• Journal of the Korea institute for structural maintenance and inspection
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• v.4 no.4
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• pp.149-160
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• 2000

As systematic methodologies are required for the evaluation on the durability of reinforced concrete structure, it is necessary to study and examine every factor which deteriorates the durability of structures. This paper aims to define factors affecting rebar corrosion and to establish a basis for a prediction of serviceability, regarding a state of harmful corrosion as a state when crack begins on the surface of concrete. The study results are followings; The corrosive current has changed by types of mixture, and this property enables the evaluations of corrosion resistance by mixture and concrete cover. The specimen using AE superplasticizer has better corrosion-resistance properties than non-AE specimen, as well those having low W/C and high unit cement weight. The procedure for calculation of durable year in this study is able to use as an indicator to establish mixture factors such as unit cement weight, W/C, amount of admixture, etc.

• Journal of the Korea Institute of Military Science and Technology
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• v.14 no.6
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• pp.1018-1025
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• 2011

The improved properties of corrosion for 90Cu10NiFe alloy in natural seawater were explained by sodium diethyl dithio carbamate(NaDDC), namely organic compound, which is reagent for heavy metal extractions of waste water. The efficiency of NaDDC as corrosion inhibitor for 90Cu10NiFe alloy has been investigated in seawater after immersion in various concentrations of NaDDC solutions for 12~36hrs at pH 8.2 by weight loss test and electrochemical techniques including potentiodynamic polarization and SEM-EDS measurements. The results showed that the corrosion resistance of 90Cu10NiFe alloy improves with the increasing concentration of NaDDC but it did not improves with increasing time any more, so the highest inhibition efficiency was 93% at 100mg/L, 36hrs. The results obtained from weight losses and corrosion rates in polarization curve measurements were in good agreement. Therefore, it showed that NaDDC is a good inhibitor for copper corrosion of 90Cu10NiFe alloy.

• Journal of the Korean institute of surface engineering
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• v.50 no.5
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• pp.332-338
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• 2017

In this study, we evaluated tendency and degree of corrosion damages of Inconel 600 after chemical decontamination treatments under three different conditions. In the decontamination processes, the oxidation and reduction were performed as one cycle. Each process was continued up to 5 cycles. Characteristics of corrosion under decontamination processes were evaluated by Tafel analysis and weight loss. Characteristics of surface damage were observed by scanning electron microscope(SEM) and three-dimensional(3D) microscope. As the cycle proceeded, weight loss and corrosion current density increased. Intergranular corrosion damage occurred on the surface of the materials. The result revealed that the surface of Inconel 600 was attacked by the strong acid solution under all chemical decontamination processes, but the degree of the corrosion damage was different depending on the processes.

• Corrosion Science and Technology
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• v.21 no.1
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• pp.32-40
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• 2022

The o-Vanillin - Glutamine Schiff base [2-Hydroxy-3-Methoxy BenzylidineCarbomyl) -2-Butanoic Acid] was examined for low carbon steel corrosion inhibition in acid media. Weight loss studies were carried out at three different temperatures to determine the inhibition efficiency (IE). Electrochemical impedance spectroscopy revealed that the charge transfer resistance controlled the corrosion reaction and Tafel polarization indicated that the Schiff base acts as mixed mode of inhibitor. SEM images were recorded for the surface morphology of the low carbon steel surface. DFT studies revealed corrosion control mechanisms using quantum chemical parameters such as E_HOMO, E_LUMO, energy gap (∆E), chemical Hardness (η), chemical Softness (σ), Electronegativity (χ), and the fraction of electron transferred (∆N), which is calculated using Gaussian software 09. The gas-phase geometry was fully optimized in the Density Functional Theory (DFT/B3LYP-6-31G (d)).The DFT results are in good agreement with the experimental results. All the results proved that the Schiff Base (2-Hydroxy-3-Metoxy BenzylidineCarbomyl) -2-Butanoic is a suitable alternative for corrosion inhibition of low carbon steel in acid media.

• Journal of the Korean Ceramic Society
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• v.27 no.2
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• pp.161-168
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• 1990

To evaluate the corrosion behavior of reaction bonded silicon carbides, corrosion test was studied for various corrosive environments. Corrosion test for reaction bonded silicon carbides was conducted at 900$^{\circ}C$ under four different gas atmospehres ; air, So2-air, Cl2-O2-Ar, Cl2-N2 and investigated these samples using weight loss, bending strength, XRD, optical micrographs and EDS respectively.

• Corrosion Science and Technology
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• v.12 no.2
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• pp.65-78
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• 2013

The present investigation deals with the corrosion inhibition of mild steel in 1M $H_2SO_4$ with 1, 4-dihydro pyridine and its derivatives prepared using microwave activation method. The synthesis of inhibitor was confirmed by IR spectra. The effect of 1, 4-dihydropyridine derivatives on the corrosion inhibition of mild steel in 1M $H_2SO_4$ was studied using weight loss and electrochemical polarization techniques. Influence of temperature (303-333K) and synergistic effect of halide ions ($I^-$, $Br^-$ and $Cl^-$) on the inhibition behaviour was also studied. Corrosion products on the metal surface were analyzed by scanning electron microscopy (SEM) and a possible mechanism of inhibition by the compounds is suggested. Thermodynamic parameters were calculated using weight loss data in order to elaborate the mechanism of corrosion inhibition. Polarization measurements revealed that the studied compounds acted as mixed type inhibitor but slightly anodic in nature. Electrochemical impedance measurements revealed that the compounds were adsorbed onto the carbon steel surface and the adsorption obeyed the Langmuir adsorption isotherm. The synergistic effect of halide ions on the IE increases with increase in concentration. The IE obtained from atomic absorption spectrophotometric studies was found to be in good agreement with that obtained from the conventional weight loss method. SEM revealed the information of a smooth, dense protective layer in presence of the inhibitors.

• Proceedings of the KSME Conference
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• 2005.11a
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• pp.143.1-143.1
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• 2005

• KIEAE Journal
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• v.7 no.4
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• pp.127-133
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• 2007

As a fundamental study on the corrosion resistance of reinforced concrete structures using Natural Inorganic Minerals exposed to carbonation environment, The test specimens were concrete(W/C=60%) with Natural Inorganic Minerals content of 0%, 10%. Accelerated carbonation and autoclave corrosion accelerated curing were then conducted with them. The corrosion resistance of steel in concrete with Natural Inorganic Minerals content of 0%, 10% was examined by corrosion form, half-cell potential, polarization resistance, corrosion area and weight loss after 24 hours of autoclave corrosion accelerated curing.The results of the study showed that as for steel in concrete with Natural Inorganic Minerals content of 10%, the corrosion resistance was more excellent than steel in concrete with Natural Inorganic Minerals content of 0%.

• Proceedings of the Korean Institute of Building Construction Conference
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• 2013.11a
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• pp.177-178
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• 2013

Steel structures of the seaside area are naturally led to surface corrosion due to incoming salt. Signature measures for this are to replace steel with steel material with a high corrosion-resistance and to block salt and other deteriorative factors beforehand through finishing work such as surface coating. However, the variety in steel materials, finishing type, and construction methods makes adhesive weight of incoming salt different depending on each type. For this research, measurement results derived from an enhancement experiment on artificial incoming salt adhesive to 4 steel finishing types and 2 material types identified a difference of adhesive weight by each sampler.

• Korean Journal of Fisheries and Aquatic Sciences
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• v.7 no.4
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• pp.234-237
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• 1974

Electro-chemical aspects of stress corrosion on the mild steels when immersed in the $5\%\;H_2SO_4$ solution and charged with 100mV and 100mA were discussed. The main results of the experiment are follows; 1. The weight loss by corrosion was concerned with the applied stress. and the larger the applied stress, the greater the weight loss. 2. Reduction of corrosion stress was a factor of inverse proportion to the applied stress. 3. Corrosion began at first on the parts of impurities concentrated and the grain boundaries, and gradually developed and spreaded out. 4. The materials of unsteady structure deformed of space lattice by the high stress or work-hardening showed less reduction of corrosion stress.