr in Zn-Cr-Mn alloys increased or decreased with the increase of current density in high current density region, respectively while Cr content of the alloy decreased noticeably with the increase of Mn content in the bath. Two phases of $\delta_1-ZnMn$ and $\gamma'-ZnCr$ were formed in the Zn-Cr-Mn alloy with above $8.6wt\%$ Mn.