• Bulletin of the Korean Chemical Society
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• v.14 no.5
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• pp.583-588
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• 1993

Encapsulation capacities $(V_{gas})$ of, $H_2,\;N_2,\;CO,\;CH_4$ and CO, for $Cs_{2.5}Na_{9.5}-A (C_s-A)$ and $Na_{12}$-A (Na-A) zeolites have been measured in order to understand the effect of molecular properties on the $V_{gas}$. With appropriate number of large blocking cations on the main windows of cavities in zeolite A, gas molecules can be encapsulated in both the ${\alpha}$ -and ${\beta}$-cages, resulting in much large $V_{gas}.\;V_{gas}$ is proportional to the encapsulation pressure (Pe) and is also dependent on the molecular properties of encapsulated gases themselves, especially on intermolecular forces originated from the quadrupole moments of molecules in the molecular-dimensioned cavities of zeolite A. At the low range of Pe, molecules with larger $V_{gas}$ and intermolecular forces apparently have smaller increasing tendencies of $V_{gas}$ upon increases in Pe, showing a linear relationship between the tendencies and intermolecular forces rather than their sizes. Interactions between encapsulated molecules of $CH_4$ and framework of Cs-A have been estimated and they seem to depend on the number of encapsulated molecules per unit cell. On the basis of calculated density of $CO_2$, presence of liquid-like phase for the encapsulated molecules in the molecular dimensioned cavities of zeolite A is postulated.

• Journal of Sensor Science and Technology
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• v.16 no.5
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• pp.337-341
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• 2007

$CsSrCl_{3}$ crystal was grown using Czochralski method from equimolar mixture of CsCl and $SrCl_{2}$. The spectrum range of the luminescence excited by 205 nm of wavelength was about $280{\sim}550$ nm, and its peak emission appeared at 343 nm. The luminescence decay curve of the $CsSrCl_{3}$ revealed two exponential components with time constants of 60 ns and 700 ns. The energy resolution for $^{137}Cs$ 662 keV ${\gamma}$-ray was 10.3 %. The pulse shape was linear at high energy, but some deviation existed in the low energy region.

• Preventive Nutrition and Food Science
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• v.7 no.2
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• pp.133-138
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• 2002

To examine the cholesterol-towering effects of extruded products made with cassava starch (CS) and blends of cassava starch with either resistant starch (CS-RS) or oat fiber (CS-OF) hamsters were fed with diets containing a high-cholesterol (2%) and high-fat (17%) diet for 20 days. Hamsters fed with a diet containing no cholesterol were used as a control. Total cholesterol (TC) levels in the CS-RS and CS-OF groups were significantly (p>0.05) lower compared to the CS group by 11.5% and 8.5%, respectively. Also, the diets containing fibers decreased the value of low-density lipoproteins plus very low-density lipoproteins fraction by 32.4% (CS-RS diet) and 51.7% (CS-OF), respectively, as compared to the CS diet. Total lipid values were significantly (p<0.05) lower in hamsters fed the CS-RS diet (916 mg/dL) and CS-OF diet (964 mg/dL) as compared to those fed the CS diet (1661 mg/dL). The results obtained in this study suggest that extruded products containing cassava starch blended with either resistant starch or oat fleer, could prevent health problems associated with high levels of cholesterol and hypertriglyceridemia induced by a high cholesterol and fat diet.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.13 no.1
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• pp.19-23
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• 2003

Polished surface of $CsB_{3}O_{5}$ (CBO) has been observed by reflection high energy electron diffraction (RHEED) and X-ray photoelectron spectroscopy (XPS). For comparison, electronic properties of CBO powder have been studied by XPS. It has been found that the crystal surface is covered by thick amorphous layer with chemical composition closely related to that of CBO. Great enrichment of top surface by cesium, ~30 % in reference to the bulk of the modified layer, has been displayed by depth profiling.

• Proceedings of the Korean Nuclear Society Conference
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• 1995.05b
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• pp.889-894
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• 1995

본 연구에서는 ANSI N13.32(1995)에서 제시한 손가락, 손목/발목 기준 팬텀(1)을 설계 제작하여 Teledye사의 말단선량계(finger와 wrist dosimeter)에 대한 방향의존성 실험을 수행하였다. 방사선원으로는 PTB 2차 베타표준선원 $^{204}$Tl(0.24 MeV), $^{90}$ sr/Y(0.8 MeV) 그리고 $^{l37}$ Cs(0.66 MeV) 표준 감마선원을 사용하였으며, 말단선량계로는 LiF Teflon(D-LiF-7-0.13)을 사용하였다. 90$^{\circ}$ 에서 $10^{\circ}$ 까지 20$^{\circ}$ 씩 수직과 수평으로 팬텀을 회전하여 정상각과 비정상각에 대한 상대응답을 제시하였다. 실험결과 90$^{\circ}$에서 모든 선량계는 잘 일치하였다. $^{90}$ Sr/Y은 50$^{\circ}$ 정도에서 다소 방향의존성이 적은 결과를 보였으며, $^{204}$ TI는 20$^{\circ}$에서 최소 13% 정도의 심한 방향의존성이 나타났다. 또한 $^{137}$Cs은 $10^{\circ}$에서도 최대 10.6% 정도의 적은 방향의존성을 나타냈다. 본 실험의 결과로부터 말단선량계는 저에너지와 낮은 투과 방사선[2]에서 심하게 방향의존성이 나타남을 알 수 있었다.

• Nuclear Engineering and Technology
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• v.37 no.1
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• pp.101-108
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• 2005

The neutron induced nuclear cross-section data for Pd-105, Ag-109, Xe-131, and Cs-133 were calculated and evaluated from an unresolved energy to 20 MeV. The energy dependent optical model potential parameters were extracted based on recent experimental data and applied up to 20 MeV. A spherical optical model and a statistical model for the equilibrium energy, and a multistep direct and a multistep compound model for the pre-equilibrium energy were used in the calculation. The direct capture model was recently introduced for fast neutron capture. The theoretically calculated cross-sections were compared with the experimental data and the evaluated files. The total and capture cross-sections calculated using the model were in good agreement with the reference experimental data. The evaluated cross-section results were compiled in ENDF-6 format and merged with the resonance component, already adopted in the ENDF/B-VI release 8. New data library files covering from thermal to 20 MeV were created. They are at the preliminary stage of an ENDF/B- VII release.

• Journal of Sensor Science and Technology
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• v.27 no.4
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• pp.232-236
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• 2018

A radiation detection sensor was developed and characterized by combining three types of CsI(Tl) scintillators and an array-type SiPM to detect the radioactive contamination of discharged water in real time. The characterization results showed that type 3 exhibited the most desirable characteristics in response linearity (R-square: 0.97889) according to detection sensitivity and incident radiation dose. Furthermore, in terms of spectral characteristics, type 3 exhibited 16.54% at 0.356 MeV (the emission gamma ray energy of $^{133}Ba$), 10.28% at 0.511 MeV (the emission gamma ray energy of $^{22}Na$), 9.68% at 0.356 MeV (the emission gamma ray energy of $^{137}Cs$), and 2.55% and 4.80% at 1.173 MeV and 1.332 MeV (the emission gamma ray energies of $^{60}Co$), respectively. These measurements confirmed the good energy characteristics. The results were used to evaluate the spectral characteristics and energy linearity in a mixed source using type 3 with the best detection characteristics. It was confirmed that the gamma ray peaks of $^{133}Ba$, $^{22}Na$, $^{137}Cs$, and $^{60}Co$ were well resolved. Moreover, it was confirmed that R-square, which is an indicator of energy linearity, was 0.99986. This indicates a good linearity characteristic. Based on this study, further commercialization studies will contribute to measurements in real time and to the management of the contamination caused by radioactive wastewater or radioactive material leakage, which originate from facilities that use radioactive isotopes or care facilities.

• Clinical and Experimental Reproductive Medicine
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• v.30 no.2
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• pp.165-169
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• 2003

Objective: To evaluate the results of CASA systems and to compare its results. Methods: Fifty semen sampales were analysed. Concentration, motility and forward progression were evaluated simultaneously on the same semen samples using Cell Soft System-3000 (CS system) and Sperm Quality Analyzer-V (SQA system). Results: Mean semen volume was $2.8{\pm}1.2\;ml$. Mean value of sperm concentration, motility, forward progression using CS system were $83.4{\pm}45.7{\times}10^6/ml$, $52.3{\pm}16.4%$ and $48.6{\pm}13.4%$, respectively. And mean value of sperm concentration, motility, forward progression using SQA system were $78.2{\pm}42.9{\times}10^6/ml$, $57.0{\pm}24.0%$ and $50.6{\pm}21.9%$, respectively. There were no statistical significancy of sperm concentration, motility, forward progression between the two devices. Conclusion: SQA system variables well correlated with the CS system. As a screening test for semen quality, CS system and SQA system is considered as useful in the management of male infertility.

• Journal of the Korean Chemical Society
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• v.45 no.3
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• pp.242-246
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• 2001

The quaternary thiophosphates, $A_2NiP_2S_6$ (A=Rb, Cs), have been synthesized with halide fluxes and structurally characterized by single-crystal X-ray diffraction technique. These compounds crystallize in the space group $C_{2h}^5-P2_1/n$ of the monoclinic system with two formula units in a cell of dimensions a=5.960(2), b=12.323(4), $c=7.491(3)\AA$, $\beta=97.05(3)^{\circ}$, and $V=546.0(3)\AA^3$ for Rb2NiP2S6 and a=5.957(4), b=12.696(7), $c=7.679(4)\AA$, $b=93.60(5)^{\circ}$, and $V=579.7(5)\AA^3$ for $Cs_2NiP_2S_6.$ These compounds are isostructural. The structure of $Cs_2NiP_2S_6$ is made up of one-dimensional $_\infty^1[NiP_2S_6^{2-}]$ chains along the a axis and these chains are isolated by $Cs^+$ ions. The Ni atom is octahedrally coordinated by six S atoms. These Ni$S_6$ octahedral units are linked by sharing three m-S atoms of the $[P_2S_6^{4-}]$ anions to form the infinite one-dimensional $_\infty^1[NiP_2S_6^{2-}]$ chain. For $Cs_2NiP_2S_6$, the magnetic susceptibility reveals an antiferromagnetic exchange interaction below 8K,which corresponds to the Neel temperature ($T_N$). Above $T_N$, this compound obeys Curie-Weiss law. The magnetic moment, C, and ${\theta}forCs_2NiP_2S_6$ are 2.77 B.M., 0.9593 K, and -19.02 K, respectively. The effective magnetic moment obtained from the magnetic data is agreed with the spin-only value of $Ni^{2+}d^8$(2.83 B.M.) system.

• Nuclear Engineering and Technology
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• v.55 no.2
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• pp.690-695
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• 2023

Recommendations are given to improve the efficiency of radiation protection of transport casks for SNF transportation. The attenuation of ${\gamma}$-quanta of long-lived isotopes ¹³⁴Cs, ^137mBa(¹³⁷Cs), ¹⁵⁴Eu and ⁶⁰Co by optimizing the thicknesses and arrangement of layers of Fe and Pb radiation shields of transport casks is studied. The fixed radiation shielding mass (fixed mass thickness) is chosen as the main optimization criterion. The effect of the placement order of Fe and Pb layers in a combined two-layer radiation shield with an equivalent thickness of 30 cm is studied in detail. It is shown that with the same mass thicknesses of the Fe and Pb layers, the placement of Fe in the first layer, and Pb - in the second one provides more than twofold attenuation of ${\gamma}$-quanta compared to the reverse placement: Pb - in the first layer, Fe - in the second. The increase in the efficiency of attenuation of ${\gamma}$-quanta for TC with combined shielding of Fe and Pb is shown to be achieved by designing the first layer of radiation shielding around the canister with SNF from Fe of the maximum possible thickness.