• Transactions on Electrical and Electronic Materials
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• 제13권2호
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• pp.51-59
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• 2012

Piezoelectric langasite crystals have superior properties such as high temperature performance and high quality Q and can be applied in combustion pressure sensors and surface acoustic wave (SAW) filters. Crystal growth, crystal structure and properties of langasite group are reviewed, and the mechanism of piezoelectricity of langasite is presented based on the crystal structure and deformation under high pressure. Finally, for the discovery of new piezoelectric materials, this paper presents the role of the framework, and recommends the search of framework crystal structure, because the characteristic of the mechanism exists on the framework of the crystal structure.

• 한국세라믹학회지
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• 제34권7호
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• pp.713-721
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• 1997

Molecular dynamic (MD) simulations with new interatomic potential function including the covalent bond were performed on the phase transition of $\alpha$-quartz-type GeO2 under high pressure. The optimized crystal structure and the pressure dependence of the lattice constant showed higher reproducibility than the previous models and were in very good agreement with the experimental data. A phase transition of $\alpha$-quartz and $\alpha$-quartz-type GeO2 by simulation was found approximately 24 GPa and 6-7 GPa, respectively. This phase transition involved an abrupt volume shrinkage and showed 4-6 coordination mixed structure with the increasing in the coordination number of cation.

• 센서학회지
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• 제13권3호
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• pp.175-181
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• 2004

A pressure sensor for high temperature was fabricated by using a SDB(Silicon-Direct-Bonding) wafer with a Si/$SiO_{2}$/ Si structure. High pressure sensitivity was shown from the sensor using a single crystal silicon of the first layer as a piezoresistive layer. It also was made feasible to use under the high temperature as of over $120^{\circ}C$, which is generally known as the critical temperature for the general silicon sensor, by isolating the piezoresistive layer dielectrically and thermally from the silicon substrate with a silicon dioxide layer of the second layer. The pressure sensor fabricated in this research showed very high sensitivity as of $183.6{\mu}V/V{\cdot}kPa$, and its characteristics also showed an excellent linearity with low hysteresis. This sensor was usable up to the high temperature range of $300^{\circ}C$.

• 한국광물학회지
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• 제9권1호
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• pp.35-42
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• 1996

Polycrystalline ZrH2 in tetragonal crystal system has been compressed in a modified Bassett-type diamond anvil cell up to 36.0 GPa at room temperature. X-ray diffraction data did not indicate any phase transitions at the present pressure range. The pressure dependence of the a-axis, c-axis, c/a and molar volume of ZrH2 was determined at pressures up to 36.0 GPa. Assuming the pressure derivative of the bulk modulus (K0') to be 4.11 from an ultrasonic value on Zr, bulk modulus (K0) was determined to be 160Gpa by fitting the pressure-volume data to the Birch-Murnaghan equation of state. Same sample was heated at $500^{\circ}C$ at the pressure of 9.8 GPa in a modified Sung-type diamond anvil cell. Unloaded and quenched sample revealed that the original tetragonal structure transforms into a hexagonal structured phase with a zero-pressure molar volume change of ~115.5%.

• 한국광물학회지
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• 제30권3호
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• pp.127-136
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• 2017

자외선 차단기능과 제균 기능을 갖는 합성 $TiO_2$-복합체에 대해 압력의 영향을 체크하기 위해 고압실험을 시행하였다. 복합체 분말시료는 아나타제와 루틸 및 염화은으로 구성되어 있으며, 입자크기는 34 nm 정도로 결정되었다. 아나타제와 루틸 모두 약 14~16 GPa 구간에서 $ZrO_2$ (배델레이트)-형태의 결정구조로 상변이하며, 본 실험의 최고압력인 22.7 GPa까지 상변이는 계속된다. 압력을 모두 제거하여 상압 상태가 되면, 루틸은 ${\alpha}-PbO_2$ 구조로 상변이하며 아나타제는 고압의 $ZrO_2$-결정구조가 유지되는 것으로 판단된다. 염화은의 회절피크는 낮은 압력에서 사라지는 것이 관찰되었다.

• 전자공학회논문지
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• 제50권6호
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• pp.305-310
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• 2013

본 연구는 Si/$SiO_2$/Si-sub 구조의 SDB(silicon-direct-bonding) 웨이퍼를 이용한 고온용 압력센서의 제작 및 특성을 연구한 것이다. 압력센서는 SDB 웨이퍼의 첫 번째 층의 단결정 실리콘을 이용하여 압저항을 제작하기 때문에 감도가 우수하며, 두 번째 층의 산화막으로 압저항과 실리콘 기판을 절연 분리하여, 일반적인 실리콘소자의 사용 온도 한계인 $120^{\circ}C$ 이상의 고온에서도 사용이 가능하다. 제작된 압력센서는 고감도의 압력감도 및 센서 출력의 직선성 및 히스테리시스 특성이 매우 우수함을 알 수 있었다.

• Progress in Superconductivity
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• 제10권2호
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• pp.87-91
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• 2009

Fluorine-doped $SmFeAsO_{1-x}F_x$ single crystals with the nominal value of x=0.2 were grown at $1350-1450^{\circ}C$ under the pressure of 3.3 GPa by using the self-flux method. Plate-shaped single crystals in the range of a few-150 ${\mu}m$ in their lateral size were obtained. The detailed crystal structure was analyzed by using the x-ray diffractometry. Superconducting transition temperature, determined by the resistive transition, of a single crystal was about 49 K with a narrow resistive transition width of ${\sim}1$ K. A relatively sharp transition, a low residual resistivity, and a large residual resistivity ratio compared with those reported for $REFeAsO_{1-x}F_x$(RE=Sm, Nd) single crystals indicate the high quality of our single crystals.

• Applied Microscopy
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• 제42권2호
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• pp.111-114
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• 2012

The scanning electron microscopy is an ideal technique for examining plant surface at high resolution. Most hydrate samples, however, must be fix and dehydrate for observation in the scanning electron microscope. Because the microscopes operate under high vacuum, most specimens, especially biological samples, cannot withstand water removal by the vacuum system without morphological distortion. Cryo-techniques can observe in their original morphology and structure without various artifacts from conventional sample preparation. Rapid cooling is the method of choice for preparing plant samples for scanning electron microscopy in a defined physiological state. As one of cryo-technique, high-pressure freezing allows for fixation of native non-pretreated samples up to $200{\mu}M$ thick and 2 mm wide with minimal or no ice crystal damage for the freezing procedure. In this study, we could design to optimize structural preservation and imaging by comparing cryo-SEM and convention SEM preparation, and observe a fine, well preserved Arabidopsis stem's inner ultrastructure using HPF and cryo-SEM. These results would suggest a useful method of cryo-preparation and cryo-SEM for plant tissues, especially intratubule and vacuole rich structure.

• Carbon letters
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• 제16권1호
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• pp.45-50
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• 2015

High crystallinity coke-based activated carbon (hc-AC) is prepared using a potassium hydroxide solution to adsorb carbon dioxide ($CO_2$). The $CO_2$ adsorption characteristics of the prepared hc-AC are investigated at different temperatures. The X-ray diffraction patterns indicate that pitch-based cokes prepared under high temperature and pressure have a high crystal structure. The textural properties of hc-AC indicate that it consists mainly of slit-like pores. Compared to other textural forms of AC that have higher pore volumes, this slit-pore-shaped hc-AC exhibits higher $CO_2$ adsorption due to the similar shape between its pores and $CO_2$ molecules. Additionally, in these high-crystallinity cokes, the main factor affecting $CO_2$ adsorption at lower temperature is the pore structure, whereas the presence of oxygen functional groups on the surface has a greater impact on $CO_2$ adsorption at higher temperature.

• 암석학회지
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• 제10권3호
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• pp.212-221
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• 2001

방사광의 특성과 방사광의 발생원리에 대한 소개를 하였다. 매우 높은 스펙트럼 휘도와 매우 넓은 영역의 스펙트럼 범위, X-선 파장 조절 가능성과 고도의 지향성 및 집속성, 그리고 시간에 따른 순간파동 구조를 갖는 방사광을 이용하여 지질학 및 지구환경과학에 적용할 수 있는 실험기법을 기술하였다. 이에는 X선 토모그라피, XRF, XANES, EXAFS, 다이아몬드 앤빌 기기 및 라지 발륨 프레스를 이용한 고온-고압 연구와 에너지문제와 관련하여 원자력발전과 핵폐기물처리에 대한 것이 포함되어 있다. 이러한 실험기법은 광물 및 암석에 대한 화학성분, 결정구조 및 결합상태 분석이 가능하며, 광상학과 고생물학 및 환경학 분야에 적용할 수 있다. 또한 이 연구방법을 이용하면 지구내부물질의 거동에 관한 정보를 얻을 수 있다.