• Journal of Magnetics
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• v.19 no.1
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• pp.59-63
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• 2014

Nano-sized nickel substituted cobalt ferrite powders, $Ni_xCo_{1-x}Fe_2O_4$ ($0.0{\leq}x{\leq}1.0$), were fabricated by the sol-gel method, and their crystallographic and magnetic properties were studied. All the ferrite powders showed a single spinel structure, and behaved ferrimagnetically. When the nickel substitution was increased, the lattice constants and the sizes of particles of the ferrite powders decreased. The M$\ddot{o}$ssbauer absorption spectra of $Ni_xCo_{1-x}Fe_2O_4$ ferrite powders could be fitted with two six-line subspectra, which were assigned to a tetrahedral A-site and octahedral B-sites of a typical spinel crystal structure. The increase in values of the magnetic hyperfine fields indicated that the superexchange interaction was stronger, with the increased nickel concentration in $Ni_xCo_{1-x}Fe_2O_4$. This could be explained using the cation distribution, which can be written as, $(Co_{0.28-0.28x}Fe_{0.72+0.28x})[Ni_xCo_{0.72-0.72x}Fe_{1.28-0.28x}]O_4$. The two values of the saturation magnetization and the coercivity decreased, as the rate of nickel substitution was increased. These decreases could be explained using the cation distribution, the magnetic moment, and the magneto crystalline anisotropy constant of the substituted ions.

• Korean Journal of Crystallography
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• v.5 no.2
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• pp.93-99
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• 1994

Growth form and surface morphology of NYAB single crystal grown by TSSG technique using a K2O/3MoOS/0.5B203 flux was investigated. In the crystal grown from <100> or <120> seed, prismatic and (101) faces were well developed with different size each other. (001) face was also developed in the crystal grown from <001> seed. While growth hillocks were observed on the prismatic face of the crystal grown from <100> seed, surface striations parallel to neighbor (101) faces were formed on that face of the crystal grown from <001> seed. The (101) faces were grown by two dimensional nucleation growth. (001) face which was developed at slow growth velocity of [001] direction was grown by screw dislocation Anisotropy of growth velocity as to seed orientation affected on crystal morphology and surface morphology.

• Journal of the Korean Society for Heat Treatment
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• v.33 no.4
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• pp.180-184
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• 2020

The crystallographic texture plays an important role in both the plastic deformation and the macroscopic anisotropy of magnesium alloys. In previous study for AZ80 magnesium alloy, it was found that the main texture components of the textures vary with the deformation conditions at high temperatures. Also, the basal texture was formed at stress of more than 15-20 MPa and the non-basal texture was formed at stress of less than 15-20 MPa. Therefore, in this study, uniaxial compression deformation of AZ80 magnesium alloy was carried out at high temperature (stress of 15-20 MPa). The uniaxial compression deformation is performed at temperature of 723 K and strain rate 3.0 × 10^-3s^-1, with a strain range of between -0.4 and -1.3. Texture measurement was carried out on the compression planes by the Schulz reflection method using nickel filtered Cu Kα radiation. EBSD measurement was also conducted in order to observe spatial distribution of orientation. As a result of high temperature deformation, the main component of texture and its development vary depending on deformation condition of this study.

• Journal of the Korean Magnetics Society
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• v.4 no.2
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• pp.184-187
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• 1994

Nuclear magnetic resonance of $^{133}Cs$ in a $CsMnCl_{3}$ single crystal grown by the Czochralski method has been investigated by employing a Bruker FT NMR spectrometer. The $^{133}Cs$ resonance of two different groups were recorded. Various transitions belonging to two cesium spectra of a different intensity ratio are analyzed. The quadrupole coupling constant of Cs(I) is $0.15{\pm}0.01$ MHz, and that of Cs(II) is $0.21{\pm}0.01$ MHz. The anisotropy parameter is zero for both. The principal axes of the EFG tensors for these two sites are found to be the same. The Z axis, conventionally the largest component of the EFG tensor, is parallel to the crystallographic c-axis.

• Bulletin of the Korean Chemical Society
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• v.28 no.12
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• pp.2214-2218
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• 2007

The effects of bath temperature on electrochemical behavior, alloy composition, crystallographic structure, morphology and the magnetic properties of electrodeposited Co-Pt-W(P) films were investigated. Electrochemical studies show that alloy electrodeposition has been shifted to more positive potentials and the critical time for nucleation decreased as electrolyte temperature increased. As the temperature increased from 40 oC to 80 oC, tungsten content in the deposit increased, while phosphorus content decreased. The films deposited at T = 40 oC exhibited soft magnetic properties. However, electrodeposited at T = 70 oC, the films exhibited hard magnetic properties. It is also demonstrated that higher temperature more than 70 oC could weaken hard magnetic properties. XRD results indicated that the deposits obtained at 50 oC-70 oC showed enhancement of [00.1] P.O. (preferred orientation) with the bath temperature, which resulted in the stronger perpendicular magnetic anisotropy.

• Proceedings of the Korean Society for Technology of Plasticity Conference
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• 2006.05a
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• pp.349-352
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• 2006

The plastic deformation of polycrystalline materials is induced by changes of the microstructure when the loading is beyond the critical state of stress. Constitutive models for the crystal plasticity have the common objective which relates microscopic single crystals in the crystallographic texture to the macroscopic continuum point. In this paper, a new consistent tangent stiffness for the anisotropic elasto-viscoplastic analysis of polycrystalline deformation is developed, which can be used in the finite element analysis for the slip-dominated large deformation of polycrystalline materials. In order to calculate the consistent tangent stiffness, the state function is defined based on the consistency condition between the elastic and plastic stress. The rate of shearing increment($\Delta{\gamma}^{\alpha}$) is calculated with satisfying the consistency condition. The consistency condition becomes zero when the trial resolved shear stress($\tau^{{\alpha}^*}$) becomes resolved shear stress($\tau^{\alpha}$) at every step. Iterative method is utilized to calculate the rate of shearing increment based on the implicit backward Euler method. The consistent tangent stiffness can be formulated by differentiating the rate of shearing increment with total strain increment after the instant rate of shearing increment converges. The proposed tangent stiffness is applied to the ABAQUS/Standard by implementing in the ABAQUS/UMAT.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.6 no.3
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• pp.431-438
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• 1996

Transmission electron microscopy has been used to investigate the microstructure of hot-pressed $TiB_{2}$. Thin foil specimens, prepared by conventional ion beam thinning, revealed many features which originated from the crystallographic anisotropy of hexagonal $TiB_{2}$. It was observed that in these specimens Fe-impurities are precipitated to form secondary Fe-rich phases at grain triple edges, in grain boundaries and sometimes in-grain. These Fe-rich precipitates were characterised by their coherence or semi-coherence to a favourably oriented grain at a grain triple edge or grain boundaries or to the matrix $TiB_{2}$ phase.

• Proceedings of the KIEE Conference
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• 1998.07d
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• pp.1447-1449
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• 1998

The c-axis orientation plays a very important role in controlling the main parameters of the perpendicular magnetic recording media, such as perepndicular magnetic anisotropy field $H_{K{\bot}}$, the ratio of coercive force $H_{C{\bot}}/H_{C//}$, the recording density $D_{50}$, and the dispersion of the c-axis orientation $\Delta\theta_{50}$, which is quite important for the performance as perpendicular recording media, as well as the magnetic properties of the film. In this study, the essential process requirement for preparing the Co-Cr films with the superior c-axis orientation, the dependence of $\Delta\theta_{50}$ and the magnetic properties on the film thickness $\delta$, and the effect of underlayer on the dispersion of c-axis orientation have been investigated for both the FTS and DCM system.

• Proceedings of the Korean Society for Technology of Plasticity Conference
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• 2007.10a
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• pp.281-284
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• 2007

The effect of Ca addition on the microstructure evolution and deformation behavior of AZ31 magnesium alloy produced by hot extrusion was investigated. For this purpose, Ca was added into AZ31 melts to the level of 0.7 and 2.0 wt.% Ca. Then, AZ31 base alloy and Ca modified AZ31 alloys were extruded at $383^{\circ}C$. Ca added alloys showed finer grain size and increased hardness value rather than AZ31 base alloy. After isothermal hot compression, the shape of tested specimen exhibited a noticeable anisotropy due to the crystallographic texture effect. The ratio of major and minor axes of ovality was not directly related to test condition and Ca amount. Flow stress level increases with the increase of Ca addition at temperature below $300^{\circ}C$ because of fine microstructure. However, at high temperature and low strain rate region ($400^{\circ}C$ and $10^{-3}s^{-1}$), reverse tendency was observed since main deformation mechanism changes from dislocation slip to grain boundary sliding or diffusional process at high temperature.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2001.11a
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• pp.77-80
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• 2001

Crystallographic and magnetic characteristics of CoCr-based magnetic thin film for perpendicular magnetic recording media were influenced on preparing conditions. In these, there is that substrate temperature was parameter that increases perpendicular coercivity of CoCrTa magnetic layer using recording layer. While preparation of CoCr-based doublelayer, by optimizing substrate temperature, we expect to increase perpendicular anisotropy of CoCr magnetic layer and prepare ferromagnetic recording layer with a good quality by epitaxial growth. CoCrTa/Si doublelayer showed a good dispersion angle of c-axis orientation $\Delta$$\theta$$_{50}$ caused by inserting amorphous Si underlayer which prepared at underlayer substrate temperature 250C. Perpendicular coercivity was constant, in-plane coercivity was controlled a low value about 2000e. This result implied that Si underlayer could restrain growth of initial layer of CoCrTa thin film, which showed bad magnetic properties effectively without participating magnetization patterns of magnetic layer. In case of CoCrTa/Si that prepared with ultra thin underlayer, crystalline orientation of CoCrTa was improved rather underlayer thickness 1nm, it was expected that amorphous Si layer played a important role in not only underlayer but also seed layer.t also seed layer.r.