• Polymer(Korea)
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• v.25 no.1
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• pp.15-24
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• 2001

In this study, the effects of different glycol molar ratios of unsaturated polyester(UPE) resins on the curing behaviors were investigated. The cross linking process was checked or monitored by differential scanning calorimetry(DSC) and by viscoelastic properties of rigid-body pendulum model. The knife-edge from which the pendulum is suspended, is immersed in a reaction mixture, and the change of the viscoelastic behavior brings on those of the period(T) and logarithmic decrement(${\Delta}$) of the damped free oscillations of the pendulum. The values of T and ${\Delta}$ obtained are related to the dynamic modulus(E') and modulus loss(E'). The information on the viscoelastic behavior of unsaturated polyester(UPE) resins during the curing process are shown to illustrate the usefulness of the techniques. As the content of NPG in a propylene glycol(PG)/NPG glycol mixture increased, both the cycle time during cure and the change of damping during cure of UPE resin decreased.

• Restorative Dentistry and Endodontics
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• v.19 no.1
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• pp.45-63
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• 1994

128 freshly extracted human molars were used to study the interaction between dentinal smear layer removal with various agents, and the shear bond strength of a light cured glass ionomer cement to dentin. It was proposed that the removal of smear layers using acidic cleaners followed by incorporation of Fe mordant with dentin could enhanced the infiltration of monomer component in light curing glass ionomer cement and resulted in a high bond strength. For the first treatment process for removal of smear layers on the surfaces of dentin, 50 % citric acid, 10% maleic acid and 10 % phosphoric acid were used, and for the second treatment process, 15% ferric chloride, 6.8% ferric oxalate or 30% potassium oxalate were used. Distilled water was used as a control. After double sequential treatment on dentin, a light curing glass ionomer cement was bonded to dentin. After being immersed in water at 31'C for 24 hours, shear bond strengths were measured Instron testing machine(Model No.4202, USA). Surface changes were also observed using SEM (Hitachi, S-2300, Japan) after treatment process with each agents. The following conclusions were drawn : 1. Dentin surface cleaned with maleic acid and treated with ferric oxalate showed the highest bond strength with light curing glass ionomer cement. 2. Bond strengths of glass ionomer cement to dentin treated with maleic acid or citric acid were the highest, and that treated with phosphoric acid showed the lowest. 3. The effect of ferric oxalate on shear bond strength to dentin was always higher than that of ferric chloride. 4. The smear layers were clearly removed and the orifices of dentinal tubules were opened widely by the citric acid, maleic acid and phosphoric acid. 5. The orifices of dentinal tubules opened after using the first solution were closed with the treatment of ferric chloride. 6. The precipitate like crystals were formed on dentin surfaces and tubules, but a significant decrease in bond strength of glass ionomer cement to dentin surface treated with potassium oxalate.

• Journal of Environmental Science International
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• v.15 no.2
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• pp.185-191
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• 2006

In this paper, removal time of side form from concrete using OPC(ordinary Portland cement) and FAC(fly ash cement) are proposed by appling logistic model, which evaluates the strength development of concrete with maturity. W/B, types of cement and curing temperatures are adapted as test parameters. The estimation of strength development by logistic model has a good agreement between calculated values and measured ones. As for the removal times of form works suggested in this paper, as W/8 increases, curing temperature decreases and fly ash is used, removal time of side form is prolonged. Removal time of form from concrete using OPC suggested in this paper is shorter $2.5\~3.5$ days than those of KASS-5 (Korean Architectural Standard Specifications-5) in the range of over $20^{\circ}C$. And in the range of $10\~20^{\circ}C$ removal time of form is shorter than that of KASS-5 by as much as $4\~4.5$ days. The use of FAC results in an increase in removal time of form compared to that of OPC by about 1 day.

• The Journal of Korean Academy of Prosthodontics
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• v.33 no.2
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• pp.231-239
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• 1995

When the complete denture is made, the record base for jaw relation is divided into temporary record base and permanent record base. However, The temporary record base include some disadvantages such as, the lackness of intimate contact between model and base, the lackness of retention during the jaw relation registration, When we obtained jaw relation the permanent record bases made from heat curing resin were utilized. We could get several advantages as follows : 1. The permanent record base provided intimate contact between the model and record base. 2. In fabricating occlusal rim on record base, the dimensional change of record base was little because the permanent record base was lesser influenced to thermal change of occlusal rim than the temporary record base. 3. At the stage of jaw relation, the retention of final denture could be early checked. 4. It could be able to get more accurate registration of jaw relation because all procedure were done on the same base during the jaw relation, artificial teeth arrangement, try-in, and final denture construction. 5. Although there was an inconvenience due to double curing procedure, the shrinkage rate in resin polimerization was relatively reduced so that more dimensional stability could be taken.

• International Journal of Highway Engineering
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• v.7 no.3 s.25
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• pp.23-30
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• 2005

Predicting distribution and variation of humidity inside concrete is essential to improve curing quality of concrete at field. The concrete humidity is predicted by numerical analysis using surface humidity as boundary condition. However, ambient humidity has been used instead of the surface humidity because the surface humidity could not be ccurately measured. Because it is hard to accurately measure the surface humidity, owever, the ambient humidity has been used instead of the surface humidity in the numerical analysis. In this paper, a methodology to accurately measure the surface humidity is suggested, and the ambient humidity and the humidity at the surface and inside the concrete measured by a series of laboratory tests are presented. The cause of low concrete humidity immediately after placement was investigated by a separately performed test. A surface humidity prediction model was developed using the measured humidity, and consequently validated through an additional test.

• Polymer(Korea)
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• v.24 no.5
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• pp.690-700
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• 2000

In this study, an elastomer-assistered compression molding process was investigated by experiments as well as modeling for the long-fiber reinforced thermoset composites. The consolidation pressure generated by fixed-volume and variable-volume conditions was thermodynamically derived for both elastomer and curing prepregs, and was compared with the pressure measured during curing of epoxy matrix. Exhibiting non-linear viscoelastic characteristics in the compressive stress-strain tests, the measured stress was well compared with a modifed KWW (Kohlrausch-Williame-Watts) equation, which is based on the Maxwell viscoelastic model. Using the developed model equations, the consolidation pressure generated by the elastomer was successfully predicted for the compression molding process of thermoset composite materials in tile closed mold system.

• Journal of Ocean Engineering and Technology
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• v.18 no.1
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• pp.53-62
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• 2004

The Purpose of this study is to recycle the waste concrete, which is generated in huge quantities, from construction works. in order to achieve this goal, it is important to determine the compressive strength, workability, slump, and ultrasonic velocity of recycled aggregate concrete. Thus, several experiment parameters are considered, such as water-cement ratios, sand percentage, and fine aggregate composition ratios, in order to apply the recycled aggregate concrete to pre-cast artificial fishing reefs. From the results, it has been shown that the proper mix designs for reef concrete are W/C=45%, S/a=50%, SR50:SN50 in recycled sand and natural sand mix combination case, W/C=45%, S/a=50%, SC50:SN50 in crushed sand and natural sand mix combination case, W/C=45%, S/a=50%, SR50:SC50 in recycled sand and crushd sand mix combination case. Also, this study shows that the shape and surface roughness of fine aggregate particles have an effect on the strength, slump, ultrasonic velocity of tested concrete, and the compressive strength ratios of 7days' and 90days' curing ages of recycled aggregate concrete are about 70% and 110% of 28days' curing age.

• Computers and Concrete
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• v.19 no.2
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• pp.217-226
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• 2017

This paper summarizes the results of experimental research, and artificial intelligence methods focused on determination of compressive strength of lightweight cement mortar with silica fume and fly ash after sulfate attack. The artificial neural network and the support vector machine were selected as artificial intelligence methods. Lightweight cement mortar mixtures containing silica fume and fly ash were prepared in this study. After specimens were cured in $20{\pm}2^{\circ}C$ waters for 28 days, the specimens were cured in different sulfate concentrations (0%, 1% $MgSO_4^{-2}$, 2% $MgSO_4^{-2}$, and 4% $MgSO_4^{-2}$ for 28, 60, 90, 120, 150, 180, 210 and 365 days. At the end of these curing periods, the compressive strengths of lightweight cement mortars were tested. The input variables for the artificial neural network and the support vector machine were selected as the amount of cement, the amount of fly ash, the amount of silica fumes, the amount of aggregates, the sulfate percentage, and the curing time. The compressive strength of the lightweight cement mortar was the output variable. The model results were compared with the experimental results. The best prediction results were obtained from the artificial neural network model with the Powell-Beale conjugate gradient backpropagation training algorithm.

• Polymer(Korea)
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• v.35 no.3
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• pp.196-202
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• 2011

The cure kinetics of a bisphenol A epoxy resin and polyoxypropylene diamine curing agent system are investigated in both dynamic and isothermal conditions by differential scanning calorimetry (DSC). In dynamic experiments, the shift of exothermic peaks obtained at different heating rates is used to obtain activation energy of overall cure reaction based on the methods of Ozawa and Kissinger. Isothermal DSC data at different temperatures are fitted to an autocatalytic Kamal kinetic model. The kinetic model is in a good agreement with the experimental data in the initial stage of cure. A diffusion effect is incorporated to describe the later stage of cure, predicting the cure kinetics over the whole range of curing process. Also, dynamic mechanical analysis is performed to evaluate the storage modulus and average molecular weight between crosslinkages.

• Proceedings of the Korea Concrete Institute Conference
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• 2010.05a
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• pp.275-276
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• 2010

In this study, using experimental results on the autogenous expansion of concrete containing MgO, autogenous expansion model which considers water-binder ratio, amount of MgO and curing temperature was suggested. The results predicted by autogenous expansion model agreed well with experiment results.