• 제목/요약/키워드: Cross Decomposition

검색결과 142건 처리시간 0.021초

Prediction of Thermal Decomposition Temperature of Polymers Using QSPR Methods

  • Ajloo, Davood;Sharifian, Ali;Behniafar, Hossein
    • Bulletin of the Korean Chemical Society
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    • 제29권10호
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    • pp.2009-2016
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    • 2008
  • The relationship between thermal decomposition temperature and structure of a new data set of eighty monomers of different polymers were studied by multiple linear regression (MLR). The stepwise method was used in order to variable selection. The best descriptors were selected from over 1400 descriptors including; topological, geometrical, electronic and hybrid descriptors. The effect of number of descriptors on the correlation coefficient (R) and F-ratio were considered. Two models were suggested, one model having four descriptors ($R^2$ = 0.894, $Q^2_{cv}$ = 0.900, F = 172.1) and other model involving 13 descriptors ($R^2$ = 0.956, $Q^2_{cv}$ = 0.956, F = 125.4).

Modal transformation tools in structural dynamics and wind engineering

  • Solari, Giovanni;Carassale, Luigi
    • Wind and Structures
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    • 제3권4호
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    • pp.221-241
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    • 2000
  • Structural dynamics usually applies modal transformation rules aimed at de-coupling and/or minimizing the equations of motion. Proper orthogonal decomposition provides mathematical and conceptual tools to define suitable transformed spaces where a multi-variate and/or multi-dimensional random process is represented as a linear combination of one-variate and one-dimensional uncorrelated processes. Double modal transformation is the joint application of modal analysis and proper orthogonal decomposition applied to the loading process. By adopting this method the structural response is expressed as a double series expansion in which structural and loading mode contributions are superimposed. The simultaneous use of the structural modal truncation, the loading modal truncation and the cross-modal orthogonality property leads to efficient solutions that take into account only a few structural and loading modes. In addition the physical mechanisms of the dynamic response are clarified and interpreted.

Adaptive MPEG Traffic Prediction

  • Jung, Souhwan;Yoo, Jisang
    • The Journal of the Acoustical Society of Korea
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    • 제16권3E호
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    • pp.7-13
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    • 1997
  • This paper addresses traffic prediction issues on MPEG. A new adaptive traffic prediction scheme is proposed using MPEG picture characteristic that picture traffic depends on the coding mode of that picture, that is, I, P, and B mode. Our prediction scheme, which is based n picture decomposition (PD) and the cross-correlation of the different types of pictures, has better performance in predicting bursty MPEG traffic than that of the first-order autoregressive (AR) prediction scheme. Our simulation results show that the performance is further improved about 15% by utilizing the cross-correlations between pictures.

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Dynamic DSC와 TGA를 이용한 NR/CR 고무블렌드의 가황시스템이 가교 및 열화반응에 미치는 영향 연구 (A Study on Effects of Vulcanization Systems on Cross-linking and Degradation Reactions of NR/CR Blends Using Dynamic DSC and TGA)

  • 민병권;박동률;안원술
    • Korean Chemical Engineering Research
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    • 제47권2호
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    • pp.169-173
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    • 2009
  • Dynamic DSC와 TGA를 이용하여 NR/CR 고무복합체의 가황시스템에 따른 가교화반응과 열화반응특성을 연구하였다. 주어진 샘플에 대하여 승온속도를 각각 달리하여 DSC 곡선을 얻었고, 가황반응이 끝난 같은 샘플을 이용하여 TGA에서도 같은 승온 속도의 실험으로 열분해 곡선을 얻은 다음, Kissinger의 해석 방법에 따라 가교 및 열화 반응의 활성화에너지를 구하고 서로 비교하였다. 실험에 사용된 NR/CR 고무복합재료는 대개 $120{\sim}180^{\circ}C$$350{\sim}450^{\circ}C$ 사이의 온도영역에서 각각 가교 반응과 열분해반응이 일어나는 것으로 관찰되었으며 Kissinger의 해석방법이 잘 적용될 수 있는 것으로 나타났다. 또한 DSC에 의한 생성 활성화에너지는 $83.0{\pm}5.0kJ/mol$로서 TGA에 의한 분해 활성화에너지인 $147.0{\pm}2.0kJ/mol$보다 매우 낮은 값을 나타내었다. 이러한 사실로부터 가황제/가황촉진제의 조성비 변화는 반응기구의 변화에는 크게 영향을 미치지 않지만 생성반응 시에는 샘플내의 저분자 화합물들과 함께 촉매역할을 하여 활성화에너지를 낮추는 역할을 하게 되는 반면, 반응이 끝난 후에는 더 이상 촉매로서 작용하지 못하게 되며 이에 따라 열분해활성화에너지는 주쇄의 분해반응에 의해 상대적으로 더 높게 나타내게 되는 것으로 생각할 수 있었다.

Block Sparse Low-rank Matrix Decomposition based Visual Defect Inspection of Rail Track Surfaces

  • Zhang, Linna;Chen, Shiming;Cen, Yigang;Cen, Yi;Wang, Hengyou;Zeng, Ming
    • KSII Transactions on Internet and Information Systems (TIIS)
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    • 제13권12호
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    • pp.6043-6062
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    • 2019
  • Low-rank matrix decomposition has shown its capability in many applications such as image in-painting, de-noising, background reconstruction and defect detection etc. In this paper, we consider the texture background of rail track images and the sparse foreground of the defects to construct a low-rank matrix decomposition model with block sparsity for defect inspection of rail tracks, which jointly minimizes the nuclear norm and the 2-1 norm. Similar to ADM, an alternative method is proposed in this study to solve the optimization problem. After image decomposition, the defect areas in the resulting low-rank image will form dark stripes that horizontally cross the entire image, indicating the preciselocations of the defects. Finally, a two-stage defect extraction method is proposed to locate the defect areas. The experimental results of the two datasets show that our algorithm achieved better performance compared with other methods.

Understanding of unsteady pressure fields on prisms based on covariance and spectral proper orthogonal decompositions

  • Hoa, Le Thai;Tamura, Yukio;Matsumoto, Masaru;Shirato, Hiromichi
    • Wind and Structures
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    • 제16권5호
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    • pp.517-540
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    • 2013
  • This paper presents applications of proper orthogonal decomposition in both the time and frequency domains based on both cross spectral matrix and covariance matrix branches to analyze multi-variate unsteady pressure fields on prisms and to study spanwise and chordwise pressure distribution. Furthermore, modification of proper orthogonal decomposition is applied to a rectangular spanwise coherence matrix in order to investigate the spanwise correlation and coherence of the unsteady pressure fields. The unsteady pressure fields have been directly measured in wind tunnel tests on some typical prisms with slenderness ratios B/D=1, B/D=1 with a splitter plate in the wake, and B/D=5. Significance and contribution of the first covariance mode associated with the first principal coordinates as well as those of the first spectral eigenvalue and associated spectral mode are clarified by synthesis of the unsteady pressure fields and identification of intrinsic events inside the unsteady pressure fields. Spanwise coherence of the unsteady pressure fields has been mapped the first time ever for better understanding of their intrinsic characteristics.

고속 Chirplet 분리기법을 이용한 VHF 대역 레이더 표적신호 모델링 및 해석 (Modeling and Analysis of Radar Target Signatures in the VHF-Band Using Fast Chirplet Decomposition)

  • 박지훈;김시호;채대영
    • 한국군사과학기술학회지
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    • 제22권4호
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    • pp.475-483
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    • 2019
  • Although radar target signatures(RTS), such as range profiles have played an important role for target recognition in the X-band radar, they would be less effective when a target is designed to have low radar cross section(RCS). Recently, a number of research groups have conducted the studies on the RTS in the VHF-band where such targets can be better detected than in the X-band. However, there is a lack of work carried out on the mathematical description of the VHF-band RTS. In this paper, chirplet decomposition is employed for modeling of the VHF-band RTS and its performance is compared with that of existing scattering center model generally used for the X-band. In addition, the discriminative signal analysis is performed by chirplet parameterization of range profiles from in an ISAR image. Because the chirplet decomposition takes long computation time, its fast form is further proposed for enhanced practicality.

Comparison Study of Thermal Decomposition Characteristics of Wattle & Pine Tannin-based Adhesives

  • Kim, Sumin;Lee, Young-kyu;Kim, Hyun-Joong;Eom, Young Geun
    • Journal of the Korean Wood Science and Technology
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    • 제30권3호
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    • pp.34-41
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    • 2002
  • This study investigated the thermogravimetric analysis of two types of cured tannin-based adhesives from wattle and pine, with three hardeners of paraformaldehyde, hexamethylenetetramine and TN (tris(hydroxyl)nitromethan), at a temperature of 170℃ and a heating rate of 5, 10, 20 and 40℃/min for 10 minutes. The 5 minutes cured wattle tannin-based adhesive with each hardener at 170℃ was also tested to compare the degree of curing. It was found that thermogravimetric analysis could be used to measure the degree of curing of a thermosetting adhesive. The TG-DTG curves of all the adhesive systems were similar and showed three steps in a similar way to a phenolic resin. This means that each adhesive system is well cross-linked. However, a high thermal decomposition rate was shown at 150 to 400℃ in the case of the pine tannin sample with TN (tris(hydroxyl)nitromethan). The Flynn & Wall expression was used to evaluate the activation energy for thermal decomposition. As the level of conversion (𝛼) increased, the activation energy of each system increased. The activation energy of the wattle tannin-based adhesive with paraformaldehyde was higher than the others.

경험적 모드분해법에 기초한 계층적 평활방법 (Hierarchical Smoothing Technique by Empirical Mode Decomposition)

  • 김동호;오희석
    • 응용통계연구
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    • 제19권2호
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    • pp.319-330
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    • 2006
  • 현실세계에서 관찰되는 시그널(signal)은 다양한 주파수(frequency)들의 시그널로 혼합되어 있는 경우가 많다. 예를 들어 태양 흑점 자료의 경우 약 11년 주기와 85년 주기로 변동한다는 사실은 널리 알려져 있다. 또한 경제 시계열 자료의 경우는 통상적으로 계절요인(seasonal component), 순환요인(cyclic component) 그리고 장기적인 추세요인(long-term trend)으로 분해하여 분석한다. 이러한 시계열 자료를 구성요소별로 분해하는 것은 오래된 주제중 하나이다. 전통적인 시계열자료 분석기법으로 스펙트럴 분석기법 등이 널리 사용되고 있으나 시계열 자료들이 비정상(nonstationary)일 경우에는 적용하기 어렵다. Huang et. al(1998)은 경험적 모드분해법(empirical mode decomposition)이라고 하는 자료적응적인(data-adaptive) 방법을 제안하였는데, 비정상성(nonstationarity)에 대한 강건성(robustness)으로 여러 분야에 널리 응용되고 있다. 그러나 Huang et. at(1998)은 잡음(error)에 의해 오염된 자료에 대한 구체적인 처리방법은 제시하지 못하고 있다. 본 논문을 통하여 효율적인 잡음제거 방법을 제안하고자 한다.

Unsteady wind loading on a wall

  • Baker, C.J.
    • Wind and Structures
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    • 제4권5호
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    • pp.413-440
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    • 2001
  • This paper presents an extensive analysis of unsteady wind loading data on a 18 m long and 2 m high wall in a rural environment, with the wind at a range of angles to the wall normal. The data is firstly analyzed using standard statistical techniques (moments of probability distributions, auto- and cross-correlations, auto- and cross-spectra etc.). The analysis is taken further using a variety of less conventional methods - conditional sampling, proper orthogonal decomposition and wavelet analysis. It is shown that, even though the geometry is simple, the nature of the unsteady flow is surprisingly complex. The fluctuating pressures on the front face of the wall are to a great extent caused by the turbulent fluctuations in the upstream flow, and reflect the oncoming flow structures. The results further suggest that there are distinct structures in the oncoming flow with a variety of scales, and that the second order quasi-steady approach can predict the pressure fluctuations quite well. The fluctuating pressures on the rear face are also influenced by the fluctuations in the oncoming turbulence, but also by unsteady fluctuations due to wake unsteadiness. These fluctuations have a greater temporal and spatial coherence than on the front face and the quasi-steady method over-predicts the extent of these fluctuations. Finally the results are used to check some assumptions made in the current UK wind loading code of practice.