• Title/Summary/Keyword: Cover Gas

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Changes in the gas chromatographic sensitivity with its analytical setting: Comparison of TDU and loop-injection system for the analysis of sulfur compounds (GC 분석 시스템의 설정과 그에 따른 감도의 차이: 열탈착 방식 대비 루프주입방식에 의한 황성분의 분석)

  • Kim, Ki-Hyun;Choi, Y.J.;Kim, S.C.
    • Analytical Science and Technology
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    • v.18 no.1
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    • pp.66-73
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    • 2005
  • In this study, we investigated the gas chromatography (GC) and pulsed flame photometric detection (PFPD) system for the analysis of four major reduced S compounds including hydrogen sulfide ($H_2S$); methyl mercaptan ($CH_3SH$); dimethyl sulfide (DMS); and dimethyl disulfide (DMDS) contained in environmental samples. To analyze these compounds in high concentration range (above ppb level), we developed a high mode analytical setting with the loop-injection system. By contrast, we also established a low mode setting for the analysis of low concentration samples (ppt-level samples from ambient air) by the combination with thermal desorption unit (TDU). Comparative analysis of both settings revealed that relative detection properties of four S compounds are systematic enough. The results of high mode analysis indicated that the patterns were systematic among S compounds: $H_2S$ exhibited the lowest sensitivity, while DMDS showed the strongest one. The results were also compared in terms of sensitivity reductions for all compounds by dividing slope ratios between low and high mode system. Although low mode system exhibited significant reductions on the order of a few tens times, their detection characteristics were highly consistent as it was shown in the high mode setting. To learn more about absolute and relative relations between two different modes of S analysis, future studies may have to be directed to cover more complicated nature of GC/PFPD performance.

An Estimation of the Carbon Stocks in Harvested Wood Products: Accounting Approaches and Implications for Korea (목제품 내 탄소 저장량 추정 : 계정 방법 및 시사점)

  • Choi, Soo-Im;Joo, Rin-Won;Lee, Soo-Min
    • Journal of the Korean Wood Science and Technology
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    • v.38 no.6
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    • pp.507-517
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    • 2010
  • This study estimated the amount of carbon stocks in harvested wood products (HWP) using accounting approaches suggested by 2006 IPCC guidelines and analyzed the impacts of different approaches on national greenhouse gas inventory and the forest sector in Korea. The change in carbon stocks was calculated at the level of semi-finished wood products, which cover sawnwood, wood-based panels, other industrial wood, paper and paperboard. An estimation of the changes in carbon stocks in HWP in use for the period 1970~2008 varied between -9,023 Gg $CO_2$/yr and 4,052 Gg $CO_2$/yr depending on the accounting approach used. The stock-change approach provided the most favorable results because Korea was a net importer of wood products. However, each approach generates different impacts on harvest, trade, the use of wood for energy production and recycling. When deciding its position on accounting approach, thus, the Government should consider future direction of national forest policies as well as the effect on national greenhouse gas inventory for the minimization of negative impacts resulting from its selection.

Fire Examples Study of Intake and Exhaust System, Alternator Tuning and Inflow of Inflammables on Exhaust Part in a Car (자동차 흡배기장치, 발전기 튜닝 및 배기측 인화성 물질 유입에 관련된 화재사례 연구)

  • Lee, Il Kwon;Kook, Chang Ho;Suh, Moon Won;You, Chang Bae;Youm, Kwang Wook;Lim, Chun Moo;Jung, Dong Hwa
    • Journal of the Korean Institute of Gas
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    • v.18 no.5
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    • pp.47-51
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    • 2014
  • This paper is to analyze and study the fire examples in respect of intake and exhaust, alternator tuning and inflow of inflammables on exhaust part in a car. In the first example, the driver diverted the intake and exhaust system for tuning of a car. Stopping a car to rest for moment, the flammable styrofoam scrap go into exhaust pipe that installed with exhaust manifold newly. It certified the fact that catched fire gradually, furthermore enlarged the fire by leaking fuel. In the second example, the driver enlarged the generator performance to divert the audio system in side room., it knew the fact that the electric wiring connected with generator gave the cause of outbreak a fire by overheating. In the third example, the serviceman replaced the engine oil using funnel-shaped, he put the a bottle of plastic pat onto engine cover carelessly. Consequentially, it found the fire occurrence in the engine room. Therefore, the driver never divert the intake and exhaust and generator construction of a car abnormally. Also, repairing and inspecting a car, the serviceman have a care to not occur the fire by inflammables.

Spatial Analysis of Carbon Storage in Satellite Radar Imagery Utilizing Sentinel-1: A Case Study of the Ungok Wetlands (위성 레이더 영상 중 Sentinel-1을 활용한 탄소 흡수원 공간분석 - 운곡습지를 대상으로 -)

  • Ha-Eun Yu;Young-Il Cho;Shin-Woo Lee;Moung-Jin Lee
    • Korean Journal of Remote Sensing
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    • v.39 no.6_3
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    • pp.1731-1745
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    • 2023
  • Within the framework of the post-2020 climate regime, the Paris Agreement's emphasis on Nationally Determined Contributions and Biennial Transparency Reporting is paramount in addressing its long-term temperature goal. A salient issue is the treatment of wetland ecosystems within the context of Land Use, Land-Use Change, and Forestry, as defined by the Intergovernmental Panel on Climate Change. In the 2019 National Inventory Report, wetlands were recategorized as emission sources due to their designation as inundated areas. This study employs C-band radar imagery to discriminate between inundated and non-inundated regions of wetlands, enabling the quantification of their spatial dynamics. The research capitalizes on 24-period Sentinel-1 satellite data to cover both the inundation and desiccation phases while centering its attention on Ungok Wetland, a Ramsar-designated inland wetland conservation area in Korea. The inundated area is quantitatively assessed through the integration of multi-temporal Sentinel-1 Single-Look Complex (SLC) data, aerial orthophotography, and inland wetland spatial information. Furthermore, the study scrutinizes fluctuations in the maximum and minimum inundated areas, with substantial changes corroborated via drone aerial reconnaissance. The outcomes of this investigation hold the potential to make substantive contributions to the refinement of national greenhouse gas absorption and emission factors, thereby informing the development of comprehensive greenhouse gas inventories. These efforts align directly with the overarching objectives of the Paris Agreement.

Comparative Assessment on Indicating Factor for Biomineralization by Bacillus Species (Bacillus종의 생광물화에 미치는 영향 인자의 비교 평가)

  • Seok, Hee-Jeong;Kim, Chang-Gyun
    • Journal of Korean Society of Environmental Engineers
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    • v.35 no.3
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    • pp.179-191
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    • 2013
  • This study was conducted to comparatively assess quantitative indicating factor for biomineralization characterizing $CO_2$ mineralization on three type of minerals (i.e., $CaCl_2$, $MgCl_2$, $CaCl_2-MgCl_2$) in an aqueous solution amended with Bacillus pasteurii or indigenous microorganisms for a S landfill cover soil. For given three types of minerals, $NH_4{^+}$ (urease activity) was released at the highest of 88 mg/L for $MgCl_2$, then 85 mg/L for $CaCl_2$, and the lowest of 42 mg/L for $CaCl_2-MgCl_2$. $CO_2$ gas in the head space was completely removed after 12, 12, and 24 hr for $CaCl_2$, $MgCl_2$ and $CaCl_2-MgCl_2$, respectively. $Ca^{2+}$ concentration in $CaCl_2$ solution was the quickest and the greatest decreased 92% for 12 hr whereas that in $CaCl_2-MgCl_2$ solution was lower at 85% for 36 hr. $Mg^{2+}$ concentration in $MgCl_2$ was more efficiently decreased at 46% for 48 hr than that of $CaCl_2-MgCl_2$ solution of 38.5% for 72 hr. Regardless of types of minerals or their concentration, pH was changed from 5.5 to 9 by biomineralization being progressed. Microbial activity ($OD_{600}$) was also changed from 0 to 0.6. SEM images indicated that spheroidal and trapezoid shape crystal were formed, which were identified as of $CaCO_3$ (Calcite) and $MgCO_3$ (Magnesite) by X-ray diffraction. In the long run, $NH_4{^+}$ (urease activity), $CO_2$ gas, $OD_{600}$, pH, $Ca^{2+}$ and $Mg^{2+}$ would be suitable for reasonable indicating factor in order to assess the degree of biomineralization efficiency.

A Study on the Availability of Spatial and Statistical Data for Assessing CO2 Absorption Rate in Forests - A Case Study on Ansan-si - (산림의 CO2 흡수량 평가를 위한 통계 및 공간자료의 활용성 검토 - 안산시를 대상으로 -)

  • Kim, Sunghoon;Kim, Ilkwon;Jun, Baysok;Kwon, Hyuksoo
    • Journal of Environmental Impact Assessment
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    • v.27 no.2
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    • pp.124-138
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    • 2018
  • This research was conducted to examine the availability of spatial data for assessing absorption rates of $CO_2$ in the forest of Ansan-si and evaluate the validity of methods that analyze $CO_2$ absorption. To statistically assess the $CO_2$ absorption rates per year, the 1:5,000 Digital Forest-Map (Lim5000) and Standard Carbon Removal of Major Forest Species (SCRMF) methods were employed. Furthermore, Land Cover Map (LCM) was also used to verify $CO_2$ absorption rate availability per year. Great variations in $CO_2$ absorption rates occurred before and after the year 2010. This was due to improvement in precision and accuracy of the Forest Basic Statistics (FBS) in 2010, which resulted in rapid increase in growing stock. Thus, calibration of data prior to 2010 is necessary, based on recent FBS standards. Previous studies that employed Lim5000 and FBS (2015, 2010) did not take into account the $CO_2$ absorption rates of different tree species, and the combination of SCRMF and Lim5000 resulted in $CO_2$ absorption of 42,369 ton. In contrast to the combination of SCRMF and Lim5000, LCM and SCRMF resulted in $CO_2$ absorption of 40,696 ton. Homoscedasticity tests for Lim5000 and LCM resulted in p-value <0.01, with a difference in $CO_2$ absorption of 1,673 ton. Given that $CO_2$ absorption in forests is an important factor that reduces greenhouse gas emissions, the findings of this study should provide fundamental information for supporting a wide range of decision-making processes for land use and management.

Case Study of Remidation and Investigation of Closed Unsanitary Landfill for Prevention of Leachate (비위생매립지 정밀조사 및 침출수 방지를 위한 정비방안 연구)

  • Kim, Sangkeun;Lee, Yongsoo
    • Journal of the Korean GEO-environmental Society
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    • v.13 no.1
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    • pp.5-13
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    • 2012
  • For the last decade the amount of waste has rapidly been increased in South Korea and many waste landfills have been built according to government guidelines specifying required systems such as landfill liner, leachate collecting facilities, final cover system, etc. This effort has led the recently constructed landfills to be under well managed sanitary condition. In a meanwhile closed waste-landfill sites in the past before the adoption of the government guidelines exits under unsanitary condition. In these cases untreated leachate flew out to the surroundings due to the absence of liner and leachate collecting facilities and caused groundwater and soils to be contaminated. Waste generated odor and gas also brought civil complaints. Because environmental influences bring serious problems nearby sites, it is required to have unsanitary waste-landfills to be appropriately treated and managed. A study to evaluate environmental influence and contamination level of surroundings nearby and on the unsanitary landfills is necessary before the establishment of "Management guide of closed landfill site." This paper presents an environmental evaluation for the closed site, Doil-dong landfill, according to "Closed landfill management regulation" by Ministry of Environment. "D" landfill, located in Pyeongtaek city, has possobility to contaminate surrounding surfacewater and groundwater by leakage of leachate. The in-situ stabilization carried out to build the DMW(deep soil mixing cutoff wall) wall and drainage systems.

A fundamental study on the development of feasibility assessment system for utility tunnel by urban patterns (도심지 유형별 공동구 설치 타당성 평가시스템 개발에 관한 기초 연구)

  • Lee, Seong-Won;Sim, Young-Jong;Na, Gwi-Tae
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.19 no.1
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    • pp.11-27
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    • 2017
  • The road network system of major domestic urban areas such as city of Seoul was rapidly developed and regionally expanded. In addition, many kinds of life-lines such as electrical cables, telephone cables, water&sewerage lines, heat&cold conduits and gas lines were needed in order for urban residents to live comfortably. Therefore, most of the life-lines were individually buried in underground and individually managed. The utility tunnel is defined as the urban planning facilities for commonly installing life-lines in the National Land Planning Act. Expectation effectiveness of urban utility tunnels is reducing repeated excavation of roads, improvement of urban landscape; road pavement durability; driving performance and traffic flow. It can also be expected that ensuring disaster safety for earthquakes and sinkholes, smart-grind and electric vehicle supply, rapid response to changes in future living environment and etc. Therefore, necessity of urban utility tunnels has recently increased. However, all of the constructed utility tunnels are cut-and-cover tunnels domestically, which is included in development of new-town areas. Since urban areas can not accommodate all buried life-lines, it is necessary to study the feasibility assessment system for utility tunnel by urban patterns and capacity optimization for urban utility tunnels. In this study, we break away from the new-town utility tunnels and suggest a quantitative assessment model based on the evaluation index for urban areas. In addition, we also develop a program that can implement a quantitative evaluation system by subdividing the feasibility assessment system of urban patterns. Ultimately, this study can contribute to be activated the urban utility tunnel.

Study on free and bond glycerines in Biodiesel from PKO(Palm Kernel Oil) and coconut oil (PKO 및 코코넛유래 바이오디젤 중 글리세린함량 분석 방법 개선 연구)

  • Lee, Don-Min;Park, Chun-Kyu;Ha, Jong-Han;Lee, Bong-Hee
    • Journal of the Korean Applied Science and Technology
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    • v.32 no.2
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    • pp.348-361
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    • 2015
  • To reduce the effects of greenhouse gas (GHG) emissions, the government has announced the special platform of technologies as parts of an effort to minimize global climate change, and the government distributed biodiesel since 2006 as the further efforts. Although there are some debates about some quality specifications and unbalanced of source (44% from palm oil), more than 400kton/year of biodiesel was produced in 2013. Moreover the amounts will be increased when the RFS is activated. To solve the unbalanced situation and to achieve the diversity of feeds, it is essential that many researches should be considered. Especially, free and bond glycerines are one of the important properties seriously affected to the combustion system in vehicle & cold properties. Previous method (KS M 2412) couldn't cover the biodiesel derived from lauric oil($C_{12:0}$) such as PKO (Palm Kernel Oil), Coconut oil because those compositions are lighter than other conventional biodiesel sources. In this study, we review the existed method and figure out the factors should improve to analysis the glycerine from PKO and Coconut oil biodiesel. Modifying the analysis conditions to enhance the resolution and change the internal standards to avoid the overlapped- peaks between Capric acid ME ($C_{10:0}$) and standard#1(1,2,4-butantriol). From this revised method, we could solve the restrictions of previous methods. And check the possibility of new method to analyze the glycerine in biodiesel regardless of sources.

Prediction Model of Remaining Service Life of Concrete for Irrigation Structures by Measuring Carbonation (중성화 측정을 통한 콘크리트의 잔존수명 예측 모델)

  • Lee, Joon-Gu;Park, Kwang-Soo;Kim, Han-Joung;Lee, Joung-Jae
    • Journal of the Korea Concrete Institute
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    • v.15 no.4
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    • pp.529-540
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    • 2003
  • Recently, the researches on the durability design of concrete structures have been studied. As the examples, models to evaluate the service life prediction of the structure have been developed. The purpose of this article is to develop the model for predicting remaining service life. The final aim is to provide the user time for repairing the concrete structures. In addition, it makes possible to maintain the concrete structure economically. 70 reservoirs out of the inland concrete structures were selected and concrete structures of their components were surveyed. Two methods were used for measuring carbonation; TG/DTA method and Phenolphtalein indicator and, the value of pH was measured by the pH meter, After deriving correlations of calcium carbonate and used year, duration from completion year to 2002, pH value, and concrete cover depth the model was developed for predicting remaining service life by measuring data as small as possible. The conventional models had been developed on the basis of experiment data obtained from the restricted lab environment like as carbon gas exposure. On the other hand this model was developed on the basis of measuring data obtained from the real field that the complex deterioration actions are occurred such as freezing and thawing, carbonation, steel corrosion, and so on. The reliability of the developed model will be evaluated high in this point and this model can help to maintain concrete structures economically by providing the manager time to repair the deteriorated concrete structures in site of facility management.