• Title/Summary/Keyword: Cu-Fe

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A study on the exchange anisotropy of Ni-Fe/Co-Fe/Mn-Ir/Cu/buffer/Si multialyers (Ni-Fe/Co-Fe/Mn-Ir/Cu/buffer/Si 다층박막의 교환이방성에 관한 연구)

  • 윤성용;노재철;전동민;임흥순;서수정
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.10 no.1
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    • pp.36-41
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    • 2000
  • We studied the exchange anisotropy of Ni-Fe/Co-Fe/Mn-Ir/Cu/buffer/Si multilayers using D.C magnetron sputtering technique. Generally, Ni-Fe/Mn-Ir/buffer(Cu)/Si multilayers cannot pin the ferromagnetic layer for the lower exchange biased field. We got $H_{ex}$ ex/ increased by two times, after using Cu/Ta as buffer layer to get larger grain size of Mn-Ir layer and inserting very thin Co-Fe layer between the Ni-Fe layer and the Mn-Ir layer to get improved grain-to-grain epitaxy relation at the interface between Ni-Fe layer and Mn-Ir layer. The variation of $H_{ex}$ by thickness of Mn-Ir layer in ferromagnete/Mn-Ir/buffer/Si multilayers is different to that in Mn-Ir/ferromagnete/buffer/Si multilayers, because the volume distribution of grain size of Mn-Ir layer and the exchange energy at the interface between the Mn-Ir and the ferromagnetic layers is different for stacking sequence.

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Effect of Copper Supplementation on Mineral Utilizations in Rats (흰쥐에 있어 구리 보충이 무기질 대사에 미치는 양향)

  • 최며경;전예숙
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.28 no.5
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    • pp.1124-1130
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    • 1999
  • The purpose of this study was to investigate the effect of copper supplementation on mineral utilizations in rats. Intakes, excretions, and tissue levels of Fe, Zn, Cu, Ca, Mg, Na, K were compared in rats fed diet with 100, 200, 400% of copper requirement(1Cu, 2Cu and 4Cu, respectively) for 6 weeks. The feed intake was significantly higher in 2Cu compared to 1Cu group, however, body weight gain was not significantly different among the three groups. While the serum level of Fe was significantly decreased, that of Cu was significantly elevated by Cu supplementation. The liver and kidney levels of Mg and Na, intakes of all the minerals, urinary excretions of Fe, Cu, Ca and Mg were significantly higher in 2Cu and/or 4Cu compared to 1Cu. The fecal excretions, retentions and absorptions of all the minerals were not affected by Cu supple mentation. In summary, these results suggest that dietary Cu supplementation has no effect on mineral utilizations, but effect on distribution in tissues of rats.

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Effect of Different Levels of Dietary Protein and Iron on the Fe, Cu and Zn Metabolism in Rats (식이내 단백질과 철분수준이 흰쥐의 Fe, Cu 및 Zn 대사에 미치는 영향)

  • Jung, Hae-Rang;Kim, Mi-Kyung
    • Journal of Nutrition and Health
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    • v.15 no.4
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    • pp.258-267
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    • 1982
  • This study was performed to investigate the effect of different levels of protein and iron in the diet upon Fe, Cu and Zn metabolism in rat during four weeks of growing period. Forty-five male weanling rats of Sprague-Dawley strain weighing $68.5{\pm}1.1g$ were divided into 9 groups and each group was given with one of the 9 different kinds of diets for four weeks. The three dietary protein levels used were 5, 20 and 40% and Fe levels 0, 35, and 350 ppms. The results obtained were summarized as following ; 1) Food intake and body weight gain in 20%(SP) and 40%(HP) dietary protein groups tended to be significantly higher than 5%(LP) protein groups. Protein efficiency ratio (PER) was higher in LP groups than in HP and SP groups. With dietary Fe levels, there were no significant differences among groups in food intake, body weight gain, and PER. 2) In LP groups, the Fe concentrations in liver, kidney, and hind limb muscle were higher than in SP and HP groups. Regarding with dietary protein levels, the liver Cu concentrations in LP groups were slightly higher, but the liver Zn concentrations were lower in LP groups. The Fe concentrations in liver and kidney tended to decrease with decrease in dietary Fe levels, but Cu and Zn concentrations showed no consistent tendency with dietary Fe levels. 3) The Fe, Cu and Zn concentrations in serum were not different from dietary treatments except that the serum Fe concentrations increased slightly in LP groups. 4) The Fe and Cu concentrations in urine tended to be higher in HP groups. Fecal Cu and Zn concentrations showed no significant differences in dietary protein or Fe levels, but the Fe concentrations tended to increase with increase in dietary Fe levels.

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Melting and Refining of Cu Powder Scraped from Waste PCB with Fe2O3 (Fe2O3 첨가에 의한 폐PCB로부터 긁어낸 Cu분말의 용융 및 정제)

  • Heo, Su-Bin;Sohn, Ho-Sang
    • Resources Recycling
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    • v.26 no.4
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    • pp.95-100
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    • 2017
  • In this study, $Fe_2O_3$ was added as a flux to decrease melting temperature and refine during melting of Cu powder from scraped surface of the waste PCB (printed circuit board). The effect of $Fe_2O_3$ ratio to Cu powder and temperature on the recovery of Cu and content of impurities were investigated. It was found that the recovery of Cu was increased with increasing addition ratio of $Fe_2O_3$ and reaction temperature. The contents of O, Si and Fe in Cu phase were also decreased with increasing addition ratio of $Fe_2O_3$ and temperature. The formation of fayalite ($2FeO{\cdot}SiO_2$) and iron oxides phases in the slag was confirmed by XRD analysis after reaction with $Fe_2O_3$. Therefore, it was considered that the decrease of melting temperature and viscosity of slag by formation of fayalite slag contributed remarkably to the Cu recovery.

Influence of Nd Content on Magnetic Properties of Nanocrystalline $\alpha$-(Fe, Co)-Based Nd-(Fe, Co)-B-Nb-Cu Alloys ($\alpha$-(Fe, Co)기 Nd-(Fe, Co)-B-Nb-Cu 초미세결정립합금의 자기특성에 미치는 Nd의 영향)

  • 조덕호;조용수;김택기;송민석;김윤배
    • Journal of the Korean Magnetics Society
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    • v.9 no.3
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    • pp.154-158
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    • 1999
  • Magnetic properties and microstructure of nanocrystalline $\alpha$-(Fe, Co)-based Nd-(Fe, Co)-B-Nb-Cu alloys have been investigated. $Nd_x(Fe_{0.9}Co_{0.1})_{90-x}B_6Nb_3Cu_1$(x=2, 3, 4, 5, 6) alloys prepared by rapid solidification process show amorphous phase except the one with x=2. By a proper annealing, the amorphous in the alloy is changed to a nanocrystalline phase. It is confirmed that the nanocrystalline alloys are composed of $\alpha$-(Fe, Co) and $Nd_2(Fe, Co)_{14}B_1$ phase. The optimally annealed $Nd_3(Fe_{0.9}Co_{0.1})_87B_6Nb_3Cu_1$ alloy shows the highest remanence of 1.55 T. The coercivity increases with the increase of Nd content The maximum coercivity of 4.6 kOe is obtained from an optimally annealed $Nd_6(Fe_{0.9}Co_{0.1})_84B_6Nb_3Cu_1$ alloy, resulting in the maximum energy product of 10.6 MGOe.

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Magnetic Properties of $\alpha$-Fe Based Nd-Fe-B Nanocrystalline with High Remanence (고잔류자화 $\alpha$-Fe기 Nd-Fe-B 초미세결정립 합금의 자기특성)

  • 조용수;김윤배;박우식;김창석;김택기
    • Journal of the Korean Magnetics Society
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    • v.5 no.1
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    • pp.38-41
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    • 1995
  • The effects of Nb and Cu additives as will as substitutional Co into $Nd_{4}Fe_{85.5}B_{10.5}$ melt-spun alloy were studied aiming for finding a $\alpha$-Fe based Nd-Fe-B composite alloys with high energy product. The addition of Nb and Cu to $Nd_{4}Fe_{85.5}B_{10.5}$ decreased the average grain size and increased the coercivity up to 207kA/m(2.6kOe), Further-more, the substitution of Co for Fe in $Nd_{4}Fe_{82}B_{10}Nb_{3}Cu_{1}$ alloy resulted in the decrease of the average grain size (<20nm) and improved the hard magnetic properties. The remanence, coercivity and energy product of optimally annealed $Nd_{4}Fe_{74}Co_{8}B_{10}Nb_{3}Cu_{1}$ alloy were 1.345, 219kA/m(2.75kOe) and $95.5kJ/m^{3}$(12MGOe), respectively.

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Magnetoresistance Effect of Ta/NiFe/Cu/Co Pseudo Spin Valve Structure (Ta/NiFe/Cu/Co Pseudo 스핀밸브 구조의 자기저항 효과)

  • Joo, Ho-Wan;Choi, Jin-Hyup;Choi, Sang-Dae;Lee, Ky-Am
    • Journal of the Korean Magnetics Society
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    • v.14 no.1
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    • pp.25-28
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    • 2004
  • The dependence of sensitivity, MR ratio, coercivity (Hc) and switching fields as a function of thickness of each magnetic layers(Co, NiFe and Cu) were investigated in pseudo spin valves with a structure of Ta/NiFe/Cu/Co. As measured results dependence of the thickness of each magnetic layer, we obtained MR ratio of 7.26% for Ta(4 nm)/NiFe(7.5 nm)/Cu(3 nm)/Co(5 nm) pseudo spin valves. Also, we could control properties of magnetoresistance for independent magnetization courses of each magnetic layer. Especially, we found that we could control coercivity as constant MR ratio dependence of Co thickness.

Synthesis of Pd/Cu-Fe polymetallic nanoparticles for in situ reductive degradation of p-nitrophenol

  • Wenbin, Zhang;Lanyu, Liu;Jin, Zhao;Fei, Gao;Jian, Wang;Liping, Fang
    • Membrane and Water Treatment
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    • v.13 no.2
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    • pp.97-104
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    • 2022
  • With a small particle size, specific surface area and chemical nature, Pd/Cu-Fe nanocomposites can efficiently remove the organic compounds. In order to understand the applicability for in situ remediation of contaminated groundwater, the degradation of p-nitrophenol by Pd/Cu-Fe nanoparticles was investigated. The degradation results demonstrated that these nanoparticles could effectively degrade p-nitrophenol and near 90% of degradation efficiency was achieved by Pd/Cu-Fe nanocomposites for 120 min treatment. The efficiency of degradation increased significantly when the Pd content increased from 0.05 wt.% and 0.10 wt.% to 0.20 wt.%. Meanwhile, the removal percentage of p-nitrophenol increased from 75.4% and 81.7% to 89.2% within 120 min. Studies on the kinetics of p-nitrophenol that reacts with Pd/Cu-Fe nanocomposites implied that their behaviors followed the pseudo-first-order kinetics. Furthermore, the batch experiment data suggested that some factors, including Pd/Cu-Fe availability, temperature, pH, different ions (SO42-, PO43-, NO3-) and humic acid content in water, also have significant impacts on p-nitrophenol degradation efficiency. The recyclability of the material was evaluated. The results showed that the Pd/Cu-Fe nanoparticles have good recycle performance, and after three cycles, the removal rate of p-nitrophenol is still more than 83%.

Magnetoresistance of ${[Co/Fe/Cu]}_20$ Multilayers (${[Co/Fe/Cu]}_20$ 다층박막의 자기저항 특성)

  • 이장로
    • Journal of the Korean Magnetics Society
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    • v.6 no.6
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    • pp.411-416
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    • 1996
  • We have studied the effect of a spin-dependence interface electron scattering on the giant magnetoresistance by adding a Fe magnetic material to the Co/Cu interfaces. The $Fe(50\;{\AA})/[Co(17\;{\AA})/Fe(t\;{\AA})/Cu(24\;{\AA})]_{20}$ multilayers are deposited on the Corning glass 2948 and 7059 substrates in a dc magnetron sputtering system. The magnetoresistance ratio is 22 % in the only Co/Cu multilayer, while it is increased to 26 % with inserted ultra thin Fe interface layer and reduced with increasing thickness of the Fe interface layer. It was investigated to the dependence of the magnetoresistance behaviors on annealing temperature. The magnetic properties of the multilayers were measured by vibrating sample magnetometer. Also, the structures and the surface roughness of samples were characterized by X-ray diffraction and atomic force microscope, respectively. The magnetoresistance ratio was increased to annealing temperature $300^{\circ}C$, but reduced at the temperature higher than $300^{\circ}C$ due to the interfacial diffuse.

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Analysis of Giant Magnetoresistance Behavior of NiFeCo/Cu/NiFeCo/FeMn Valves (NiFeCo/Cu/NiFeCo/FeMn 스핀밸브 구조의 자기저항 거동 해석)

  • 배성태;김진영;민경익;신경호
    • Journal of the Korean Magnetics Society
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    • v.6 no.2
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    • pp.112-116
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    • 1996
  • 스퍼터링법으로 제조한 NiFeCo/Cu/NiFeCo/FeMn 스핀밸브 자성 다층막의 자기적 성질과 자기저항에 대해 연구하였다. Cu 사잇층 두께가 15 .angs. 인 경우 약 6%의 자기저항을 얻을 수 있었다. NiFeCo/FeMn에서 교환이방성 자계는 약 20 Oe 정도였는데, 이는 NiFe/FeMn 계 스핀밸브 구조에서 보고된 값(100 Oe 이상) 보다 현저히 작은 것이다. 3 mTorr에서 제조한 NiFeCo 박막은 약 10 Oe 정도의 큰 보자력을 보임으로써 비슷한 조건에서 제조한 NiFe 박막의 경우(약 2 Oe)보다 상당히 큰 값을 갖는 것으로 관찰되었다. 작은 교환이방성 자계와 큰 보자력으로 인해 음 .rarw. 양 방향과 양 .rarw. 음 방향의 자화거동에 있어서 비대칭적인 자기저항 이력곡선 거동을 보이는 것으로 나타났다.

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