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Characterization and performance of post treated PVDF hollow fiber membrane

  • Eman S. Sayed;Hayam F. Shaalan;Magda I. Marzouk;Heba A. Hani
    • Membrane and Water Treatment
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    • v.15 no.2
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    • pp.79-88
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    • 2024
  • Modification of Polyvinylidene fluoride (PVDF) hollow fiber membranes (HFMs) characteristics and performance were investigated via post treatment using different oxidants. sodium hypochlorite (NaOCl), hydrogen peroxide (H2O2) and potassium persulfate (KPS). Fourier transform infrared (FTIR) and Proton nuclear magnetic resonance (1H-NMR) results revealed no structural differences after post treatment. Cross-sectional micrographs show finger-like structures at the outer and inner walls of the HFMs and sponge-like structures in middle, where NaOCl and KPS post treated fibers exhibited a decrease in finger-like structures in addition to aggregates appearing on the surface, consequently leading to an increase in the surface roughness (Ra) from 48 nm to 52.8nm and 56 nm, respectively. Hydrogen peroxide post treatment only was observed to decrease the water contact angle from 98° to 81.4°. It was also observed that the elongation at break and the modulus deceased after NaOCl post treatment from 34.5 to 28.5% and from 19.3 Mpa to 16.6 Mpa, respectively. Moreover, pure water flux after H2O2 post treatment increased from 87.8 LMH/bar to 113 LMH/bar at 0.45 bar, while no changes were detected for the methylene blue dye rejection (74%) between raw and hydrogen peroxide post treated fibers at the same pressure. According to the findings hydrogen peroxide post treated PVDF HFMs have the most uniform surfaces, with almost no alterations in structural and mechanical properties or porosities with enhanced hydrophilicity and pure water flux maintaining appropriate rejection. Therefore, it is considered an efficient surface modifying agent for UF/NF membranes or low-pressure separators.

Estimation of Buckling and Plastic Behaviour according to the Analysis Model of the Stiffened Plate (보강판의 해석모델에 따른 좌굴 및 소성거동 평가)

  • Ko, Jae-Yong;Oh, Young-Cheol;Park, Joo-Shin
    • Journal of Navigation and Port Research
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    • v.31 no.3 s.119
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    • pp.271-279
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    • 2007
  • Ship structures are basically an assembly of plate elements and estimation load-carrying capacity or the ultimate strength is one of the most important criterion for estimated safety assessment and rational design on the ship structure. Also, Structural elements making up ship plated structures do not work separately against external load. One of the critical collapse events of a ship structure is the occurrence of overall buckling and plastic collapse of deck or bottom structure subjected to longitudinal bending. So, the deck and the bottom plates are reinforced by a number af longitudinal stiffeners to increase their strength and load-carrying capacity. For a rational design avoiding such a sudden collapse, it is very important to know the buckling and plastic behaviour or collapse pattern of the stiffened plate under axial compression. In this present study, to investigate effect af modeling range, the finite element method are used and their results are compared varying the analysis ranges. When making the FEA model, six types of structural modeling are adopted varying the cross section of stiffener. In the present paper, a series of FEM elastoplastic large deflection analyses is performed on a stiffened plate with fiat-bar, angle-bar and tee-bar stiffeners. When the applied axial loading, the influences of cross-sectional geometries on collapse behaviour are discussed. The purpose of the present study is examined to numerically calculate the characteristics of buckling and ultimate strength behavior according to the analysis method of ship's stiffened plate subject to axial loading.

Sedimentology of Inclined Heterolithic Stratification in Sukmo Channel, Kyonggi Bay, Korea - Application to Oil Sand Exploration (경기만 석모수도 수로제방 조간대층에 발달하는 경사이질암상층리의 퇴적학적 연구 - 오일샌드 탐사 적용가능성)

  • Choi, Kyung-Sik;Dalrymple, R.W.;Chun, Seung-Soo;Kim, Sung-Pil;Park, Se-Jin
    • The Korean Journal of Petroleum Geology
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    • v.11 no.1 s.12
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    • pp.18-26
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    • 2005
  • An occurrence of inclined heterolithic stratification (IHS) is described from a tidal point bar in a 40-m-deep distributary of the macrotidai, Han River delta, Korea. The channel bank demonstrates a convex-upward profile with intermittent presence or wave-formed scarps and terraces near the low-water level. The vertical succession of IHS is approximately 25 m thick and dips into the channel with angles reaching up to $14^{\circ}C$. The IHS overlies 15 m of trough cross-bedded sand deposited in the channel bottom. Even though the channel as a whole is ebb dominated, the preserved cross bedding is predominantly flood directed because the mutually evasive nature of the ebb and flood currents causes the point bar surface to be flood dominated. The IHS itself consists of inter-stratified fine sand, sandy silt, and silt with an fining-upward textural trend. Seasonal discharge variations of the Han River are not obvious in the deposits, because tile large size, distal location, and energetic tidal environment of the studied channel reduces the impart of river-stage fluctuations.

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A Study on the Channel Planform Change Using Aerial Photographs and Topographic Map in the Mangyoung River (영상자료를 이용한 만경강 하도변화에 관한 연구)

  • Hong, Il;Kang, Joon-Gu;Yeo, Hong-Koo
    • Journal of Korea Water Resources Association
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    • v.45 no.2
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    • pp.127-136
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    • 2012
  • River is able to change by various environmental factors. In order to conduct river restoration design, it is necessary to evaluate the stable channel through the analysis of past and present river channels. River evaluation requires various data, such as geometry, hydraulic and hydrology, but there is a lot of difficulty to understand topographical information of river change on time and space due to a lack of past data by domestic conditions. This study was analyzed abandoned channel formation, changes in the vertical-section and cross-section length of rivers, and micro-landform changes etc using an image analysis technique. Purpose of this research is to evaluates the stable channel through a river channel morphology change from past and present river channels image. Mangyoung river was conducted artificial river maintenance through straight channel consolidation form 1920 to 1930 year. In the result river maintenance, mangyoung river length was decreased by 15 km and abandoned channels of six points were made. Since then, weir was continuously increased to control bed slope and use water. Install of weir was to be the reason of changes on channel width, thalweg, vegetated bar, sand bar, water area. Present Mangyoung river show that water area was temporary increased in upper and middle reach because of weir installation. Total sand bar was only decreased in upper channel. The change of vegetated bar and sand bar was slight recently. In this result, Mangyoung river is inferred to reach stabilized channel although there is some difference to the lower reach.

Strength Properties of Wooden Model Erosion Control Dams Using Domestic Pinus rigida Miller I (국내산 리기다소나무를 이용한 목재 모형 사방댐의 강도 성능 평가 I)

  • Kim, Sang-Woo;Park, Jun-Chul;Lee, Dong-Heub;Son, Dong-Won;Hong, Soon-Il
    • Journal of the Korean Wood Science and Technology
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    • v.36 no.6
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    • pp.77-87
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    • 2008
  • Wooden model erosion control dam was made with pitch pine, of which the strength properties was evaluated. Wooden model erosion control dam was made with diameter 90 mm of pitch pine round posts treated with CUAZ-2 (Copper Azole), changing joint in three different types. In each type, erosion control dam was made in nine floor (cross-bar of five floors and vertical-bar of four floors), of which the hight was 790 mm. And then strength properties were investigated through horizontal loading test and impact strength test, and the deformation of structure through image processing (AICON 3D DPA-PRO system). In horizontal loading test of wooden model erosion control dam using round post of diameter 90 mm, whether there was stone or not did not affect strength much when using self drill screw, but strength was decreased by 23%. In monolithic type of erosion control dam using screw bar, strength was increased by 1.5 times and deformation was decreased when filling with stone. When reinforcing with screw bar that ring is connected to self drill screw, strength was increased by 4.8 times. In impact strength test of wooden model erosion control dam made with round post of diameter 90 mm, the erosion control dam connected with self drilling screw not filling with stone was totally destroyed by the 1st impact, and the erosion control dam using screw bar was ruptured at cross-bar at which 779 kgf of impact was loaded in the 1st impact. In the 2nd impact, the base parts were ruptured, and reaction force was decreased to 545 kgf. In the 3rd impact, whole base parts were destroyed, and reaction force was decreased to 263 kgf.

Seismic Performance of Octagonal Flared RC Columns using Oblong Hoops (장방형 띠철근을 이용한 팔각형 플레어 RC 기둥의 내진성능)

  • Ko, Seong-Hyun
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.19 no.6
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    • pp.1-9
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    • 2015
  • Transverse steel bars are used in the plastic hinge zone of columns to insure adequate confinement, prevention of longitudinal bar buckling and ductile behavior. Fabrication and placement of rectangular hoops and cross-ties in columns are difficult to construct. Details of reinforcement for rectangular section require a lot of rectangular hoops and cross-ties. In this paper, to solve these problems, the new lateral confinement method using oblong hoop is proposed for the transverse confinement of the flared column. It can be the alternative for oblong cross-section and flared column with improved workability and cost-efficiency. The final objectives of this study are to suggest appropriate oblong hoop details and to provide quantitative reference data and tendency for seismic performance or damage assessment based on the drift levels such as residual deformation, elastic strain energy. This paper describes factors of seismic performance such as ultimate displacement/drift ratio, displacement ductility, response modification factor, equivalent viscous damping ratio and effective stiffness.

Fast Neutron Dosimetry in Nuclear Criticality Accidents (핵임계사고시(核臨界事故時)에 있어서 속중성자선량(速中性子線量) 측정(測定))

  • Yook, Chong-Chul;Ro, Seung-Gy
    • Journal of Radiation Protection and Research
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    • v.2 no.1
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    • pp.17-23
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    • 1977
  • The neutron dosimetrical parameters, i. e., the fission neutron spectrum-averaged cross-sections and the fluence-to-dose conversion factors have been calculated for some threshold detectors with the aid of a computer. The threshold detectors under investigation were the $^{115}In(n,\;n')^{115m}In,\;^{32}S(n,\;p)^{32}P$ and $^{27}Al(n,\;{\alpha})^{24}Na$ reactions. It is revealed that the average cross-sections($\bar{\sigma}$) for the $^{32}S(n,\;p)^{32}P$ reaction are independent of the spectral functions, namely, the Watt-Cranberg and Maxwellian forms. In the case of the $^{27}Al(n,\;{\alpha})^{24}Na$ reaction a variation of the $\bar{\sigma}$ values appears to be highly dependent on the fissioning types. It seems that both the average cross-section for the $^{115}In(n,\;n')^{11m}In$ reaction and the conversion factor are insensitive to the spectral deformation of fission neutrons. These phenomena make it applicable to use indium as a possible integral fast neutron dosimeter in nuclear criticality accidents provided that the virgin fission neutrons are completely free from the scattered neutrons.

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A Study on the Stifness of Coil Spring in the Three Dimensional Space (3차원 공간에서 코일스프링의 강성에 관한 연구)

  • 이수종
    • Journal of Advanced Marine Engineering and Technology
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    • v.25 no.5
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    • pp.1130-1139
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    • 2001
  • Springs are widely utilized in machine element. To find out stiffness of coil spring, the space beam theory using the finite element method is adopted in this paper. In three dimensional space, a space frame element is a straight bar of uniform cross section which is capable of resisting axial forces, bending moments about two principal axes in the plane of its cross section and twisting moment about its centroidal axis. The corresponding displacement degrees of freedom are twelve. The displacements of nodal points due to small increment of force are calculated by the finite element method and the calculated nodal displacements are added to coordinates of nodal points. The new stiffness matrix of the system using the new coordinates of nodal points is adopted to calculated the another increments of nodal displacements, that is, the step by step method is used in this paper. The results of the finite element method are fairly well agreed with those of various experiments. Using MATLAB program developed in this paper, spring constants can be predicted by input of few factors.

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Analysis of Stiffness for Frustum-shaped Coil Spring (원추형 코일스프링의 강성해석)

  • Kim, Jin-Hun;Lee, Soo-Jong;Kim, Jung-Ryul
    • Journal of Advanced Marine Engineering and Technology
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    • v.32 no.2
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    • pp.250-255
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    • 2008
  • Springs are widely utilized in machine element. To find out stiffness of frustum-shaped coil spring, the space beam theory using the finite element method is adopted in this paper. In three dimensional space, a space frame element is a straight bar of uniform cross section which is capable of resisting axial forces, bending moments about two principal axes in the plane of its cross section and twisting moment about its centroidal axis. The corresponding displacement degrees of freedom are twelve. To find out load vector of coil spring subjected to distributed compression. principle of virtual work is adapted. And this theory was programming using MATLAB software. To compare FEM using MATLAB software was applied MSC. Nastran software. The geometry model for MSC. Patran was produced by 3-D design modeling software. Finite element model was produced by MSC. Patran. Finite element was applied tetra (CTETRA) having 10 node. The analysis results of the MATLAB and MSC. Nastran are fairly well agreed with those of various experiments. Using MATLAB program proposed in this paper and MSC. Nastran, spring constants and stresses can be predicted by input of few factors.

Enhanced Adhesion and Transmittance Uniformity in Laminated Polymer-Dispersed Liquid Crystal Films

  • Yoo, Seong-Hyeon;Park, Min-Kyu;Park, Ji-Sub;Kim, Hak-Rin
    • Journal of the Optical Society of Korea
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    • v.18 no.6
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    • pp.753-761
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    • 2014
  • We propose a two-step UV irradiation procedure to fabricate polymer-dispersed liquid crystal (PDLC) films by lamination. During the first UV treatment, before lamination, the UV-curable monomers coated on one film substrate are solidified through photo-polymerization as the phase separation between the liquid crystals and the monomers. Introducing an adhesion-enhancement layer on the other plastic substrate and controlling the UV irradiation conditions ensure that UV-induced cross-linkable functional groups remain on the surfaces of the photo-polymerized layers. Thereby, the adhesion stability between the top and bottom films is much improved during a second (post-lamination) UV treatment by further UV-induced cross-linking at the interface. Because the adhesion-enhancement and PDLC layers prepared by the bar-coating process are solidified before lamination, the PDLC droplet distribution and the cell gap between the two plastic substrates remain uniform under the lamination pressure. This ensures that the voltage-controlled light transmittance is uniform across the entire sample.