• Title/Summary/Keyword: Cross Calibration

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Measurement of Surface Color and Fermentation Degree in Tea Products Using NIRS (근적외선 분광광도계를 이용한 차제품의 표면 색상 및 발효정도 측정)

  • Chun, Jong-Un
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.54 no.1
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    • pp.55-60
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    • 2009
  • This study was conducted to measure tea surface colors using the visible bands ($400{\sim}700$ nm) with near-infrared spectroscopy (NIRS). The surface colors of 117 tea products were measured with a colorimeter. The $a^*/b^*$ (CIE color scale) or a/b (Hunter color scale) ratios in different tea products accounted for about 99.7% of the variation in fermentation degree (FD), indicating that the $a^*/b^*$ (a/b) ratio is a very useful trait for assessing fermentation degree. Also tea powders were scanned in the visible bands used with NIRS. Calibration equations for surface colors and fermentation degree were developed using the regression method of modified partial least-squares (MPLS) with internal cross validation. The equations had low SECV (standard errors of cross-validation), and high $R^2$ (coefficient of determination in calibration) values with $0.779{\sim}0.999$, indicating that the whole bands ($400{\sim}2500\;nm$) with NIRS could be used to rapidly measure traits related to surface color, fermentation degree and other chemical components in tea products with high precision and ease at a time.

Prediction of the Chemical Composition and Fermentation Parameters of Fresh Coarse Italian Ryegrass Haylage using Near Infrared Spectroscopy

  • Kim, Ji Hye;Park, Hyung Soo;Choi, Ki Choon;Lee, Sang Hoon;Lee, Ki-Won
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.37 no.4
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    • pp.350-357
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    • 2017
  • Near infrared spectroscopy (NIRS) is a rapid and accurate method for analyzing the quality of cereals, and dried animal forage. However, one limitation of this method is its inability to measure fermentation parameters in dried and ground samples because they are volatile, and therefore, respectively lost during the drying process. In order to overcome this limitation, in this study, fresh coarse haylage was used to test the potential of NIRS to accurately determine chemical composition and fermentation parameters. Fresh coarse Italian ryegrass haylage samples were scanned at 1 nm intervals over a wavelength range of 680 to 2500 nm, and optical data were recorded as log 1/reflectance. Spectral data, together with first- and second-order derivatives, were analyzed using partial least squares (PLS) multivariate regressions; scatter correction procedures (standard normal variate and detrend) were used in order to reduce the effect of extraneous noise. Optimum calibrations were selected based on their low standard error of cross validation (SECV) values. Further, ratio of performance deviation, obtained by dividing the standard deviation of reference values by SECV values, was used to evaluate the reliability of predictive models. Our results showed that the NIRS method can predict chemical constituents accurately (correlation coefficient of cross validation, $R_{cv}^2$, ranged from 0.76 to 0.97); the exception to this result was crude ash ($R_{cv}^2=0.49$ and RPD = 2.09). Comparison of mathematical treatments for raw spectra showed that second-order derivatives yielded better predictions than first-order derivatives. The best mathematical treatment for DM, ADF, and NDF, respectively was 2, 16, 16, whereas the best mathematical treatment for CP and crude ash, respectively was 2, 8, 8. The calibration models for fermentation parameters had low predictive accuracy for acetic, propionic, and butyric acids (RPD < 2.5). However, pH, and lactic and total acids were predicted with considerable accuracy ($R_{cv}^2$ 0.73 to 0.78; RPD values exceeded 2.5), and the best mathematical treatment for them was 1, 8, 8. Our findings show that, when fresh haylage is used, NIRS-based calibrations are reliable for the prediction of haylage characteristics, and therefore useful for the assessment of the forage quality.

Analysis of the Radar Cross Section of an X-band Active Transponder (X-밴드 대역 능동 전파반사기 RCS 분석 연구)

  • Hwang, Ji-Hwan;Kwon, Soon-Gu;Won, Joong-Sun;Oh, Yi-Sok
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.22 no.3
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    • pp.327-335
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    • 2011
  • A study on the RCS of a self-manufactured active transponder, which has a manually adjustable RCS, for SAR(Synthetic Aperture Radar) external calibration and image analysis at X-band is presented in this paper. The RCS of the active transponder was comparably analyzed using the lab-test and the COSMO-SkyMed SAR system, and also precisely analyzed the difference between the adjusted and estimated RCSs. A maximum RCS of the designed and manufactured active transponder is 60 dBsm. The active transponders with 60 dBsm and the adjusted RCS of 40 dBsm were measured using the single target calibration technique(STCT) and 2D target scanning technique(2DTST). And the extracted RCS using power-spill integration technique in a SAR image was compared with the measured RCS of active transponder. The comparison results show that the measured and extracted RCSs are 59.7 dBsm, 40.2 dBsm and 57.3 dBsm, 39.2 dBsm, respectively.

Dynamic Load Allowance of Highway Bridges by Numerical Dynamic Analysis for LRFD Calibration (LRFD 보정을 위한 동적해석에 의한 도로교의 동적하중허용계수)

  • Chung, Tae Ju;Shin, Dong-Ku;Park, Young-Suk
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.28 no.3A
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    • pp.305-313
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    • 2008
  • A reliability based calibration of dynamic load allowance (DLA) of highway bridge is performed by numerical dynamic analysis of various types of bridges taking into account of the road surface roughness and bridge-vehicle interaction. A total of 10 simply supported bridges with three girder types in the form of prestressed concrete girder, steel plate girder, and steel box girder is analyzed. The cross sections recommended in "The Standardized Design of Highway Bridge Superstructure" by the Korean Ministry of Construction are used for the prestressed concrete girder bridges and steel plate girder bridges while the box girder bridges are designed by the LRFD method. Ten sets of road surface roughness for each bridge are generated from power spectral density (PSD) function by assuming the roadway as "Average Road". A three dimensionally modeled 5-axle tractor-trailer with its gross weight the same as that of DB-24 design truck is used in the dynamic analysis. For the finite element modeling of superstructure, beam elements for the main girder, shell elements for concrete deck, and rigid links between main girder and concrete deck are used. The statistical mean and coefficient of variation of DLA are obtained from a total of 100 DLA results for 10 different bridges with each having 10 sets of road surface roughness. Applying the DLA statistics obtained, the DLA is finally calibrated in a reliability based LRFD format by using the formula developed in the calibration of OHBDC code.

Comparison and Analysis of Matching DEM Using KOMPSAT-3 In/Cross-track Stereo Pair (KOMPSAT-3 In/Cross-track 입체영상을 이용한 매칭 DEM 비교 분석)

  • Oh, Kwan-Young;Jeong, Eui-Cheon;Lee, Kwang-Jae;Kim, Youn-Soo;Lee, Won-Jin
    • Korean Journal of Remote Sensing
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    • v.34 no.6_3
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    • pp.1445-1456
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    • 2018
  • The purpose of this study is to compare the quality and characteristics of matching DEMs by using KOMPSAT-3 stereo pair capture in in-track and cross-track. For this purpose, two stereo pairs of KOMPSAT-3 were collected that were taken in the same area. The two stereo pairs have similar stereo geometry elements such as B/H, convergence angle. Sensor modeling for DEM production was performed with RFM affine calibration using multiple GCPs. The GCPs used in the study were extracted from the 0.25 m ortho-image and 5 meter DEM provided by NGII. In addition, matching DEMs were produced at the same resolution as the reference DEMs for a comparison analysis. As a result of the experiment, the horizontal and vertical errors at the CPs indicated an accuracy of 1 to 3 pixels. In addition, the shapes and accuracy of two DEMs produced in areas where the effects of natural or artificial surface land were low were almost similar.

High Resolution Spaceborne SAR Operation and Target Recognition Simulator Using STK (STK를 이용한 고해상도 위성 SAR 운용 및 표적물 추출 기법)

  • Lee, Bo-Yun;Lee, Seul-Ki;Lee, Woo-Kyung
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.24 no.3
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    • pp.299-309
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    • 2013
  • A comprehensive SAR(Synthetic Aperture Radar) simulation is considered to be a complicated task since a full knowledge of the signal propagation characteristics, antenna pattern, system internal errors and interference noises should be taken into account. In high resolution target application modes, the time varying nature of target RCS(Radar Cross Section) strongly affects the generated SAR images. In this paper, in-depth SAR simulations are performed and analyzed incorporating the STK tools and MATLAB software. STK provides realistic orbit parameters while its radar module helps to extract accurate radiometric parameters of ground targets. SAR raw data corresponding to a given target is generated and processed using MATLAB simulator. The performance is measured by PSLR(Peak Sidelobe Ratio) and ISLR(Integrated Sidelobe Ratio) for a point target, which can be used as reference parameters for accurate radiometric calibration. Finally, high resolution target simulations are performed by adopting time varying target RCS characteristics.

Simultaneous Quantification of Urinary L-, and D-Lactate by Reversed-Phase Liquid Chromatography Tandem Mass Spectrometry (액체크로마토그래프-탠덤질량분석기(LC-MS/MS)를 이용한 소변 내 D-, L- Lactate 분리 및 정량)

  • Moon, Chul Jin;Yang, Song Hyun
    • Journal of The Korean Society of Inherited Metabolic disease
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    • v.15 no.2
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    • pp.59-64
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    • 2015
  • Purpose: Lactate has two optical isomers, L-lactate and D-lactate. In human L-lactate is the most abundant enantiomer of lactate. As plasma and urinary levels of L-lactate is associated with inherited metabolic disorders in general, D-lactate have been linked to the presence of diabetes and inflammatory bowel disease. Previously developed techniques have shown several limitations to further evaluate D-lactate as a biomarker for this condition. In this paper, we describe a highly sensitive, specific and fast liquid chromatography tandem mass spectrometry (LC-MS/MS) method for the analysis of D-, L-lactate in urine. Methods: D- and L-lactate were quantified using high performance liquid chromatography tandem mass spectrometry (LC-MS/MS) with labelled internal standard. Samples were derivatized with (+)-O,O'-diacety-L-tartaric anhydride (DATAN) and seperated on a Poroshell 120 EC-C18 column. Results: Quantitative analysis of D-, and L-lactate was achieved successfully. Calibration curves were linear (r>0.999) over $0.5-100{\mu}g/mL$. Stabilities for samples were within the 10% varation. Inter- and Intra-day assay variations were below 10%. Conclusion: The presented method proved to be suitable for the quantitation of D- and L-lactate and opens the possibility to explore the use of D-lactate as a biomarker.

Analysis of the first core of the Indonesian multipurpose research reactor RSG-GAS using the Serpent Monte Carlo code and the ENDF/B-VIII.0 nuclear data library

  • Hartanto, Donny;Liem, Peng Hong
    • Nuclear Engineering and Technology
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    • v.52 no.12
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    • pp.2725-2732
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    • 2020
  • This paper presents the neutronics benchmark analysis of the first core of the Indonesian multipurpose research reactor RSG-GAS (Reaktor Serba Guna G.A. Siwabessy) calculated by the Serpent Monte Carlo code and the newly released ENDF/B-VIII.0 nuclear data library. RSG-GAS is a 30 MWth pool-type material testing research reactor loaded with plate-type low-enriched uranium fuel using light water as a coolant and moderator and beryllium as a reflector. Two groups of critical benchmark problems are derived on the basis of the criticality and control rod calibration experiments of the first core of RSG-GAS. The calculated results, such as the neutron effective multiplication factor (k) value and the control rod worth are compared with the experimental data. Moreover, additional calculated results, including the neutron spectra in the core, fission rate distribution, burnup calculation, sensitivity coefficients, and kinetics parameters of the first core will be compared with the previous nuclear data libraries (interlibrary comparison) such as ENDF/B-VII.1 and JENDL-4.0. The C/E values of ENDF/B-VIII.0 tend to be slightly higher compared with other nuclear data libraries. Furthermore, the neutron reaction cross-sections of 16O, 9Be, 235U, 238U, and S(𝛼,𝛽) of 1H in H2O from ENDF/B-VIII.0 have substantial updates; hence, the k sensitivities against these cross-section changes are relatively higher than other isotopes in RSG-GAS. Other important neutronics parameters such as kinetics parameters, control rod worth, and fission rate distribution are similar and consistent among the nuclear data libraries.

Mid-infrared (MIR) spectroscopy for the detection of cow's milk in buffalo milk

  • Anna Antonella, Spina;Carlotta, Ceniti;Cristian, Piras;Bruno, Tilocca;Domenico, Britti;Valeria Maria, Morittu
    • Journal of Animal Science and Technology
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    • v.64 no.3
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    • pp.531-538
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    • 2022
  • In Italy, buffalo mozzarella is a largely sold and consumed dairy product. The fraudulent adulteration of buffalo milk with cheaper and more available milk of other species is very frequent. In the present study, Fourier transform infrared spectroscopy (FTIR), in combination with multivariate analysis by partial least square (PLS) regression, was applied to quantitatively detect the adulteration of buffalo milk with cow milk by using a fully automatic equipment dedicated to the routine analysis of the milk composition. To enhance the heterogeneity, cow and buffalo bulk milk was collected for a period of over three years from different dairy farms. A total of 119 samples were used for the analysis to generate 17 different concentrations of buffalo-cow milk mixtures. This procedure was used to enhance variability and to properly randomize the trials. The obtained calibration model showed an R2 ≥ 0.99 (R2 cal. = 0.99861; root mean square error of cross-validation [RMSEC] = 2.04; R2 val. = 0.99803; root mean square error of prediction [RMSEP] = 2.84; root mean square error of cross-validation [RMSECV] = 2.44) suggesting that this method could be successfully applied in the routine analysis of buffalo milk composition, providing rapid screening for possible adulteration with cow's milk at no additional cost.

Revisiting the Z-R Relationship Using Long-term Radar Reflectivity over the Entire South Korea Region in a Bayesian Perspective

  • Kim, Tae-Jeong;Kim, Jin-Guk;Kim, Ho Jun;Kwon, Hyun-Han
    • Proceedings of the Korea Water Resources Association Conference
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    • 2021.06a
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    • pp.275-275
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    • 2021
  • A fixed Z-R relationship approach, such as the Marshall-Palmer relationship, for an entire year and for different seasons can be problematic in cases where the relationship varies spatially and temporally throughout a region. From this perspective, this study explores the use of long-term radar reflectivity for South Korea to obtain a nationwide calibrated Z-R relationship and the associated uncertainties within a Bayesian regression framework. This study also investigates seasonal differences in the Z-R relationship and their roles in reducing systematic error. Distinct differences in the Z-R parameters in space are identified, and more importantly, an inverse relationship between the parameters is clearly identified with distinct regimes based on the seasons. A spatially structured pattern in the parameters exists, particularly parameter α for the wet season and parameter β for the dry season. A pronounced region of high values during the wet and dry seasons may be partially associated with storm movements in that season. Finally, the radar rainfall estimates through the calibrated Z-R relationship are compared with the existing Z-R relationships for estimating stratiform rainfall and convective rainfall. Overall, the radar rainfall fields based on the proposed modeling procedure are similar to the observed rainfall fields, whereas the radar rainfall fields obtained from the existing Marshall-Palmer Z-R relationship show a systematic underestimation. The obtained Z-R relationships are validated by testing the predictions on unseen radar-gauge pairs in the year 2018, in the context of cross-validation. The cross-validation results are largely similar to those in the calibration process, suggesting that the derived Z-R relationships fit the radar-gauge pairs reasonably well.

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