• Title/Summary/Keyword: Cr-Mo 강

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A study on the residual stress at the weld joint of 2.25Cr-1.6W heat resistant steel (보일러용 배관재 2.25Cr-1.6W계 내열강의 용접부 응력 해석)

  • Lee, Y.S.;Lee, K.W.;Lee, J.B.;Kim, Y.D.;Kong, B.W.;Ryu, S.H.;Kim, J.T.;Kim, B.S.;Jang, J.C.
    • Proceedings of the KWS Conference
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    • 2009.11a
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    • pp.62-62
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    • 2009
  • 석탄화력발전소의 CO2배출량 감소와 고효율, 대용량화로 인해 초초임계압(USC:Ultra Super Critical) 화력발전소의 건설이 증가하고 있다. USC 발전소는 효율향상을 위한 증기온도와 압력의 상승 때문에 보일러 고온고압부에 기존의 소재에 비해 고온강도와 내산화성의 재료물성이 향상된 신소재 적용이 불가피하다. 특히 사용된 신소재 중에서 보일러 본체를 구성하는 수냉벽관(Water wall), 과열기와, 재열기용 튜브 및 후육부인 헤더와 배관재로 기존의 2.25Cr-1Mo강을 개량한 2.25Cr-1.6W계 내열강이 적용되고 있다. 2.25Cr-1.6W강은 SMI와 MHI가 공동개발한 소재로 1995년 튜브제품이, 1999년에 단조, 파이프재, 플레이트제품이 ASME code case로 등재되었고, 2009년 ASME code case 2199-4로 개정되어 사용 중이다. 이 소재는 2.25Cr-1Mo강에 고온강도 개선을 위해 석출강화효과가 있는 V과 Nb을 첨가하였고, 탄화물의 열적안정성과 고용강화효과 증대를 위해 W을 첨가하였다. 그리고 제작성과 용접성 및 재료의 인성 향상을 위해 B첨가와 C함량을 낮추었다. 합금성분의 첨가와 조정에 의해 고온강도는 개선되었지만, 보일러 설치 및 보수를 위한 용접과정에서 용접금속과 CGHAZ(Coarse Grain HAZ)에서 용접균열이 발생하였다. 대부분의 용접균열은 용접결함이나 고온 혹은 저온균열이 아닌 2.25Cr-1.6W계강의 강도 개선을 위해 첨가한 V과 Nb이 용접후열처리 도중 입내에 MX형태의 미세석출로 입내를 강화시킴으로서 발생한 재열균열 민감성 증대에 기인된 것으로 판단된다. 이에 본 연구에서 용접 및 후열처리 과정에서 용접금속과 HAZ에서 발생하는 용접금속의 응력분포를 전산해석을 통해 확인하고 실제 후육파이프 용접부에서 잔류응력을 측정해 비교하였다. 용접부 응력분포는 SYSWELD 프로그램을 사용해 해석을 수행하였고, 발전소 실배관재의 용접부 응력측정은 수평부 측정이 용이하도록 지그를 부착한 Potable 잔류응력측정기를 사용해 Hole Drilling Method(HDM)를 적용하여 잔류응력을 측정하였다. 해석 결과 CGHAZ부위의 잔류응력이 용접금속과 기타 부위에 비해 높은 응력분포를 나타냈으며, 이는 CGHAZ와 용접용융선 부근에서 균열이 발생하는 실제값과 일치하는 결과를 보였다. 실제 배관재 용접부에서 측정한 잔류응력값은 항복응력의 약 50% 이하 응력값을 나타냈다. 배관 구조에 기인한 시스템응력의 영향을 제거하기 위해 배관재 용접부를 중심으로 양끝단을 절단 후 용접부에서 측정한 응력은 항복응력 대비 25%수준의 낮은값을 보였다. 그러나 배관재가 장기간 고온환경에 노출되었고 용접금속 내부의 균열이 발생한 상태에서 측정하였기 때문에 용접잔류응력은 상당부분 해소되어 상대적으로 낮은 응력값이 얻어진 것으로 판단된다.

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A Study on the High Frequency Ultrasonic Attenuation Characterization in Artificially Aging Degraded 2.25Cr-1Mo Steel (2.25Cr-1Mo 강 인공 열화재의 고주파수 초음파 감쇠특성에 관한 연구)

  • Park, Ik-Keun;Park, Un-Su;Kim, Chung-Seok;Kim, Hyun-Mook;Kwun, Sook-In;Byeon, Jai-Won
    • Journal of the Korean Society for Nondestructive Testing
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    • v.21 no.4
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    • pp.439-445
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    • 2001
  • The destructive method is reliable and widely used lot the estimation of material degradation but, it have time-consuming and a great difficulty in preparing specimens from in-service industrial facilities. Therefore, the estimation of degraded structural materials used at high temperature by nondestructive evaluation such as electric resistance method, replica method, Barkhausen noise method, electro-chemical method and ultrasonic method are strongly desired. Ultrasonic nondestructive evaluation technique has been reported good to attain efficiency of measurement, high sensitivity of measurement, and rapidity and reliability of result interpretation. In this study, it was verified experimentally the feasibility of the evaluation of degraded 2.25Cr-1Mo steel specimens which were prepared by the isothermal aging heat treatment at $630^{\circ}C$ by high frequency longitudinal wave method investigating the change of attenuation coefficient by FFT analysis and wavelet transform. Because of carbide precipitation increase and spheroidization near grain boundary of microstructure to aging degradation, attenuation coefficient had a tendency to increase as degradation proceeded. It was identified possibly to evaluate degradation using the characteristics of high-frequency ultrasonics. Frequency dependence of ultrasonic attenuation coefficient to aging degradation appeared large, which made sure that attenuation coefficient is an important parameter for evaluation of aging degradation.

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A Basic Study on Growth Characteristics of the Small Surface Crack in 21/4 Cr-1 Mo Steel (2 1/4 Cr-1Mo강의 작은 표면균열의 성장에 관한 기초적 연구)

  • 서창민;강용구
    • Journal of Ocean Engineering and Technology
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    • v.1 no.1
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    • pp.104-110
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    • 1987
  • Fatigue tests by axial loading (R = 0.05) were carried out to investigate fatigue crack growth characteristics of small surface cracks in 2 1/4 Cr-1 Mo steel at room temperature by using flat specimens with a small artificial pit. All the data of the fatigue crack growth rate obtained in the present test are determined as a function of the stress intensity factor range about a semi-elliptical crack, so that the application of linear fracture mechanics to the surface fatigue crack growth and to the fatigue crack growth into depth, and all the data obtained from tests were discussed in comparison with the data of Type 304 stainless steel and two type of mild steel under the same test conditions. The obtained results are as follows: 1)When the cycle ratios are same, surface fatigue crack length and its depth are almost same and fall within a narrow scatter band in spite of different stress levels. 2)Relations of the surface fatigue crack growth rate (da/dN) and fatigue crack growth rate into depth (db/dN) to its stress intensity factor range ($\Delta K_{Ia}, \Delta K_{Ib}$) can be plotted as a straight line at log-log diagram without dependence of stress level and coincide with the data of part-through crack in various steels.

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Thermo-Mechanical Fatigue Crack Propagation Behaviors of 1.5Cr-0.67Mo-0.33V Alloy (1.5Cr-0.67Mo-0.33V강의 열피로 크랙전파 거동)

  • 송삼홍;강명수
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.19 no.9
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    • pp.2133-2141
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    • 1995
  • The thermo-mechanical fatigue tests were performed on the specimens extracted from 1.5Cr-0. 67Mo-0.33V alloy. The characteristics of thermo-mechanical fatigue crack propagation were examined and reviewed in view of fracture mechanics. The results obtained from the present study are summarized as follows : (1) The propagation characteristics of isothermal low-cycle fatigue crack are dominated by .DELTA.J$_{f}$ in case of PP waveform, and .DELTA.J$_{c}$ in case of CP waveform. (II)The propagation characteristics of thermo-mechanical fatigue crack are dominated by .DELTA.J$_{c}$ for in-phase case, and by .DELTA.J$_{c}$ for out-of-phase. The present results were in good agreement with the equation of propagation law for isothermal low-cycle fatigue crack in case of thermo-mechanical fatigue.tigue.e.

Creep Property Assessment and Creep Life Estimation for High-Temperature Tube Material(2.25Cr1Mo Steel) in Power Plants by LMP (발전용 고온 배관재료 2.25Cr1Mo 강의 크리프 특성과 LMP에 의한 크리프 수명의 예측)

  • Lee, Sang-Guk;Jeong, Min-Hwa;O, Se-Gyu;Song, Jeong-Geun
    • Journal of Ocean Engineering and Technology
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    • v.12 no.2 s.28
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    • pp.65-70
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    • 1998
  • In this report, the creep properties and creep life estimation by Larson-Miller Parameter(LMP) Method for 2.25Cr1Mo steel to be used as power plant tubes or other components were presented at the high temperatures of 500, 550, and $600^{\circ}C$. It was confirmed experimentally and quantitatively that a creep life estimation equation at such various high temperatures was well derived by LMP and could be used very effectively within the creep life of 10$^3$ hours, but very unreliable and even dangerous for design in a long term of creep life such as 10$^4$ or $10^5$ hours.

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Assessment of Creep Damage on a High Temperature Pipe Bend of 0.5Cr0.5Mo0.25V Ferritic Steel for Thermal Power Plant (화력발전소용 0.5Cr 0.5Mo 0.25V 강 곡관배관의 크리프 손상평가)

  • Hyun, Jung-Seob;Heo, Jae-Sil;Kim, Bong-Soo
    • Journal of the Korean Society for Precision Engineering
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    • v.27 no.3
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    • pp.127-134
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    • 2010
  • Components in thermal power plants are subjected to service conditions under which creep damages take place causing material exhaustion. Comprehensive creep damage investigations have been performed on a 0.5Cr0.5Mo0.25V pipe bend which had been taken out of service after 117,603h and 501 start-ups because of severe cracks. The propagation of creep damage in a long term exposed pipe bend has been analysed by the replication, Indentation and hardness tests. Also, Calculation of creep lifetime has been investigated in order to verify actual lifetime of a damaged pipe bend. By measuring diametrical expansion, Accumulated creep strain and creep strain rate were calculated. Calculated results of creep lifetime on the Larson-Miller Parameter method are good agreement with actual service-exposed hour.

Evaluation of Degradation Behavior of the Long-Term Serviced Boiler Header (장기 사용 보일러 헤더의 열화거동 평가에 관한 연구)

  • Gwon, Jae-Do;Bae, Yong-Tak;Choe, Seong-Jong
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.24 no.7 s.178
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    • pp.1673-1680
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    • 2000
  • The degradation of a boiler header constructed by a material, 1Cr-0.5Mo steel in a fossil power plant is observed when the header is exposed for a long period to the high temperature and pressure. The present investigations are for evaluating the effect of the degradation on the material, such as its strength changes. Reheat-treated metal is used to compare the mechanical properties of the degraded and that of reheat-treated materials. Through the investigation, following results are obtained 1) the area ratio of ferrite in the reheat-treated material is larger than that of the degraded material, 2) the hardness and tensile strength of the degraded material are lower than that of the reheat-treated material, 3) the ductile-brittle transition temperature(DBTT) increased toward high temperature region, 4) the fatigue crack growth rate(FCGR) of the degraded material is higher than that of the reheat-treated material in the region of low ΔK value while FCGR of the both materials are similar in high ΔK region.

A Study on High Temperature Crack Growth Behavior in 2.25Cr-lMo Steel Weldments at $550^{\circ}C$ ($550^{\circ}C$에서의 2.25Cr-1Mo 강 용접부의 고온 균열성장 거동에 관한 연구)

  • Kim, Ho-Kyung;Chung, Kang;Chung, Chin-Sung
    • Journal of Welding and Joining
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    • v.19 no.3
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    • pp.278-284
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    • 2001
  • Both creep deformation and creep crack growth experiments have been conducted on 2.25Cr-1Mo steel weldment in order to provided an information on residual life prediction of structural component weldment containing a crack. The stress exponent of creep deformation equation for the base metal and weldment at 823k were found to be 10.2 and 7.3, respectively. These two values could be assumed that dislocation climb processes are controlling the creep deformation of both materials. The creep rate of the weldment was very low, compared with that of base metal under the same applied stress. Whereas the creep crack growth rate of the weldment was almost twice higher than that of base metal under the fixed value of $C^*$. This may indicate that the weldment is stronger than the base metal in view of creep deformation and is brittle during creep crack growth due to the intrinsic microstructure of banite and relatively higher and Mn contents.

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A Study on the Fatigue Crack Propagation Behavior of Cr-Mo-V Alloy with Micro Defects at High Temperature. (미소 원공결함을 갖는 Cr-Mo-V강의 고온피로 크랙전파거동)

  • Song, Samhong;Kang, Myungsoo
    • Journal of the Korean Society for Precision Engineering
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    • v.13 no.12
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    • pp.70-77
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    • 1996
  • Fatigue tests were carried out at high temperature on a Cr-Mo-V steel in order to assess the fatigue life of components used in power plants. The characteristics of high temperature fatigue were divided in terms of cycle-dependent fatigue and time-dependent fatigue, each crack propagation rate was examined with respect to fatigue J-integral range, .DELTA. J$_{f}$and creep J-integral range, .DELTA. J$_{c}$. The fatigue life was evaluated by analysis of J-integral value at the crack tip with a dimensional finite element method. The results obtained from the present study are summarized as follows : The propagation characteristics of high temperature fatigue cracks are determined by .DELTA. J$_{f}$for the PP(tensile plasticity-compressive plasticity deformation) and PC(tensile plasticity - compressive creep deformation) stress waveform types, and by .DELTA. J$_{c}$for the CP(tensile creep- compressive plasticity deformation) stress waveform type. The crack propagation law of high temperature fatigue is obtained by analysis of J-integral value at the crack tip using the finite element method and applied to examine crack propagation behavior. The fatigue life is evaluated using the results of analysis by the finite element method. The predicted life and the actual life are close, within a factor of 2.f 2.f 2.

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Characteristics of microstructure and mechanical strength of ASTM A387-Gr.91 Steel deteriorated under high-temperature (고온 열화된 ASTM A387-Gr. 91 강의 미세 조직 및 기계적 강도 특성)

  • Jeong, Gwang-Hu;Han, Min-Su;Kim, Seong-Jong
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2018.06a
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    • pp.111-111
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    • 2018
  • ASTM A387-Gr.91 강은 우수한 고온 강도, 크리이프 저항성 그리고 내산화성 등으로 인해 화력 및 바이오매스 발전 시설과 같은 고온 설비의 구조재료로 널리 사용되고 있다. 고온 환경에서 높은 강도는 탄화물과 탄질화물에 의한 석출강화가 주 요인으로 작용한다. 열처리 과정에서 Mo, Cr, Mn, 그리고 Fe는 구-오스테나이트 및 마르텐사이트 라스 입계에 $M_{23}C_6$ 탄화물로 석출되며, V, Nb, 및 N은 조직 내부에 미세한 MX 탄질화물로 석출된다. 따라서 합금의 고온 강도는 조직 내 석출물의 개수밀도와 크기에 크게 의존한다. 그러나 적용 환경의 특성 상 고온 노출에 따른 2차상 석출 및 조대화의 조직열화 현상이 발생하며, 이는 재료의 강도를 저하시킨다. 본 연구에서는 ASTM A387-Gr.91 강의 미세조직 열화에 따른 강도저하 및 파괴 양상을 고찰하는데 그 목적을 두었다. 본 연구에서 사용된 ASTM A387-Gr.91 강의 화학성분(wt, %)은 0.1 C, 0.38 Si, 0.46 Mn, 0.25 Ni, 8.38 Cr, 0.93 Mo, 0.18 V, 0.09 Nb, 그리고 나머지는 Fe 이다. 조직열화 및 기계적 강도저하 특성을 평가하기 위한 등온열화는 $650^{\circ}C$의 대기 환경에서 최대 1000시간동안 실시하였다. 열화된 시험편의 미세조직 및 탄화물에 대한 분석은 SEM과 EDS를 이용하여 실시하였다. 그리고 기계적 강도 평가는 인장실험과 비커스 경도시험을 통해 실시하였다. 또한 열화 시간에 따른 파단양상의 변화를 관찰하기 위해 인장시험편의 파단면을 SEM과 EDS를 이용하여 분석하였다. 그 결과, 열화에 따른 마르텐사이트 라스의 소실, 탄화물의 조대화, 그리고 2차상 석출의 조직 열화현상이 나타났다. 또한 기계적 강도는 조직 열화에 따라 저하되는 경향을 나타냈다.

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