• 제목/요약/키워드: Cross linking

검색결과 662건 처리시간 0.03초

우리 학회 활성화 방안

  • 한만청
    • 대한의용생체공학회:의공학회지
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    • 제10권2호
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    • pp.89-90
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    • 1989
  • To develop an artificial bone substitute that is gradually degraded and replaced by the regenerated natural bone, the authors designed and produced a composite that is consisted of calcium phosphate and collagen. Human umbilical cord origin pepsin treated type I atelocollagen was used as the structural matrix, by which sintered or non-sintered carbonate apatite was encapsulated to form an inorganic-organic composite. With cross linking atelocollagen by UV ray irradiation, the resistance to both compressive and tensile strength was increased. Collagen degradation by the collagenase induced collagenolysis was also decreased.

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코폴리에테르에스테르 고무 탄성체의 물성에 미치는 가교제의 효과 (Effect of cross-linking agents on the properties of copolyetherester elastomer)

  • Jang, Young-Joo;Kim, Hae-Young;Baik, Doo-Hyun
    • 한국섬유공학회:학술대회논문집
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    • 한국섬유공학회 2001년도 가을 학술발표회 논문집
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    • pp.355-358
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    • 2001
  • Copolyetheresters are us,ed as an engineering thermoplastic elastomer due to their excellent mechanical properties, thermooxidative stability up to high temperatures and a good resistance against many chemicals. However, fibers made from the copolyetheresters exhibited elastic recovery of about 80-85% after being stretched 200%, while spandex fibers usually showed 90-95% recovery. (omitted)

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STUDY PROCESSES OF INTUMESCENCE IN FIRE-PROTECTING COATINGS

  • Efremov, V.L.;Paltseva, N.G.;Leiman, Z.A.
    • 한국전기전자재료학회:학술대회논문집
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    • 한국전기전자재료학회 2005년도 하계학술대회 논문집 Vol.6
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    • pp.657-658
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    • 2005
  • Flame retard of polymers was studied for prevention from burning by various additives stimulated the char formation during heating and thermal degradation of polymer materials. Forming char have high porosity, low thermal conductivity and act as thermal shield for heat transmission from the flame to the polymer and. oxygen towards the polymer. The results showed that various additives may regulate the processes of intumecsence. The efficient fire protective intumescent char was result of processes of melting, gas evolution, cross-linking, carbonization etc.

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PVP-기반 유기 절연막 형성과 OTFT 제작 (Formation of PVP- Based Organic Insulating Layers and Fabrication of OTFTs)

  • 장지근;서동균;임용규
    • 한국재료학회지
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    • 제16권5호
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    • pp.302-307
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    • 2006
  • The formation and processing of organic insulators on the device performance have been studied in the fabrication of organic thin film transistors (OTFTs). The series of polyvinyls, poly-4-vinyl phenol(PVP) and polyvinyltoluene (PVT), were used as solutes and propylene glycol monomethyl ether acetate(PGMEA) as a solvent in the formation of organic insulators. The cross-linking of organic insulators was also attempted by adding the thermosetting material, poly (melamine-co-formaldehyde) as a hardener in the compound. The electrical characteristics measured in the metal-insulator-metal (MIM) structures showed that insulating properties of PVP layers were generally superior to those of PVT layers. Among the layers of PVP series: PVP(10 wt%) copolymer, 5 wt% cross-linked PVP(10 wt%), PVP(20 wt%) copolymer, 5 wt% cross-linked PVP(20 wt%) and 10 wt% cross-linked PVP(20 wt%), the 10 wt% cross-linked PVP(20 wt%) layer showed the lowest leakage current characteristics. Finally, inverted staggered OTFTs using the PVP(20 wt%) copolymer, 5 wt% cross-linked PVP(20 wt%) and 10 wt% cross-linked PVP(20 wt%) as gate insulators were fabricated on the polyether sulphone (PES) substrates. In our experiments, we could obtain the maximum field effect mobility of 0.31 $cm^2/Vs$ in the device from 5 wt% cross-linked PVP(20 wt%) and the highest on/off current ratio of $1.92{\times}10^5$ in the device from 10 wt% cross-linked PVP(20 wt%).

A New Alternative Hole-transporting Layer to PEDOT:PSS for Realizing Highly Efficient All Solution-processable PLEDs

  • Kang, Beom-Goo;Kang, Hong-Kyu;Lee, Kwang-Hee;Lee, Chang-Lyoul;Lee, Jae-Suk
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2012년도 제42회 동계 정기 학술대회 초록집
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    • pp.362-363
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    • 2012
  • A new cross-linkable polymer, cross-linked d-PBAB, which has the triphenylamine as the hole transporting moiety and ethynyl group as the thermal cross-linker is firstly synthesized by the combination of anionic polymerization and deprotection process. The thermal cross-linking reaction was performed at $240^{\circ}C$ for 50 min and cross-linked d-PBAB layer showed smooth surface and is not soluble at organic solvent under spin-coating of emitting layer (EML). The solution-processed PLED which was fabricated with cross-linked d-PBAB as HTL showed approximately two times higher Lmax and four times higher LEmax than those obtained from PLED with PEDOT:PSS as the HTL. These result is ascribed to better ability of cross-linked d-PBAB to block electrons and to prevent exciton-quenching than those of PEDOT : PSS at the EML interface. This results strongly suggested that cross-linked d-PBAB can be a promising material to replace conventional PEDOT : PSS. It can be suspected that PLEDwith cross-linked d-PBAB would show longer lifetime compared with that of PLED with PEDOT : PSS, and thus further studies are under investigation.

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효소 특성 개선을 위한 Exiguobacterium sp. β-glucosidase의 키토산 비드에 효소 고정화 (Immobilization of β-Glucosidase from Exiguobacterium sp. DAU5 on Chitosan Bead for Improved Enzymatic Properties)

  • 창지에;박인혜;이용석;정수열;방숙군;슈보쉬 찬드라;최용락
    • 생명과학회지
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    • 제20권11호
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    • pp.1589-1594
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    • 2010
  • Exiguobacterium sp. 유래의 $\beta$-glucosidase 고정을 위하여 글루타르알데하이드를 사용한 키토산 비드를 조제하였다. 키토산 비드의 교차결합 및 고정화의 조건을 최적화하였다. $\beta$-glucosidase 고정화의 최적생산 조건에서 20%의 수율과 5.22 U/g의 효소활성을 나타냈다. 최적 pH 와 온도는 9.0과 $55^{\circ}C$를 나타냈다. 고정된 효소의 안정성은 pH 7.0-10.0에서는 80%, $40^{\circ}C$ 2시간 반응에서는 80% 및 $50^{\circ}C$ 1시간 반응에서는 48%의 활성을 보유하였다. 이러한 결과는 높은 pH와 고온에서 비고정 효소보다 안정성을 보여주었다. 고정된 효소를 가지고 대두 이소플라본 배당체의 높은 가수분해능을 확인하였다. 이상의 결과는 고정화 효소의 다양한 이용 가능성을 시사하였다.

Cycling Performance of Li4Ti5O12 Electrodes in Ionic Liquid-Based Gel Polymer Electrolytes

  • Kim, Jin-Hee;Kang, Yong-Ku;Kim, Dong-Won
    • Bulletin of the Korean Chemical Society
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    • 제33권2호
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    • pp.608-612
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    • 2012
  • We investigated the cycling behavior of $Li_4Ti_5O_{12}$ electrode in a cross-linked gel polymer electrolyte based on non-flammable ionic liquid consisting of 1-butyl-1-methylpyrrolidinium bis(trifluoromethanesulfonyl) imide and vinylene carbonate. The $Li_4Ti_5O_{12}$ electrodes in ionic liquid-based gel polymer electrolytes exhibited reversible cycling behavior with good capacity retention. Cycling data and electrochemical impedance spectroscopy analyses revealed that the optimum content of the cross-linking agent necessary to ensure both acceptable initial discharge capacity and good capacity retention was about 8 wt %.

교과학습과 연계한 학습독서의 실제 (A Practice of Reading to Learn Linking the Subject Learning)

  • 송기호
    • 한국도서관정보학회지
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    • 제38권1호
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    • pp.423-441
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    • 2007
  • 독서능력은 학생의 문제해결능력과 자기주도 학습능력 그리고 평생학습능력을 위한 핵심능력이며, 학습독서는 자원기반학습이나 탐구기반학습을 통해서 이루어진다. 본 연구에서는 학습독서의 한 방법으로서 통합교육과정을 제시하고 있는데, 이 방법은 교과교사와의 협력을 통해서 완성된다. 특히 본 연구에서는 통합교육과정과 협동수업을 위한 구체적인 학습모형으로서 독서기반 정보문제 해결모형을 소개한다.

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격자화 효소결정;전자이동 중개체에 대한 알콜 탈수소격자화 효소결정의 안정도 (Cross-Linked Enzyme Crystal(CLEC);Stability of Horse Liver Alcohol Dehydrogenase CLEC against Electron Transfer Mediators)

  • 이강민
    • 대한화학회지
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    • 제45권1호
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    • pp.61-66
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    • 2001
  • 효소결정을 격자화하여 안정화한 CLEC은 생촉매제로써 뿐아니라 효소센서로 이용할 수 있다. 전자이동 중개체로 사용되고 있는 PMS는 HLADH에 대하여 가장 효율적인 전자이동 활성도를 가졌다. NQS는 PMS에 비하여 52%, phenothiazine은 37%, ferrocene aldehyde는 3 5%의 전자 이동 활성도를 가졌다. HLADH는 용액상태에서 PMS, NQS에 대하여 매우 불안정하였다. 반면에 HLADH-CLEC은 용액상태에서 불안정했던 PMS, NQS, ferrocene aldehyde에 대하여 매우 안정하였다.

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