• Applied Biological Chemistry
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• 제15권1호
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• pp.27-33
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• 1972

본(本) Monascus속(屬) 균주(菌株)를 Wheat bran 배지(培地)에 배양(培養)하여 여기서 얻은 Alkaline protease의 효소학적(酵素學的) 성질(性質)은 다음과 같다. 1) 본(本) Protease의 최적(最適) pH는 $10{\sim}12$에 위치(位置)하고 있으며 2) 최적온도(最適溫度)는 $50^{\circ}C$ 이었으며 3) 안정(安定) pH는 $5{\sim}12$에 위치(位置)하며 4) 본(本) Protease는 $40^{\circ}C$ 이하(以下)에서 안정(安定)하였으며 5) 금속(金屬) Ion 중(中) $Hg^#$와 $Fe^#$는 조해적(阻害的)으로 작용(作用)하여 $Pb^#$, $Ba^#$, $Co^#$, $Zn^#$, $Cu^#$등은 보호작용(保護作用)을 나타내었고 이 중(中) $Cu^#$는 $10^{-2}$ 농도(濃度)에서 본(本) protease의 실활(失活)을 강(强)하게 보호(保護)함을 알았다. 6) E.D.T.A는 본(本) Protease에 대(對)해서 아무 영향을 주지 않음을 알았다.

• 한국식품과학회지
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• 제9권4호
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• pp.291-294
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• 1977

맥주공장의 폐수 오니(汚泥)를 가축의 사료로 이용하기 위하여 그 화학성분을 분석한 결과 다음과 같은 결과를 얻었다. 1. 3일간 천일건조한 sludge의 일반성분을 분석한 결과 수분 15.4%, 조단백 46.47%, 조지방 1.57%, 조섬유 4.02%, 조회분 13.12%, 가용성 무질소물 19.41%이었다. 2. Amino acid 의 분석 결과 확인된 17종의 총 아미노산 함량은 건물의 38.05%이었고 병아리 육추의 경우에 필요한 필수 아미노산은 전량이 충분하였으며 특히 그중 Isoleucine, Leucine, Phenylalanine, Tryosine Glycine 그리고 Serine은 필요량의 2-3배에 달했다. 3. 무기물은 병아리 육추의 표준사료와 비교 했을때 Mg와 Cu는 충분하였으나 그 밖의 성분은 상당량 부족하였다.

• 한국식품영양과학회지
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• 제22권4호
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• pp.484-488
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• 1993

본 연구는 전라북도내 서해안 농촌지역 저수지나 강에서 서식하는 붕어의 중금속 함량을 측정하여 다음과 같은 결과를 얻었다. 1 . Hg, Cu의 함량은 동림저수지에서 0.0167ppm, 0.1094ppm으로 가장 낮았고 As의 함량은 지산저수지 에서 0.0018ppm, 만경강에서 0.0012ppm으로 검출되었으나 다른 지역에서는 검출되지 않았다. Pb은 탑천강에서 0.3536ppm, Cd은 동림저수지에서 0.1094ppm, Mn은 만경강에서 2.9059ppm, Zn은 동진강에서 14.3096ppm으로 가장 낮았다. 2. Hg, Pb의 함량은 지산저수지에서 0.0407ppm, 0.6593pm으로 가장 높았고 Cd은 옥구 저수지에서 0.1935ppm, Cu는 탑천강에서 0.3792ppm, Mn은 동림저수지에서 6.9335ppm, Zn은 가천강에서 48.1615ppm으로 가장 높았다. 3. FAO/WHO의 최대허용량과 비교할 때 모두가 훨씬 낮았지만 그 안전성 여부는 다른 식품과 연관시켜 판단되어야 할 문제라고 생각된다. 4. 중금속 함량 측정을 주로 서해안 지역에 위치하고 있는 담수어중 가장 많은 붕어만을 채취하여 측정하였는데 앞으로는 여러 종류의 담수어와 더불어 계절별로 또 전라남북도 지방과 함께 계속 연구를 하고자 한다.

• 농업과학연구
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• 제46권4호
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• pp.799-811
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• 2019

The aim of this study was to evaluate heavy metal contamination and pollution index of agricultural soils around industrial complexes in the Jeon-Buk Regions of Korea. Soil samples near industrial complexes in 2017 were collected at two depths (0 - 15 and 15 - 30 cm) within a 500- and 1000-meter radius before planting. Eight heavy metals (Arsenic (As), cadmium (Cd), chromium (Cr), Cupper (Cu), nickel (Ni), lead (Pb), mercury (Hg) and zinc (Zn)) and the pollution index (PI), geoaccumulation index (Igeo) and soil pollution index (SPI) were evaluated based on soil contamination warning standard (SCWS). Overall, the heavy metal concentrations were below the SCWS. The PI ranged from 0.1 to 0.9 and categorized into Group 1 which is not polluted with any heavy metals. The average Igeo values of all the soil samples ranged from - 2.56 to 3.22. The Igeo values of Cd and Hg may not represent well the pollution index because the heavy metal concentrations in the soil is lower compared to the SCWS. In fact, based on the heavy metal concentrations, the Igeo for monitored soils should be categorized into Group 1, uncontaminated to moderately contaminated. However, the Igeo of Cd and Hg are classified into heavily contaminated. These results suggest that for calculating the Igeo, the heavy metal concentration and background concentration should be used very carefully if the heavy metal concentration in the soil is lower than the background concentration. SPI for all the soil samples ranged from 0.00 to 0.11 which indicates no heavy metal pollution was observed.

• Applied Biological Chemistry
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• 제32권1호
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• pp.37-43
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• 1989

식용대두유의 산화방지를 위하여 항산화제로서 phenolics의 항산화 효과를 mild한 조건 (67ml $O_{2}/min$, $50^{\circ}C$) 하에서 active oxygen method로 측정하였다. phenolics의 항산화 효과는 OH group의 수의 증가와 더불어 증가하는 경향을 나타내었으며, ferulic acid(101.5%), quinalizarin(126.7%), sesamol(149.1%), alizarin(230.7%), fisetin(355.2%), purpurogallin(360.8%) 순으로 증가하였다. 또한 control에 비하여 각각 1.5,26.7,49.1,130.7,255.2,260.8% 증가하였다. 금속이온을 첨가할 경우 역시 항 산화효과를 나타내었으나 ferulic acid, alizarin, quinalizarin의 경우는 그 효과가 적었다. 본 실험과 같이 mild한 산화조건하에서 NMR 분석법을 이용하여 항산화효과를 측정할 수 있었으나 UV와 IR 분석법은 적당치 않았다.

• 한국토양비료학회지
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• 제47권3호
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• pp.191-198
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• 2014

Absorption and accumulation of heavy metals in plants were determined by phytoavailable contents rather than total contents of heavy metals. Therefore, phytoavailability-based management protocol should be prepared for safe food crop production in contaminated agricultural lands. This study was conducted to understand the distribution and phytoavailability of heavy metal in the Korean agricultural soils affected by abandoned mining sites along with investigation of soil properties (soil pH, OM, DOC, clay content, Al/Fe/Mn content) influencing on the metal phytoavailability. For this, 142 agricultural soils located nearby 39 abandoned mining sites distributed in five province in Korea, were analyzed. Among the four different heavy metals, cadmium (Cd) and zinc (Zn) appeared to exist in more phytoavailable form than cupper (Cu) and lead (Pb). Soil pH was the main factor governing phytoavailable Cd, Pb, and Zn showing positive relationship with partitioning coefficients of the corresponding metals; Cd (r = 0.66, P < 0.001), Pb (r = 0.70, P < 0.001), and Zn (r = 0.62, P < 0.001). This implied higher phytoavailability of the corresponding metals with higher soil pH. In contrast, phytoavailability of Cu (r = 0.41, p < 0.01) was only negatively related with soil DOC (dissolved organic carbon).

• 한국환경농학회지
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• 제34권1호
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• pp.21-29
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• 2015

BACKGROUND: Heavy metal adsorptionnot only depends on biochar characteristics but also on the nature of the metals involved and on their competitive behavior for biochar adsorption sites. The goal of this study was to investigate the competitive absorption characteristics of Cu and Cd in mono-metal and binary-metal forms by biochar derived from Phragmites communis. METHODS AND RESULTS: Batch and column experiments were conducted to evaluate the competitive adsorption characteristics of the biocharfor Cu and Cd. In the batch experiments, the maximum adsorption capacity of Cd(63 mg/g) by biochar was higher than that for Cu (55 mg/g) in the mono-metal adsorption isotherm. On the other hand, the maximum Cu adsorption capacity (40 mg/g) by biochar was higher than that for Cd(25 mg/g) in the binary-metal adsorption isotherm. Cu was the most retained cations. Cd could be easily exchanged and substituted by Cu. The amounts of adsorbed metals in the column experiments were in the order of Cd (121 mg/g) > Cu (96 mg/g) in mono-metal conditions, and Cu (72 mg/g) > Cd (29 mg/g) in binary-metal conditions. CONCLUSION: Overall, the results demonstrated that competitive adsorption among metals increased the mobility of these metals. Particularly, Cd in binary-metal conditions lost its adsorption capacity most significantly.

• 식물병연구
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• 제11권1호
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• pp.39-42
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• 2005

Sphaerotheca aphanis var. aphanis에 의한 딸기 흰가루 병은 수확기에 발생하여 국내에서 가장 큰 문제가 되고 있는 중요한 병해이다. 딸기 흰가루병은 초기에 적절히 방제하지 않았으 경우 급격히 전반되어 방제가 어렵기 때문에 재배초기의 적절한 약제처리가 흰가루병 방제에 필수적이다. 이 연구는 효과적인 수확기 흰가루병 방제를 위한 최적의 약제처리시기를 밝혀내고자 감수성 품종인 'Akihime'와 'Dochiodome'를 대상으로 개화 전 약제 처리체계에 따른 방제효과를 비교, 분석하였다. Strobilulin 계통의 azoxystrobin과 kresoxim-methyl 및 유기동제인 DBEDC를 처리시기와 방법을 달리하여 딸기 수확기까지 처리하였다. 여러 가지 처리조합 가운데 딸기 묘를 정식 전 DBEDC에 침지 처리한 후 개화 전 멀칭시기에 kresoximmethyl 엽면살포하는 방법이 흰가루병 방제에 가장 효과적이었다. 이 방제체계는 촉성재배시 수확기 흰가루병 방제에서 처리시기의 중요성을 제시할 뿐만 아니라 재배자에게도 저농약 재배방법을 제공하고 경영비도 감소시켜 줄 것이다.

• 한국산업보건학회지
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• 제5권1호
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• pp.87-103
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• 1995

Since being granted permission for self-assessment of the work environment by the Department of Labor in 1992, POSCO's Industrial Hygiene Laboratory has participated in domestic and Foreign Quality Control Programs 8 times and has obtained remarkable results. It has made a lot of effort to be a proficient laboratory with the ability to observe and analyse environmental monitoring data. The summary of results is as follows: 1. POSCO's Industrial Hygiene Laboratory has received a "P(Proficient)" grade from the round 115 to round 119 of AIHA/NIOSH PAT Program for analysis of such metals as lead, cadmium, zinc, and chromium, and also has received a "P(Proficient)" grade from its round 119 of for organic solvent analysis, i,e,. Trichloroethylene(TCE), Carbon Tetr-achloride(CTC), 1,2-Dichloroethane(DCE), 1,1,1-Trichloroethane(MCM), Tetrachloroethylene (PCE), Chloroform(CFM), Benzene(BNZ), toluene(TOL), and O-xylene(OXY). 2. In the Quality Control Evaluation Program performed by the Industrial Health Research Institute,Korea Industrial Safety Corporation, POSCO has passed impressively in the3-metal analysis test for lead, cadmium, cupper, and in the 6 organic solvent analysis test for Benzene(BNZ), toluene(TOL), O-xylene(OXY), Trichloroethylene(TCE) and Methyl isobutyl keton(MIBK), n-Hexane with 2 standard deviations. These analytic techniques should be practically applied to various fields, and reliable results of environmental monitoring should be considered to improve the work environment and to keep workers from occupation related diseases.

• 한국지하수토양환경학회지:지하수토양환경
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• 제28권6호
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• pp.33-44
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• 2023

A risk assessment on the heavy metals including arsenic (As), cupper (Cu), lead (Pb), and zinc (Zn) was investigated by setting exposure routes in agricultural fields. Moreover, the factors requiring improvement in risk assessment were also discussed through a review of the dermal absorption slope factor (SF_abs) and total amount of suspended particles (TSP) in the current risk assessment guidelines. Assessment results show that the total cancer risk (TCR) of As through crop and soil ingestion was 1.51E-03 in adults and 6.37E-4 in children, which indicated a carcinogenic risk (exceeding 1E-05). On the other side, the harzard index (HI) was 3.37 in adults and 1.41 in children, which was evaluated as having a non-carcinogenic risk (>1). The carcinogenic purification targets for As were calculated to be 6.84 mg/kg in adults and 6.86 mg/kg in children, while the non-carcinogenic purification targets were calculated to be 13.43 mg/kg for adults and 22.54 mg/kg for children. When applying SF_abs 61 of the current guidelines, it appears that there is a carcinogenic risk even though the As exposure concentration is below the area of concern 1 standard (25 mg/kg), which suggestes that additional research on this factor is required for the risk assessment. In order to apply the measured suspended particle concentration to risk assessment, TSP should be derived from PM10 using an appropriate correlation equation. As a result, it is suggested to improve the risk assessment guidelines so that the mesured PM10 value measured in the field can be used directly.