• 제목/요약/키워드: Coupled magnetic resonance

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Hard Tissue Analysis of NMR after Fluoride Administration

  • Kim, Hye-Young;Nam, Seoul-Hee;Han, Man-Seok
    • Journal of Magnetics
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    • 제21권4호
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    • pp.599-602
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    • 2016
  • Fluoride (F) is an important element for the mineralization of body tissues. The purpose of this study was to administer fluoride prenatally to rats to evaluate its beneficial concentration for rat bone using microstructural analysis, to analyze its effect on the bone structure, and to evaluate the effect of its transfer through rat placenta. Fourier transform infrared spectroscopy (FTIR) and nuclear magnetic resonance spectrometry (NMR) were performed. The $^{19}F$ NMR and $^{31}P$ NMR signals suggested the existence of fluoride ions in the apatite lattice because the signals were caused by the fluoride ions that were coupled to the phosphate atoms and were affected in the phosphate phases other than the element phases in the apatite. Consequently, if it was not affected too much, the desirable concentration of prenatal fluoride treatment could have a helpful effect on the bone crystal structure through placental fluoride transfer.

교환 결합력을 갖는 CoFe/MnIr 박막에서 강자성 공명 선폭의 각도 의존성 연구 (Angular Dependence of Ferromagnetic Resonance Linewidth in Exchange Coupled CoFe/MnIr Bilayers)

  • 윤석수;김동영
    • 한국자기학회지
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    • 제26권2호
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    • pp.50-54
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    • 2016
  • 본 연구에서는 교환 결합력을 갖는 CoFe/MnIr 박막 재료의 각도에 따른 강자성 공명 선폭 변화 특성을 분석하였다. 선폭의 최대 및 최소값은 교환 결합력에 의한 일방 이방성의 자화 곤란축 및 용이축 방향에서 각각 관측되었으며, 고정된 MnIr의 스핀에 의한 교환 바이어스 자기장의 각도 의존성과 일치하였다. 따라서, 최대 선폭은 고정된 MnIr 스핀의 반대 방향에서 자기장 방향으로 꼬여있는(twist) CoFe의 자화에 기인한다. 한편, CoFe 단일 박막에 비하여 증가된 최소 선폭은 각도 의존성이 없는 회전 이방성 자기장과 관련되며, 선폭 증가의 원인은 MnIr 입도의 자화 용이축 분포 특성으로 설명된다.

교환 바이어스 인위적 준강자성 기준층을 포함한 자기 터널 접합의 강자성 공명 (Ferromagnetic Resonance of Magnetic Tunnel Junctions with an Exchange Biased Synthetic Ferrimagnetic Reference Layer)

  • 윤정범;유천열;정명화
    • 한국자기학회지
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    • 제21권4호
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    • pp.121-126
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    • 2011
  • 자유층과 고정 기준층으로 이루어진 자기 터널 접합의 스핀 동역학을 강자성 공명 시늉내기로 연구 하였다. 먼저 교환 바이어스 인위적 준강자성 기준층을 포함한 자기 터널 접합에서 DC 자기장에 대한 각 층의 자화 방향을 확인하고 터널 자기저항을 계산하였다. 자기 터널 접합에서 스핀의 들뜸 모드들을 확인하기 위해 DC와 RF 자기장을 함께 인가하여 강자성 공명 주파수 스펙트라를 관찰 하였다. 각 층 별로 들뜸 모드들을 확인하여 자유층과 기준층의 자화 방향의 차이로 계산된 터널 자기저항의 들뜸 모드들을 분석 하였다. 전체적으로 스핀의 들뜸 모드는 자유층이나 기준층의 자화 방향에 관련해서 DC 자기장의 음, 양의 방향에 따라 상이하게 나타났다. 음의 방향 자기장에 대해서 자유층과 기준층의 강자성 공명 주파수 스펙트라는 수정된 Kittel 방정식으로 잘 설명되지만 양의 방향 자기장에 대해서는 예측하기 어려운 들뜸 모드들로 인해 분석적 해답을 찾기 어려웠다. 자기터널 접합의 강자성 층들은 서로 상호 작용을 하기 때문에 이에 대한 스핀 동역학 연구는 자유층 뿐만 아니라 기준층, 고정층과도 밀접하게 연관되어 있다.

Spectroscopic characterization of N,N'-bis(salicylidene)pentane-1,3-diamine nickel(II) complex

  • Kim, Gilhoon;Won, Hoshik
    • 한국자기공명학회논문지
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    • 제18권2호
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    • pp.74-81
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    • 2014
  • The $N_2O_2$ tetradentate Schiff base ligand, N,N'-bis(salicylidene)pentane-1,3-diamine (Salpn), coupled with 1:2 concentration ratio of 1,3-diaminopentane and salicylaldehyde was used to produce a series of macrocyclic Nikel(II) complexes. In the metal complexation, it was observed that Salpn macrocyclic ligand can adopt more than a metal ion giving an unique multinuclear metal complexes including Ni(II)Salpn and $Ni(II)_3(Salpn)_2$. Characteristic IR ${\upsilon}(M-O)$ peaks for Ni(II)Salpn and $Ni(II)_3(Salpn)_2$ were observed to be $1028cm^{-1}$ and $1024cm^{-1}$, respectively. Characteristic UV-Vis absorption ${\lambda}_{max}$ peaks for $Ni(II)_3(Salpn)_2$ were observed to be 241nm and 401 nm. Structural characterization of $Ni(II)_3(Salpn)_2$ by NMR exhibits that the salicylidene ring moiety has two different resonance signals originated from the magnetically asymmetric diligand and trinuclear bis complex. Complete NMR signal assignments and characterizations elucidating structural features of $Ni(II)_3(Salpn)_2$ were described in detail.

Wireless Energy Transfer System with Multiple Coils via Coupled Magnetic Resonances

  • Cheon, Sanghoon;Kim, Yong-Hae;Kang, Seung-Youl;Lee, Myung Lae;Zyung, Taehyoung
    • ETRI Journal
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    • 제34권4호
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    • pp.527-535
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    • 2012
  • A general equivalent circuit model is developed for a wireless energy transfer system composed of multiple coils via coupled magnetic resonances. To verify the developed model, four types of wireless energy transfer systems are fabricated, measured, and compared with simulation results. To model a system composed of n-coils, node equations are built in the form of an n-by-n matrix, and the equivalent circuit model is established using an electric design automation tool. Using the model, we can simulate systems with multiple coils, power sources, and loads. Moreover, coupling constants are extracted as a function of the distance between two coils, and we can predict the characteristics of a system having coils at an arbitrary location. We fabricate four types of systems with relay coils, two operating frequencies, two power sources, and the function of characteristic impedance conversion. We measure the characteristics of all systems and compare them with the simulation results. The flexibility of the developed model enables us to design and optimize a complicated system consisting of many coils.

자화 플라즈마의 분산특성과 유효광학계수 변화 (dispersion characteristics and RE power absorption for a mangetized plasma)

  • 라상호;정재성;오범환;박세근
    • 한국진공학회지
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    • 제9권3호
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    • pp.285-289
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    • 2000
  • 축방향의 약한 자기장(약 1∼20 gauss)으로 자화된 inductively coupled plasm의 투과깊이와 전파 상수의 특성변화를 계산하였다. 자화 플라즈마에 있어서 전자밀도의 증가로 인한 플라즈마의 투과깊이 감소와, 그와 상반되는 충돌주파수 증가로 인한 투과깊이 증가를 고려하여, 보다 균일한 플라즈마 공정을 위한 기초 자료로서 중성 입자와 전자간의 충돌주파수, 전자밀도 및 자기장의 크기와 플라즈마 투과깊이 간의 상관관계를 확인하였다. 통상적인 저압 공정 플라즈마 조건하에서, 약 4.8 gauss의 자기장이 축방향으로 인가되는 경우 cyclotron 공명에 의해 투과깊이가 최소값을 가지는 것을 재확인하였으며, 그 이상의 자기장에서는 원형 편광파의 침투깊이를 비롯한 제반 특성의 급격한 변화를 볼 수 있었다.

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유도결합형 플라즈마원을 이용한 고선택비 산화막 식각에 관한 연구 (A Study on the High Selective Oxide Etching using Inductively Coupled Plasma Source)

  • 이수부;박헌건;이석현
    • 한국전기전자재료학회논문지
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    • 제11권4호
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    • pp.261-266
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    • 1998
  • In developing the high density memory device, the etching of fine pattern is becoming increasingly important. Therefore, definition of ultra fine line and space pattern and minimization of damage and contamination are essential process. Also, the high density plasma in low operating pressure is necessary. The candidates of high density plasma sources are electron cyclotron resonance plasma, helicon wave plasma, helical resonator, and inductively coupled plasma. In this study, planar type magnetized inductively coupled plasma etcher has been built. The density and temperature of Ar plasma are measured as a function of rf power, flow rate, external magnetic field, and pressure. The oxide etch rate and selectivity to polysilicon are measured as the above mentioned conditions and self-bias voltage.

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스위칭에 따른 전자기 가진력에 의한 스위치드 릴럭턴스 전동기의 고정자 변위해석 (Stator Displacement Analysis of Switched Reluctance Motor Due to Electromagnetic Force According to Switching)

  • 하경호;홍정표;김규탁
    • 대한전기학회논문지:전기기기및에너지변환시스템부문B
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    • 제49권1호
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    • pp.20-26
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    • 2000
  • This paper deals with the modal analysis and the displacement of stator due to electromagnetic forces in Switched Reluctance Motor(SRM). A free-free model of the stator based on structural 3-dimensional Finite Element Method(FEM) is used for investigation the natural frequencies and the mode shapes of the stator. In addition, The displacement caused by magnetic force acting on stator pole is analyzed by the structural FEM coupled with the magnetic force. From these results, the resonance speed is obtained by the relation of the natural frequencies of the harmonic frequencies of magnetic force. And, the eccentricity with respect to rotor is predicted from the analysis result of the mechanical displacement of stator. The natural frequencies of stator are compared with experimental ones measured by modal testing.

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Time-Domain Analysis of Wireless Power Transfer System Behavior Based on Coupled-Mode Theory

  • Shim, Hyunjin;Nam, Sangwook;Lee, Bomson
    • Journal of electromagnetic engineering and science
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    • 제16권4호
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    • pp.219-224
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    • 2016
  • In this paper, coupled-mode theory (CMT) is used to obtain a transient solution analytically for a wireless power transfer system (WPTS) when unit energy is applied to one of two resonators. The solutions are compared with those obtained using equivalent circuit-based analysis. The time-domain CMT is accurate only when resonant coils are weakly coupled and have large quality factors, and the reason for this inaccuracy is outlined. Even though the time-domain CMT solution does not describe the WPTS behavior precisely, it is accurate enough to allow for an understanding of the mechanism of energy exchange between two resonators qualitatively. Based on the time-domain CMT solution, the critical coupling coefficient is derived and a criterion is suggested for distinguishing inductive coupling and magnetic resonance coupling of the WPTS.

Identification of Xanthium Sibiricum Components using LC-SPE-NMR-MS Hyphenated System

  • Sohn, Ji Soo;Jung, Youngae;Han, Ji Soo;Hwang, Geum-Sook
    • 한국자기공명학회논문지
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    • 제22권2호
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    • pp.26-33
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    • 2018
  • Xanthium sibiricum is used as a traditional folk medicine for the treatment of cancer, fever, headache, nasal sinusitis, and skin pruritus. This study aimed to identify components from Xanthium sibiricum extracts using an SPE-800MHz NMR-MS hyphenated system. The simultaneous acquisition of MS and NMR spectra from the same chromatographic peaks significantly increases the depth of information acquired for the compound and allows the elucidation of structures that would not be possible using MS or NMR data alone. LC -NMR analysis was conducted using a HPLC separation system coupled to 800 MHz spectrometer equipped with a cryoprobe, and a SPE unit was used to automatically trap chromatographic peaks using a HPLC pump. LC-MS analysis was conducted with a Q-TOF MS instrument using ESI ionization in the negative ion mode. Using the hyphenated analysis, several secondary metabolites were identified, such as 3',5'-O-dicaffeoylquinic acid, 1',5'-O-dicaffeoyl- quinic acid, and ethyl caffeate. These results demonstrate that the SPE-800MHz NMR-MS hyphenated system can be used to identify metabolites within natural products that have complex mixtures.