• Title/Summary/Keyword: CrB

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Characteristics of a Novel Acinetobacter sp. and Its Kinetics in Hexavalent Chromium Bioreduction

  • M., Narayani;K., Vidya Shetty
    • Journal of Microbiology and Biotechnology
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    • v.22 no.5
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    • pp.690-698
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    • 2012
  • Cr-B2, a Gram-negative hexavalent chromium [Cr(VI)] reducing bacteria, was isolated from the aerator water of an activated sludge process in the wastewater treatment facility of a dye and pigment based chemical industry. Cr-B2 exhibited a resistance for 1,100 mg/l Cr(VI) and, similarly, resistance against other heavy metal ions such as $Ni^{2+}$ (800 mg/l), $Cu^{2+}$ (600 mg/l), $Pb^{2+}$ (1,100 mg/l), $Cd^{2+}$ (350 mg/l), $ZN^{2+}$ (700 mg/l), and $Fe^{3+}$ (1,000 mg/l), and against selected antibiotics. Cr-B2 was observed to efficiently reduce 200 mg/l Cr(VI) completely in both nutrient and LB media, and could convert Cr(VI) to Cr(III) aerobically. Cr(VI) reduction kinetics followed allosteric enzyme kinetics. The $K_m$ values were found to be 43.11 mg/l for nutrient media and 38.05 mg/l for LB media. $V_{max}$ values of 13.17 mg/l/h and 12.53 mg/l/h were obtained for nutrient media and LB media, respectively, and the cooperativity coefficients (n) were found to be 8.47 and 3.49, respectively, indicating positive cooperativity in both cases. SEM analysis showed the formation of wrinkles and depressions in the cells when exposed to 800 mg/l Cr(VI) concentration. The organism was seen to exhibit pleomorphic behavior. Cr-B2 was identified on the basis of morphological, biochemical, and partial 16S rRNA gene sequencing chracterizations and found to be Acinetobacter sp.

Electrical Properlies of $Cr_2$$O_3$ Added $CaMnO_3$-$CaTiO_3$ Perovskite Thermistor ($Cr_2$$O_3$가 첨가된 $CaMnO_3$-$CaTiO_3$계 페로브스카이트 써미스터의 전기적 특성)

  • 양기호;윤상옥;윤종훈;장성식
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.07a
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    • pp.399-402
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    • 2000
  • For improvement of B constant in $CaMnO_3$-$CaTiO_3$ perovskite type thermistors, effect of $Cr_2$$O_3$ addition ranged from 0.0wt% to 5.0wt% on electrical properties were investigated with contents and sintering temperatures in the view of crystal and microstructures. The solubility limit of Cr$_2$O$_3$was up to 0.5wt% judging from the result of lattice parameter. The grain size was decreased and the resistance at room temperature and B constant were increased with the addition of $Cr_2$$O_3$.On particular, B constant of$CaMnO_{3-x}$$Cr_2$$O_3$ system was increased greatly from 1574k to 2598k at 0.5wt% $Cr_2$$O_3$addition. Further addition of $Cr_2$$O_3$, however, resulted in the decrease of the resistance and B constant due to the $Cr_2$$O_3$ precipitation on the grain boundary. As the$CaTiO_3$contents increased in the $CaMnO_3$-$CaTiO_3$ system, the resistance at room temperature and B constant were highly changed.

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Precipitation Behavior of α-Cr Particle in B2-type Intermetallic Compounds β-NiAl (B2형 금속간화합물 β-NiAl중에 α-Cr입자의 석출거동)

  • Han, Chang-Suck;Kim, Youn-Che
    • Journal of the Korean Society for Heat Treatment
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    • v.9 no.2
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    • pp.91-102
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    • 1996
  • Microstructural control to produce multiphase structure has received much attention to improve the high temperature strength as well as low temperature ductility of intermetallics. Transmission electron microscopic investigation has been carried out concerning the effect of Cr-precipitation on the mechanical properties of B2-ordered NiAl containing 4 to 8 mol% of Cr. By aging at temperatures around 973 K after solution annealing, fine spherical precipitates took place homogeneously in the NiAl matrix and the alloys hardened appreciably. Selected area electron diffraction (SAED) patterns have not revealed any additional extra-spots during aging, because the Cr-particles show cube-cube orientation relationship and keep a perfect coherency with the ordered matrix lattice. Dislocations were confirmed to bypass the particles during deformation. Although the dispersion of Cr-particles increased the yield strength of NiAl at intermediate temperature, the strength decreased appreciably at higher temperatures.

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Effects of Cr and Nb on the nigh Temperature Oxidation of TiAl

  • D.B. Lee;K.B. Park;M. Nakamura
    • Transactions of Materials Processing
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    • v.8 no.3
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    • pp.319-319
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    • 1999
  • From isothermal and cyclic oxidation tests on thermomechanically treated Ti-5%Al, Ti47%Al-4%Cr, and Ti-48%Al-2%Cr-2%Nb alloys at 800, 900, 1000℃ in air, it was found that Ti-48%Al-2%Cr-2%Nb and Ti-47%Al-4%Cr had the best and the worst oxidation resistance, respectively. The oxide scales consisted primarily of TiO₂and Al₂O₃, with and without a small amount of dissolved Cr and 7b ions, depending on the alloy composition. These ions were slightly enriched inside the inner oxide layer, and strongly enriched around the scale-matrix interface. The outer TiO₂-rich layer was formed by the outward diffusion of Ti ions, while the inner (TiO₂+A1₂O₃,) mixed layer was formed by the inward transport of oxygen. The outward movement of Al ions farmed the intermediate Al₂O₃-rich Iayer, above talc prepared alloys.

Effects of Alloying Elements on the Pitting Behavior of Ti-Al Intermetallic Compounds (TiAl 금속간화헙물의 공식거동에 미치는 합금원소의 영향)

  • 이호종;최한철
    • Journal of Surface Science and Engineering
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    • v.31 no.3
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    • pp.157-164
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    • 1998
  • Effects of alloying elements on the pitting behavior of Ti-Al intermetalic compounds in the electrolytic soution containing Cl- were investigated through electrochemical tets and corrosion morphologies. Corrosion potential increased in the case of Cr addition to Ti-48%Al, whereas it decreased in the case of Si and B addition. The simultaneous addition of Cr and Si increased passive current density and decrosion corrosion potential. The passive current density of N addtion was higher than that of B addition in H2SO4 solution. With the addition of alloying elements, The pitting resistance decreased in order of TiAl>TiAlSi>TiAlN>TiAlB>TiAlCr and whin siumultaneous addition, it decreased in order of TiAlCrSi>TiAlCrBN>TiAlCrrN. The surface merohology after pitting test showed that the TiAl coataining Si had for fewer pits than that containing Cr and N simultaneously.

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The Effect of Additional Elements and Grain Size Distribution on the Magnetic Properties of the Nd-Fe-B Sintered Magnets (Nd-Fe-B계 소결자석의 자기적 특성에 미치는 첨가원소와 결정립 분포의 영향)

  • Hong, Yeon-Gi;Kim, Jong-O
    • Korean Journal of Materials Research
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    • v.8 no.9
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    • pp.819-824
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    • 1998
  • The influence of casting cooling rate during the preparation of ingots on the grain size distribution and the magnetizing ability of $\textrm{Nd}_{16}\textrm{Fe}_{72}\textrm{V}_{4}\textrm{B}_{8}$ sintered magnets were investigated. Sintered magnets prepared from copper mold which allow a higher cooling rate, show a smaller grain size distribution and god magnetizing ability. The effects of adding bride forming elements, such as Cr, Mn, Nb, and W on the magnetic properties of Nd-Fe-B sintered magnets were also investigated. Both Cr and W addition increase coercivity and the resultant $\textrm{Nd}_{16}\textrm{Fe}_{72}\textrm{Cr}_{4}\textrm{B}_{9}$ alloy exhibits a similar magnetizing ability in comparison with $\textrm{Nd}_{16}\textrm{Fe}_{72}\textrm{V}_{4}\textrm{B}_{8}$ alloy.

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Effects of doping on the electrical conductivity and particle size in olivine type $LiFePO_4$ powders (올리빈형 $LiFePO_4$ 분말의 전기전도도와 입도 크기에 미치는 도핑의 영향)

  • Bai, Jin-Tao;Ha, Jung-Soo;Kim, Chang-Sam
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.18 no.6
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    • pp.248-252
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    • 2008
  • To get a fine $LiFePO_4$ powder with high electrical conductivity, the influences of doping of aliovalent elements(Cr+B and Cr+Al) on electrical conductivity and of heat treatment conditions on particle size of the doped powders were studied. Two kinds of the doped powders $LiFe_{0.965}Cr_{0.03}B_{0.005}PO_4$ and $LiFe_{0.065}Cr_{0.03}Al_{0.005}PO_4$ were synthesized using mechanochemical milling and subsequent heat treatment at $675{\sim}750^{\circ}C$ for $5{\sim}10\;h$. The doping enhanced grain growth and electrical conductivity. The electrical conductivity at $30^{\circ}C$ was $1{\times}10^{-8}S/cm$ in the doped with Cr and Al, and $5{\times}10^{-10}S/cm$ in the undoped one.

The Study of Hyperfine Fields for Co0.9Zn0.1Cr1.9857Fe0.02O4 (Co0.9Zn0.1Cr1.9857Fe0.02O4 물질의 초미세자기장 연구)

  • Choi, Kang-Ryong;Kim, Sam-Jin;Kim, Chul-Sung
    • Journal of the Korean Magnetics Society
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    • v.18 no.1
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    • pp.39-42
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    • 2008
  • [ $AB_2X_4$ ](A, B=Transition Metal, X=O, S, Se) are cubic spinel normal ferrimagnets, in which M ions occupy the tetrahedral sites and Cr ions occupy the octahedral sites. Recently, they have been investigated for behaviour of B site ions and A-B interaction. Polycrystalline $[Co_{0.9}Zn_{0.1}]_A[Cr_{1.98}{^{57}Fe_{0.02}}]_BO_4$ compound was prepared by wet-chemical process. The ferrimagnetic transition was observed around 90K. $M\"{o}ssbauer$ absorption spectra at 4.2K show that the well-developed two sextets are superposed with small difference in hyperfine fields($H_{hf}$). The hyperfine fields of $CoCr_{1.98}{^{57}Fe_{0.02}}O_4$ and $Co_{0.9}Zn_{0.1}Cr_{1.98}{^{57}Fe_{0.02}}O_4$ were determined to be 488, 478 kOe and 486, 468 kOe, respectively. We notice that the one of the magnetic hyperfine field values changes with Zn ion substitution. These results suggest the incommensurate states and spin-reorientation temperature($T_S=18K$) changes with Zn ions substitution below spin-reorientation temperature($T_S=28K$) of $CoCr_{1.98}{^{57}Fe_{0.02}}O_4$

The Efficient Detection Algorithm of Various CR signals using Channel Bonding in TV White Space (TV White Space에서 채널 본딩된 다양한 CR 시스템의 효율적인 검출 알고리즘)

  • Lim, Sun-Min;Jung, Hoi-Yoon;Jeong, Byung-Jang
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.36 no.5A
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    • pp.536-542
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    • 2011
  • For efficient utilization of spectrum resources in TV white space after DTV transition, FCC allowed usage of the spectrum for CR system. The CR system is required to cognize channel usage state for utilizing the unused spectrum in TV white space which coexists various primary and secondary systems. In the meantime, as a demand for high throughput communication had been increased recently, CR systems also consider to adopt channel bonding technology, thus spectrum sensing for channel bonded system is essentially required. In this paper, we propose a novel spectrum sensing algorithm for channel bonding system using a single channel receiver. For IEEE 802.l1af signal, the proposed algorithm provide detection probability of 90% with false alarm probability 10% at SNR -18dB for single channel system and at SNR -7dB for 8 channel bonded system, respectively. Utilizing the proposed scheme, we can detect channel bonded signal using only a single receiver, therefore system overhead for spectrum sensing can be reduced significantly.