• Bulletin of the Korean Chemical Society
• /
• 제5권2호
• /
• pp.55-60
• /
• 1984

The NMR shift arising from the electron angular momentum and electron spin dipolar-nuclear spin angular momentum interactions has been investigated for a $4d^1$system in a strong crystal field environment of tetragonal symmetry. A general formula for NMR shift is used to compute the NMR shifts along the (100), (010), (001), (110) and (111) axes. We find that from the computed results, the NMR shift along the (100) and (010) axes is consistent with each other in a strong crystal field environment of tetragonal symmetry, but the NMR shift along the (001) axis is about triply greater in magnitude than those along the (100) and (010) axes and is opposite in sign to those along (100) and (010) axes. In this work, we express the expansion coefficients $a_1^{(i)}$ and $b_1^{(i)}$ of $A_i$ and $B_i$ in terms of $g_m^{(i)}$ and $h_m^{(i)}$ and two matrices $c_{lm}$ and $d_{lm}$ of radial dependence. The NMR shift is also separated into the contributions of multipolar terms. We find that $1/R^3$ term contributes dominantly to the NMR shift along the (100), (010), (001) and (110) axes while along the (111) axis $1/R^5$ term dominantly contributes. However, the contribtions of the other terms may not be negligible.

• Bulletin of the Korean Chemical Society
• /
• 제4권2호
• /
• pp.64-67
• /
• 1983

NMR shift arising from the electron orbital angular momentum and the electron spin dipolar-nuclear spin angular momentum interactions has been investigated for a $4d^{1}$ system in a strong crystal field of octahedral symmetry. To examine the NMR shif for a $4d^{1}$ system in a strong crystal field of octahedral symmetry, we derive a general expression for ${\Delta}$B/B using a nonmultipole expansion technique. From this expression all the multipolar terms are determined. For the $4d^{1}$ system in a strong crystal field of octahedral symmetry the exact solution for NMR shift, ${\Delta}$B, is compared with the multipolar results. ${\Delta}$B/B for the $4d^{1}$ system is also compared with that for the $3d^{1}$ system. It is found that the $1/R^{7}$ term contributes dominantly to the NMR shift. However, there is good agreement between the nonmultipole and multipolar results for R-values larger than 0.2 nm for the $4d^{1}$ system but for R-values larger than 0.4 nm for the $3d^{1}$ system.

• 한국광학회지
• /
• 제26권2호
• /
• pp.110-114
• /
• 2015

본 논문에서는 스위칭 가능한 브래그 반사판의 한 종류인 콜레스테릭 액정 셀에 염료를 주입함으로써 입사각에 따라 단파장대로 이동된 반사광을 제거하는 셀을 구현하였다. 액정과 카이랄 도펀트를 일정 비율로 혼합하여 원하는 파장대역을 반사하는 콜레스테릭 액정 셀을 제작하였고, 이에 특정한 파장대역을 흡수하는 성질을 가지는 이색성 염료를 혼합함으로써, 빛의 입사각이 증가할 때 단파장으로 이동된 빛을 흡수하여 초기에 설계된 색을 유지할 수 있다. 염료를 혼합하지 않은 콜레스테릭 액정 셀에서는 입사각에 따라서 반사 된 빛이 눈에 띄게 단파장대로 이동되는데 반해, 제안된 방법에서는 염료의 혼합 비율이 1, 2 wt%로 증가할수록 단파장대로 이동된 빛을 더 잘 흡수하는 것을 확인하였다.

• Bulletin of the Korean Chemical Society
• /
• 제5권3호
• /
• pp.93-97
• /
• 1984

A general expression using the nonmultipole expansion method is derived for the NMR shift arising from 3d electron angular momentum and the 3d electron spin dipolar-nuclear spin angular momentum interactions for a 3$d^2$ system in a strong crystal field environment of octahedral symmetry when the threefold axis is chosen as the quantization axis. The NMR shift is separated to the contribution of constant, $1/R^5\;and\;1/R^7$ terms and compared with the multipolar terms. We find that $1/R^5$ term contributes dominantly to the NMR shift but the contribution of $1/R^7$ term may not be negligible. It is also found that the exact values of the NMR shift are in agreement with the multipolar results for distances larger than 0.35 nm.

• Bulletin of the Korean Chemical Society
• /
• 제6권2호
• /
• pp.63-67
• /
• 1985

The NMR chemical shift arising from 3d electron spin dipolar nuclear spin angular momentum interactions for a 3d$^2$ system in a strong crystal field environment of octahedral symmetry has been investigated when the fourfold axis is chosen to be our axis of quantization. The NMR shift is separated into the contribution of 1/R$^5$ and 1/R$^7$ terms. A comparision of the multipolar terms with nonmultipolar results shows that the 1/R$^5$ term contributes dominantly to the NMR shift and there is in good agreement between the exact solution and the multipolar results when R ${\ge}$ 0.25. A temperature dependence analysis may lead to the results that the 1/T$^2$ term has the dominant contribution to the NMR shift for a paramagnetic 3d$^2$ system but the contribution of the 1/T term may not be negligible.

• Journal of the Optical Society of Korea
• /
• 제16권2호
• /
• pp.170-173
• /
• 2012

We present a method that enables dual threshold voltages in a vertical alignment liquid crystal device, through which the gamma shift can be reduced with no subsequent decrease in the contrast ratio. By forming polymer layers, the threshold voltage shift is accomplished through the utilization of the voltage drop effect. We expect that the proposed method can be applied to the conventional 4-domain mode in order to achieve an 8-domain mode without the need for complex driving schemes.

• Bulletin of the Korean Chemical Society
• /
• 제6권5호
• /
• pp.255-259
• /
• 1985

The NMR chemical shift arising from 4d electron orbital angular momentum and 4d electron spin dipolar-nuclear Spin angular momentum interactions for a $4d^2$ system in a strong crystal field environment of octahedral symmetry has been investigated when the four fold axis is taken as the quantization axis. The NMR results are comparted with the multipolar shift at various R-values and we find that the exact results are in agreement with the multipolar shift when $R{\geqslant}0.20 nm.$ We also separate the NMR shift into the contribution of the $1/R^5$ and $1/R^7$ terms. It is found that the contribution of the $1/R^5$term to the NMR shift is dominant than the contribution of the $1/R^7$ term. Temperature dependence analysis shows that the $1/T^2$ term is the dominant contribution to the NMR shift for a $4d^2$ system but the contribution of the 1/T term may not negligible. The similar results are obtained for a $4d^1$ system from the temperature dependence analysis.

• 비교문화연구
• /
• 제32권
• /
• pp.167-179
• /
• 2013

This paper focuses on a sociologic approach, the theory of planned behavior (Ajzen 1991) and a sociolinguistic field, the language shift (Fishman 1991, Crystal 2000). It describes the theoretical background of language shift and briefly mentions the history of Hungarian language and Romanian language contacts. After presenting language use of the Hungarian minority students and explaining the theory of planned behavior, it turns to apply the theory of planned behavior to the language shift from the view of bilingual speaker(s). This paper wants to propose the application of the theory of planned behavior in language shift and open new perspective in bilingual research.

• 전자공학회논문지D
• /
• 제35D권3호
• /
• pp.63-69
• /
• 1998

In this paper, a new input method is proposed to improve shift-invariant property of a photorefractive correlator andwe implemented real-time optical pattern recognition system using it. In the conventional photorefractive correlator, it is vrey difficult to satisfy the Bragg condition in the pattern recognition process. So, correlation peak is decreased heavily for the shift of input image. If a liquid crystal television(LCTV) without an anlyzer is used as input device, we can get the correlation result regardless of shift of input image because beam path is not changed during storage of holographic filter and correlation process. Also recording time of a holographic matched filter in photorefractive crystal is reduced and the correlation peak is increased because incident beam on the LCTV is transmitted completely. Therefore total optical efficiency is improved. We compared and analyzed the correlation results of proposed photorefractive correlator by computer simulation and optical experiment. We used a BaTiO$_{3}$ single crystal which has high diffraction efficiency in optical experiment.

• Journal of the Optical Society of Korea
• /
• 제16권4호
• /
• pp.409-413
• /
• 2012

Off-axis color shift in the dark state and gray scale inversion in an in-plane switching (IPS) liquid crystal display (LCD) device were investigated. Analyses were performed using the Poincar$\acute{e}$ sphere representation. The results show that color shift in the dark state and gray scale inversion in an IPS LCD can be reduced by using a biaxial film. We confirmed the extent of these improvements by measuring the optical performance of a fabricated IPS LCD.