• 한국막학회:학술대회논문집
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• 한국막학회 2004년도 첨단 분리막 연구동향
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• pp.1-11
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• 2004

Ion-exchange membranes have been widely used in various applications such as diffusion dialysis, electrolysis, electrodialysis, fuel cell etc [1-2]. When an electric current passes through the membrane system, the current is carried by both positive and negative ions in the bulk solution phases, whereas it is carried mainly by the counter-ions in the membrane. (omitted)

• Nuclear Engineering and Technology
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• 제48권3호
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• pp.719-726
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• 2016

The problem of separation of isotopes in a concurrent gas centrifuge is solved analytically for an arbitrary binary mixture of isotopes. The separative power of the optimised concurrent gas centrifuges for the uranium isotopes equals to ${\delta}U=12.7(V/700m/s)^2(300K/T)(L/1m)kg{\cdot}SWU/yr$, where L and V are the length and linear velocity of the rotor of the gas centrifuge and T is the temperature. This equation agrees well with the empirically determined separative power of optimised counter-current gas centrifuges.

• 한국수산과학회지
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• 제25권2호
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• pp.133-143
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• 1992

The water-quality control for coastal waters is continuously required in view point of the environmental protection. The purpose of this study is to simulate the hydrodynamic process and the dispersion phenomena of several pollutants in Suyeong Bay, Pusan. The present study employs the depth-averaged 2-dimensional model for nemerical simulation of the hydrodynamics and diffusion. The nemerical solution is obtained by ADI(Altenating Direction Implicit) scheme which is frequently used for tidal current and diffusion computations in the coastal zone. To verify the nunlerical results, the field observations of various water quality parameters such as COD, SS and nutrients were performed during the spring tide. In the results of this study, the computed tidal currents show the clockwise flows for ebb tide and counter-clockwise flows for flood tide. In comparison with the water-qualities in ebb tide and flood tide, there seems to be slightly deteriorated in ebb tide and especially near the estuary of Suyeong River. In flood tide, however, the water-quality near Kwangan Beach is deteriorated. The computed distributions of COD and SS are in god agreements with the observed ones, while those of $PO_4\;^{3-}-P\;and\;NO_3\;^--N$ show slight differences due to the complex transformation processes.

• 대한기계학회논문집B
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• 제28권5호
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• pp.501-509
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• 2004

Unipolar diffusion charging of non-spherical particles was investigated for various particle shapes. We researched with TiO$_2$agglomerates produced by the thermal decomposition of titanium tetraisopropoxide (TTIP) vapor. TTIP was converted into TiO$_2$, in the furnace reactor and was subsequently introduced into the sintering furnace. Increasing the temperature in the sintering furnace, aggregates were restructured into higher fractal dimensions. The aggregates were classified according to their mobility using a differential mobility analyzer. The projection area and the mass fractal dimension of particles were measured with an image processing technique performed by using transmission electron microscope (TEM) photograph. The selected aggregates were charged by the indirect photoelectric-charger and the average number of charges per particle was measured by an aerosol electrometer and a condensation particle counter. For the particles of same mobility diameter, our results showed that the particle charge quantity decreases as the sintering temperature increases. This result is understandable because particles with lower fractal dimension have larger capacitance and geometric surface area.

• 폴리머
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• 제25권1호
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• pp.90-97
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• 2001

Poly(ethylene-co-acrylic acid) (PEAA)를 암모늄과 나트륨의 두 가지 서로 다른 반대 이온을 사용하여 수분산 하고 이의 필름을 제조하였다. 얻어진 필름에 대한 urea 수용액의 확산계수를 측정하고 필름의 물리, 화학적 구조와의 상관관계를 조사하였다. 측정된 구조적 특징은 DSC에 의한 유리전이온도와 결정화도, WAXD에 의한 결정 및 이온성 클러스터의 구조, 그리고 FT-IR에 의한 carboxyl기의 존재 형태 등이었다. 결정성 고분자인 폴리에틸렌 이오노머의 투과특성은 반대이온의 종류나 중화도는 물론 필름형성시의 조건, 그리고 초기 입자의 크기와 같은 다양한 변수에 영향을 받음을 관찰하였다.

• Journal of Electrochemical Science and Technology
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• 제1권2호
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• pp.75-80
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• 2010

We report Co-tetramethoxyphenylporphyrin on carbon particles (Co-TMPP/C) as a non-Pt catalyst for tri-iodide reduction in dye-sensitized solar cells (DSSCs). The presence of well-dispersed carbon and cobalt source in the catalyst surface is confirmed by transmission electron microscopy, scanning electron microscopy, and energy dispersive X-ray analysis. In the C 1s, Co 2p, and N 1s peaks measured by X-ray photoelectron spectroscopy, the C-N, Co-$N_4$, and N-C are assigned to the component at 285.7, 781.8, and 401 eV, respectively. Especially, the Co-TMPP/C shows improved current density, diffusion coefficient, and charge-transfer resistance in the ${I_3}^-/I^-$ redox reaction compared to conventional catalysts. Furthermore, in the DSSCs performance, the Co-TMPP/C shows increased short circuit current density, higher open circuit voltage, and improved cell efficieny in comparison with Pt/C.

• 설비공학논문집
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• 제12권1호
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• pp.102-111
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• 2000

A numerical model which simulates the simultaneous heat and mass transfer within a vertical tube GAX absorber was developed. The ammonia vapor and the solution liquid are in counter-current flow, and the hydronic fluid flows counter to the solution liquid. The film thickness and the velocity distribution of the liquid film were obtained by matching the shear stress at the liquid-vapor interface. Two-dimensional diffusion and energy equations were solved in the liquid film to give the temperature and concentration, and a modified Colburn-Drew analysis was used for the vapor phase to determine the heat and mass fluxes at the liquid-vapor interface. The model was applied to a GAX absorber to investigate the absorption rates, temperature and concentration profiles, and mass flow rates of liquid and vapor phases. It was shown that the mass flux of water was negligible compared with that of ammonia except the region near the liquid inlet. Ammonia absorption rate increases rapidly near the liquid inlet and decrease slowly. Both the absorption rate of ammonia vapor and the desorption rate of water near the liquid inlet increase as the vapor mass flow rate increases, but the mass fluxes of the ammonia and the water near the liquid outlet decrease as the mass flow rate of the vapor increases.

• 분석과학
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• 제12권5호
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• pp.428-435
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• 1999

액체섬광계수기를 이용한 수용액시료 중의 미량의 Rn-222 및 Ra-226 농도 측정을 위한 분석방법을 확립하였다. 라돈 분석을 위해 자이렌계열 섬광용액(xylene-based cocktail) 12 mL를 사용하여 물 시료(10mL)내 라돈을 선택적으로 용매 추출하였다. 추출된 라돈을 측정용기 내에서 딸핵종과의 방사 평형을 위해 3시간동안 방치한 후 저준위 액체섬광계수기를 이용하여 계측하였다. Ra-226 분석을 위해서는 화학적 분리과정을 거친 후 자이렌 계열 섬광용액이 포함된 측정용기 내에서 일정 기간동안의 방사평형을 거쳐 생성된 Rn-222 및 알파선 딸핵종을 계측하였다. Rn-222 및 그의 알파선 딸핵종의 계측을 위한 최적 파형분석(PSA) 준위는 바탕시료에 대한 최대 효율값(Figure of Merit)을 조사하여 설정하였다. PSA 준위 100에서 폴리에틸렌 용기와 자이렌계열 섬광용액을 사용하여 준비된 시료를 200분 동안 계측하였을 때 얻어진 검출하한값(MDA)은 알파선의 총 피크영역에서 0.14 Bq/L(3.78 pCi)이었고, Po-214 만의 피크영역에서는 0.06 Bq/L(1.63 pCi)이었다. 섬광용액에 대한 시료의 부피비와 시료용기의 취급 및 시료용기를 통한 라돈기체의 손실등이 계측치에 미치는 영향을 고찰하였다.

• Management Science and Financial Engineering
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• 제8권1호
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• pp.21-38
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• 2002

Rapid advances in information technology(IT) and telecommunication systems impact the number and quality of decision-making in organizations. Specifically, middle mangers must posses or develop the creativity necessary for survival in a constantly changing and volatile business environment. While tradition and conventional wisdom tell us that a middle managers role centers on control and monitoring, todays competitive arena has spun out a new managerial requirement developing and maintaining an innovative attitude. Problematically, most previous research has focused on the issue of changing decision authority (i. e. centralization/decentralization). Moreover, much previous research has also largely ignored environmental changes exposing new roles that middle managers have assumed. This study explores the means of identifying middle managerial roles, managerial possibilities involving the growing popularity of open systems through electronic brainstorming, and an adaptation and development of Diffusion Theory and attempt to counter criticism leveled at the theory's inability to provide an adequate explanation for diffusion of complex organizational technology. This paper develops three ideas: 1) Introducing the 'Chasing Curve' as a theoretical background. 2) Suggesting a new methodology using electronic brainstorming for analyzing the gap between Knowing (the perceived importance of middle managers' roles) and Doing (the degree of current status of middle managers' roles), which we term the 'Spiral Gap Analysis Model'. 3) Identifying a feedback system for minimizing the Knowing - Doing gap, aimed at development of IT strategic priority decision support, which we call this the 'Star Process'.

• 에너지공학
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• 제11권4호
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• pp.350-358
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• 2002

The present work determined the flame structure characteristics of coal syngas combusted inside swirl burners with various nozzle types. Fuel nozzle types are largely classified into two groups of axial and tangential. Experiments were carried out for investigating the effects of fuel nozzle geometry, fuel composition ratio, heating rate, excess air, and degree of swirl on the turbulent diffusion flame structure. To determine the characteristics of the flame structure, axial type fuel nozzle diameter of laboratory-scale combustor is varied to 1.23, 1.96, and 2.95 ㎜ and the direction of tangential type nozzles are varied to radial, clockwise, and counter-clockwise. The comparison of the experimental results was performed to understand functional parameters relating the flame structure. Data analysis showed that the vertical straight flame height generally decreased with increasing swirl number and decreasing axial type nozzle diameter. Flame height established with tangential type nozzle is 3 times shorter than that with vertical type. The flame structures among the 3 different tangential fuel nozzles relatively showed no particular difference. By increasing the heating rate, the width of flame increased generally in both vertical and tangential flame. Within the present experimental parameters of the investigation, flame structure is mainly depends on the nozzle type of the combustor. The visually investigated flame lengths are confirmed through the analysis of temperature profile of each flame.