• Title/Summary/Keyword: Cure Cycle

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Curing Behaviors and Viscoelastic of UPE Resins with Different Glycol Molar Ratios (글리콜 몰비가 다른 불포화 폴리에스테르 수지의 경화거동 및 점탄성)

  • Lee, Sang-Hyo;Park, Yung-Hoon;An, Seung-Kook;Lee, Jang-Oo
    • Polymer(Korea)
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    • v.25 no.1
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    • pp.15-24
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    • 2001
  • In this study, the effects of different glycol molar ratios of unsaturated polyester(UPE) resins on the curing behaviors were investigated. The cross linking process was checked or monitored by differential scanning calorimetry(DSC) and by viscoelastic properties of rigid-body pendulum model. The knife-edge from which the pendulum is suspended, is immersed in a reaction mixture, and the change of the viscoelastic behavior brings on those of the period(T) and logarithmic decrement(${\Delta}$) of the damped free oscillations of the pendulum. The values of T and ${\Delta}$ obtained are related to the dynamic modulus(E') and modulus loss(E'). The information on the viscoelastic behavior of unsaturated polyester(UPE) resins during the curing process are shown to illustrate the usefulness of the techniques. As the content of NPG in a propylene glycol(PG)/NPG glycol mixture increased, both the cycle time during cure and the change of damping during cure of UPE resin decreased.

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Chemorheological Behavior of Cyanate Ester Resin and Properties of Carbon Fiber Reinforced Polymer Composites (시아네이트 에스터 수지의 화학유변학적 거동 및 탄소섬유강화 고분자 복합재료의 물성)

  • Na, Hyo Yeol;Yoon, Byung Chul;Kim, Seung Hwan;Lee, Seong Jae
    • Elastomers and Composites
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    • v.48 no.2
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    • pp.133-140
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    • 2013
  • Carbon fiber reinforced polymer (CFRP) composites consist of carbon fibers in a polymer matrix. Recently, CFRP composites having high thermal stability and low outgassing are finding their use in high performance materials for aerospace and electronics applications under high temperature and high vacuum conditions. Cyanate ester resin is one of the most suitable matrix resins for this purpose. In this study, proper combination of cyanate ester and catalyst, curing behavior, and cure cycle were determined by chemorheology. Optimum condition was found to be catalyst content of 100 ppm and curing temperature of $150^{\circ}C$. Thermal stability and outgassing of cured resin composition were analyzed and the results showed thermal decomposition temperature of $385^{\circ}C$ and total mass loss of 0.29%. The CFRP prepregs and subsequent composites were fabricated by predetermined resin composition and the cure condition. Tensile moduli of the composites were compared with theoretical models and the results were very consistent.

Thermal Stability of Furfuryl Alcohol/Graphite Powder Mixtures for Impregnation of Carbonaceous Composite (탄화복합재료 함침을 위한 퍼퓨릴알콜/흑연분말 혼합물의 열안정성)

  • An, Yeong-Seok;Jo, Dong-Hwan
    • Korean Journal of Materials Research
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    • v.8 no.4
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    • pp.299-303
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    • 1998
  • We examined, using thermoanalytical methods, the effects of $2000^{\circ}C$ heat-treated graphite powders and heating rate of cure after impregnation on the thermal stability and carbon yield of furfuryl alcohol, which is frequently used not only as an impregnant but also as a matrix precursor for carbon fiber-reinforced carbon composites. It was founded that the addition of 30wt% graphite powders to furfuryl alcohol and the heating rate of $35^{\circ}C$/min showed the highest thermal stability of furfuryl alcohol/graphite powder mixture. The carbon yield above $1000^{\circ}C$ was enhanced more than 10% in comparison with the absence of graphite powders. It would be expected that this result can contribute to some extent to reduce the repeating number of processing cycle (carbonization-impregnation-cure-re-carbonization) required to densify a carbonaceous composite.

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A Study of Thermo-rheological Behaviour from Long Term Responses of Solid Composite Propellant (고체 추진제 장시간 물성거동 반응 연구)

  • Ryu, Taeha;Kim, Nakhyun;Khil, Taeock;Choi, Yongkyu
    • Journal of the Korean Society of Propulsion Engineers
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    • v.21 no.1
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    • pp.8-16
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    • 2017
  • Structural integrity of solid rocket depends on the residual reactions between constituents of its composition(post cure, migration etc.), the oxygen(or anti-oxydent) in the free volume and humidity (desiccant) under the perfect sealed condition. Mechanical Properties of composite solid propellant arising from those factors are very complex. Moreover the propulsion are faced with thermal loads from diurnal & seasonal cycle till firing. In this study, the fast evaluation method of long term mechanical properties is suggested based on Thermo-Rheological Simplicity from curing oven to cool-down stage in view point of thermal stabilization. For this subject, endurance tester having temperature control capability are devised. From the results from incremental load and strain, non-linear characteristics are discussed.

Analysis of Foodservice Quality Management in Korean Welfare Institutions for the Homeless (한국 부랑인 복지시설의 급식품질관리 분석)

  • Lee, Jin-Mi
    • Journal of the Korean Dietetic Association
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    • v.8 no.3
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    • pp.318-327
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    • 2002
  • The purposes of this study were to: a) examine charateristics of foodservice manaegment practices; b) investigate characteristics of recipients; c) analyze foodservice systems; and d) provide feedback for the efficient and effective foodservice management of welfare institutions for the homeless in Korea. A total of 27 sites was analyzed by questionnaire survey. Satatistical data analysis was completed using the SPSS package program for descriptive analysis. As results of site recipients' characteristics, 69% of total sites were males and 31% were female recipients. Average 60% of recipients were from 30 to 50 years old. Major diseases of recipients were high pressure, and obesity. According to the result of foodservice system analysis, the average meal cost per day was about 2,943 won and average food cost percentage was 29%. Average number of meals per day was about 600 meals. Mostl sites had one dietitian and 48.1% of sites had one cook as a full-time employee. In the part of procurement, dietitians were major chargers of sites for purchasing foods. Major purchasing method was the order and delivery contract. About a half of sites used cycle menu system and standardized recipies. Most of sites had recipients' survey systems for evaluating meal satisfaction. Dietitians at sites had problems on lack of cooking professionals and low meal cost budget for providing higher quality of foods to cure recipients. The results suggested that financial and systematical supports by the government would be very necessary to meet the goal of nutritional balanced meal services.

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Forming Characteristics with Cavity Pressure and Temperature Signal Inside Mold in High-Pressure Resin Transfer Molding Process of Carbon Fiber Reinforced Composite Material (탄소섬유강화복합소재의 고압수지이송성형공정에서 금형 내 캐비티의 압력 및 온도신호에 따른 성형특성)

  • Han, Beom-Jeong;Jeong, Yong-Chai;Kim, Sung-Ryul;Kim, Ro-Won;Kang, Myung Chang
    • Journal of the Korean Society of Manufacturing Process Engineers
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    • v.16 no.6
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    • pp.81-86
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    • 2017
  • The high-pressure resin transfer molding (HP-RTM) process has a very effective for the mass production of carbon fiber reinforced plastic (CFRP) for light weight in the automotive industry. In developing robust equipment, new process and fast cure matrix systems reduces significantly the cycle time less than 5 minutes in recent years. This paper describes the cavity pressure, temperature and molding characteristics of the HP-RTM process. The HP-RTM mold was equipped with two cavity pressure sensors and three temperature sensors. The cavity pressure characteristics of the HP-RTM injection, pressurization, and curing processes were studied. This experiment was conducted with selected process parameters such as mold cap size, maximum press force, and injection volume. Consequently, this monitoring method provides correlations between the selected process parameters and final forming characteristics in this work.

Apoptosis and Autophagy Induced by Methanol Extract of Kochia scoparia in Human Mucoepidermoid Carcinoma Cell Line (점액표피양암종 세포주에서 Kochia scoparia 추출물의 세포자멸과 자가포식 유도 효과)

  • Do, Mihyang;Ryu, Mi Heon;Kim, Uk-Kyu
    • The Korean Journal of Oral and Maxillofacial Pathology
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    • v.42 no.6
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    • pp.167-174
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    • 2018
  • Natural products are vastly utilized as a source of chemotherapeutic agents for human cancers. Kochia scopraia is traditionally used for the cure of urological and dermatological diseases. Recently, methanol extract of Kochia scoparia (MEKS) has been shown to have anti-cancer activity to various human cancers. However, there is no report demonstrating the anti-cancer activity of MEKS in human mucoepidermoid carcinoma (MEC) cells. In this study, the authors studied the effects of MEKS on the cell proliferation and underlying mechanism in YD15 human MEC cells. MEKS decreased YD15 cell proliferation proven by trypan blue exclusion assay and induced apoptosis, evidenced by cell cycle analysis and western blotting. Autophagy induction by MEKS was verified by western blotting. In addition, MEKS regulated the expression of phosphorylated Akt, phosphorylated p38 and Nrf2 protein. This results can imply that MEKS might be a potential candidate for the treatment of human MEC cells.

Characteristics of Dynamic Parameter of Sandy Soil According to Grout Injection Ratio (그라우트 주입율 변화에 따른 사질토의 동적계수 특성)

  • Ahn, Kwangkuk;Park, Junyoung;Oh, Jonggeun;Lee, Jundae;Han, Kihwan
    • Journal of the Korean GEO-environmental Society
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    • v.12 no.5
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    • pp.59-63
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    • 2011
  • Ground dynamic parameter such as shear elastic modulus and damping ratio is a very important variable in design of ground-structure with repeated load and dynamic load. Shear elastic modulus and damping ratio on small strain below linear limit strain is constant regardless of strain. Shear elastic modulus as the maximum shear elastic modulus and damping ratio as the minimum damping ratio were considered. As a lot of experiment related to the maximum shear elastic modulus, which is in dynamic deformation characteristics, have been conducted, many factors including voiding ratio, over consolidation ratio(OCR), confining pressure, geology time, PI, and the number of load cycle affect to dynamic soil characteristic. However, the research of ground dynamic characteristic improved with grout is absent such as underground continuous wall construction, deep mixing method, umbrella arch method. In order to investigate the dynamic soil characteristics improved with grout, in this study, resonant column tests were performed with changing water content(20%, 25%, 30%) and injection ratio of grout(5%, 10%, 15%), cure time(7th day, 28th day) As a result, shear elastic modulus and damping ratio, which are ground dynamic parameter, are affected by the injection ratio of milk grout, cure time and water content.

The Effect of Water Immersion on the Surface Strength and the Flexural Strength of the Acrylic Resin for Occlusal Appliances (교합장치용 아크릴레진의 표면경도와 굴곡강도에 대한 침수의 영향)

  • Lee, Hoy-Youn;Im, Yeong-Gwan;Kim, Byung-Gook;Lim, Hoi-Soon;Kim, Jae-Hyung
    • Journal of Oral Medicine and Pain
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    • v.35 no.1
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    • pp.75-81
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    • 2010
  • By repeating nocturnal bruxism occlusal appliance's wearing condition that is used to cure temporomandibular disorders into the vitro experiment, research aims to find out how moisture infiltrated and drying cycle process affects on the surface microhardness of the resin for occlusal appliance and flexural strength. By utilizing resin for occlusal appliance which is the main component of poly methyl methacrylate, bar shaped sample was produced. For the resin sample utilized as the controlled group 1, the sample was infiltrated in the moisture for 7 days in the temperature of 37C. Then, the resin sample of the controlled group 2 was maintained in a dry condition for 7 days in the normal temperature. After that, each sample's surface microhardness and flexural strength were measured. For the resin sample that is utilized as the experimental sample, the sample was infiltrated in the moisture for 7 days in the temperature of 37C. Then, it was inundated for 8 hours a day and dried in the normal temperature for 16 hours with the continuous process of moisture infiltration and dry cycle process for 30 days. During this cycle process, sample's surface and flexural strength were measured in the 1st day, 7th day, and 30th day. Then, it was statistically analyzed to find out the difference of controlled and experiment group's surface microhardness and flexural strength. Results are 1. For the experimental and controlled group's surface microhardness of the resin for the occlusal appliance, it did not show any significant differences after moisture infiltration and dry cycle process repetition. 2. In case of the flexural strength for resin for the occlusal appliance, experimental group with moisture infiltration and dry cycle for 30 day process had greater effect than the experimental group at the 1st day and controlled group These results can be considered to be utilized from the patients of the temporomandibular disorders towards occlusal appliance used and maintained method.

Foodservice Systems of Meal Service Programs for Mental Disorder Care Sites in Korea (한국 정신요양시설의 급식 서비스 현황 분석)

  • Lee, Jin-Mi
    • Journal of the Korean Dietetic Association
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    • v.7 no.1
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    • pp.80-86
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    • 2001
  • The purposes of this study were to: a) examine characteristics of foodservice management practices; b) investigate characteristics of recipients; c) analyze foodservice systems; and d) provide feedback for the efficient and effective foodservice management of mental disorder care sites in Korea. A total of 46 sites was analyzed by questionnaire survey. Statistical data analysis was completed using the SPSS package program for descriptive analysis. As results of site recipients' characteristics, 60% of total sites were males and 40% were female recipients. Average 60% of recipients were from 30 to 40 years old. Major diseases of recipients were mental disorder, high pressure, and obesity. According to the result of foodservice system analysis, the average meal cost per day was about 2,921 won and average food cost percentage was 39%. Average number of meals per day was about 600 meals. All sites had on dietitian and 88.3% of sites had one cook as a full-time employees. In the part of procurement, dietitians were major chargers of sites for purchasing foods. Major purchasing method was the order and delivery contract. About a half of sites used cycle menu system and standardized recipies. Most of sites had recipients survey systems for evaluating meal satisfaction. About 60% of sites provided liquid diets to recepients and 22% provided diabetic diets. Dietitians at sites had problems on low meal cost budget, lack of cooking professionals, and lack of information about treatment meals for mental disorders for providing higher quality of foods cure recipients. The results suggested that financial and systematical supports by the government would be very necessary to meet the goal of nutritional balanced meal services.

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