• Transactions of Materials Processing
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• v.28 no.1
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• pp.15-20
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• 2019

The superplastic forming/diffusion bonding process has been developed to fabricate a core frame structure with joint nodes out of tubes, for the development of a titanium high performance bicycle. The hydroforming process has been applied for bulging of a tube in the superplastic condition before, and during the diffusion bonding process. In this experiment, a commercial Ti-3Al-2.5V tube was selected as raw material for the study. The forming experiment has been performed using a servo-hydraulic press with a capacity of 200 ton. Next, nitrogen gas was used to acquire necessary pressure for the bulging and bonding of the tubes to fabricate the joint nodes. The pertinent processing temperature was $870^{\circ}C$ for the superplastic hydroforming/diffusion bonding (SHF/DB) process, using the Ti-3Al-2.5V tube. The bonding quality and the progress of bulging and diffusion bonding have been observed by the investigation of the joining interfaces at the cross section of the joint structure. The control of the nitrogen pressure throughout the SHF/DB process, was an important factor to avoid any significant defects in the joint structure. The whole progress stage of the diffusion bonding could be observed at a joint interface. A core structure with 5 joint nodes to manufacture a titanium bicycle could be obtained in a SHF/DB process.

• Journal of the Korean Wood Science and Technology
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• v.44 no.4
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• pp.607-615
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• 2016

The delamination along the annual ring on the cross-section of laminae and the bonding strength according to the tangential angle between laminae were evaluated for the production of 3-ply cross-laminated timber (CLT) using domestic larch. Since there is no standard for CLT in Korea, the production and test of specimens for bonding strength followed the standard procedure of "Structural glued laminated timber" (KS F 3021). The standard specifies to exclude any measurement from the cracks of timbers resulted from drying or knots during delamination test of the glued laminated timbers. However, the failure of cross-sectional tissues along the annual rings was observed near the glue-line of all specimens during the delamination test. Because this phenomenon can generate defects in the CLT that may be exposed to various temperatures and relative humidities after the actual construction, the delamination percentage was measured by including this wood failure. As a result, the delamination percentage of the CLT which had been combined in such a way that the annual rings of outer lamina were directed inward was the lowest, which was around 13%, regardless of the annual ring direction of the middle lamina. On the other hand, the delamination percentage of the CLT which had been combined in such a way that the annual rings of outer lamina were directed outward was the highest, which was around 26%. Furthermore, end-split occurred in the outer lamina during the drying process of the boiling delamination test, which affected the delamination percentage. Therefore, the soaking delamination test was found to be more appropriate for evaluating the delamination strength of CLT. The block shear strength of larch CLT was $3.9{\pm}0.9$ MPa on average, which was 46% lower than the block shear strength requirement (7.1 MPa) of the standard, but satisfied the criteria of the block shear strength (3.5 MPa) of the European Standard (prEN 16351: 2013).

• Membrane Journal
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• v.10 no.3
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• pp.148-154
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• 2000

Poly(vinyl alcohol)(PVA)/sulfur-siccinic acid(SSA) membrane performances have been studied for the vapor permeation separation of methyl tort-butyl ether(MTBE)/methanol mixtures with varying operation temperatures, amount of cross-linking agents, and feed compositions. 1'here are two factors, the membrane network and the hydrogen bonding, in the swelling measurements of PVA/SSA membranes. These two factors act interdependently on the membrane swelling. The sulfuric acid group in SSA took an important role in the membrane performance. The cross-linking effect might be more dominant than the hydrogen bonding effect due to the sulfuric acid group at 7% SSA membrane. Hydrogen bonding effect was more important for 5% SSA membrane. In vapor permeation, density or concentration of methanol in vapor feed is lower than that of methanol in liquid feed, as a result, the hydrogen bonding portion between the solvent and the hydroxyl group in PVA is reduced in vapor permeation. In this case, the 7% SSA membrane shows the highest separation factor of 2187 with the flux of 4.84g/$m^2$hr for MTBE/methanol=80/20 mixtures at 3$0^{\circ}C$.

• The Bulletin of The Korean Astronomical Society
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• v.36 no.2
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• pp.125.2-125.2
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• 2011

We are developing medium resolution cross-dispersed silicon grisms in the near IR region ($1.45{\sim}5.2{\mu}m$). The grisms will be installed in MIMIR, a multifunction instrument at the Lowel Observatory, USA. The two devices are designed to cover H and K band and L and M band simultaneously. Our goal is to make grism with R=3000 at 1.2 arcsec slit. The Silicon has high refractive index (n=3.4 at $1.5{\mu}m$) which enhances the resolving power by up to 5 times when compared to conventional material such as BK-7 (n=1.5 at 1.5 ${\mu}m$). The bonded grisms will be installed in a filter wheel for the uses switch from spectroscopic mode to imaging mode easily. Our device is compact and light weighted while it provides a decent resolving power. We produce monolithic grisms using e-beam lithography at the NASA JPL and chemically etching the grooves on the silicon prisms. Moreover, the main-disperser and cross-disperser will be contacted together by direct Si-Si bonding technique and eventually turn into one piece. The bonded pair offers more stability in terms of the layout of the spectrum and removes the Fresnel loss at the intersection of two grisms. We report on the proper wafer bonding steps through this research, and inspected the bonding quality thermally, optically and mechanically.

• Journal of the Korean Wood Science and Technology
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• v.52 no.1
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• pp.58-69
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• 2024

To evaluate the adhesive characteristics of mixed cross-laminated timber (CLT) using domestic softwoods structural lumber proposed by KS F 3020 and yellow poplar, penetration depth of adhesive and thickness of bonding line were analyzed based on the results of boiling water soaking delamination. 3 Types of adhesives and 2 types of major layer were divided into a 5 ply CLT using yellow popular as minor layer. The bonding performance of the mixed CLT as structural members was evaluated based on the KS F 2081. The thickness of bonding line between layers of the mixed CLT was measured with a scanning electron microscope, and the adhesive penetration depth in the layer members was measured with an optical microscope. As a result of boiling water soaking delamination test of mixed CLT, the CLT specimens using PRF and PUR adhesives met the requirements of KS F 2081. It was verified that the penetration path of the adhesive in the layes was mainly through the tracheid cell in the case of Japanese larch and Korean red pine layers, and through the vessel and radial tissue in yellow popular layers. The penetration depth of the adhesive was the highest for the PRF adhesive under the same pressing time conditions, and the thickness of the bonding line was in inverse proportion to the penetration depth in the case of the PUR adhesive.

• Journal of the Korean Wood Science and Technology
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• v.47 no.5
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• pp.655-662
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• 2019

This study evaluated the multi-bonding performances of timbers as well as those of reinforcement and timber to obtain data for preparing guidelines regarding the use of timbers as large structural members. For the multi-bonding performances of timbers, four types of bonding surfaces were prepared according to the pith position. For the bonding performances of FRP (fiber-reinforced plastic)/steel plate and timber, a total of 11 types of specimens were produced for the selection of the appropriate adhesive. The bonding performances of the produced specimens were evaluated through a water soaking delamination test, a water boiling delamination test, and a block shear strength test. The test results showed that the bonding strength of the bonding surface according to the pith position was highest in the specimen for which the two sections with the pith at the center of the cross-section on timber and between the bonding surfaces (the tangential and radial sections were mixed) were bonded. Furthermore, the specimens for which the section (radial section) with the pith on the bonding surface of the timber was bonded showed a high delamination percentage. The results of the block shear strength test showed that the bonding section did not have a significant effect on the shear strength, and that the measured wood failure percentage was higher than the KS standard value. The PVAc adhesive showed the highest bonding strength between larix timber and GFRP (glass FRP). Furthermore, the epoxy and polyurethane adhesives showed good bonding strength for CFRP (carbon FRP) and structure steel, respectively.

• Journal of Surface Science and Engineering
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• v.54 no.5
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• pp.207-212
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• 2021

The mechanical and electrical characteristics can be improved in 3D stacked IC technology which can accomplish the ultra-high integration by stacking more semiconductor chips within the limited package area through the Cu direct bonding method minimizing the performance degradation to the bonding surface to the inorganic compound or the oxide film etc. The surface was treated in a ultrasonic washer using a diamond abrasive to remove other component substances from the prepared cast plate substrate surface. FE-SEM was used to analyze the bonding characteristics of the bonded copper substrates, and the cross section of the bonded Cu conjugates at the sintering junction temperature of 100 ℃, 150 ℃, 200 ℃, 350 ℃ and the pressure of 2303 N/cm² and 3087 N/cm². At 2303 N/cm², the good bonding of copper substrate was confirmed at 350 ℃, and at the increased pressure of 3087 N/cm², the bonding condition of Cu was confirmed at low temperature junction temperature of 200 ℃. However, the recrystallization of Cu particles was observed due to increased pressure of 3087 N/cm² and diffusion of Cu atoms at high temperature of 350 ℃, which can lead to degradation in semiconductor manufacturing.

• Membrane Journal
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• v.19 no.4
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• pp.310-316
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• 2009

The degradation characteristics of cross-linked lactide/hyaluronic acid (LA/HA) membranes were investigated for purpose of applying to tissue engineering. The lactide/hyaluronic acid cross-linked with 1,3-butadiene diepoxide (BD) and 1-ethyl-3-(3-dimethyl aminopropyl) carbodiimide (EDC) was degradated in deionized water in water bath at $37^{\circ}C$. As the LA/HA mole ratio or crosslinking agent concentration decreased, the degradation rate of the crosslinked membranes increased. In order to investigate the structure change of the membrane in the degradation process, the control sample and 3, 6, 9 days-degradated samples were analysed by the nuclear magnetic resonance spectroscopy. In case of the membranes crosslinked with EDC, the HA-EDC bonding structure was degradated slowly whereas the HA-LA bonding structure was degradated quickly and dissappeared completely after 6 days. In case of the membranes crosslinked with BD, all the crosslinked bonding structure degradated slowly. The HA-BD bonding structure maintained its original state about 89, 83% in case of 3, 6 days-degardated samples respectively whereas the HA-LA bonding structure maintained its original state about 83, 65%. The scanning electron microscopy of the degradated membranes showed that the pore density in the surface, and the structure in the surface and cross section, of the before and after-degradation membranes did not change greatly, so the membranes was shown to be applied to materials for tissue engineering.

• Journal of the Institute of Electronics Engineers of Korea SD
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• v.42 no.6 s.336
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• pp.17-22
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• 2005

Organic-inorganic hybrid type thin films are the next generation candidates as low-k materials. SiOC films are analyzed the bonding structure by the red and blue chemical shift using the fourier transform infraredspectra. Conventional chemical shift of organic chemistry is a red shift, but hybrid type SiOC films were observed the red and blue shift. The chemical shift originates from the interaction between the C-H bond and high electronegative atoms, and the blue shift in SiOC films is caused by the porosity due to the increase of the electron rich group such as much methyl radicals. The bonding structures of SiOC films are also divided into the Si-O-C cross-link structure and the Si-O-C cage-link structure due to the chemical shifts. The Si-O-C cross-link structure progressed the adhesion attributed to the C-H bond elongation in the reason of the red shift, and the dielectric constant also decreases.

• Journal of the Korean Wood Science and Technology
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• v.41 no.2
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• pp.158-163
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• 2013

Cross laminated timber (CLT) has been an rising issue as a promising building material replacing steel-concrete in mid story rise construction. But, there was no specific standard for CLT because it had been developed in industrial section. Recently, new draft for requirements of CLT was proposed by EN which suggested to evaluate the performance of adhesive in CLT by the same method as glulam. But, it has been reported that shear performance of cross laminated timber is governed by rolling shear. Therefore, block shear tests were carried out to compare parallel to grain laminating and cross laminating using commercial one component PUR (Poly urethane resin). The result showed that the current glulam standard for evaluating bonding performance is not appropriate for CLT. Beacause shear strength of cross laminating decreased to 1/3 of parallel to grain laminating and this strength was representing shear performance of wood itself not the bond. However, cross laminating showed no significant effect on wood failure. Thus, wood failure can be used as a requirement of CLT bonding. Based on the results, cross laminating effect should be included when evaluating adhesive performance of CLT correctly and should be considered as an important factor.