• Journal of the Korean institute of surface engineering
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• v.52 no.3
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• pp.111-116
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• 2019

Chromium was coated on a steel substrate by the Cr(III) electroplating method, and corroded at $500-900^{\circ}C$ for 5 h in $N_2/0.1%H_2S-mixed$ gas to study the high-temperature corrosion behavior of the Cr(III) coating in the highly corrosive $H_2S-environment$. The coating consisted of (C, O)-supersaturated, nodular chromium grains with microcracks. Corrosion was dominated by oxidation owing to thermodynamic stability of oxides compared to sulfides and nitrides. Corrosion initially led to formation of the thin $Cr_2O_3$ layer, below which (S, O)-dissolved, thin, porous region developed. As corrosion progressed, a $Fe_2Cr_2O_4$ layer formed below the $Cr_2O_3$ layer. The coating displayed relatively good corrosion resistance due to formation of the $Cr_2O_3$ scale and progressive sealing of microcracks.

• Journal of the Korean institute of surface engineering
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• v.20 no.2
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• pp.49-59
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• 1987

The properties of $Cr_2O_3-Al_2O_3-SiO_2$ composite oxide coatings on steel surface were investigated. The results obtained were as follows: The microhardness of oxide coating layer increased with increasing heat-treatment temperature and $Cr_2O_3$ content in coating layer. The hardness showed the highest value (850Hv) treated at 700$^{\circ}C$ for $SiO_2:Al_2O_3:Cr_2O_3$=1:1:4. Increasing heat-treatment temperature, corrosion current density became lower and coating layer became denser. The corrosion current density showed the lowest value $(6.5{\times}10^{-5}\;Acm^2)$ treated at 750$^{\circ}C\;for\;SiO_2:Al_2O_3:Cr_2O_3$=1:1:3. These results were explained by protective layer which was formed during heat-treatment. The bonding between matrix and coating layer is expected to be made mechanically and chemically by the inter diffusion of Ni and Fe. The composite oxide coating was formed by softening of the binder with increasing heat-treatment temperature. The strengthening of coating layer is to be resulted from the dispersion of major oxide particles.

• Journal of Powder Materials
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• v.24 no.5
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• pp.370-376
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• 2017

In this study we manufacture a Ni-Cr-B-Si +WC/12Co composite coating layer on a Cu base material using a laser cladding (LC) process, and investigate the microstructural and mechanical properties of the LC coating and Ni electroplating layers (reference material). The initial powder used for the LC coating layer is a powder feedstock with an average particle size of $125{\mu}m$. To identify the microstructural and mechanical properties, OM, SEM, XRD, room and high temperature hardness, and wear tests are implemented. Microstructural observation of the initial powder and LC coating layer confirm the layer is composed mainly of ${\gamma}-Ni$ phases and WC and $Cr_{23}C_6$ carbides. The measured hardness of the LC coating and Ni electroplating layers are 653 and 154 Hv, respectively. The hardness measurement from room up to high temperatures of $700^{\circ}C$ result in a hardness decrease as the temperature increases, but the hardness of the LC coating layer is higher for all temperature conditions. Room temperature wear results show that the wear loss of the LC coating layer is 1/12 of the wear level of the Ni electroplating layer. The measured bond strength is also greater in the LC coating than the Ni electroplating.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2017.05a
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• pp.857-863
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• 2017

In this paper, the process of electro Ni and electro Cr plating is studied for the purpose of thermal barrier to protect the inner wall combustion chamber. The chamber is under the environment of very high temperature and high pressure when propellants burn in there. As one of the thermal barrier coatings, Zr-based thermal spray coating has been applied to the chamber. However, peeling of coating layer can occur under such a hard condition because of the difference of thermal expansion coefficients between the ceramic and the metallic wall. We study the characteristics of Ni-Cr coating and establish its process. It is found that the thickness of over $100{\mu}m$ of Ni and Cr coating layers with the uniformity of ${\pm}10%$ can be obtained with the used of as-developed plating bath.

• Journal of the Korean Society of Propulsion Engineers
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• v.14 no.5
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• pp.45-50
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• 2010

Thermal analyses have been performed to study the effect of location of fuel ring and thermal barrier coatings in regenerative cooling channels in a full-scale combustor. For the effective cooling, the fuel ring has better be installed near axial location of the low expansion ratio and low heat flux, and branching of cooling channels is preferable. Also, the radiative cooled nozzle extension is thought to be reasonable for the cooling of combustor walls. Among the possible coatings, $Y_2O_3$ stabilized $ZrO_2$ coating and Ni/Cr coating have been adopted. Compared with Ni/Cr coating which has high oxidation resistance, $Y_2O_3$ stabilized $ZrO_2$ coating, one of ceramic coatings is found to be much effective to sustain the thermal survivability of combustion walls.

• Journal of the Korean Ceramic Society
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• v.48 no.2
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• pp.160-167
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• 2011

Plasma sprayed ceramic coatings inherently contain pores and usually also cracks. Post-treatment of the plasma sprayed coatings is a way to close the connected pores and cracks. In this study, post-sealing treatment in plasma sprayed $Al_2O_3$ coatings was employed to overcome the reduction of coating properties. $Al_2O_3$ plasma thermal spray coating was made on aluminum alloys plate, $CrO_3$ post coating and heat treatment at $550^{\circ}C$ was carried out in order for final $Cr_2O_3$ to be saturated through phase transformation. Chromia sealing began at the fine defect in coated microstructure, while larger pores were permeated later. The increase in concentration and treatment frequency of sealing solution resulted in the decrease of porosity of coating layer, while cracks occurred partially after the third treatment. After twice treatment of 10M $CrO_3$ solution, microhardness and breakdown voltage of $Al_2O_3$ coatings were found to increase by ${\fallingdotseq}$ 50% and ${\fallingdotseq}$ 390% respectively than without post-treatment.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2018.06a
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• pp.131-131
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• 2018

최근 절삭공구산업은 자동차, 항공기, IT, 선박, 에너지 등 첨단산업의 증가로 인해 CGI, CFRP, 내열합금 등 난삭재의 수요가 증가하고 있다. 난삭재는 고내열, 고경도, 초경량 같은 특성을 지니며 우수한 기계적 물성을 갖지만 가공의 어려움이 있어 산업에 적용하는데 한계가 있다. 이러한 한계를 극복하기 위해 개발된 가공기술 중 하드 코팅은 공구코팅비용 대비 공구의 표면경도와 수명을 효율적으로 향상시킬 수 있다고 알려져 있다. 대표적인 하드코팅으로는 AlN계, TiN계 코팅이 있다. 이러한 코팅의 경우 높은 기계적 물성과 우수한 내마모성으로 인해 절삭공구의 성능을 향상시킬 수 있기 때문에, 많은 연구가 진행되고 있으며 절삭공구산업에서 각광받고 있다. 기존 선행연구 결과에 따르면 질화물 코팅의 우수한 물성은 질화물(Nitride) 생성 및 질화 공정에 의한 코팅층의 고밀도화에 의해 나타난다고 알려져 있다. 그 중에서 AlCrN coating은 우수한 내마모성 및 향상된 고온경도를 갖고 있다. AlCrN based coating에 미량의 원소를 첨가하여 기존 AlCrN coating의 기계적 특성을 더욱 향상 시킨 coating은 일반적인 고성능 코팅 대비 공구수명이 길다고 알려져 있으며, 전반적으로 우수한 특성에 의해 전 세계적으로 습식 및 건식 기계 가공 용도로 사용되고 있다. 본 연구에서는 AlCrN based coating에 미량의 원소를 첨가한 coating의 우수한 기계적 특성의 원인을 규명하기 위해 텅스텐카바이드(WC) 기판 위에 아크 이온 플레이팅 장비를 이용하여 AlCrN based coating을 증착 시킨 sample을 분석하였다. 결정구조 및 상 분석을 위해 X선 회절분석(XRD)을 실시하였으며, 미세 구조를 분석하기 위해 전계방출형 주사전자현미경(FE-SEM), 투과 전자현미경(TEM) 분석을 실시하였다. 또한 코팅층의 화학적 성분 분석을 위해 EDX분석을 실시하였으며 기계적 특성 평가를 위해 나노압입시험(Nano-indentation test)을 진행하였다.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2010.05a
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• pp.145-149
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• 2010

Thermal analyses have been performed to study the effect of location of fuel ring and thermal barrier coatings in regenerative cooling channels in a full-scale combustor. For the effective cooling, the fuel ring has better be installed near axial location of the low expansion ratio and low heat flux, and branching of cooling channels is preferable. Also, the radiative cooled nozzle extension is thought to be reasonable for the cooling of combustion walls. Among the possible coatings, $Y_2O_3$ stabilized $ZrO_2$ coating and Ni/Cr coating have been adopted. Compared with Ni/Cr coating which has high oxidation resistance, $Y_2O_3$ stabilized $ZrO_2$ coating, one of ceramic coatings is found to be much effective to sustain the thermal survivability of combustion walls.

• Tribology and Lubricants
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• v.15 no.4
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• pp.328-334
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• 1999

Acoustic emission (AE) sensor was used to evaluate the wear-life of CrN-coated steel disks with 1 $\mu\textrm{m}$ and 4 $\mu\textrm{m}$ coating thickness. The relationship between Af and friction signal from scratch test and sliding test was investigated. The first spatting of CrN film was detected by AR signals in the early stage of coating failures, and overall failures by friction signals. Therefore, the conservative design for coating-life should be done using the results of AE signals. Using the percent contact load, the ratio of sliding normal load to the critical scratch load and the number of cycles to failure was measured to predict the wear-life of CrN film. On the wear-life dia-gram the percent contact loads and the number of cycles to failure showed a good linear relationship on the log coordinate. As the load percentage was decreased, the diagram showed that the wear-limits, at which the coated steels survived more than 35,000 cycles, were about 4∼5% of the critical scratch loads.

• Journal of Ocean Engineering and Technology
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• v.12 no.3 s.29
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• pp.49-59
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• 1998

The damage mechanism of $Cr_2O_3$ plasma coated soda-lime glass and uncoated glass by steel ball particle impact was analyzed in this study. And the shape variation of the cracks was investigated by stereo-microscope according to the impact velocity and steel ball diameter. In order to improve the damage reduction effect by $Cr_2O_3$ coating layer, crack size was measured and surface erosion state was observed for both of two kinds of specimen after impact experiment. And the results were compared with each other. The 4-point bending test was performed according to ASTM D790 testing method to evaluate the effect of coating layer for bending strength variation. As a result, it was found that the crack size of $Cr_2O_3$ coated specimen was smaller than that of uncoated one, because of the impact absorption by interior pores in the coating layer and the load dispersion by the structural characteristic of the coating layer. For the specimens subjected to the steel ball impact, the bending strength of coated specimen was higher than that of uncoated specimen.