• 한국환경농학회지
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• 제25권4호
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• pp.316-322
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• 2006

본 연구는 도곡 광산의 광미 중 Cd, Cu, Pb, Zn의 용출 특성을 탐색하기 위해 수행하였으며, 환경에 영향을 미칠 수 있는 수용성과 0.1 M HCl 용출물을 대상으로 Batch 시험과 Column 시험을 실시하였다. Batch 시험에서 수용성 중금속은 Cd 2.31 mg/kg, Cu 129.38 mg/kg, Pb 17.17 mg/kg, Zn 287.53 mg/kg이었으며, 0.1H HCl 추출물은 Cd mg/kg, Cu mg/kg, Pb mg/kg, Zn mg/kg이었다. 수용성 중금속의 초기 용출농도는 Zn > Cu > Pb > Cd의 순이었으며, 수용성 중금속의 용출속도상수는 Pb > Cu > Cd > Zn의 순이었다. 0.1M HCl 추출물의 초기 용출농도는 Zn > Cu > Pb > Cd의 순이었으며, 용출속도상수는 Pb > Cd > Zn > Cu의 순이었다. 중금속의 용출속도는 주로 추출액과 광미의 물리적 화학적 특성에 따라 달라질 수 있으며, 이러한 결정 요소에 의하여 본 시험에서는 Pb의 용출속도가 가장 높은 것으로 조사되었다. Column시험에서 수용성 중금속은 Cd과 Cu, Zn의 경우 2 pore volume에서 의사평형에 도달하였으나, Pb의 경우 10 pore volume에서 의사 평형에 도달하였다. 0.1 M HCl을 column에 통과시켰을 때 Cd, Cu, Zn은 1 pore volume에서 용출농도의 최대점을 나타냈으나, Pb은 5 pore volume에서 최대점을 나타내었으며, 이동속도는 Cd > Zn > Cu > Pb의 순으로 조사되었다.

• 한국진공학회:학술대회논문집
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• 한국진공학회 2015년도 제49회 하계 정기학술대회 초록집
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• pp.236.2-236.2
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• 2015

The copper-zinc(Cu-Zn) nanofiber was prepared by electrospinning method. The Cu/PVP (polyvinylpyrrolidone) and Zn/PVP precursor solutions were prepared by dissolution of copper sulfate and zinc acetate in methanol, respectively. The PVP was used to control the viscosity of the precursor solutions. The optimized ratio for the Cu/PVP and Zn/PVP nanofibers was determined separately. Then the suitable ratio of the precursor solutions was applied for fabrication of Cu/Zn/PVP nanofiber. For the electrospinning method, the precursor solutions were filled in a syringe. The distance between metallic needle on the syringe and collector was fixed at 16 cm and the voltage was applied on the tip was 13.0 kV. And the as-spun nanofiber was heated at 353K for removal of residual solvent. Then the heated nanofibers were calcined at 973K to decompose PVP. The obtained Cu, Zn, and Cu-Zn nanofibers were investigated with X-ray photoelectron spectroscopy (XPS) for the chemical properties, scanning electron microscopy (SEM) for the morphologies, and X-ray diffraction (XRD) to characterize the crystallinity and phase of nanofibers.

• Bulletin of the Korean Chemical Society
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• 제28권12호
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• pp.2329-2332
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• 2007

Salsolinol, endogenous neurotoxin, is known to be involved in the pathogenesis of Parkinson's disease (PD). In the present study, we have investigated the oxidative damage of DNA induced by the reaction of salsolinol with Cu,Zn-SOD. When plasmid DNA incubated with salsolinol and Cu,Zn-SOD, DNA cleavage was proportional to the concentrations of salsolinol and Cu,Zn-SOD. The salsolinol/Cu,Zn-SOD system-mediated DNA cleavage was significantly inhibited by radical scavengers such as mannitol, ethanol and thiourea. These results indicated that free radicals might participate in DNA cleavage by the salsolinol/Cu,Zn-SOD system. Spectrophotometric study using a thiobarbituric acid showed that hydroxyl radical formation was proportional to the concentration of salsolinol and was inhibited by radical scavengers. These results indicated that hydroxyl radical generated in the reaction of salsolinol with Cu,Zn-SOD was implicated in the DNA cleavage. Catalase and copper chelators inhibited DNA cleavage and the production of hydroxyl radicals. These results suggest that DNA cleavage is mediated in the reaction of salsolinol with Cu,Zn-SOD via the generation of hydroxyl radical by a combination of the oxidation reaction of salsolinol and Fenton-like reaction of free copper ions released from oxidatively damaged SOD.

• 분석과학
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• 제9권4호
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• pp.373-381
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• 1996

몇 가지 금속을 제거하기 위한 목적으로 건조된 해조류를 이용하였다. 금속 흡착제로 사용하기 위하여 40~60 mesh의 해조 분말을 칼럼에 충진시킨 후, 금속 용액을 1mL/min의 속도로 흘려 보내면서 금속이온을 흡착시켰다. Cu(II), Zn(II) 이온 모두 갈조류인 Sargassum horneri(Turner) C. Agarch보다 녹조류인 Ulva pertusa Kjellman에서 더 많은 흡착량을 보였고 두 해조류 모두 Zn(II) 이온보다 Cu(II) 이온이 더 많이 흡착하였다. 금속의 회수율은 산성 또는 중성일 경우에 켰으며 Zn(II) 이온보다 Cu(II) 이온의 회수율이 다소 높았다.

• 한국물환경학회지
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• 제20권4호
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• pp.307-312
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• 2004

This study was focused on experiment for the separation and concentration process of Cu(II), Zn(II) solution with the variation of applied pressure and concentration using reverse osmosis plate and frame modules. Rejection coefficient and degree of concentration for Cu(II) component using single and multi-stage reverse osmosis process were showed 96.3~97.8%, 0.044~0.191(in single-stage), 96.3~98.4%, 0.400~2.264(in multi-stage) within the range of experimental condition, respectively. Those of Zn(II) were 93.3~97.1%, 0.019~0.395(in single-stage), 96.3~98.2%, 0.365~1.454(in multi-stage), respectively. Degree of concentration of multi-stage were higher than those of single-stage. Heavy metal[Cu(II), Zn(II)] separation was very efficient in using reverse osmosis plate and frame type modules. Separation efficiency for a mixed solution Cu(II) and Zn(II) was higher than those of each one of Cu(II) and Zn(II).

• E2M - 전기 전자와 첨단 소재
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• 제9권8호
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• pp.819-824
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• 1996

We have investigated the temperature dependence of CO gas sensitivity for ZnO and ZnO-CuO thick films at 200 ppm CO gas, where those films were prepared by thermal transformation. The ZnO thick film shows the maximum sensitivity of -4 at >$300^{\circ}C$ On the other hand, ZnO-CuO(more than 1mol%) thick film shows that the maximum sensitivity reduced to less than 1.5. The decrease in sensitivity of CO gas with increasing the CuO contents is due to the decrease of the oxygen absorption in thick films.

• 공업화학
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• 제21권3호
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• pp.328-332
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• 2010

본 연구에서는 다이에틸렌글리콜 용매 상에서 공침법을 이용하여 기공성 아연 구형 산화물과 구리-아연 복합 산화물을 합성하였다. 합성된 물질들의 물리화학적 특성은 전자현미경, X-선 회절분석, $N_2$ 흡착, $H_2$-TPR 방법을 통하여 분석되었고, 다양한 Cu 함량(0, 6.6, 21.3 36.4, 54.6, 77.8 wt%)을 포함한 Cu-ZnO 복합 산화물을 고정층 반응 장치에서 일산화탄소 산화 반응성을 고찰하였다. 합성된 산화물 중에서 Cu 함량이 증가할수록 Cu-ZnO의 비표면적과 미세 기공 부피는 감소하였으며, Cu (36.4 wt%)-ZnO이 가장 좋은 일산화탄소 산화 반응성을 나타내었다.

• Journal of Magnetics
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• 제17권3호
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• pp.163-167
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• 2012

The effects on the ferromagnetism of the O or Zn defect in Cu-doped ZnO with the concentration of 2.77-8.33% have been investigated by the first-principles calculations. The Cu doping in ZnO was calculated to be a kind of p-type ferromagnetic half-metals. When the Zn vacancy exists in Cu-doped ZnO, the Cu magnetic moment increases, while for the O vacancy it is reduced. It is noticeable that the ferromagnetic state was originated from the hybridized O(2p)-Cu(3d)-O(2p) chain formed through the p-d coupling. The carrier-mediated ferromagnetism by nitrogen or fluorine does not depend on their concentration.

• 대한용접접합학회:학술대회논문집
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• 대한용접접합학회 2005년도 춘계학술발표대회 개요집
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• pp.25-27
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• 2005

Sn-9Zn solder balls were bonded to Cu and ENIG (Electroless Nickel/Immersion Gold) pads, and the effect of aging on their joint reliability was investigated. The interfacial products were different from the general reaction layer formed in a Sn-base solder. The intermetallic compounds formed in the solder/Cu joint were $Cu_{5}Zn_{8}$ and $Cu_{6}Sn_{5}$. After aging treatment, voids formed irregularly at the bottom side of the solder because of Sn diffusion into the $Cu_{5}Zn_{8}$ IMC. In the case of the solder/ENIG joint, $AuZn_{3}$ IMCs were formed at the interface. In the case of the Sn-9Zn/ENIG, the shear strength remained nearly constant in spite of aging for 1000 hours at $150^{\circ}C$. On the other hand, in the case of the Sn-9Zn/Cu, the shear strength significantly decreased after aging at $150^{\circ}C$ for 100hours and then remained constant by further prolonged aging. Therefore, the protective plating layer such as ENIG must be used to ensure the mechanical reliability of the Sn-9Zn/Cu joint.

• 한국분말재료학회지
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• 제14권1호
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• pp.38-43
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• 2007

Cu-Zn alloy nano powders were fabricated by the electrical explosion of Zn-electroplated Cu wire along with commercial brass wire. The powders exploded from brass wire were composed mainly of ${\alpha},{\beta},\;and\;{\gamma}$ phases while those from electroplated wires contained additional Zn-rich phases as ${\varepsilon}$, and Zn. In case of Zn-elec-troplated Cu wire, the mixing time of the two components during explosion might not be long enough to solidify as the phases of lower Zn content. This along with the high vapor pressure of Zn appears to be the reason for the observed shift of explosion products towards the high-Zn phases in electroplated wire system.