• Title/Summary/Keyword: Cubic structure

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The study of the $BiO_{6}$ octahedra structure in superconducting $Ba_{0.6}K_{0.4}BiO_3$ single crystal by extended x-ray absorption spectroscopy (EXAFS에 의한 $Ba_{0.6}K_{0.4}BiO_3$ 단결정의 초전도 상태에서 $BiO_{6}$ octahedra 구조의 연구)

  • 김봉준;김영철;김현탁;강광용;이재민
    • Progress in Superconductivity
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    • v.4 no.2
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    • pp.148-152
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    • 2003
  • We have observed the temperature dependences of Bi $L_{III}$ edge spectra by extended X-ray absorption spectroscopy for a high quality single crystal and a powder of the $Ba_{0.6}K_{0.4}BiO_3$ superconductor. $Ba_{0.6}K_{0.4}BiO_3$ has the cubic structure and metallic states. The deformation of the $BiO_{6}$ octahedra, which is due to the anomalies of the Bi-O and Bi-Ba bond length, was showed by the double-shell fit. It was clearly found that these anomalies are owing to the difference in the strength of Bi-O bonds. The temperature dependences of both bond lengths and the Debye-Walter factor ${\sigma}^2$ of the Bi-O and Bi-(Ba,K) bond are discussed to illustrate local structural features of the $Ba_{0.6}K_{0.4}BiO_3$

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Doping-Concentration and Annealing Effects on Photoluminescence Profile of Eu(III)-doped CeO2 nanorods

  • Lee, Juheon;Park, Yohan;Joo, Sang Woo;Sohn, Youngku
    • Bulletin of the Korean Chemical Society
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    • v.35 no.11
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    • pp.3319-3325
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    • 2014
  • Eu(III)-doped $CeO_2$ nanorods were prepared by a co-precipitation method at room temperature, and their photoluminescence profiles were examined with different Eu(III)-doping concentrations and thermal annealing temperatures. Scanning electron microscopy, X-ray diffraction crystallography and UV-Vis absorption spectroscopy were employed to examine the morphology, crystal structure and photon absorption profiles of the nanorods, respectively. Additionally, their 2D and 3D-photoluminescence profile maps were obtained to fully understand the photoluminescence mechanism. We found that the magnetic dipole $^5D_0{\rightarrow}^7F_1$ and the electric dipole $^5D_0{\rightarrow}^7F_2$ transitions of Eu(III) were highly dependent on the doping concentration, annealing temperature and excitation wavelength, which was explained by the presence of different Eu(III)-doping sites (with and without an inversion center) in the $CeO_2$ host with a cubic crystal structure.

The Structure Determination of La2/3-xLi3x1/3-2xTiO3 by the Powder Neutron and X-ray Diffraction

  • Kang, Eun-Tae;Kwon, Young-Jean
    • Journal of the Korean Ceramic Society
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    • v.40 no.6
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    • pp.513-518
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    • 2003
  • La/sub 2/3-x/Li/sub 3x/□/sub 1/3-2x/TiO₃ compounds with x=0.13 and 0.12 were prepared by slow cooling (x=0.13) and rapid quenching (x=0.12) into the liquid nitrogen after sintering at 1350℃ for 6 h. Their crystal structure has been determined by Rietveld refinement of both the powder neutron and X-ray diffraction data. From neutron diffraction data, we found that the main phase was not tetragonal (P4/mmm), but trigonal (R3cH). The refinement of neutron diffraction for the slow cooled samples were in a good agreement with a new model; a mixture of trigonal (R3cH, 45.7 wt%), tetragonal (p4/mmm, 37.0 wt%), and Li/sub 0.57/Ti/sub 0.86/O₂(pbnm, 17.2 wt%), but the quenched sample was found not to contain tetragonal (p4/mmm). X-ray diffraction data couldn't be well fitted because of the Poor scattering factor of lithium ions and the similar reflection patterns among trigonal (R3cH), tetragonal (p4/mmm), and cubic (Pm3m). We also knew that one transport bottlenecks is destroyed by one La vacancy in the case of trigonal (R3cH).

A Study on the Aesthetic Characteristics of Korean Knit Fashion (니트 패션의 미적 특성에 관한 연구 - 패션 잡지에 나타난 국내 니트 디자인을 중심으로 -)

  • Choi, Hae-Joo
    • Journal of the Korea Fashion and Costume Design Association
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    • v.10 no.3
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    • pp.61-71
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    • 2008
  • Knit wear with comfortable feeling of wearing and various coordinations gives new values to the modern people, who seek activities and individualities, and the demand for knit wear is on the rise. This article aims to analyze the aesthetic characteristics of Korean knit fashion. Fashion photographs from leading monthly fashion magazines in Korea from 2005 to 2007 had been analyzed. The knitting techniques, and designing characteristics and aesthetic values of Korean knit fashion had been studied. The major conclusions of the study are the following: 1. Korean knit fashion applies various knitting techniques. The knitting techniques used in Korean knit fashion are hand-knitting technique, crochet techniques, lace techniques, plain stitch, rib stitch, and purl stitch technique. 2. Decorations by trimming and matching with different textile materials are used more frequently than decorations by knit material itself. Decorating methods include fringes, spangle, beads, Rhine stone, motif and embroidery decorating. Matching with different textile materials made contrasting decoration effect. 3. Patterms by knitting structure and by arranging colors are applied. Cubic effect by knitting structure patterns, and geometric patterns by arranging colors are emphasized. 4. The formative feature beauties are natural beauty, feminine beauty, and decorative beauty. Korean knit fashion has developed creative and decorative designs through various knitting techniques and decorating techniques. As individual activities may be increased in the future, the designs and applications of knit fashion may be diversified.

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Synthesis and Exploitation in Solar Cells of Hydrothermally Grown ZnO Nanorods Covered by ZnS Quantum Dots

  • Mehrabian, Masood;Afarideh, Hossein;Mirabbaszadeh, Kavoos;Lianshan, Li;Zhiyong, Tang
    • Journal of the Optical Society of Korea
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    • v.18 no.4
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    • pp.307-316
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    • 2014
  • Improved power conversion efficiency of hybrid solar cells with ITO/ZnO seed layer/ZnO NRs/ZnS QDs/P3HT/PCBM/Ag structure was obtained by optimizing the growth period of ZnO nanorods (NRs). ZnO NRs were grown using a hydrothermal method on ZnO seed layers, while ZnS quantum dots (QDs) (average thickness about 24 nm) were fabricated on the ZnO NRs by the successive ionic layer adsorption and reaction (SILAR) technique. Morphology, crystalline structure and optical absorption of layers were analyzed by a scanning electron microscope (SEM), X-ray diffraction (XRD) and UV-Visible absorption spectra, respectively. The XRD results implied that ZnS QDs were in the cubic phase (sphalerite). Other experimental results showed that the maximum power conversion efficiency of 4.09% was obtained for a device based on ZnO NR10 under an illumination of one Sun (AM 1.5G, $100mW/cm^2$).

A Study of the Mechanical Properties of Patch-Bonded and Riveted Repairs on Cracked Al 6061-T6 alloy Structures

  • Yoon, Young-Ki;Kim, Guk-Gi;Yoon, Hi-Seak
    • International Journal of Precision Engineering and Manufacturing
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    • v.1 no.2
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    • pp.55-60
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    • 2000
  • A comparison of Riveted and bonded repairs, bearing and net tension failures, and Al 6061-T6 plates is presented. The results are then compared with previous papers about bonded repairs on different patch materials and shapes. Aluminum alloys, including Al 6061-T6, have a face-centered-cubic crystal structure. Under normal circumstances, these types of crystal structures do not exhibit cleavage fractures even at very low temperatures. In aluminum-base structures, the cracked plate structures are frequently repaired using mechanical fasteners-either rivets of bolts- even though patch-bonding techniques are applied to repair and reinforce the structure. Static test results indicate that the riveted repairs are affected by the position of the rivers. When using the same size of patch, the bonded repair technique is stronger; the rate of elongation is also increased. Form FEM analysis, it is revealed the origin of patch debonding in patch-bonded structures is the edge of the patch along to the tensile strength.

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Fabrication of CdTe thin films by sputtering and its application on CdTe/CdS solar cells (Sputtering에 의한 CdTe박막제조 및 CdTe/CdS태양전지에의 응용)

  • Jung, H.W.;Lee, C.;Kim, S.;Shin, S.H.;Park, K.J.
    • Proceedings of the KIEE Conference
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    • 1996.07c
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    • pp.1645-1647
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    • 1996
  • Polycrystalline CdTe thin films -have been studied for photovoltaic application because of their high absorption coefficient and optimal band gap energy (1.54 eV) for solar energy conversion. In this study, we prepared CdTe films using RF-magnetron sputtering method and investigated structural, optical and electrical properties with spectrophotometer, XRD, EDX, and resistivity meter. CdTe films at $200\;^{\circ}C$ showed a mixture of zinc blend (Cubic) and wurtzite (hexagonal) phase. On the other hand, the films at $400\;^{\circ}C$ showed highly oriented structure having hexagonal structure. The resistivity of CdTe films deposited on $SiO_2$ substrates was about $10_7\;{\Omega}cm$. The value of resistivity decreased with the increase of the substrate temperature. CdTe were sputtered on CdS thin films prepared by chemical bath deposition for the formation of the heterojunction. I-V characteristics of these cells were measured at a light density of $100mw/cm^2$, AM. 1.0. The present thin film solar cells showed a conversion efficiency of about 5%.

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M ssbauer effect of ${Ni_{1-x}}{Cd_x}{FeAlO_4}$ (${Ni_{1-x}}{Cd_x}{FeAlO_4}$의 Mossbauer 효과)

  • Ko, Jeong-Dae;Hong, Sung-Rak
    • Korean Journal of Materials Research
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    • v.11 no.10
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    • pp.859-862
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    • 2001
  • The crystal structure and magnetic properties of the $Ni_{1-x} Cd_xFeAlO_4$(0$\leq$x$\leq$0.5) have been investigated by means of X-ray diffractometry and Mossbauer spectroscopy. The samples($0\leq$x$\leq$0.5) have been prepared by the ceramic sintering method. The X-ray diffraction pattern shows that the crystal structure of the samples is a cubic spinel type. The lattice constant has been found by extrapolation using the Nelson- Riley function and it increases slightly from $8.321{\AA}$ to $8.410{\AA}$ with Cd concentration. The Mossbauer spectra for x<0.4 show a superposition of two sextets and a paramagnetic doublet at room temperature. The cation distribution for x=0 was determined to be $[Fe_{0.75}Al_{0.25}]^A[NiFe_{0.25}Al_{0.75}^BO_4$. The superparamagnetic doublet for x< 0.4 seems to be due to A1 ion in tetrahedral site by the superparamagnetic clustering effect.

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Microstructural evolution and mechanical properties of $Al_{71.6}Ge_{28.4}$ eutectic alloy ($Al_{71.6}Ge_{28.4}$ 공정합금의 미세구조 및 기계적 성질의 평가)

  • Park, Jin-Man;Yook, Wan;Kim, Do-Hyang
    • Journal of Korea Foundry Society
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    • v.27 no.4
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    • pp.167-172
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    • 2007
  • In the present study, the microstructural evolution and mechanical properties of $Al_{71.6}Ge_{28.4}$ eutectic alloy have been investigated. Stable (fcc ${\alpha}$-Al and diamond cubic ${\beta}$-Ge) and various metastable crystalline (monoclinic, rhombohedral) phases were produced by competitive phase selection during non-equilibrium processing methods i.e. melt spinning and injection casting. The as-injection casted samples containing metastable-equilibrium eutectic (${\alpha}$-Al + monoclinic) structure showed much higher strength than samples with equilibrium eutectic (${\alpha}-Al+{\beta}-Ge$) structure but plasticity disappointingly diminished. In order to endow the enhanced ductility without significant strength drop, the alloys was heat-treated at transition temperature from metastable phase to stable phase. The annealed specimen displayed the phase transformed microstructural evolution and enhanced macroscopic plasticity.

Magnetic Properties and Crystalline Transition for the NiCr1.7Fe0.3O4

  • Park, Seung-Iel;Choi, Kang-Ryong;Kouh, Tae-Joon;Kim, Chul-Sung
    • Journal of Magnetics
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    • v.12 no.4
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    • pp.137-140
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    • 2007
  • We have studied the temperature dependent magnetic properties and crystalline phase transitionn in small amount Fe doped nickel chromite. The Crystalline structure of $NiCr_{1.7}Fe_{0.3}O_4$ is spinel cubic (Fd-3m) structure with a lattice constant $a_0=8.317\AA$ at room temperature. The magnetic $N\acute{e}el$ temperature $(T_N)$ of the Fe doped nickel chromite sample is determined to be 250 K. The $M\ddot{o}ssbauer$ spectra exhibit that there are two magnetic phases with the two different sites for the $Cr^{3+}$ ions. The spectrum at 4.2 K is fitted to two magnetic components of the magnetic hyperfine fields $H_{hf}=496$ and 485 kOe. From the spectrum at 295 K, the electric quadrupole splittings are observed with large values of 0.49 and 0.50 mm/s, respectively. The values of the isomer shifts at all temperature ranges show that the Fe ions are ferric states. We are suggested that the dynamic Jahn-Teller distortion and anisotropic magnetic relaxation effects due to the crystalline phase transition.