• Title/Summary/Keyword: Cu content

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Absorption of Copper(Cu) by Vegetation on Reservoir Sediment Exposed after Drawdown (저수위시 노출된 저수지 저니 상의 식생과 구리(Cu)의 흡수)

  • Lee, Chung-U;Cha, Yeong-Il
    • Journal of Environmental Science International
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    • v.2 no.2
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    • pp.29-29
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    • 1993
  • Shingal reservoir is a relatively small (211ha) and shallow impoundment, and approximately 25 ha of its sediment is exposed after spring drawdown. At least 14 vascular p13n1 species germinate on the exposed sediment, but Persimria vulgaris Webb et Moq. quickly dominates the vegetation. In order to estimate the role of the vegetation in the dynamics of heavy metal pollutants in the reservoir, Cu concentration of water, fallout particles, exposed sediment, and tissues of p. vulgaris, Ivas analyzed. Cu content in reservoir water decreased from $13.10mg/m^2$ on May 15 (before dralvdown) to $3.08mg/m^2$ in June 1 (after drawdown), mainly due to the loiwering of water level. Average atmospheric deposition of Cu by fallout particles was $10.84 {\mu}g/m^2/day$. Cu content in the surface 15cm of exposed sediment decreased from $5.094g1m^2$ right after drawdown, to $0.530g/m^2$ in 41 days, which is a 89.6% decrease. Therefore up to 99.7% of Cu in the reservoir appears to exist in the sediment. only 0.3% in water If the rate of atmospheric Input by fallout particles is assumed to have been the same since 1958, when the reservoir was completed, cumulative input of Cu during the 38 years would have been $150.35mg/m^2$, which is only 3.0% of Cu content in sediment right after drawdown. Therefore, most of Cu in the Shingal reservoir must have been transported by the Shingal-chun flowing into the reservoir, Standing crop of vegetation on the exposed sediment 41 days after drawdown was $730.67g/m^2$, of which 630.91g/m2 was p. vulgaris alone, and Cu content in P vulgaris at this time was $6.612mg/m^2$. This was only 0.13% of Cu in the exposed sediment, but was 50.5% of Cu in water before drawdown, or 167% of the average annual input of Cu by atmospheric deposition. If other plants were assumed to absorb Cu to the same concentration as p. vulgaris, total amount of Cu absorbed in 41 days by vegetation on the exposed sediment is estimated to be 1913.3 g, which is a considerable contribution to the purification of the reservoir water.

Effects of Dietary Garlic Powder and Copper on Cholesterol Content and Quality Characteristics of Chicken Eggs

  • Lim, K.S.;You, S.J.;An, B.K.;Kang, C.W.
    • Asian-Australasian Journal of Animal Sciences
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    • v.19 no.4
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    • pp.582-586
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    • 2006
  • This experiment was conducted to investigate the dietary effect of garlic powder (GP) and copper (Cu) on laying performances and the cholesterol content and quality characteristics of eggs during storage in laying hens. A total of one hundred and eighty, 50-wk-old, Hy-Line Brown layers were divided into 6 groups with 3 replicates per group (10 layers per replicate) and fed one of six diets containing GP 0%, GP 1%, GP 3%, GP 5%, Cu 200 ppm, or GP 3%-Cu 200 ppm for 5 wks. There were no differences in the laying performances and feed intakes bertween treatments. Eggshell strength, eggshell thickness and yolk color were also not affected by feeding of GP and Cu. With increasing dietary GP, Haugh unit was linearly increased after 2 wk of storage (p<0.05). The levels of serum total cholesterol in hens fed diets containing GP or Cu were lower than that of the control (p<0.05), but high density lipoprotein-cholesterol was not influenced by dietary GP or Cu. The content of egg yolk cholesterol from hens fed diets containing GP or Cu was significantly decreased from that of the control, except for the GP 1% group. Based on the results of this experiment, the decrease of Haugh unit during storage was alleviated by feeding of GP. The feeding of GP or Cu alone and in combination altered the cholesterol fractions in serum and reduced the content of egg yolk cholesterol in laying hens.

Mechanical and Electrical Properties of Heavily Drawn Cu- Nb Nanocomposites with Various Nb contents (Nb함량에 따른 Cu-Nb나노복합재료의 기계적.전기적 특성)

  • Kim, Jong-Min;Jeong, Jin-Hui;Hong, Sun-Ik
    • Korean Journal of Materials Research
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    • v.11 no.4
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    • pp.312-318
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    • 2001
  • The mechanical and electrical properties of Cu-Nb filamentary nanocomposite fabricated by the bundling and drawing process were examined. The strength increased gradually with increasing Nb content while the ductility was insensitive to Nb content. The ratio of yield stresses at 293K and 75K are found to be 치ose to that of Young's moduli in various Cu-Nb nanocomposites, suggesting that athermal obstacles primarily control the strength. The fracture morphologies show ductile fractures irrespective of Nb contents. Secondary cracking along the interfaces between subelemental wires was occasionally observed and the frequency of secondary cracking increased with increasing Nb content. The conductivity and the resistivity ratio decreased with increasing Nb content. The decrease of the conductivity and the resistivity ratio(${\rho}_{293k}$/$\{rho}_{75k}$) can be explained by the increasing contribution of interface scattering.

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Effects of Cr content and Thermomechanical Treatment on Tensile Strength and Electrical Conductivity of Cu-Cr Alloys (Cu-Cr 합금의 인장강도와 전기전도도에 미치는 Cr 첨가량 및 가공열처리의 영향)

  • Kim, Ki-Tae;Jung, Woon-Jae;Shin, Han-Chul;Choi, Chong-Sool
    • Journal of the Korean Society for Heat Treatment
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    • v.14 no.1
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    • pp.17-21
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    • 2001
  • The effects of Cr content above its solubility limit and thermomechanical treatment on tensile strength and electrical conductivity of Cu-Cr alloys were studied to obtain optimum Cr content exhibiting a high tensile strength without degradation of electrical conductivity. The increase in Cr content above the solubility limit increased tensile strength of Cu-Cr alloys without deterioration of the electrical conductivity. The electrical conductivity was not affected by cold rolling. The electrical conductivity of a Cu-3.5%Cr alloy subjected to cold rolling ${\rightarrow}$ aging treatment ($450^{\circ}C{\times}1hr$) ${\rightarrow}$ cold rolling was equal to that of the alloy subjected to cold rolling ${\rightarrow}$ aging treatment. However, the tensile strength of the alloy subjected to the former thermomechanical treatment was superior to that of the alloy subjected to the latter thermomechanical treatment at all the deformation degrees.

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Phase Transformation and Reversible Shape Memory Effect of Ti-Ni-Cu Alloys (Ti-Ni-Cu 합금의 상변태 및 가역형상기억효과)

  • Hong, S.W.;Lee, O.Y.;Kim, D.K.
    • Journal of the Korean Society for Heat Treatment
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    • v.5 no.3
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    • pp.149-156
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    • 1992
  • Transformation behavior and reversible shape memory effct of Ti-Ni-Cu alloys with various Cu content has been investigated by means of electrical resistivity measurement, differential scanning calorimetry. X-ray diffraction and strain gage sensor. The transformation sequence in Ti-Ni-Cu alloys substituted by Cu for Ni up to 5at.% occurs to $B2{\leftrightarrow}B19^{\prime}$ and it proceeds in two stages by addition of 10 at.%Cu. i.e. $B2{\leftrightarrow}B19{\leftrightarrow}B19^{\prime}$. But the content of Cu increases up to 20at.%, it has been transformed in one stage ; $B2{\leftrightarrow}B19$. The shape change of Ti-40Ni-10Cu alloy which was constrain aged in circular form bended in $B2{\leftrightarrow}B19$ transformation but it spreaded out in $B19{\leftrightarrow}B19^{\prime}$ transformation. The amount of reversible shape change (${\Delta}{\varepsilon}$) of Ti-47Ni-3Cu alloy constrain aged at $400^{\circ}C$ after solution treatment has a maximum value of about $5.6{\times}10^{-3}$, but that of cold rolled and constrain aged specimens exhibits a little value independent of Cu concentrations.

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Phase Changes and Microstructural Properties of Ti Alloy Powders Produced by using Attrition Milling Method (어트리션 밀링법으로 제조된 티타늄합금의 상변화 및 미세조직특성)

  • Cha, Sung-Soo
    • Journal of Technologic Dentistry
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    • v.23 no.1
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    • pp.9-19
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    • 2001
  • Microstructure and phase transformation of Ti-Ni-Cu alloy powders produced by using attrition milling method were studied. Mixed powders of Ti-(50-X)Ni-XCu ($X=0{\sim}20$ at%) in composition range were mechanically alloyed for maximum 20 hours by using SUS 1/4" ball in argon atmosphere. Ball to powder ratio was 50: 1 and impeller speed was 350rpm. Mechanically alloyed with attrition millimg method. powder was heat treated at the temperature up to $850^{\circ}C$ for 1 hour in the $10^{-6}$ torr vacuum. Ti-Ni-Cu alloy powders have been fabricated by attrition milling method. and then phase transformation behaviours and microstructual properties of the alloy powders were investigated to assist in improving the the high damping capacity of Ti-Ni-Cu shape memory alloy powders. The results obtained are as follows: 1. After heat treating of fully mechanically alloyed powder at $850^{\circ}C$ for 1hour. most of the B2 and B 19' phases was formed and $TiNi_3$ were coexisted. 2. The B 19' martensite were formed in Ti-Ni-Cu alloy powders whose Cu-content is less than 5a/o. where as the B19 martensite in those whose Cu-content is more than 10at%. 3. The powders of as-milled Ti-Ni-Cu alloys whose Cu-contents is less than 5at% are amorphous. whereas those of as-milled Ti-Ni-Cu alloys whose Cu-content is more than 10at% are crystalline. This means that Cu addition tends to suppress amorphization of Ti-Ni alloy powders.

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Fractionation and Availability of Cu and Zn in Paddy Soils Following a Long-Term Applications of Soil Amendments (토양개량제를 장기연용한 논토양에서 구리와 아연의 분획화 및 유효도)

  • Jung, Goo-Bok;Lee, Jong-Sik;Kim, Won-Il;Yeon, Beong-Yeal;Ryu, In-Soo
    • Korean Journal of Soil Science and Fertilizer
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    • v.31 no.2
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    • pp.107-113
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    • 1998
  • We investigated the effects of a long term application of soil amendments such as lime, silicate, compost, or combinations of these materials on the contents of Cu and Zn in paddy soil and brown rice. The results obtained from a sequential extraction of Cu and Zn in paddy soils and brown rice, using $H_2O$, $KNO_3$, $Na_2$-EDTA and $HNO_3$ and showed that the most of Cu and Zn were NaOH-extractable (organically bound form) and $HNO_3$-extractable (sulfide and residual form). Cu contents of NaOH and EDTA extractable increased with the long term application of compost while the contents of Zn extracted by $KNO_3$ was decreased even though $HNO_3$ extractable-Zn was prominent chemical form in paddy soils. The percentage and contents of Zn, extracted by $KNO_3$ for each combination treatment of soil amendments, was decreased but the contents of Cu was not affected. The content of NaOH extractable-Cu was proportionally increased with increase in organic matter content irrespective of the extractants used in this experiment. The contents of Zn and exchangeable K were also increased with increase in organic matter content. However, we could not find any relationship between the extractable forms of Cu and Zn, and CEC, OM. while increase in CEC, contents of cations, and organic matter decreased the content of Cu in brown rice.

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Preparation and Characterization of Cu/MCM-41 Mesoporous Catalysts for NO Removal (Cu/MCM-41 메조포러스 촉매 제조 및 NO 제거 특성)

  • Park, Soo-Jin;Cho, Mi-Hwa;Kim, Seok;Kwon, Soo-Han
    • Applied Chemistry for Engineering
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    • v.16 no.6
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    • pp.737-741
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    • 2005
  • In this study, the effect of copper content on the NO removal efficiency by Cu/MCM-41 has been investigated. MCM-41 was prepared by hydrothermal synthesis using a gel mixture of colloidal silica solution and cetyltrimethylammonium. Cu/MCM-41 was manufactured with copper content (5, 10, 20, and 40%) in Cu(II) acetylacetonate. The surface properties of MCM-41 were investigated by using pH, XRD, and FT-IR analyses. $N_2/77K$ adsorption isotherm characteristics, including the specific surface area and micropore volume were studied by BET's equation and Boer's t-plot methods. NO removal efficiency was confirmed by gas chromatography technique. From the experimental results, the MCM-41 was analyzed to have the surface functional groups of Si-OH and Si-O-Si and the characteristic diffraction lines (100), (110), (200), and (210) corresponding to a hexagonal arrangement structure. The copper content supported on MCM-41 appeared to increase the NO removal efficiency in spite of decreasing the specific surface areas or micropore volumes. Consequently, it was found that the copper content in Cu/MCM-41 played an important role in improving the NO removal efficiency, which was mainly attributed to the catalytic reactions.

Characteristics of Natural Pedo-geochemical Background for Ni, Cu and Zn in Volcanic Soils of Jeju (제주도 화산회토양에서 Ni, Cu 및 Zn의 자연함유량 특성)

  • Lim, Han-Cheol;Moon, Kyung-Hwan;Jeon, Seung-Jong;Chang, Kong-Man;Hyun, Hae-Nam
    • Korean Journal of Soil Science and Fertilizer
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    • v.41 no.3
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    • pp.199-205
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    • 2008
  • This study was carried out to find out causes of high Ni content and characteristics of potential increase of Cu and Zn contents in the soils of Jeju area. Soil samples were collected from 4 series of Alfisols, 35 series of Andisols, 9 series of Entisols, 16 series of Inceptisols, and 1 series of Ultisols, respectively. Parent material (gravel) samples were also collected from the same sites where soil samples were taken. Both soil and parent material samples were analyzed for Ni, Cu, and Zn. The average Ni content of all the soil samples was $79.2mg\;kg^{-1}$, which was exceeded warning standard for Ni against the Soil Conservation Act in Korea, whereas that of Cu and Zn contents were lower than the warning standard for Cu and Zn. The difference of Ni, Cu and Zn content was not consistent depending upon soil color. Ni content in the soil samples from Entisols was particularly high, whereas that from the other soil orders was similar to each other. Cu and Zn contents in the soil samples were similar regardless of the difference in soil order. Ni content in Seongsan Formation(SSF), Cinder cone(C) and acicular Feldspar Olivine Basalt(FOB) was high, while that in Feldspar Basalt(FB) and Trachy Andesite lava(TA) was low. Ni content in the non-agricultural land was higher compared with that in the agricultural land, whereas Cu and Zn contents in the non-agricultural land were significantly lower than that of agricultural land. The topsoil/subsoil ratios for Ni content in most of the soil samples were less than 1, while that for total contents of Cu and Zn in many of the soil samples were larger than 1 indicating potential Cu and Zn accumulation in topsoil by artificial reasons.

Influence of Ag Addition on the Mechanical Properties and Electrical Conductivity of Cu-Mg-P Alloys (Cu-Mg-P 합금의 기계적 성질과 전기전도도에 미치는 Ag첨가의 영향)

  • Kim, Jeong-Min;Park, Joon-Sik;Kim, Ki-Tae
    • Journal of the Korean Society for Heat Treatment
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    • v.23 no.1
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    • pp.10-16
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    • 2010
  • The microstructure of Cu-Mg-P alloy sheet consisted of Cu matrix and very fine MgP precipitate, and it has been observed that the microstructure remains virtually unchanged by Ag additions up to 2%. Ag solutes were dissolved into the matrix and hardly found in the precipitates. The hardness increased with increase of the Ag content, while the conductivity slightly decreased. Strain hardening through cold rolling was found to be effective in improving the hardness, especially in high-Ag alloys. Aging treatment was conducted either before the first cold rolling or between the first and the final cold rolling, and the conductivity was significantly higher at the former case, regardless of the Ag content. Softening of Cu-Mg-P alloy sheet was remarkable above $400^{\circ}C$ and the Ag content did not show any significant effect on it.