• Journal of the Korean Ceramic Society
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• v.50 no.3
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• pp.212-217
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• 2013

Ultra hard TiN coatings were fabricated by DC and ICP (inductively coupled plasma) magnetron sputtering techniques. The effects of ICP power, ranging from 0 to 300 W, on the coating microstructure, crystallographic, and mechanical properties were systematically investigated with FE-SEM, AFM, HR-XRD and nanoindentation. The results show that ICP power has a significant influence on the coating microstructure and mechanical properties of TiN coatings. With an increasing ICP power, the film microstructure evolves from an apparent columnar structure to a highly dense one. Grain sizes of TiN coatings decreased from 12.6 nm to 8.7 nm with an increase of the ICP power. A maximum nanohardness of 67.6 GPa was obtained for the coatings deposited at an ICP power of 300 W. The crystal structure and preferred orientation in the TiN coatings also varied with the ICP power, exerting an effective influence on film nanohardness.

• Journal of the Korean institute of surface engineering
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• v.36 no.1
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• pp.1-8
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• 2003

In general, the microstructure in thin films was known to evolve in similar manner according to the energy striking the condensing film at similar homologous temperature, Th for the materials of the same crystal structure. The fundamental factors affecting particle energy are a function of processing parameters such as working pressure, bias voltage, target/sputtering gas mass ratio, cathode shape, and substrate orientation. In this study, Al, Cu, Pt films of the same crystal structure of face centered cubic (FCC) have been prepared under various processing parameters. The influence of processing variables on the microstructures and residual stress states in the films has been studied.

• Coupled systems mechanics
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• v.6 no.1
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• pp.41-54
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• 2017

Shape-memory alloys (SMA) have interesting behaviors and important mechanical properties due to the solid-solid phase transformation. These phenomena are dominated by the evolution of microstructures. In recent years, the microstructures in SMAs have been studied extensively and modeled using molecular dynamics (MD) simulations. However, it remains difficult to identify the crystal variants in the simulation results, which consist of large numbers of atoms. In the present work, a method is developed to identify the austenite phase and the monoclinic martensite crystal variants in MD results. The transformation matrix of each lattice is calculated to determine the corresponding crystal variant. Evolution of the volume fraction of the crystal variants and the microstructure in Ni-Ti SMAs under thermal and mechanical boundary conditions are examined. The method is validated by comparing MD-simulated interface normals with theoretical solutions. In addition, the results show that, in certain cases, the interatomic potential used in the current study leads to inconsistent monoclinic lattices compared with crystallographic theory. Thus, a specific modification is applied and the applicability of the potential is discussed.

• The Journal of Korean Academy of Prosthodontics
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• v.36 no.5
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• pp.772-785
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• 1998

This study was undertaken to clarify the microstructure of the different IPS Empress ingots by etching and to observe the change of leucite crystal structure according to subsequent heat treatment and the crystal distribution according to sprue types(${\phi}2.8mm$, single sprue; ${\phi}1.8mm$, double sprue) by scanning electron microscopy. IPS Empress T1, O1 ingots used for staining technique, and Dentin(A2) ingots used for layering technique were selected for this study. To observe the microstructures of these ingots before pressing, the specimens were prepared in splinters($3{\times}3{\times}3mm$) taken from the original ingots. And to estimate crystal distribution and microstructural change by sprue type and subsequent heat treatment. the specimens($3{\times}3{\times}3mm$) were heat-pressed through the two types of sprues with different diameters and numbers, and all specimens were fired according to the recommended firing schedule. The observed surface was ground with waterproof papers($#800{\sim}#1800$) on the grind polisher and was cleaned ultrasonically. All specimen were etched with 0.5% hydrofluoric acid. After etching, the surface was treated by ion sputter coating for SEM observation at an accelerating voltage of 20kV. In all specimens, the central area of ground surface was observed because there was less difference in microstructure between the peripheral area and the central area. The results were as follows ; 1. In the microstructure according to the ingot type, there was a wide difference between the staining (T1,O1) and layering(Dentin A2) ingots, but there was not a considerable difference between the T1 ingot and the O1 ingot for staining technique. 2. In all specimens, the crystal dispersion of IPS Empress ceramic using double sprue was significantly more scattered than that of IPS Empress ceramic using single sprue. The degree of scattering was strongest in the Dentin(A2) specimen and weakest in the O1 ingot. 3. In the microstructural change according to the subsequent heat treatment, all of ingots had some microcracks in the inside of the leucite crystal and the glass matrix after pressing. The inner splinters of the leucite crystal became smaller, and more microcracks occurred in the glass matrix due to increasing heat treatment times. 4. The size of leucite crystals varied from $1{\mu}m\;to\;5{\mu}m$. The mean size of mature crystals was about $5{\mu}m$. The form of the crystal was similar to a circle when it was smaller and similar to an ellipse when it was larger.

• Proceedings of the Korean Society for Technology of Plasticity Conference
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• 2003.10b
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• pp.40-42
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• 2003

The aim of this paper is to illustrate which factors influence the martensite grain fineness made by subsequently surface carburizing of extruded component. The effects of surface decarburizing by annealing, residual stress, initial microstructure and crystal oriental made by forward extrusion were taken into account. The available evidence suggests that the residual stress inside crystal or the crystal orientation is the main factor that results coarse martensite while cold extruded component was treated by carburizing.

• Journal of the Korean Ceramic Society
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• v.33 no.7
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• pp.809-815
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• 1996

When Li2O.2SiO2 glass was crystallized between the temperature of maximum nucleation and the temperature of maximum crystal growth it was found that the control of heating rate had serious effect on the crystallinity and microstructure and the greatly changed physical properties. Density and elastic modulus tends to increase but thermal expansion coefficient decreased with increased crystallinity. When heating rate between the tempe-rature of maximum nucleation and the temperature of maximum crystal growth was 10~5$0^{\circ}C$/hr. crystallinity was increased to result in the increment of strength. When nuclation was done at 44$0^{\circ}C$ for 5 hours and the temperature of crystal growth was held at 575$^{\circ}C$ strength was increased until crystallinity reached 65% and strength was decreased with higher crystallinity. These phenomena could be explained that even for the same crystallinity different heat rates resulted in different number and size of cracks.

• Proceedings of the Korea Association of Crystal Growth Conference
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• 1996.06a
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• pp.502-504
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• 1996

• Proceedings of the Korea Association of Crystal Growth Conference
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• 1996.06a
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• pp.529-530
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• 1996

• Journal of the Korean Ceramic Society
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• v.26 no.1
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• pp.139-145
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• 1989

An eutectic melt in the system(Bi2O3)0.85·(Nb2O5)0.15-6Bi2O3·SiO2 was unidirectionally solidfield at a rate of 0.5mm/h under a thermal gradient of 100℃/cm. Double crucibles and seed crystal plate were used in order to botain the composite crystals which had uniform microstructure throughout the ingot. The obtained composite crystals showed uniform microstructure, in which needle-like δ-(Bi2O3)0.85·(Nb2O5)0.15 crystals were arrayed in parallel in a matrix of γ-6Bi2O3·SiO2 single crystal. It was found that the <110> direction of δ-(Bi2O3)0.85·(Nb2O5)0.15 crystal was essentially parallel to the <111> direction of γ-6Bi2O3·SiO2 crystal in the composite crystals. A transverse thin plate of the composite crystals showed a high resolution optical transmission like an optical fiber array, and sharp chatoyancy was observed in the cabochon shaped composite crystals. Then, this may be useful for applications such as screen of a cathode ray tube or artificial cat's eye gem stones.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.29 no.4 s.235
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• pp.511-517
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• 2005

Fretting fatigue is often the root cause of the nucleation of cracks at attachments of structural components. Since fretting fatigue damage accumulation occurs over relatively small volumes, the subsurface cyclic plastic strain is expected to be rather non-uniformly distributed in polycrystalline materials. The scale of the cyclic plasticity and the damage process zones is often on the order of microstructure dimensions. Fretting damage analyses using cyclic crystal plasticity constitutive models have the potential to account for the influence of size, morphology, and crystallographic orientation of grains on fretting damage evolution. Two-dimensional plane strain simulations of fretting fatigue are performed using the cyclic properties of Ti-6Al-4V. The crystal plasticity simulations are compared to an initially isotropic $J_{2}$ theory with nonlinear kinematic hardening as well as to experiments. The influence of initially isotropic versus textured microstructure in the presence of crystallographic slip is studied.