• 제목/요약/키워드: Current Collectors

검색결과 56건 처리시간 0.034초

연료전지 전극(Cathode)의 성능해석 및 설계에 관한 연구 (A Study on the Performance Analysis and Design of Cathode in Fuel Cells)

  • 김홍건;강성수;송하영;강영우;곽이구
    • 한국공작기계학회논문집
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    • 제16권1호
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    • pp.75-79
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    • 2007
  • The cathode design is one of the most important parts in order to enhance the performance of fuel cells. A 3-D model of the porous oxygen reducing cathode with perforated current collectors is analysed for the enhanced design in fuel cells. Simulation is performed using equations of electric potential balance, momentum balance, and mass balance. The gas concentrations are quite large and are significantly affected by the reactions that take place. The weight fraction of oxygen, velocity field for the gas phase, and local overvoltage are illustrated in the porous reactive cathode layer. The current density is also analysed and the result shows the distribution and variation are stated in a wide range. It is found that the rate of reaction and the current production is higher beneath the orifice, and decreases as the distance to the gas inlet increases. The significance of the results is discussed in the viewpoint of the mass transportation phenomena, which is inferred that the mass transport of reactants dictates the efficiency of the electrode in this design and at these conditions.

핀이 부착된 와이어형 방전극의 형상에 따른 코로나 방전특성에 대한 연구 (Experimental Study on the Corona Discharge Characteristics of the Pin-plate Electrode Geometries)

  • 정성일;이재근;정동규;안영철
    • 대한기계학회논문집B
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    • 제30권2호
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    • pp.95-100
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    • 2006
  • Electrostatic precipitators(EPs) have low pressure drop and high dust collection efficiency and are widely used for industrial dust collectors. The current-voltage characteristics, which are important to maintain high dust collection efficiency, depend on several factor: discharge electrode shape, gas flow property, dust loading etc. In this study, experiments are performed to investigate the current-voltage characteristics of the corona discharge of various electrode geometries and an empirical model is proposed to predict current-voltage characteristics of the corona discharge. The corona onset voltage correction coefficient$(\alpha)$ and the geometry correction coefficient$(k_g)$ are used to the conventional equation for wire-plate type discharge electrode. The corona onset voltages are -6.3kV and almost constant when the numbers of discharge pins are varied from 3 to 9. The length of discharge pins has very sensitive effects on the corona onset voltage. They are increased from -6.3 to -7.8kV when the discharge pin length are 8.5 and 4.5mm, respectively. The empirical model shows good agreement with experimental results and can predict the effects of discharge pin length and number.

High Performance of Nano-sized LiFePO4 Positive Electrode Using Etched Al Current Collector

  • Lee, Gil-Won;Ryu, Ji-Heon;Oh, Seung-M.
    • 전기화학회지
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    • 제13권3호
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    • pp.157-162
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    • 2010
  • The electrodes comprising nano-sized $LiFePO_4$, carbon black and binder are prepared with two different Al current collectors. One is the generally used normal Al foil and the other is the chemically etched Al foil. Surface characteristics of each Al foil and electrochemical performance of the cathodes using each foil are investigated. The electrode from the etched Al foil exhibits better physical and electrochemical properties as compared to those of the normal Al foil because the etched Al foil has rough surface with sub-micron pores which improve the adhesion between the electrode materials and the substrate. The electrode on the etched Al foil has such a strong peel strength that the impedance is smaller than that of normal one. Indeed the $LiFePO_4$ electrode from the etched Al foil exhibits a better rate capability and remains intact even after storage for 1 week at the charged state at the elevated temperature $60^{\circ}C$.

Development of a model for animal health monitoring system in Gyeongnam I. Design, data and frequencies of selected dairy cattle diseases

  • Kim, Jong-shu;Kim, Yong-hwan;Choi, Min-cheol;Kim, Gon-sup;Kim, Chung-hui;Park, Jeong-hee;Hah, Dae-sik;Heo, Jung-ho;Jeong, Myeong-ho;An, Dong-won
    • 대한수의학회지
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    • 제39권4호
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    • pp.730-737
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    • 1999
  • A national animal health monitoring system(NAHMS) in Gyeongnam area was started from 1997 to develop statistically valid data for use in estimating disease frequencies in dairy cattle, and the associated costs. The objectives of this study were to : (1) discribe what was done to implement and maintain the system in Gyeongnam ; (2) present selected disease frequencies ; (3) discuss the epidemiological consideration of what was done and implications for the results obtained. Veterinary Medical Officers(VMOs-professors and graduate students from Gyeongsang National University, Faculty of Gyeongnam Livestock Promotion Institute, and Clinic veterinarians) served as data collectors. After training on current disease and management problems of dairy cattle, interview techniques, sampling methods, and data collection instruments, the VMOs participated in selection of the sample herds and data gathering. Forty of 167 dairy herds were selected randomly and the VMOs visited farms once a month for 12 months to collect data about management, disease, inventory, production, preventive treatment, financial and any other relevant data. Strict data quality control devices were used. Specific feed-back was developed for the producers and data collectors. Of the three age groups studied, cows had the greatest number of disease problems. The six disorders found most frequently were (from the highest to the lowest) breeding problems, clinical mastitis, birth problems, gastrointestinal problems. metabolic problems, and lameness. In young stock, respiratory, multiple system, breeding problems, and gastrointestinal problems were pre dominant, whereas in calves, gastrointestinal, respiratory, and integumental problems were major.

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남한강 본류 3개 보의 저서성 대형무척추동물의 공간적 분포 (Spatial Distribution of Benthic Macroinvertebrates at Three River Weirs in The Namhan River)

  • 권용주;김진영;김필재;김정우;민정기;공동수
    • 한국물환경학회지
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    • 제36권1호
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    • pp.36-47
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    • 2020
  • Three large scale weirs were constructed 2010 - 2011 in the Namhan river, Korea. The purpose of this study was to investigate the spatial distribution of benthic macroinvertebrates and the influence of environmental factors at the weirs 2014 - 2015. The number of species was higher in the riparian zone than in the transition or the limnetic zone. This seems to be because of the diversification of microhabitats and food sources according to the development of littoral zones. From the riparian zone to the limnetic zone, the individual abundance proportion of gathering collectors among functional feeding groups decreased, and that of filtering collectors increased. In the limnetic zone, sprawlers and climbers among habitat orientation groups decreased, and burrowers increased. This means that coarse particulate organic matter originated from land or riparian zone was transformed to fine particulate organic matter in the limnetic zone. Asian clam (Corbicula fluminea) and chironomids were dominant species based on individual abundance. Asian clam, a major taxon considering biomass, was abundant toward the limnetic zone. This is becasue of the shallow depth, suitable water current, slightly coarse substrate, and good water quality. There was no significant relationship between the water quality and the characteristics of the benthic macroinvertebrate community because the water quality was spatially not heterogenous. The more influential factors for benthic community were physical factors, especially water depth. Water depth showed a markedly significant correlation with Shannon-Weaver's species diversity (r=-0.90), Margalef's species richness (r=-0.82), and McNaughton's dominance (r=0.86). Water depth showed a positive correlation (r=0.68) with the Kong and Kim BMSI (Bentic Macroinverebrates Streambed Index), and this may be related to the coarse substrate of the limnetic zone.

집전체에 따른 NI-YSZ Cermet 기반의 가역적 고체산화물 연료전지를 이용한 고온 수증기 전기분해 특성 (Current Collector Effects on High Temperature Electrolysis by NI-YSZ Cermet Supported Solid Oxide Cells)

  • 신의철;안평안;서현호;이종숙;유지행;우상국
    • 한국수소및신에너지학회논문집
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    • 제21권6호
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    • pp.533-539
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    • 2010
  • Ni-YSZ supported button cells were prepared by spray-coating YSZ and screen-printing YSZ-LSM powder as an electrolyte and oxygen electrode on Ni-YSZ cermet disks. In order to identify the polarization loss mechanism in high temperature electrolysis current-voltage characteristics coupled with electrochemical impedance spectroscopy were investigated as a function of temperature, current load, and the humidity. The effects of the different current collectors of platinum and silver for oxygen electrodes were compared. With Ag current collector two polarization losses were distinguished. The high frequency component was attributed to the Ni-YSZ cermet which was less susceptible to temperature variation but increasing in loss with humidity. The lower frequency component was attributed to the LSM electrode. Platinum current collector led to a much lower polarization loss.

실 규모 태양열 집열판 제작을 위한 구리 및 알루미늄 기판에의 태양광 선택흡수박막 전착;Pulse Current Electrolysis 적용 (Application of Pulse Current Electrolysis to the Large Scale of Copper and Aluminium Substrates for Solar Selective Coatings on Solar Collectors)

  • 이태규;김동형;김형택;여운택
    • 에너지공학
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    • 제5권2호
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    • pp.108-114
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    • 1996
  • 태양열 집열판의 효율을 증대시키기 위하여는 집열판에 조사되는 태양광의 흡수율을 높이고 복사에 의한 열손실을 감소시키는 선택적 박막을 집열판에 입히는 것이 중요한 인자이다. 본 실험에서는 이와같은 광학적 특성을 지니게 하고 동시에 전류효율이 우수한 pulsecurrent 전해법을 도입하여 실제 실용화 규모인 230 cm$\times$60 크기의 대형 기판에 선택흡수박막의 전착을 실시하였다. 도금액의 조성은 크롬산 280 g/$\ell$, propionic acid 15g/$\ell$, 그리고 제 2첨가제10g/$\ell$이었으며, 도금 대상기판으로는 구리와 알루미늄이 사용되었다. 구리 기판의 경우에는 선택흡수박막의 흡수율이 약 0.98이고 복사율은 약 0.17의 광학적 성질을 보였으며, 30$0^{\circ}C$공기 중에서 24시간동안 열처리 후에도 광학적 우수성을 지니고 있어 상품적 가치가 매우 우수하다고 판단되었다. 알루미늄 기판의 경우에는 흡수율이 약 0.97, 복사율이 0.15로서 광학적 성질은 구리 기판에 비해 다소 떨어지지만, 열전도도와 경제성을 고려하면 상품적 가치가 충분하다고 생각된다. 또한 이와 같은 대형기판을 적용하여 안정된 태양광 선택흡수박막의 성공적 제조로 공정의 단순화 및 대량생산 기술을 확보하였으며, 상용화에 돌입하게 되었다.

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CMOS 공정에 의한 2차원 SSIMT의 제작 및 특성 (Fabrication and characteristics of 2-Dimensional SSIMT using a CMOS Process)

  • 송윤귀;이지현;최영식;김남호;류지구
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2003년도 추계학술대회 논문집 Vol.16
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    • pp.443-446
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    • 2003
  • A 2-Dimensional SSIMT(Suppressed Sidewall Injection Magnetotransistor) sensor with high linearity is presented in this paper. The prototype is fabricated by using the Hynix $0.6{\mu}m$ CMOS Process. The fabricated SSIMT shows that the variation of each collectors current are extremely linear by varing the magnetic induction from -200mT to 200mT at $I_B\;:\;1000{\mu}A,\;V_{CE}\;=\;5V\;and\;V_{SUB}\;=\;5V$. The relative sensitivity is up to 13%/T. At B = 0, magnetic offset is about 40mT, there relative sensitivity is 4.72%/T. The nonlinearity of the fabricated 2-D SSIMT is measured about 1.2%.

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Flexible and Transparent Plastic Electrodes Composed of Reduced Graphene Oxide/Polyaniline Films for Supercapacitor Application

  • Sarker, Ashis K.;Hong, Jong-Dal
    • Bulletin of the Korean Chemical Society
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    • 제35권6호
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    • pp.1799-1805
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    • 2014
  • In this article, we described about the preparation and electrochemical properties of a flexible energy storage system based on a plastic polyethylene terephthalate (PET) substrate. The PET treated with UV/ozone was fabricated with multilayer films composed of 30 polyaniline (PANi)/graphene oxide (GO) bilayers using layer-by-layer assembly of positively charged PANi and negatively charged GO. The conversion of GO to the reduced graphene oxide (RGO) in the multilayer film was achieved using hydroiodic acid vapor at $100^{\circ}C$, whereby PANi structure remained nearly unchanged except a little reduction of doping state. Cyclic voltammetry and charge/discharge curves of 30 PANi/RGO bilayers on PET substrate (shorten to PANi-$RGO_{30}$/PET) exhibited an excellent volumetric capacitance, good cycling stability, and rapid charge/discharge rates despite no use of any metal current collectors. The specific capacitance from charge/discharge curve of the PANi-$RGO_{30}$/PET electrode was found to be $529F/cm^3$ at a current density of $3A/cm^3$, which is one of the best values yet achieved among carbon-based materials including conducting polymers. Furthermore, the intrinsic electrical resistance of the PANi-$RGO_{30}$/PET electrodes varied within 20% range during 200 bending cycles at a fixed bend radius of 2.2 mm, indicating the increase in their flexibility by a factor of 225 compared with the ITO/PET electrode.

용융탄산염 연료전지 Anode부 집전판의 부식특성 (Corrosion Behavior of Anode Current Collectors in Molten Carbonate Fuel Cells)

  • 한원규;주정운;신정철;강성군;전중환;임희천
    • 한국재료학회지
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    • 제18권5호
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    • pp.259-265
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    • 2008
  • The corrosion and degradation factors of a current collector in a molten carbonate fuel cell (MCFC) were investigated to determine the optimized coating thickness of nickel on STS316L. The results show that the surface morphology and electrical properties depended on the nickel coating thickness. The surface morphology gradually changed from a flat to a porous structure along as the nickel coating thickness decreased, and the electrical resistance of the nickel-coated STS316L increased as the nickel coating thickness decreased. This can be attributed to the diffusion of elements of Fe and Cr from the substrate through the nickel grain boundaries. Additionally, carburization in the metal grains or grain boundaries in an anodic environment was found to influence the electrical properties due to matrix distortion. The resistance of Cr-oxide layers formed in an anodic environment causes a drop in the potential, resulting in a decrease in the system efficiency.