• Title/Summary/Keyword: Critical viscosity temperature

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Rheological Characteristics of Thermal Gelatinized Corn Starch Solution (옥수수 전분 호화액의 리올로지 특성)

  • Kim, Ju-Bong;Lee, Shin-Young;Kim, Sung-Kon
    • Korean Journal of Food Science and Technology
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    • v.24 no.1
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    • pp.54-58
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    • 1992
  • The reological properties of commercial corn starch solutions at various concentrations($4{\sim}9%$) and temperatures($30{\sim}60^{\circ}C$) were investigated. The rheological behavior of corn starch solutions was illustrated by Herschel-Bulkley equation and exhibited pseudoplastic behavior with yield stress. The degree of pseudoplasticity of starch solution increased as the starch concentration increased but was independent on temperature. Apparent viscosity and yield stress of starch solutions were exponentially dependent on concentration and temperature. The critical concentrations for sol-gel transition and for the onset of close-packing of the starch granules were $6.22{\sim}6.52%\;and\;2.68{\sim}2.78%$ respectively.

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Synthesis of Multi-Walled Carbon Nanotube/Polystyrene (MWCNT/PS) Composites by Solution Process and Their Thermal Behavior (용액공정을 이용한 다중벽 탄소 나노튜브/폴리스티렌(MWCNT/PS) 복합체 합성 및 열적 거동)

  • Teng, Dayong;Shin, Young Hwan;Kwon, Younghwan
    • Applied Chemistry for Engineering
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    • v.19 no.4
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    • pp.421-426
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    • 2008
  • Multi-walled carbon nanotube/polystyrene (MWCNT/PS) composites with various MWCNT contents were prepared by using a solution process with an aid of surfactant. Particularly, PS's with 3 different molecular weights (${\bar{M}}_n$ = 101500 g/mole for PS-1, ${\bar{M}}_n$ = 89900 g/mole for PS-2, and ${\bar{M}}_n$ = 85000 g/mole for PS-3) were used in this study. Thermal behavior of these composites was examined by using an oscillator rheometer at $210^{\circ}C$ and $180^{\circ}C$, of above and below the critical flow temperature ($T_{cf}{\sim}195^{\circ}C$) of PS matrix, respectively. The storage and loss modulus, and the complex viscosity of these composites increased with increasing MWCNT content at both temperatures. Largest increases in the frequency-dependent moduli and complex viscosity were observed between 2 wt% and 5 wt% of MWCNTs at $210^{\circ}C$ and $180^{\circ}C$. Only the composite at $210^{\circ}C$ showed the rheological phase transition from a viscous-dominant to an elastic-dominant behavior of the composites at a certain MWCNT content. The MWCNT content at the rheological phase transition of MWCNT/PS composites generally increased with decreasing molecular weight of PS, and was measured to be 3.5 wt% for MWCNT/PS-1, 3.2 wt% for MWCNT/PS-2, and 3.0 wt% for MWCNT/PS-3 composites.

Changes of Quality in Stirred Yogurt during Storage at Various Conditions of Temperature and Shaking (저장온도와 교반조건을 달리한 요구르트의 저장 중 품질변화)

  • Lee, H.J.;Suh, D.S.;Shin, Y.K.;Goh, J.S.;Kwak, H.S.
    • Korean Journal of Food Science and Technology
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    • v.24 no.4
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    • pp.353-360
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    • 1992
  • This study was carried out to investigate the changes of quality in yogurt during delivery and storage. To do this, microbiological, physico-chemical and sensory properties in stirred yogurt were studied at different temperatures $(10^{\circ}C$ & $20^{\circ}C)$ and shakings (100 rpm & 200 rpm for 30 min). Titratable acidity and TCA soluble nitrogen in yogurt were increased in accordance with increase of temperature and time, while pH, lactose and lactic acid bacteria tended to be decreased. Interestingly enough, shaking conditions almost did not influence these studies. In sensory evaluation it showed that acidity was strong and sweetness was weak as increasing the storage temperature and time, but there were no significant differences until 10 days at $10^{\circ}C$ and 3 days at $20^{\circ}C$. Off-flavor was developed after 12 days at $10^{\circ}C$ with only 200 rpm shaking and after 6 days at $20^{\circ}C$ in both shaking conditions. These yogurts were not suitable for consumer. Viscosity in the yogurt became high as the temperature and time were increased. Viscosity was lower in yogurt shaked at 200 rpm than in non-shaked yogurt. Finally, this study indicates that temperature and shaking during delivery of yogurt may be critical in keeping quality of yogurt.

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Seismic behavior of deep-sea pipeline after global buckling under active control

  • Jianshuo Wang;Tinghao Meng;Zechao Zhang;Zhihua Chen;Hongbo Liu
    • Earthquakes and Structures
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    • v.26 no.4
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    • pp.261-267
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    • 2024
  • With the increase in the exploitation depth of offshore oil and gas, it is possible to control the global buckling of deep-sea pipelines by the snake lay method. Previous studies mainly focused on the analysis of critical buckling force and critical temperature of pipelines under the snake-like laying method, and pipelines often suffer structural failure due to seismic disasters during operation. Therefore, seismic action is a necessary factor in the design and analysis of submarine pipelines. In this paper, the seismic action of steel pipes in the operation stage after global buckling has occurred under the active control method is analyzed. Firstly, we have established a simplified finite element model for the entire process cycle and found that this modeling method is accurate and efficient, solving the problem of difficult convergence of seismic wave and soil coupling in previous solid analysis, and improving the efficiency of calculations. Secondly, through parameter analysis, it was found that under seismic action, the pipe diameter mainly affects the stress amplitude of the pipeline. When the pipe wall thickness increases from 0.05 m to 0.09 m, the critical buckling force increases by 150%, and the maximum axial stress decreases by 56%. In the pipe soil interaction, the greater the soil viscosity, the greater the pipe soil interaction force, the greater the soil constraint on the pipeline, and the safer the pipeline. Finally, the pipeline failure determination formula was obtained through dimensionless analysis and verified, and it was found that the formula was accurate.

Analysis of Whole Grains Extrusion by Response Surface Methodology (반응표면분석법에 의한 전곡립의 압출성형공정 분석)

  • Shin, Hae-Hun;Park, Bo-Sun;Lee, Hye-Lim;Choi, Moon-Jung;Hwang, Jae-Kwan
    • Korean Journal of Food Science and Technology
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    • v.33 no.6
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    • pp.686-692
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    • 2001
  • The effects of extrusion on solubilization of brown rice, glutinuous rice, barley and job's tear were analyzed by response surface methodology (RSM). Solubilization of whole grains by extrusion was characterized in terms of water solubility index (WSI), concentration of water soluble polysaccharides (C) and intrinsic viscosity $([\eta])$. Considering both concentration and intrinsic viscosity, a dimensionless target parameter $([\eta])$ was also included for analysing the extrusion effects on cereal extrusion. Response surface methodology analysis showed that the moisture content was the most significant contributor among screw speed, temperature and moisture content affecting the solubilizing phenomena of cereals processed with extrusion. Brown rice was not showed the significant relationship on $([\eta])$ because $([\eta])$ was more affected by intrinsic viscosity. The critical point of whole grains extrusion except brown rice was corresponded to screw speed of 300 rpm, moisture content of 20% and temperature of $120^{\circ}C$.

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Experimental Assessment of Drag Torque of Wet Clutch (습식 클러치 드래그 토크 특성의 실험적 평가)

  • Kim, Hansol;Chung, Koo-Hyun
    • Tribology and Lubricants
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    • v.33 no.6
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    • pp.269-274
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    • 2017
  • Currently, fuel efficiency becomes one of critical issues for automotive industries as concerns about environmental and energy problems grow. In an automatic transmission of an automobile, a drag torque due to a viscous drag of a fluid between friction and clutch plates is one of factors that degrade fuel economy. In this work, the drag torque characteristics of a wet clutch was experimentally investigated with respect to rotational speed, temperature of automatic transmission fluid (ATF), and gap between friction and clutch plates. The experimental results showed that drag torque increases to a certain level, and then decrease to the steady state value with increasing rotational speed. This behavior may be associated with two-phase flow of air and ATF at gap between friction and clutch plates. Also, it was found that the maximum drag torque value decreased as ATF viscosity decreases with increasing temperature. However, it was shown that the point at which the maximum drag torque occurs was not significantly affected by the ATF temperature. In addition, maximum drag torque was found to decrease as the gap between friction and clutch plates increased from 0.1 mm to 0.2 mm. Furthermore, it was observed that the generation of maximum drag torque was delayed as the gap increased. The outcomes of this work are expected to be helpful to gain a better understanding of drag torque characteristic of a wet clutch, and may therefore be useful in the design of wet clutch systems with improved performance.

Thermal Deformation Induced Preload Changein the Tilting Pad Journal Bearing (열변형으로 인한 틸팅패드 저널베어링의 예압 변화)

  • Suh, Junho;Hwang, Cheolho
    • Tribology and Lubricants
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    • v.32 no.1
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    • pp.1-8
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    • 2016
  • This paper focuses on the thermal deformation induced preload change in the tilting pad journal bearing, using a three-dimensional (3D) thermo-hydro-dynamic (THD) approach. Preload is considered as a critical factor in designing the tilting pad journal bearing. The initial preload measured under nil external load and nil thermal gradient is influenced by two factors, namely, the thermal deformation and elastic deformation. Thermal deformation is due to a temperature distribution in the bearing pads, whereas the elastic deformation is due to fluid forces acting on the pads. This study focuses on the changes induced in preload and film clearance due to thermal deformation. The generalized Reynolds equation is used to evaluate the force of the fluid and the 3D energy equation is used to calculate the temperature of the lubricant. The abovementioned equations are combined by establishing a relationship between viscosity and temperature. The heat transfer within the bearing pads, the lubricant, and the spinning journal is calculated using the heat flux boundary condition. The 3D Finite Element Method (FEM) is used in modeling the (1) heat conduction in the spinning journal and bearing pads, (2) thermal gradient induced thermal distortion of the spinning journal and pads, and (3) viscous shearing, and heat conduction and convection in a thin film. This evaluation method has an increased fidelity, and it can prove to be a cost-effective tool that can be used by designers to predict the dynamic behavior of a bearing.

Estimation on clamping load of high strength bolts considering various environment conditions

  • Nah, Hwan-Seon;Choi, Sung-Mo
    • Steel and Composite Structures
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    • v.24 no.4
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    • pp.399-408
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    • 2017
  • Of high strength bolts, the torque shear type bolt is known to be clamped normally when pin-tails are broken. Sometimes the clamping loads on slip critical connections considerably fluctuate from the required tension due to variation of torque coefficient. This is why the viscosity of lubricant affects the torque coefficient by temperature. In this study, the clamping tests of high strength bolts were performed independently at laboratory conditions and at outdoor environment. The temperatures of outdoor environment candidates were ranged from $-11^{\circ}C$ to $34^{\circ}C$ for six years. The temperature at laboratory condition was composed from $-10^{\circ}C$ to $50^{\circ}C$ at each $10^{\circ}C$ interval. At outdoor environment conditions, the clamping load of high strength bolt was varied from 159 to 210 kN and the torque value was varied from 405 to 556 Nm. The torque coefficients at outdoor environment were calculated from 0.126 to 0.158 when tensions were measured from 179 to 192 kN by using tension meter. The torque coefficients at outdoor environment conditions were analyzed as the range from 0.118 to 0.152. From these tests, the diverse equations of torque coefficient, tension dependent to temperature can be acquired by statistic regressive analysis. The variable of torque coefficient at laboratory conditions is 0.13% per each $1^{\circ}C$ when it reaches 2.73% per each $1^{\circ}C$ at outdoor environment conditions. When the results at laboratory conditions and at outdoor environment were combined to get the revised equations, the change in torque coefficient was modified as 0.2% per each $1^{\circ}C$ and the increment of tension was adjusted as 1.89 % per each $1^{\circ}C$.

Optimization of Process Condition for Fe Nano Powder Injection Molding

  • Oh, Joo Won;Lee, Won Sik;Park, Seong Jin
    • Journal of Powder Materials
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    • v.24 no.3
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    • pp.223-228
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    • 2017
  • Nanopowders provide better details for micro features and surface finish in powder injection molding processes. However, the small size of such powders induces processing challenges, such as low solid loading, high feedstock viscosity, difficulty in debinding, and distinctive sintering behavior. Therefore, the optimization of process conditions for nanopowder injection molding is essential, and it should be carefully performed. In this study, the powder injection molding process for Fe nanopowder has been optimized. The feedstock has been formulated using commercially available Fe nanopowder and a wax-based binder system. The optimal solid loading has been determined from the critical solid loading, measured by a torque rheometer. The homogeneously mixed feedstock is injected as a cylindrical green body, and solvent and thermal debinding conditions are determined by observing the weight change of the sample. The influence of the sintering temperature and holding time on the density has also been investigated. Thereafter, the Vickers hardness and grain size of the sintered samples have been measured to optimize the sintering conditions.

Synthesis and Surface Active Properties of Long Chain N-Acyl Collagen Derivatives (고급 지방산 N-아실 콜라겐 유도체의 합성 및 계면활성)

  • Kim, T.Y.;Nam, K.D.;Nam, S.I.;Ahn, J.H.;Lee, J.H.
    • Journal of the Korean Applied Science and Technology
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    • v.10 no.2
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    • pp.81-90
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    • 1993
  • The Surfactants composed of acylated aterocollagen which is produced by the acylation of the side chain amino radicals of aterocollagen with an aliphatic acid having 12 to 18 carbon atoms will be discussed in this study. This condensation is done at moderate reaction temperature (<$25^{\circ}C$) in aqueous alkaline solution. The products of this reaction were identified by UV/VIS spectroscopy and infrared spectroscopy. For these compounds, surface active properties and physical properties including isoelectric point, Krafft point, surface tension, critical micelle concentration(cmc), foaming power, viscosity behaviour, water holding capacity, skin irritation and emulsifying power were measured respectively. The experimental results received that the products have a good emulsifying power, excellent water holding capacity while having low skin irritation. Thus, these derivatives will be expected to be used as an emulsifying agent for O/W type cosmetic emulsion.