• 한국지반환경공학회 논문집
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• 제17권10호
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• pp.73-81
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• 2016

선진국에서는 준설토의 고함수비 특성을 제어하기 위해 다양한 고화제를 이용하는 공법을 개발하고 있으며 이 중 점토에 시멘트를 혼합하는 방법은 주로 심층혼합공법 등 연약지반의 개량공법으로 사용되어 왔다. 그러나 이에 관련된 연구는 고화제가 10% 전후의 혼합률을 갖고 있으며 이러한 혼합점토의 단기적인 특성에 대한 실험적 구명에 집중되어 왔다. 본 연구에서는 연약지반의 개량공법 적용 시 준설점토를 시멘트와 친토양 경화재로 고결시켜 장비의 주행성을 확보할 목적으로 시멘트와 친토양 경화재(NSS)를 혼합교반 하였다. 이를 바탕으로 원지반의 건조중량 대비 시멘트, NSS의 혼합비 및 양생기간(7일, 14일, 28일)에 따른 개량토의 일축압축강도 특성을 규명하고자 하였으며, 준설토 재활용을 위한 기술개발을 위하여 경량화제를 첨가하지 않은 시멘트혼합처리 방법과 친토양 경화재인 NSS를 혼합한 지반의 강도특성을 제공함으로써 차후 연약지반 개량을 위한 장비의 주행성을 확보하는데 연구의 목적을 두었다.

• 한국도로학회논문집
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• 제4권2호
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• pp.1-8
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• 2002

최근 새로운 교면포장 재료로 사용되고 있는 라텍스 개질 콘크리트(LMC; Later Modified Concrete)는 부착강도 및 휨 강도가 우수하고 염분 및 수분침투에 방수효과가 있어 점차 활용이 증가될 전망이다. 또한, 초속경시멘트를 사용한 라텍스 개질 콘크리트(RSLMC; Rapid-Setting Latex Modified Concrete)는 3시간에 실용강도를 발휘하여 긴급을 요하는 공사나 보수재료로서 적합하나, 염화물의 침투 및 동결융해로 인한 내구성능 저하 등의 문제가 검증되지 않아 이에 대한 연구가 필요한 실정이다. 따라서, 본 연구에서는 RSLMC의 내구특성을 평가하기 위해 염소이온 투과실험 및 동결융해 저항성 실험을 수행하여 투수특성과 동결융해 저항성을 분석하였다. 실험은 ASTM 규정과 KS 규정에 따라 실시하였으며, 실험변수는 라텍스 혼입률 0, 5, 10, 15, 20%와 소포제 혼입률 0, 1.6, 3.2, 4.8, 6.4%로 수행하였다. 실험결과 RSLMC는 라텍스 혼입률 15%에서 소포제 혼입량에 상관없이 모두 100이하의 전하량을 나타내어 매우 낮은 투수특성을 보였다. 또한, 소포제의 혼입률 3.2% 이상인 경우 동결융해 300 싸이클까지 상대동탄성계수가 90% 이상을 유지하여 소포제의 사용이 동결융해 저항성에 효과가 있는 것으로 나타났다.

• 한국도로학회논문집
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• 제4권2호
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• pp.19-31
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• 2002

대표적인 산업부산물인 폐주물사와 플라이애쉬의 재활용은 매우 시급한 현안중의 하나이다. 이러한 산업부산물의 재활용을 위해 저강도 콘크리트 개념을 적용한 유동성채움재(CLSM)로의 재활용을 위한 기본 연구가 지난 3년간 수행되었다. 본 연구에서는 폐주물사중 환경오염문제의 발생 가능성이 적은 것을 선별하여 CLSM용 잔골재로 이용하였다. 특히, 폐주물사에 화학약품처리를 하여 재활용 잔골재로 이용하는 방식사 역시 실험 재료로 이용하였다. 실험은 기존에 보편적으로 이용되는 뒤채움재 시공시 발생하는 사일로 토압에 대한 검증과 토압 경감효과에 대한 연구를 수행하였다. 실험결과 CLSM은 기존의 뒤채움재와는 그 성질이 매우 달라서, 옹벽배면과 절개면사이의 거리가 짧아서 발생하는 사일로 토압효과는 나타나지 않았다. 이는 기존의 뒤채움재와는 상당히 다른 재료이고, 또한, 기존에 이용되는 각종 토압론의 공식적용에 다소 신중해야 할 것으로 판단된다. 사용된 잔골재용 시료중에서는 방식사가 가장 큰 토압경감 효과를 나타냈고, 사용된 CLSM의 잔골재 특성에 따라 토압경감 효과에 다소 시간적인 차이는 있으나, 그 절대값은 어느 정도 일정한 값으로 수렴하는 것으로 나타났다.

• 한국환경과학회지
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• 제23권5호
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• pp.771-780
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• 2014

Tetragonia tetragonides is a medicinal plant native to ocean sand soil of southern provinces and has significant effects on the prevention and curing of gastroenteric disorders. Despite of its popularity, supply of the plant has never met the level of demand because of the absence of an adequate culturing method. The present study, thereby, was conducted for classifying the plants with geographically different characteristics, studying growth habits, developing a new culturing method and establishing a large scale propagation system of selected superior individual plants. The study was also aimed for revealing optimum conditions for seed treatment, fertilization, and efficient culturing system and thereby, for utilizing the plant as a new income source for rural communities. The seed was elongated with size of 2.6 mm (width) ${\times}$ 1.8 mm (length). No difference in seed size was observed depending on different inhabitate. Each flower produced about 4.5~4.8 seeds. Germination rate was high for seeds matured for 40 days after fertilization, but deceased to 50% for seeds matured only for 20 or 30 days. Seed dormancy lasted 6 months and seed storage at humid $5^{\circ}C$ facilitated germination. Mechanical obstruct of seed germination was due to seed coat and removal of seed coat enhanced the germination rate. Optimum temp. for seed storage was $5^{\circ}C$, and high germination rate was maintained for 350 days. However, for stratification condition or at room temperature, germination was significantly reduced as storage time increased Optimum treatment of plant growth regulators was soaking in $GA_3$ 250 mg/L for 1 hr. The priming treatment with 50 mM $Ca(NO_3)_2$ at $20^{\circ}C$ for two days improved the seed germination with 10% compared to non-treated control. The treatment of 20% NaOCl for 3 hr. improved the seed germination rate up to 10% and 1 day ahead.

• 한국정밀공학회지
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• 제28권7호
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• pp.777-782
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• 2011

Micro features on the surface are well-known to have significant effects on optical or mechanical properties such as the optical interference, reflectance at the surface, contact angle, interfacial friction, etc. These surface micro features are increasingly employed to enhance the functionality of the applications in various application areas such as optical components for LCD or solar panel. Diverse surface features have been proposed and some of them are showing excellent efficiency or functionality, especially in optical applications. Most applications employing the micro features need manufacturing process for mass production and the injection molding and roll-to-roll forming, which are typical processes for mass production adopting polymeric materials, may be also preferred for micro patterned plastic product. Since the functionality or efficiency of the surface structures generally depends on the shape and the size of the structure itself or the array of the structures on the surface, it would be very important to replicate the features very precisely as being designed during the molding the micro pattern applications. In this paper, a series of research activities is introduced for roll-to-roll forming of micro patterned film including filling of patterns with UV curable resin, demolding of surface structures from the roll tool, control of surface energy and cure shrinkage of resin and dispose time and intensity of the UV light for curing of UV curable resin.

• 한국터널지하공간학회 논문집
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• 제21권6호
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• pp.811-823
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• 2019

최근에는 수직구 구조물 시공방법으로 현장타설 공법 대비 시공속도가 빠르며, 안전하고 경제적인 연속상승 슬립폼 공법이 다수의 현장에 적용되고 있다. 슬립폼 공법으로 시공 가능한 높이는 2.5~4 m/day로 알려져 있는데, 콘크리트 온도가 10~30℃의 범위 밖에서는 강도 변화나 탄성 특성의 변화에 미치는 영향이 크므로 동절기 공사에서는 3 m/day 이상의 시공속도를 내기가 어렵다. 또한, 콘크리트는 수화 작용으로 인해 수화열이 발생하는데, 이는 콘크리트의 온도 균열을 초래한다. 따라서 슬립폼 연속상승시 콘크리트의 온도 제어 양생이 필요하며, 본 연구에서는 히팅 패널 및 시험용 연속상승 장치를 개발하여 반발경도, 초음파 전파시간, 수화열 및 외부온도를 측정하였다. 이를 기반으로 히팅슬립폼을 제작하였으며, "김포 현장"과 "신월 현장"에 히팅슬립폼을 적용하였다. 김포현장은 주간(08:00~17:30) 평균 1.9 m/day 또는 0.200 m/hr, 신월 현장은 2.0 m/day 또는 0.210 m/hr를 목표 상승속도 값으로 비교하였다.

• Advances in concrete construction
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• 제10권4호
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• pp.301-310
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• 2020

The following paper concentrates on the objective of studying the influences of extent of duration and temperature on the Pozzolanic properties as well as reactivity of locally existing natural clay of Nai Gaj, district Dadu, Sindh Pakistan. The activation of the clay only occurs through heating when temperature in a furnace chamber reaches 600, 700 and 800oC for 1, 2 and 3 hours and at 900 and 1000℃ for 1 and 2 hours. Furthermore, the strength activity index (SAI) of advanced pozzolanic material happens to be identified through 20% cement replacement for different samples of calcined clay as per ASTM C-618. The compressive strength test of samples had been operated for 7 and 28-days curing afterwards. The maximum compressive strength had been seen in mix E in which cement was replaced with clay calcined at 700℃ for 1 hour that is 27.05 MPa that is 24.31% more than that of control mix. The results gathered from the SAI verdicts the optimal activation temperature is 700℃ within a one-hour time period. The SAI at a temperature of 700℃ with a one-hour duration at 28 days is 124.31% which happens to satisfy the requirements of the new Pozzolanic material, in order to be applied in mortar/concrete (i.e., 75%). The Energy- dispersive spectrometry (EDS) along with the X-ray diffraction (XRD) have been carried out in means of verifying whether there is silica content or amorphous silica present in metakaolin that has been developed. The findings gathered from the SAI were validated, as the analysis of XRD verified that there is in fact Pozzolanic activity of developed metakaolin. Additionally, based on observation, the activated metakaolin holds a significant influence on the increase in mortar's compressive strength.

• 한국농공학회지
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• 제16권3호
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• pp.3472-3476
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• 1974

This test was attempted to investigate the effects of some mix designs of concreteon the compressive strengths and corrosive rates when exposed to sea water of the West Sea. In this test, concrete mixes consisted of an ordinary concrete, a pozzolan concrete and concretes with different admixtures such as fly ash, pozzolith and vinsol resin. Compressive strengths of the concrete were measured at ages of 1-year and 2-years when exposed to both sea water and fresh water. Corrosive rate was tested at ages of 1-year and 2-years when exposed to sea water only. The results obtained from the test may be summarized as follows: (1) When all of concretes were exposed to fresh water, compressive strength of an ordinary concrete was the lowest at all mixes of concretes, and all of them showed higher strength as the exposing age is longer. It was evidance that the uses of pozsolan cement, fly ash, pozzolith and vinsol resin in mix design of concrete had an effect on increasing compressive strength and that fresh water also had an effect on curing concretes even though at a long-time age. (2) When concretes were exposed sea water, a concrete with fly ash was the highest in compressive strength and its strength was increasing as the exposing age is longer, but the other concretes were decreased at 2-year exposure. It was found that a concrete with fly ash was the most effective on compressive strength of all concrete, but the other concretes were attacked by action of the sea water. (3) The use of vinsol resin admixture was the most resistant to corrosion by sea water, while the use of pozzolith was the most serious at corrosion and the others were corroded to almost same extent. (4) The relationship between corrosions and compressive strengths of concretes was not clearly correlated yet. It was known that the corrosive rate of concretes could not affect to compressive strengths by 2-year exposure of the sea water. (5) Pozzolan concrete was the most effective in compressive strength when exposed to fresh water only, However, the use of a fly ash admixture was available for compressive strength when exposing to both fresh water and sea water. It was also noticed that the use of vinsol resin was not available for strengths of concrete but for resistance to corrosion when exposed to sea water. (6) It was found that the use of pozzolith was so defective in compressive strengths and corrosiive resistance when exposing to sea water that it was only available for fresh water.

• 한국응용과학기술학회지
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• 제24권2호
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• pp.124-139
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• 2007

In order to obtain the maximum flame retardancy with the minimal deterioration of physical properties of PU flame-retardant coatings, chlorine and phosphorous functional groups were introduced into the pre-polymer of modified polyesters. In the first step, the tetramethylene bis(orthophosphate) (TBOP) and neohexanediol dichloroacetate (DCA-adduct) intermediates were synthesized. In the second step, 1,4-butanediol and adipic acid monomers were polymerized with the two kind of intermediates to obtain copolymer. The modified polyesters containing chlorine and phosphorous (ATBA-10C, -20C, and -30C) were synthesized by adjusting the contents of chlorine compound (dichloroacetic acid, 10, 20, 30 wt%) with fixed the content of phosphorous compound (2 wt%). The PU flame-retardant coatings (TTBAH -10C, -20C, and -30C) were prepared using the synthesized ATBAs and HDI-trimer as curing agent at room temperature. The physical properties of PU flame-retardant coatings with chlorine and phosphorous were inferior to those with phosphorous only and the properties were getting worse with increasing chlorine content. Flame retardancy was tested with three methods. With the vertical method, Complete combustion time of ATBAHs were $259^{\sim}347$ seconds, which means that the prepared coatings are good flame-retardant. With the $45^{\circ}$ Meckel burner method, char lengths of the three prepared coatings were less than 2.9 cm, which indicates that the prepared coatings are 1st grade flame retardancy. With the limiting oxygen index (LOI) method, the LOI values of the three prepared coatings were in the range of $30^{\sim}35%$, which proves good flame retardancy of the prepared coatings. From the results of flame retardancy tests of the specimens that contain the same amounts of flame retarding compounds, it was found that the coatings containing both phosphorous and chlorine show higher flame retardancy than the coatings containing phosphorous alone. This indicates that some synergy effect of flame retardancy exists between phosphorous and chlorine.

• 한국응용과학기술학회지
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• 제29권2호
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• pp.193-198
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• 2012

태양광 또는 풍력을 이용해 발생된 에너지를 효율적으로 저장과 사용을 위한 납 축전지의 성능을 향상 시키기 위해 전해액을 Semi-gel화 하여 납축전지에 적용하여 시험한 결과, 다음과 같은 결과를 얻었다. Semi-gel 전해액은 silica를 5wt.% 혼합한 전해액이 1시간 30분경과 시 gel화가 시작되었다. 이는 전해액이 격리판과 극판 활물질 내부까지 완전히 스며들기에 충분한 시간으로 가장 적정한 gel화 시간을 나타내었다. Semi-gel 전해액을 사용한 납축전지와 액상 전해액을 사용한 납축전지의 방전 성능을 비교한 결과, 저율방전 성능은 semi-gel전해액이, 고율방전 성능은 액상 전해액이 높은 성능을 나타내었다. 이는 gel 전해액의 경우 액상 전해액에 비해 반응속도가 느려 고율방전 성능이 낮은 것으로 나타내었다. 수명성능을 DOD 10%, DOD 100%로 시험한 결과, 5%-silica 전해액이 액상 전해액을 사용한 납축전지에 비해 우수한 수명 성능을 나타내었다. 이는 Semi-gel상 태의 전해액이 납축전지 내부 화학반응 시 발생하는 gas의 재결합 효율을 높여 전해액 감액량이 최소화로 한 결과로 수명성능에서 큰 차이를 나타내었다. 태양광, 풍력 등과 같은 에너지 저장 효율을 높이고, 수명성능을 향상시키기 위해 전해액에 5%-silica전해액을 사용하면 전해액의 감액량이 최소로 되어 DOD 100% 수명시험의 경우 4.8%, DOD 10% 수명시험의 경우 20%의 수명성능이 향상되었다.