• Title/Summary/Keyword: Critical materials

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Oxidation Effect on the Critical Velocity of Pure Al Feedstock Deposition in the Kinetic Spraying Process (저온분사 공정에서 알루미늄 분말의 산화가 임계 적층 속도에 미치는 영향)

  • Kang, Ki-Cheol;Yoon, Sang-Hoon;Ji, Youl-Gwun;Lee, Chang-Hee
    • Journal of Welding and Joining
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    • v.25 no.4
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    • pp.35-41
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    • 2007
  • In kinetic spraying process, the critical velocity is an important criterion which determines the deposition of a feedstock particle onto the substrate. In other studies, it was experimentally and numerically proven that the critical velocity is determined by the physical and mechanical properties and the state of materials such as initial temperature, size and the extent of oxidation. Compared to un-oxidized feedstock, oxidized feedstock required a greater kinetic energy of in-flight particle to break away oxide film during impact. The oxide film formed on the surface of particle and substrate is of a relatively higher brittleness and hardness than those of general metals. Because of its physical characteristics, the oxide significantly affected the deposition behavior and critical velocity. In this study, in order to investigate the effects of oxidation on the deposition behavior and critical velocity of feedstock, oxygen contents of Al feedstock were artificially controlled, individual particle impact tests were carried out and the velocities of in-flight Al feedstock was measured for a wide range of process gas conditions. As a result, as the oxygen contents of Al feedstock increased, the critical velocity increased.

Critical Current Degradation Analysis in HTS Pancake Coil due to Self Field Effects

  • Nah, Wan-Soo;Joo, Jin-Ho;Yoo, Jai-Moo
    • Progress in Superconductivity
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    • v.1 no.1
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    • pp.68-72
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    • 1999
  • Since the discovery of high Tc superconductors, great efforts have been focused to develop high performance HTS magnets for the ultimate applications to power system devices. Magnet designers, however, have had difficulties in the estimation of the maximum operating current of the designed magnet from the tested short sample data, due to the degradation of the critical current density in the magnet. Similar story applies to the HTS electrical bus bar. It has been found that the critical current of Bi-2223 stacked tapes is much less than the total summation of critical currents of each tape, which is mainly attributed to the self magnetic fields. Furthermore, since the critical current degradation of Bi-2223 tape is greater in the normal magnetic field (to the tape surface) than in the parallel one, detailed magnetic field configurations are required to reduce the self field effects. In this paper, we calculate the self field effects of a stacked conductor, defining self field factors of normal and parallel magnetic fields to the tape surface. Finally, the critical current degradations in the HTS magnet are explained by the introduced self field factors of the stacked conductor.

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Pressure-Temperature Diagram of Critical Condition for Disproportionation of Nd-Fe-B Alloy in Hydrogen

  • Kwon, H.W.;Kim, D.H.;Yu, J.H.
    • Journal of Magnetics
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    • v.15 no.4
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    • pp.155-158
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    • 2010
  • The HDDR (hydrogenation, disproportionation, desorption, and recombination) process can be used as an effective way of converting a no coercivity Nd-Fe-B ingot material, with a coarse $Nd_2Fe_{14}B$ grain structure, to a highly coercive one with a fine grain structure. Careful control of the HDDR process can lead to an anisotropic powder with good $Nd_2Fe_{14}B$ grain texture; the most critical step for inducing texture is disproportionation. The critical conditions (hydrogen pressure and temperature) for the disproportionation reaction of fully hydrogenated $Nd_{12.5}Fe_{81.1-(x+y)}B_{6.4}Ga_xNb_y$ (x = 0 or 0.3, y = 0 or 0.2) alloys, in different atmospheres of pure hydrogen and a mixed gas of hydrogen and argon, was investigated with TPA (thermopiezic analyser). From this, the hydrogen pressure-temperature diagram showing the critical conditions was established. The critical disproportionation temperature of the fully hydrogenated $Nd_{12.5}Fe_{81.1-(x+y)}B_{6.4}Ga_xNb_y$ alloys was slightly increased as the hydrogen pressure decreased in both pure hydrogen and mixed gas. The critical disproportionation temperature of the hydrogenated alloys was higher in the mixed gas than in pure hydrogen. Addition of Ga and Nb increased the critical disproportionation temperature of the fully hydrogenated Nd-Fe-B alloys.

Frriction and Wear of Siamond-Like Carbon Films Produced by Plasma-Assisted CVD Technique

  • AkihiroTanaka;KazunoriUmeda;KazuyukiMizuhara;Ko, Myoung-Wan;Kim, Seong-Young;Shin, Seung-Yong;Lee, Sang-Hyun
    • The Korean Journal of Ceramics
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    • v.3 no.3
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    • pp.182-186
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    • 1997
  • Diamond-like carbon(DLC) films were deposited on silicon substreates by using an RF plasmaassisted CVD apparatus; the effects of deposition conditions such as CH4 gas pressure and substrate bias voltage on DLC film friction and wear were examined in both friction and scratch tests. In friction tests critical loads at which the friction coefficient increases abruptly depend on substrate bias voltages: critical loads deposited at a bias voltage of -100 V exceed those deposited at other bias voltages. Critical loads are correlated with DLC film hydrogen content. Critical DLC film loads in scratch tests depended considerably less than in friction tests. The friction coefficient of DLC films depends on neither substrate bias voltage nor CH4 gas pressure.

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Effect of Grain Size and Heat-treating Atmosphere on the Phase Stability of Y-TZP (입자크기와 열처리 분위기 변화에 따른 Y-TZP에서의 상안정성 변화)

  • Chung, Tai-Joo;Ahn, Seung-Su;Song, Eun-Wha;Oh, Kyung-Sik;Lee, Jong-Sook;Kim, Young-Sik
    • Journal of Powder Materials
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    • v.13 no.5 s.58
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    • pp.360-365
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    • 2006
  • The phase stability of tetragonal phase in Y-TZP was investigated in terms of the distribution of grain sizes and heat-treating atmosphere. Y-TZP with various grain sizes were prepared using duration time at $1600^{\circ}C$ as experimental parameter. Accumulated grain size distributions were built from the SEM micrographs and the amount of tetragonal phase were measured using XRD. Both results were compared to determine the critical grain size before and after heat-treatment in vacuum. The critical grain size drastically decreased compared with the small increase of average grain size due to the autocatalytic effect which critically affects the tetragonal to monoclinic phase transformation. After heat-treatment in reductive atmosphere critical grain size relatively increased due to the stabilization of tetragonal phase. The formation of oxygen vacancies during heat-treatment was ascribed to the increase of stability.

Improved Critical current Density in $MgB_2$ by Graphene nano-platelets (그래핀 나노플레이트에 의한 $MgB_2$의 임계전류밀도 향상)

  • Sinha, B.B.;Chung, K.C.;Chang, S.H.;Kim, J.H.;Dou, S.X.
    • Progress in Superconductivity
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    • v.14 no.1
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    • pp.34-38
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    • 2012
  • The effect of graphene inclusion in the ex-situ $MgB_2$ was analyzed with the help of resistivity behavior and critical current density studies. Amount of graphene was systematically varied from 0% for pristine sample to 3% by the weight of $MgB_2$. Graphene that is considered as a good source of carbon was found to be intact without any significant carbon doping in $MgB_2$ structure as reveled by XRD measurements. There was no signature of graphene inclusion as far as the superconducting transition is concerned which remained same at 39 K for all the samples. The transition width being sensitive to defect doping remained more or less about 2 K for all the samples showing no variation due to doping. Although there was no change in the superconducting transition or transition width, the graphene doped sample showed noticeable decrease in the overall resistivity behavior with respect to decrease in temperature. The graphene inclusion acted as effective pinning centers which have enhanced the upper critical field of these samples.

High field HTS insert coils : Status and key technical issue

  • Schwartz, Justin
    • 한국초전도학회:학술대회논문집
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    • v.10
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    • pp.22-22
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    • 2000
  • The discoveries of high temperature superconductors received great attention due to their high critical temperatures. These materials also exhibit extremely high critical magnetic fields and high critical current density at low temperature, high magnetic field. Thus, they are the most promising materials for superconducting magnets above 20 T. In this talk, progress in the development of HTS materials and insert coils at the National High Magnetic Field Laboratory will be reviewed. In 1999, a Bi-2212 stack of double pancakes generated 3 T in a 19 T background field. These results will be reviewed in terms of implications for future systems. Individual double pancakes of Bi-2223 have also been tested and their performance will also be discused. The present goal of a 57 system will be presented and the key technical requirements for larger, higher field systems will be addressed. It will be shown that in addition to increased critical current density, improved mechanical performance (stain resistanced) is necessary for high field systems. Furthemore, improvements in the conductor n-value will improve prospects for operational systems.

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