• Korean Chemical Engineering Research
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• v.60 no.4
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• pp.588-593
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• 2022

Terephthalaldehyde (TPA) is introduced as a cross liker to enhance electron transfer of hemin-based cathodic catalyst consisting of polyethyleneimine (PEI), carbon nanotube (CNT) for hydrogen peroxide reduction reaction (HPRR). In the cyclic voltammetry (CV) test with 10 mM H₂O₂ in phosphate buffer solution (pH 7.4), the current density for HPRR of the suggested catalyst (CNT/PEI/hemin/PEI/TPA) shows 0.2813 mA cm^-2 (at 0.2 V vs. Ag/AgCl), which is 2.43 and 1.87 times of non-cross-linked (CNT/PEI/hemin/PEI) and conventional cross liker (glutaraldehyde, GA) used catalyst (CNT/PEI/hemin/PEI/GA), respectively. In the case of onset potential for HPRR, that of CNT/PEI/hemin/PEI/TPA is observed at 0.544 V, while those of CNT/PEI/hemin/PEI and CNT/PEI/hemin/PEI/GA are 0.511 and 0.471 V, respectively. These results indicate that TPA plays a role in facilitating electron transfer between the electrodes and substrates due to the π-conjugated cross-linking bonds, whereas conventional GA cross-linker increases the overpotential by interrupting electron and mass transfer. Electrochemical impedance spectroscopy (EIS) results also display the same tendency. The charge transfer resistance (R_ct) of CNT/PEI/hemin/PEI/TPA decreases about 6.2% from that of CNT/PEI/hemin/PEI, while CNT/PEI/hemin/PEI/GA shows the highest R_ct. The polarization curve using each catalyst also supports the superiority of TPA cross liker. The maximum power density of CNT/PEI/hemin/PEI/TPA (36.34±1.41 μWcm^-2) is significantly higher than those of CNT/PEI/hemin/PEI (27.87±0.95 μWcm^-2) and CNT/PEI/hemin/PEI/GA (25.57±1.32 μWcm^-2), demonstrating again that the cathode using TPA has the best performance in HPRR.

• Korean Journal of Materials Research
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• v.19 no.2
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• pp.90-94
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• 2009

The development of low-k materials is essential for modern semiconductor processes to reduce the cross-talk, signal delay and capacitance between multiple layers. The effect of the $CH_4$ concentration on the formation of SiOC(-H) films and their dielectric characteristics were investigated. SiOC(-H) thin films were deposited on Si(100)/$SiO_2$/Ti/Pt substrates by plasma-enhanced chemical vapor deposition (PECVD) with $SiH_4$, $CO_2$ and $CH_4$ gas mixtures. After the deposition, the SiOC(-H) thin films were annealed in an Ar atmosphere using rapid thermal annealing (RTA) for 30min. The electrical properties of the SiOC(-H) films were then measured using an impedance analyzer. The dielectric constant decreased as the $CH_4$ concentration of low-k SiOC(-H) thin film increased. The decrease in the dielectric constant was explained in terms of the decrease of the ionic polarization due to the increase of the relative carbon content. The spectrum via Fourier transform infrared (FT-IR) spectroscopy showed a variety of bonding configurations, including Si-O-Si, H-Si-O, Si-$(CH_3)_2$, Si-$CH_3$ and $CH_x$ in the absorbance mode over the range from 650 to $4000\;cm^{-1}$. The results showed that dielectric properties with different $CH_4$ concentrations are closely related to the (Si-$CH_3$)/[(Si-$CH_3$)+(Si-O)] ratio.

• Korean Journal of Clinical Pharmacy
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• v.7 no.2
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• pp.51-63
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• 1997

The effect of cimetidine administration on the pharmacokinetic parameters of cyclosporine were determined in healthy voluteers. This study was performed in 10 volunteers of age ranged 22-48 years and body weight 48-62 kg. This study was performed with cross-over design. Mono cyclosporine and cyclosporine metabolites was extracted from whole blood analysed by fluororescence polarization immune assay (TDX-FLX, Abbott). After coadministration of cimetidine (300 mg) with cyclosporine (300 mg) orally, maximum concentration of mono cyclosporine was significantly increased $1221{\pm}143\;ng/ml\;to\;1562{\pm}184\;ng/ml$ (P<0.05), area under the time curve of cyclosporine (12 hr) also was significantly increased $7478{\pm}829\;ng/ml{\cdot}hr\;to\;9721{\pm}879\;ng/ml{\cdot}hr$ (P<0.05) and absolute baioavailability of cyclosporine was increased $50\pm5.6\%\;to\;57.6\pm6.1\%\;(P<0.05)$ compared to control group. The blood concentrations of cyclopsorine metabolites were significantly decrased (P<0.05) after coadministration of cimetidine. In cimetidine pretreated group, blood mono cyclosporine concentrations were increased significan시y $1220.0\pm203.00\;ng/ml\;to\;1510.0\pm204.00\;ng/ml$ compared with control group (P<0.05). In the mono cyclosporine pharmacokinetic parameter after oral administration absorption rate and maximum concentration were significantly higher in cimetidine coadministered and pretreated group than control group (P<0.05). The ratio of metabolites and mono cyclosporine concentrations was decreased significantly from $70.8\%\;in\;control\;to\;34.8\%$ in coadministration of cimetidine orally. As matter of facts these reults are considered to inhibition of cyclosporine hepatic metabolism and increasing of cyclosporine absorption rate in gastrointestinal tract because of maintaining cyclosporine stability in elevated gastric pH by cimetidine. We considered, it appeares that cimetidine increase bioavailability of cyclosporine by increasing oral absorption and by decreasing hepatic clearance. But the absorption and clearance of cyclosporine was highly variable individually, and therefore we consider that cyclosporine blood level monitoring would be essential in patients with cimetidine co-administration.

• Journal of electromagnetic engineering and science
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• v.12 no.1
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• pp.101-106
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• 2012

In this study, we investigated the effect of groove pattern and gap-fill with lossy materials at 15 GHz frequency of Ku-band. We used Epoxy/MWCNT composite materials as gap-fill materials. Although epoxy does not have an absorbance capability, epoxy added conductive fillers, which are multi-walled carbon nanotubes (MWCNT), can function as radar absorbing material. Specimens were fabricated with different MWCNT mass fractions (0, 0.5, 1.0, 2.0 wt%) and their permittivity in the Ku-band was measured using the waveguide technique. We investigated the effect of gap-fill on monostatic RCS by calculating RCS with and without gap-fill. For arbitrarily chosen thickness and experimentally obtained relative permittivity, we chose the relative permittivity of MWCNT at 2 wt% (${\varepsilon}_r$=8.8-j2.4), which was the lowest reflection coefficient for given thickness of 3.3 mm at V-pol. and $80^{\circ}$ incident angle. We also checked the monostatic RCS and the field intensity inside the groove channel. In the case of H-pol, gap-fill was not affected by the monostatic RCS and magnitude was similar with or without gap-fill. However, in the case of V-pol, gap-fill effectively reduced the monostatic RCS. The field intensity inside the groove channel reveals that different RCS behaviors depend on the wave polarizations.

• The Journal of Korean Institute of Electromagnetic Engineering and Science
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• v.19 no.4
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• pp.451-460
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• 2008

Gregorian offset dual-shaped reflector antennas have been widely used in the satellite communication systems for their high gain and low sidelobe characteristics. However, in this paper, it is designed as the CATR(Compact Antenna Test Range) reflector system, and its near-field characteristics are investigated. The CATR facility needs to provide an uniform plane wave with the minimum amplitude and phase ripple and the low cross polarization to the test region. Therefore, the reflector near-field patterns are calculated and presented with the variations of the aperture power distribution, the feed horn pattern, and the distance from the aperture to the test zone. Also, the offset dual-shaped reflector is fabricated at 30 GHz, and its near-field patterns are measured. The measured results are in good agreement with the calculated results. From theses results, we confirm that the designed offset dual-shaped reflector can be used as the reflector system for the compact antenna test range.

• Journal of the Korea Institute of Information and Communication Engineering
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• v.14 no.7
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• pp.1529-1536
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• 2010

In this paper, we propose a Axially displaced ellipse gregorian antenna with conical feed horn operating in Ku-band. For fast searching satellite position, it is designed the sub-reflector rotates about $1.5^{\circ}$ tilted by the central axis. the curvature and feed center of the main-reflector and sub-reflector are optimized to achieve maximum antenna efficiency. The designed reflector antenna shows the gain of 33dB and the cross polarization level of less than -21dB and the side-lobe level of less than －14 dB at 12.2 GHz. and C/N ratio of 19dB is proved by reception experiment of Koreasat with fabricated antenna.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.42 no.1
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• pp.90-97
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• 2014

In this paper, we have designed the antenna for Korea SAT-5 Satellite Communication which can use Ka band in the earth station. The antenna structure consist of the the dual-offset gregorian reflector that has high gain and efficiency, the corrugated horn that has symmetric radiation patterns and low side lobe levels, the iris polarizer that make circular polarization and the OrthoMode Transducer that separate transmitting and receiving signals. The designed antenna gain is more than 45.7dBi in Tx-band which use LHCP and 42.0dBi in Rx-band which use RHCP. The co-polarized and cross-polarized radiation pattern comply with ITU-R S.580-6 and S.731-1 that are recommended by International Telecommunication Union in the geostationary satellite. The Axial ratio is less than 1.0dB in Tx-band and 1.5dB in Rx-band that meet MIL-STD-188-164A.

• Journal of the Institute of Electronics Engineers of Korea TC
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• v.45 no.1
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• pp.85-90
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• 2008

In this paper, we studied on dual reflector adjusted to monopulse antenna system. As a result, when the efficiency of main reflector is more than 70%, The size of reflector is 30 wavelength of maximum frequency and minimum frequency gain is 37.9dBi, and Maximum frequency gain is 38.6dBi. Also, when a radius is D and Focus-distance is $F_e$, a scheme for efficiency improvement of Sub Reflector is to increase the Focus-distance to Diameter Ratio. In this case, Cross polarization in Far field improved and spherical spreading loss in circumference of reflector reduced. The influence of Radiation pattern followed by the side displacement of feed antenna(at $x_sy_s$) is decreased, it is confirmed that performance of scanning is improved.

• The Journal of Korean Institute of Electromagnetic Engineering and Science
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• v.19 no.7
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• pp.707-712
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• 2008

In this paper, the sequentially rotated array(SRA) antenna with 256 elements applicable for satellite broadcasting reception was designed by arraying this triple(4+8+4 element) SRA antenna as a sub-array antenna. The structure of a triple SRA antenna is a combination of three coaxial shells composed with 4 elements of inner shell and 8 elements of middle shell and 4 elements of outer shell. In accordance with the optimum design rules for realizing a high gain antenna, the sequential array factors(M, P) of inner shell and outer shell have been chosen M=4 and P=1 and that of middle shell has been chosen M=8 and P=1. The results of the simulation and the measurement for the proposed triple(4+8+4 element) SRA antenna and the SRA antenna with 256 elements show good characteristics on the integration, bandwidth of the axial ratio and the cross-polarization, the gain respectively.

• Tribology and Lubricants
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• v.20 no.6
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• pp.306-313
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• 2004

Many of the current development in surface modification engineering are focused on multilayered coatings, which have the potential to improve the tribological properties. Four different multilayered coatings were deposited on AISI D2 steel in this study. The prepared samples are designed as $WC-Ti_{0.6}Al_{0.4}N,\;WC-Ti_{0.53}Al_{0.47}N,\;WC-Ti_{0.5}Al_{0.5}N\;and\;WC-Ti_{0.43}Al_{0.57}N$. The multilayered coatings were investigated with respect to coating surface and cross-sectional morphology, roughness, adhesion, hardness, porosity and tribological behaviors. Especially, wear tests of four multilayered coatings were performed by using a ball-on-disc configuration with a linear sliding speed of 0.017 m/sec and a normal load of 5.38 N load. The tests were carried out at room temperature in air by employing AISI 52100 steel ball $(H_R\;=\;66) $ having a diameter of 10 mm. The surface morphology, and topography of the wear scars of samples and balls have been determined by using scanning electron spectroscopy (SEM). Also, wear mechanism was determined by using SEM coupled with energy-dispersive spectroscopy (EDS). Results have showed an improved wear resistance of the $WC-Ti_{1-x}Al_xN$coatings with increasing of Al (aluminum) concentration.