• Macromolecular Research
• /
• v.10 no.5
• /
• pp.273-277
• /
• 2002

Ultra-thin polymer films containing cobalt(II) meso-tetraphenylporphyrin(CoTPP) have been prepared by vacuum codeposition of the metal complex and trans-2-butene as an organic monomer using an inductively coupled RF glow discharge operating at 7-9 Watts. The polymer films were characterized by sorption measurements. Sorption data obtained for polymer films containing CoTPP indicate that the CoTPP molecules are capable of reversibly binding oxygen molecules. It was found that the adjacent CoTPP molecules in the aggregated metal complex phase could irreversibly share the oxygen molecules. A dispersion of the metal complex molecules in the polymer matrix was made to maintain the reversible reactivity of the metal complex molecules with oxygen in the polymer films via vacuum evaporation process. The Henry mode solubility constant, the Langmuir mode capacity constant, the amount of binding oxygen, and the dissociation equilibrium in the dual mode sorption theory were discussed.

• International Journal of Naval Architecture and Ocean Engineering
• /
• v.11 no.2
• /
• pp.688-698
• /
• 2019

If heave motion in the platform causes horizontal parametric vibration of a Compliant Vertical Access Riser (CVAR), the riser may become unstable. A combination of riser parameters lies in the unstable region aggravates vibrational damage to the riser. Change of axial tensile stress in the riser combined with its natural frequency and mode shape change results in mode coupling. In accordance with the state transition matrices of the riser in the coupled and uncoupled states, the stable and unstable regions were obtained by Floquet theory, and the vibration response under different conditions was obtained. The parametric excitation of the CVAR is shown to occur mainly in first-order unstable regions. Mode coupling may cause parametric excitation in the least stable regions. Damping reduces the extent of unstable regions to a certain extent.

• Proceedings of the Korean Society for Noise and Vibration Engineering Conference
• /
• 2004.11a
• /
• pp.709-712
• /
• 2004

A study of the coupled flexural-torsional vibrations of thin-walled beams with monosymmetric cross-section is presented. The governing differential equations for free vibration of such beams are solved numerically to obtain natural frequencies and their corresponding mode shapes. The beam model is based on the Bernoulli-Euler beam theory and the effect of warping is taken into consideration. Numerical results are given for two specific examples of beams with free-free, clamped-free, hinged-hinged, clamped-hinged and clamped-clamped end constraints both including and excluding the effect of warping stiffness. The effect of warping stiffness on the natural frequencies and mode shapes is discussed and it is concluded that substantial error can be incurred if the effect is ignored.

• Journal of the Korea Academia-Industrial cooperation Society
• /
• v.19 no.7
• /
• pp.16-23
• /
• 2018

Chaos is one of the most significant topics in nonlinear science, and has been intensively studied since the Lorenz system was introduced. One characteristic of a chaotic system is that the signals produced by it do not synchronize with any other system. It therefore seems impossible for two chaotic systems to synchronize with each other, but if the two systems exchange information in just the right way, they can synchronize. This paper addresses the problem of synchronization in a modified Lorenz chaotic system based on active control, sliding mode control, and the Lyapunov stability theory. The considered synchronization scheme consists of identical drive and response generalized systems coupled with linear state error variables. For this, a brief overview of the modified Lorenz chaotic system is given. Then, control rules are derived for chaos synchronization via active control and slide mode control theory, with a strategy for solving the chattering problem. The asymptotic stability of the overall feedback system is established using the Lyapunov stability theory. A set of computer simulation works is presented graphically to confirm the validity of the proposed method.

• Journal of the Korean Chemical Society
• /
• v.60 no.6
• /
• pp.410-414
• /
• 2016

The anharmonic frequency of a local OH stretching mode of a water monomer and dimer was calculated using various levels of density functional theory. The quantum chemical potential energy curves as a function of the OH bond distance were calculated, and they were fitted with the Morse potential function to analytically obtain the fundamental transition frequency. By comparing those values with the frequencies similarly calculated using an ab initio quantum chemical method, the coupled cluster theory including both single and double excitations with the perturbative inclusion of triple excitation in the complete basis limit, the accuracy of various density functional methods in the calculation of anharmonic vibration frequency of water molecules was assessed. For a water monomer, X3LYP and B3LYP methods give the best accuracy, whereas for a water dimer, B972, LCBLYP, ${\omega}B97X$, ${\omega}B97$ methods show the best performance.

• The Journal of Korean Institute of Communications and Information Sciences
• /
• v.19 no.1
• /
• pp.100-110
• /
• 1994

In this paper, we present a new analysis of monolithic laser-waveguide coupling structure employing the beam propagation method. Monolithic laser-waveguide coupler has both passive and active components It has too many parameters to consider for an analysis. So we present proper model of coupler by use of directional coupler. We employ the beam propagation method th analyze the proposed structure, we could employ the coupled mode theory but we thought in the case of this paper the beam propagation method is more appropriate than coupler mode theorybecause a number of variables which to consider is too many for the coupled mode theory. Also we use finite difference method to calcurate trial field which is a starting point of beam propagation analysis. Through this approach, we can consider more parameters. And we propose a new structure of monolothic laser-waveguide coupler which has taper structure between the distance in which coupling is taking place and passive waveguide. We can obtain 79% high coupling efficiency from our structure.

• Journal of the Optical Society of Korea
• /
• v.2 no.2
• /
• pp.58-63
• /
• 1998

Cross-talk effects in high-density volume holographic interconnections are investigated using perturbative iteration method of the integral form of Maxwell's wave equation. In this method, the paraxial approximation and negligence of backward scattering introduced in conventional coupled mode theory is not assumed. Interaction geometries consisting of non-coplanar light waves and multiple index gratings are studied. Arbitrary light polarization is considered. Systematic analysis of cross-talk effects due to multiple index gratings is performed in increasing level of diffraction orders corresponding to successive iterations. Some numerical examples are given for first and third order diffraction.

• Transactions of the Korean Society for Noise and Vibration Engineering
• /
• v.21 no.2
• /
• pp.169-177
• /
• 2011

In this paper, the natural frequency of a cracked cantilever L-beams with a coupled bending and torsional vibrations is investigate by theory and experiment. In addition, a method for detection of crack in a cantilever L-beams is presented based on natural frequency measurements. The governing differential equations of a cracked L-beam are derived via Hamilton's principle. The two coupled governing differential equations are reduced to one sixth order ordinary differential equation in terms of the flexural displacement. Futher, the dynamic transfer matrix method is used for calculation of a exact natural frequencies of L-beams. The crack is assumed to be in the first mode of fracture and to be always opened during vibrations. In this study, the differences between the actual and predicted positions and sizes of crack are less than about 10 % and 39.5 % respectively.

• Journal of the Optical Society of Korea
• /
• v.7 no.1
• /
• pp.20-27
• /
• 2003

A theoretical presentation of evanescent coupling is offered with respect to the refractive indexes between a side-polished optical fiber and an infinitely planar waveguide with a conductor cladding (PWGCC). The PWG is suspended at a constant distance from an unclad fiber core and attached with the perfect conductor (PEC) on one side. The behavior of the distributed couple. is examined using a coupled mode model, which takes account of the two dimensions of the waveguide configuration. The coupling and propagation of light were found to depend on both the relationship between the refractive index values of each structure and the configuration of the side-polished fiber used in the PWGCC. The spreading of light in the unconfined direction of the PWGCC is described in terms of a simple geometrical interpretation of the synchronization condition that is in agreement with a previous investigation of the problem based on the coupled-mode theory (CMT). The power of the light propagation in the fiber decreased exponentially along the fiber axis as it was transferred to the PWGCC, where it was carried away.

• Coupled systems mechanics
• /
• v.6 no.3
• /
• pp.251-272
• /
• 2017

In this paper, the thermo-mechanical vibration characteristics of functionally graded (FG) nanobeams subjected to three types of thermal loading including uniform, linear and non-linear temperature change are investigated in the framework of third-order shear deformation beam theory which captures both the microstructural and shear deformation effects without the need for any shear correction factors. Material properties of FG nanobeam are assumed to be temperature-dependent and vary gradually along the thickness according to the power-law form. Hence, applying a third-order shear deformation beam theory (TSDBT) with more rigorous kinetics of displacements to anticipate the behaviors of FG nanobeams is more appropriate than using other theories. The small scale effect is taken into consideration based on nonlocal elasticity theory of Eringen. The nonlocal equations of motion are derived through Hamilton's principle and they are solved applying analytical solution. The obtained results are compared with those predicted by the nonlocal Euler-Bernoulli beam theory and nonlocal Timoshenko beam theory and it is revealed that the proposed modeling can accurately predict the vibration responses of FG nanobeams. The obtained results are presented for the thermo-mechanical vibration analysis of the FG nanobeams such as the effects of material graduation, nonlocal parameter, mode number, slenderness ratio and thermal loading in detail. The present study is associated to aerospace, mechanical and nuclear engineering structures which are under thermal loads.