• 제목/요약/키워드: Counter electrodes

검색결과 108건 처리시간 0.023초

Improved Conversion Efficiency of Dye-sensitized Solar Cells Based on TiO2 Porous Layer Coated TiO2 Nanotubes on a Titanium Mesh Substrate as Photoanode

  • Lim, Jae-Min;He, Weizhen;Kim, Hyung-Kook;Hwang, Yoon-Hwae
    • Current Photovoltaic Research
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    • 제1권2호
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    • pp.90-96
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    • 2013
  • We report here flexible dye-sensitized solar cells (DSSC) based on Ti-mesh electrodes that show good mechanical flexibility and electrical conductivity. $TiO_2$ nanotube arrays prepared by electrochemical anodizing Ti-mesh substrate were used as photoanode. A Pt-coated Ti-mesh substrate was used as counter electrode. The photoanodes were modified by coating a $TiO_2$ porous layer onto the $TiO_2$ nanotubes in order to increase the specific surface area. To increase the long term stability of the DSSCs, a gel type electrolyte was used instead of a conventional liquid type electrolyte. The DSSC based on $33.2{\mu}m$ long porous $TiO_2$ nanotubes exhibited a better energy conversion efficiency of ~2.33%, which was higher than that of the DSSCs based on non-porous $TiO_2$ nanotubes.

뇌졸중 환자의 인두기능 회복을 위한 전기자극기 설계 (Electrical Stimulation System Design for Pharyngeal Dysfunction of Stroke Patients)

  • 유지혜;배하석;최병철;김성민
    • 한국정밀공학회지
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    • 제22권7호
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    • pp.185-190
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    • 2005
  • The purpose of this study is to design electrical stimulation system fur stroke patients with pharyngeal dysfunction(dysphagia). Dysphagia is that the food has trouble in passing to the mouth from the stomach. Although we have many treatment methods for dysphagia, electrical stimulation system will be useful for stroke patients having dysphagia. Electrical stimulation system can be divided into body and electrodes. The body stimulation is composed to frequency counter, time control and current measurement part. These parts are to control the frequency, stimulating time and current intensity And they can be variable according to the patient's clinical assessment. The electrode plays a role to deliver the current from the system to the muscle. Also the position of the electrode can be variable according to the treatment method. We performed the clinical experiment with stroke patients who had swallowing disorder. The videofluoroscopy was used fur the observation. From the result of clinical experiment based on electrical stimulation, we expected that the dysfunction(in pharynx) level of the patient could be improved. However we could not have enough effectiveness of the treatment because of the number of patients, patient's adaptation and treatment period. We will design the optimized electrical stimulation system based on enough clinical experiment in the future.

AC Impedance Study of Hydrogen Oxidation and Reduction at Pd/Nafion Interface

  • Song, Seong-Min;Koo, Il-Gyo;Lee, Woong-Moo
    • 한국수소및신에너지학회논문집
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    • 제12권3호
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    • pp.231-238
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    • 2001
  • Electrocatalytic activity of palladium for hydrogen oxidation and reduction was studied using AC impedance method. The system under study was arranged in electrolytic mode consisting of Pd electrode under study, Pt counter electrode and Nafion electrolyte between them. Two types of Pd electrodes were used - carbon-supported Pd (Pd/C) and Pd foil electrode. Pd/C anode contacting pure hydrogen showed a steady decrease of charge transfer resistance with the increase of anodic overpotential, which is an opposite trend to that found with Pd foil anode. But Pd foil cathode also exhibited a decrease of the resistance with the increase of cathodic overpotential. The relationship between imposition of overpotential and subsequent change of the charge transfer resistance is determined by the ratio of the rate of faradaic process to the rate of mass transportation; if mass transfer limitation holds, increase of overpotential accompanies the increase of charge transfer resistance. Regardless of the physical type of Pd electrode, the anode contacting hydrogen/oxygen gas mixture did not reveal any independent arc originated from local anodic oxygen reduction.

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바 형태 정전기제거장치의 정전기제거성능 향상을 위한 연구 (1) (A Study on Improvement of the Performance of Pulsed AC Ion Bar (1))

  • 이동훈;최동수;정용철;김상민
    • 한국안전학회지
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    • 제29권3호
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    • pp.34-38
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    • 2014
  • In Display such as LCD, LED, and AMOLED or semiconductor related industries are required to have static ionizer in order to produce reliable goods since the ionizer can create balanced ion that is delivered to producing goods to minimize electrical damages when manufacturing. However, the most general type of ionization is called, "Corona Discharge" that has a slight chances to generate unequal and unstable amount of each +/- ion to the target object. Then, the ionization performance will drastically decrease and end up with quality deterioration problem. In this research, our objective to resolve the current issue via applying "Coupling Condenser" on each counter electrodes of Corona discharging type ionizer. The result is that the ion balance was maintained the satisfied range that is within +/-100V when we changed the duty ratio of the High Voltage of Pulse AC about 40 ~ 70%. In addition, when levelling the High Voltage of Pulse AC, the ion balance holds the range within +20 ~ 0V. Even though we have tested the same experiment for a year, we have seen the range changes roughly ${\pm}50V$.

조기화재 감시시스템을 위한 CO센서의 시그널컨디셔너 성능개선 (Performance Improvement of CO Sensor Signal Conditioner for Early Fire Detection System)

  • 박종찬;손진근
    • 전기학회논문지P
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    • 제66권2호
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    • pp.82-87
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    • 2017
  • This paper presents performance improvement of CO gas sensor signal conditioner for early fire warning system. The warning system is based on the CO sensor and its advanced signal conditioning modules network that employ electochemical gas sensor. The electochemical has advantage of having a linear output and operating with a low consumption and fast response. This electrochemical gas sensor contains a gas membrane and three electrodes(working, counter, reference electrode) in contact with an electrolyte. To use a three-electrode sensor, a voltage has to be applied between the working and the reference electrode according to the specification of the sensor. In this paper, we designed these requirements that should be considered in temperature compensation algorithm and electrode measurement of CO sensor modules by using advanced signal conditioning method included 3-electrode. Simulation and experimental results show that signal conditioner of CO sensor module using 3-electrode have a advantage linearity, sensitivity and stability, fast response etc..

Synthesis of TCO-free Dye-sensitized Solar Cells with Nanoporous Ti Electrodes Using RF Magnetron Sputtering Technology

  • Kim, Doo-Hwan;Heo, Jong-Hyun;Kwak, Dong-Joo;Sung, Youl-Moon
    • Journal of Electrical Engineering and Technology
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    • 제5권1호
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    • pp.146-150
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    • 2010
  • A new type of dye-sensitized solar cell (DSC) based on a porous type Ti electrode without using a transparent conductive oxide (TCO) layer is fabricated for low-cost high-efficient solar cell application. The TCO-free DSC is composed of a glass substrate/dye-sensitized $TiO_2$ nanoparticle/porous Ti layer/electrolyte/Pt sputtered counter electrode. The porous Ti electrode (~350 nm thickness) with high conductivity can collect electrons from the $TiO_2$ layer and allows the ionic diffusion of $I^-/I_3{^-}$ through the hole. The vacuum annealing treatment is important with respect to the interfacial necking between the metal Ti and porous $TiO_2$ layer. The efficiency of the prepared TCO-free DSC sample is about 3.5% (ff: 0.48, $V_{oc}$: 0.64V, $J_{sc}$: 11.14 mA/$cm^2$).

주파수분할 다중방식에 의한 심전신호 및 부가정보신호 무선전송 (Radiotelemetry for ECG and Event Signals Using FDM)

  • 이훈규;박동철
    • 대한의용생체공학회:의공학회지
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    • 제21권4호
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    • pp.345-351
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    • 2000
  • 본 연구는 심전신호와 부가정보 신호의 다중신호를 주파수분할 다중방식과 주파수변조에 의해 무선전송하기 위함이다. 심전신호는 전극으로부터 유도되고 아날로그 증폭기에 의해 증폭된다. 전극 전착부실, 간호사 호출 및 저전압 배터리 신호의 부가정보 신호는 서로 주파수가 중복되지 않도록 발진되고 주파수분할 다중방식에 의해 합성되어 주파수 변조된다. 주파수 변조된 신호는 콜피츠회로에 의해 발진된 기본 반송파로 주파수 변조되고 체배되어 송신 반송주파수로 변환된다. 수신된 신호는 슈퍼헤테로다인 방식에 의해 중간주파수로 변환되고 쿼드래처 복조기에 의해 주파수 변조된 신호는 복조된다. 펄스카운터와 저역통과필터에 의해 심전신호와 부가정보 신호들은 복조된다.

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Pt포일 양극을 이용한 전기화학적 암모니아 수전해 특성 연구 (Characterization of Electrochemical Ammonia Electrolysis Using a Platinum Electrode for Anodic Reaction)

  • 최정민;김학덕;송주헌
    • 한국수소및신에너지학회논문집
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    • 제33권4호
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    • pp.337-342
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    • 2022
  • In this study, a water electrolysis was studied to investigate the effect of ammonia on current density and H2 gas production. A H type cell with three electrodes was used and KOH solution was used as electrolyte. The conventional platinum foil was used for working electrode, whereas nickel foam was used for counter electrode. CV experiment was performed to see the activity of ammonia oxidation reaction. In addition, CP experiment was done to examine the dependence of Faraday efficiency of hydrogen on current density and NH3 concentration. The CV result shows the 0.5M NH3 concentration required for highest current density and reliable operation. The CP result shows the increased current density leads to higher H2 generation. The higher H2 production and subsequent energy efficiency was observed for 0.5M NH3 using a Pt/13%Rh coil for a cathode as compared to those in water electrolysis.

증류수 계면처리를 이용한 고온초전도체 죠셉슨 접합 제작 (HTS Josephson Junctions with Deionized Water Treated Interface)

  • 문승현;박완규;계정일;박주도;오병두
    • Progress in Superconductivity
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    • 제2권2호
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    • pp.76-80
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    • 2001
  • We have fabricated YBa$_2$Cu$_3$$O_{7-x}$ (YBCO) ramp-edge Josephson junctions by modifying ramp edges of the base electrodes without depositing any artificial barrier layer. YBa$_2$Cu$_3$O/7-x//SrTiO$_3$ (YBCO/STO) films were deposited on SrTiO$_3$(100) by on-axis KrF laser deposition. After patterning the bottom YBCO/STO layer, the ramp edge was cleaned by ion-beam and then reacted with deionized water under various conditions prior to the deposition of counter-electrode layers. The top YBCO/STO layer was deposited and patterned by photolithography and ion milling. We measured current-voltage (I-V) characteristics, magnetic field modulation of the critical current at 77 K. Some showed resistively shunted junction (RSJ)-type I-V characteristics, while others exhibited flux-flow behaviors, depending on the dipping time of the ramp edge in deionized water. Junctions fabricated using optimized conditions showed fairly uniform distribution of junction parameters such as I$_{c}$R$_{n}$ values, which were about 0.16 mV at 77 K with 1$\sigma$~ 24%. We made a dc SQUID with the same deionized water treated junctions, and it showed the sinusoidal modulation under applied magnetic field at 77 K. 77 K.

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열처리된 탄소나노튜브 상대전극의 전기화학적 특성 연구 (Electrochemical properties of heat-treated multi-walled carbon nanotubes)

  • 이수경;문준희;황숙현;김금채;이동윤;김도현;전민현
    • 한국진공학회지
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    • 제17권1호
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    • pp.67-72
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    • 2008
  • 본 연구에서는 염료감응 태양전지의 상대전극으로써 다중벽 탄소나노튜브를 사용하여 전기화학적 특성에 미치는 열처리 효과에 대해 연구하였다. 다중벽 탄소나노튜브는 실리콘 기판위에 철 촉매를 사용하여 열화학 기상증착법으로 합성하였다. 직경이 다른 다중벽 탄소나노튜브를 각각 성장하여 두 개의 샘플을 준비하였고 질소 분위기의 RTA(rapid thermal annealing) system에서 $900^{\circ}C$ 온도로 1분간 열처리 하였다. 다중벽 탄소나노튜브의 구조적, 전기적, 전기화학적 특성은 FE-SEM, Raman spectroscopy, 2-point probe station, electrochemical impedance spectroscopy (EIS)을 이용하여 측정하였다. 라만 스펙트럼 분석에서 열처리 한 다중벽 탄소나노튜브의 I(D)/I(G) ratio는 상당히 감소한 것을 확인하였으며, 다중벽 탄소나 노튜브 표면과 전해질과의 산화 환원 반응 특성에서는 열처리 전보다 열처리 후의 전해질과의 산화 환원 반응 특성이 향상된 것을 알 수 있었다. 표면에서의 반응 저항 또한 열처리 후의 다중벽 탄소나노튜브가 더 낮은 값을 나타내었다. 그 결과, 열처리 후의 다중벽 탄소나노튜브를 상대전극으로 사용하였을 때의 전기화학적 특성이 더 좋은 것을 확인하였다.