• Title/Summary/Keyword: Cure property

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A Study on the Characteristics of IR/CR Rubber Blends by Surface Treatment with Chlorine (염소의 표면처리에 따른 IR 및 CR Blend의 특성 연구)

  • Park, Ji-Hye;Lee, Chang-Seop;Park, Hyun-Ho
    • Journal of the Korean Chemical Society
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    • v.54 no.6
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    • pp.749-754
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    • 2010
  • In this study, rubber vulcanization property, change in physical property, morphology and chemical characteristics of blended rubber depending on various IR/CR ratio were investigated for the purpose of the improvement of material property and durability. The effect of surface treatment by chlorine on the friction coefficient was also studied with various conditions of surface treatment. In terms of vulcanization property, as the amount of CR content increased, the speed of cure was decreased, while the density of crosslinking stayed constant. It means hardness and modulus were increased as the CR content increased. It is related to change in cure property and mechanical strength was improved by the effect of crystallization reaction. In the aging property, as the CR content increases, the changed amount of basic properties were decreased, which acts as a reducing factor in change of aged property by complementing weak point in mechanical property. It was found that the degree of property change for surface treated samples were reduced. According to the microscopic result, the degree of surface dispersion on rubber blends was increased by increasing CR content. Rubber surface showed uniform direction in pattern with increased smoothness and luster by treatment with chlorine. The degree of rubber reforming was measured by the remaining amount of chlorine and the friction coefficient was dependent on the amount of chlorine combined with rubber. In the initial stage of surface treatment, from 10 to 40 phr, the friction coefficient of specimen was rapidly reduced. However, as the concentration of chlorine solution increased, the change in friction coefficient was decreased.

Cure Characteristics, Mechanical Properties, Abrasion Property and Thermal Properties of EVM/EPM Blends Containing Flame Retardants

  • Sung, Il Kyung;Lee, Won Ki;Park, Chan Young
    • Elastomers and Composites
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    • v.52 no.2
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    • pp.105-113
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    • 2017
  • The curing behavior, mechanical properties, hot-air aging resistance, abrasion properties,thermal properties, etc., of EVM/EPM/APP (ammonium polyphosphate)/DPER (dipentaerythritol)/EG (expandable graphite) and EVM/EPM/ATH (aluminium trihydroxide) flame retarding systems in ethylene vinyl acetate rubber (EVM) blends with EPM (ethylene propylene rubber) were sequentially examined. For both flame retarding systems, the torque values increased with the content of EPM rubber and with the vulcanization time. As the content of EPM rubber increased, the scorch time became shorter, whereas the optimum cure time followed an increasing trend. For the EVM/EPM/APP/DPER/EG flameretarding system, as the content of EPM rubber increased, the hardness did not change,whereas the tensile strength and elongation at break decreased. A hot-air aging resistance test at $150^{\circ}C$ showed that the heat resistance decreased with the EPM content regardless of the kinds and contents of flame retardants. As the EPM content increased, the abrasion rate became higher and the abrasion resistance of the EVM/EPM/APP/DPER/EG flame retarding systems exceeded that of the EVM/EPM/ATH flame retarding counterparts. In comparison with the EVM/EPM/ATH flame retarding systems, the thermal stability of the EVM/EPM/APP/DPER/EG flame retarding system showed an increasing tendency.

Properties and UV-cut effects of cotton fabric treated with $TiO_2$/PEG ($TiO_2$/PEG처리 면직물의 물성과 자외선 차단성능)

  • 김정진;장정대
    • Textile Coloration and Finishing
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    • v.14 no.4
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    • pp.223-228
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    • 2002
  • Cotton fabric was treated with $TiO_2$-PEG600 dispersion colloid by pad-dry-cure and wet-fixation process to improve the performance properties as well as UV-cut effect. As the concentration of $TiO_2$/PEG increased tensile strength, crease resistance, stiffness of treated cotton fabric increased. Application of wet-fixation method provided a further improvement in tensile strength, crease resistance, stiffness of treated cotton fabric. Cotton fabric treated with $TiO_2$/PEG was more efficient in UV-cut property than untreated cotton.

Effect of Binder's Concentration and Fiber Type on Mechanical Properties of Fragrant Fabrics (마이크로캡슐을 이용한 방향가공시 바인더 농도 및 섬유 종류에 따른 물성)

  • 김혜림;송화순
    • Journal of the Korean Society of Clothing and Textiles
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    • v.28 no.7
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    • pp.1029-1036
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    • 2004
  • The fragrant fabrics were prepared by treatment with eucalyptus microcapsules. 100% cotton fabric, 100% polyester fabric and 100% wool fabric were used as test specimens. Using pad-dry-cure method, microcapsules were attached on each specimen by acrylic binder under conditions of varying concentration. Surface property, stiffness, and air permeability of fragrant fabrics were evaluated. As increasing concentration of binder, add-on yield was increased. Add-on yield was decreased with increasing laundering cycle, especially in polyester fabric. As the concentration of binder was increased, the properties of stiffness and air permeability were decreased. Also it fumed out that pad-dry-cure method was not suitable to polyester fabric.

A Study on the Effect of Reactive Plasticizer (반응성(反應性) 가소제(可塑劑)의 효과(效果)에 관한 연구(硏究))

  • Park, Gun-Rok;Kim, Hong-Sun;Choi, Sei-Young
    • Elastomers and Composites
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    • v.27 no.4
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    • pp.247-254
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    • 1992
  • The purpose of this dissertation is to study the vulcanization characteristics, compression set and other physical properties of NBR vulcanizates according to the various plasticizer and its content. Vulcanization characteristics were investigated by using cure that has obtained by means of rheometer and Mooney viscometer. The result of physical properties, vulcanization characteristics are as fellows. 1. The results of test for optimum cure time in vulcanization characteristics of NBR compounds indicated the rapidity of scorch time according to the increase of amounts of plasticizer. 2. In the test of compression set property, LCR was the best effect. 3. In the test of oil resistance, LCR was the best effect.

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Physical Property Analysis by Table of Orthogonal Arrays of Three-level on the Cotton Fabrics Treated with Formaldehyde and Urea (포름알데히드와 우레아로 처리한 면직물의 3수준 직교배열표에 의한 성능 분석)

  • 이방원;김형우;김찬영;박병기
    • Textile Coloration and Finishing
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    • v.2 no.1
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    • pp.14-20
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    • 1990
  • The cotton fabrics were treated with formaldehyde in the presence of zinc nitrate catalyst and urea. The effects of HCHO concentration, urea concentration, catalyst ratio, cure time and cure temperature on the physical properties of fabrics were studied. Cotton fabric finished with HCHO and urea had the lower tensile strength and tear strength than untreated one. These strength losses resulted from tighter oxymethylene crosslinks. The enhanced wrinkle recovery for fabric treated with formaldehyde in the presence of urea was indicative of the formation of urea-formaldehyde polymer. These experimental conditions were set up according to table of orthogonal arrays.

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A Study on the Sorption and Physical Properties of the BTCA Finished Cotton Fabrics (BTCA로 방추가공한 면직물의 수착 성질 및 물리적 성질의 연구)

  • 최연주;유효선
    • Journal of the Korean Society of Clothing and Textiles
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    • v.22 no.4
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    • pp.535-542
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    • 1998
  • Cotton fabrics were treated with BTCA, which is used to improve the wrinkle recovery property of cotton fabrics. BTCA, with varying its concentrations, was treated on cotton fabrics by pad dry-cure technique. BTCA contents in treated cotton fabrics were determined by the weight gain and the FT-lR spectrometer. The effects on the sorption and physical properties of BTCA treated fabrics were investigated. IR spectra showed that ester-crosslinks were produced in BTCA treated cotton fabrics. And as increasing the concentration of BTCA, ester-crosslinks are increased in amorphous regions of fabrics. Moisture regain and water imbibition of treated fabrics were reduced. But, they were increased over a certain concentration. Dye sorptions also were reduced, but they were similar over 6% BTCA. When BTCA was treated on cotton fabrics, DP rating and wrinkle recovery angle were improved. On the other hand, strength retentions of treated fabrics were lower than untreated fabrics. Stiffness was increased.

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A Oriental Medical Study on the Castanea mollissima Bl. (율(栗)에 대(對)한 한의학적(韓醫學的) 문헌고찰(文獻考察))

  • Lee Soo-Jin;Kim Myung-Dong;Nam Young-Jae
    • Journal of Society of Preventive Korean Medicine
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    • v.4 no.1
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    • pp.122-131
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    • 2000
  • This dissertation is try to figure out why chestnut belongs to kidney channel, from the viewpoint of five elements theory. After studying chestnut's property, flavor, channel tropism, main cure ability, prescriptions, shape, sweet, and prohibitions, I came to the following results. 1. Property of chestnut is warm and has no toxicity, so it is less related than kidney property. 2. Flavor of chestnut is salty and sweet, so it has some relation to kidney and spleen properties. 3. Channel tropism of chestnut enters mainly into kidney channel, and then spleen and stomach channels. 4. Chestnut controls kidney function of storing the essence of life, determining the condition of bone and marrow, conduction water metabolism, affecting reasoning activity, and controls activity of nine openings of body. It also has effects on functions of spleen, intestines and stomach. 5. Prescriptions including chestnut is similar to that of human brain, it is possible to reason out that chestnut has some relation to human brain. 7. As flavor of chestnut flower is similar to that of spermatic fluid, so it has som relation to kidney property. 8. As chestnut has property of blocking qi and it causes spleen, stomach and colon system to be confused, so it is suggested that persons with weakende spleen and stomach be not allowed to take in.

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The Changes of Vulcanization and Physico-Mechanical Properties of NR/BR Blend with the Content of Sulfur and Accelerator (황 및 가황 촉진제의 함량에 따른 NR/BR 블렌드의 가황과 물리적·기계적 특성의 변화)

  • Kim, Wan-Young;Lee, Dai-Soo;Kim, Youn-Sop;Kim, Hyung-Soon;Nah, Chang-Woon
    • Applied Chemistry for Engineering
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    • v.2 no.4
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    • pp.356-362
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    • 1991
  • The physico-mechanical properties of NR/BR blend were measured, and the results were interpreted in terms of the crosslink density with cure system. The cure rate, maximum torque and crosslink density increase with the content and ratio of curative for cure system. Hardness, 300 % tensile modulus, rebound and wear resistance increase with crosslink density of the vulcanizate but heat build-up and tan $\delta$ at $60^{\circ}C$ decrease. It is expected that semi-EV(efficient vulcanization) cure system is appropriate for application in tire tread of truck/bus in which load bearing property is impotant.

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A Study of Relations of Chain Lengths and Properties for Bifunctional linear DGEBF/Linear Amino (EDA, HMDA) Cure Systems (선형 이관능성 DGEBF/선형아민(EDA, HMDA) 경화계의 경화제 사슬길이와 물성과의 관계에 대한 연구)

  • Myung In-Ho;Lee Jae-Rock
    • Composites Research
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    • v.17 no.6
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    • pp.37-43
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    • 2004
  • To determine the effect of chain length and chemical structure of linear amine curing agents on thermal and mechanical properties, a standard bifunctional linear DGEBF epoxy resin was cured with EDA and HMDA having amine group at the both ends of main chain in a stoichiometrically equivalent ratio in condition of preliminary and post cure. From this work, the effect of linear amine curing agents on the thermal and mechanical properties is significantly influenced by numbers of carbon atoms of main chain. In contrast, the results show that the DCEBF/EDA system having two carbons had higher values in the thermal stability, density, shrinkage (%), grass transition temperature, tensile modulus and strength, flexural modulus and strength than the DGEBF/HMDA system having six carbons, whereas the DGEBF/EDA cure system had relatively low values in maximum ekothermic temperature, maximum conversion of epoxide, thermal expansion coefficient than the DGEBF/HDMA cure system. These findings indicate that the packing capability (rigid property) in the EDA structure affects the thermal and mechanical properties predominantly. It shows that flexural fracture properties have a close relation to flexural modulus and strength.