• Corrosion Science and Technology
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• v.21 no.2
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• pp.147-157
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• 2022

Electrochemical characteristics and damage behavior of 6061-T6 aluminum alloy used as a battery housing material for electric vehicles were investigated in solution simulating the acid rain environment with chloride concentrations. Potentiodynamic polarization test was performed to analyze electrochemical characteristics. Damage behavior was analyzed through Tafel analysis, measurement of damage area, weight loss, and surface observation. Results described that corrosion current density was increased rapidly when chloride concentration excceded 600 PPM, and it was increased about 7.7 times in the case of 1000 PPM compared with 0 PPM. Potentiodynamic polarization experiment revealed that corrosion damage area and mass loss of specimen increased with chloride concentrations. When chloride concentration was further increased, the corrosion damage area extended to the entire surface. To determine damage tendency of pitting corrosion according to chloride concentration, the ratio of damage depth to width was calculated. It was found that the damage tendency decreased with chloride concentrations. Thus, 6061-T6 aluminum alloy damage becomes larger in the width direction than in the depth direction when a small amount of chloride is contained in an acid rain environment.

• Corrosion Science and Technology
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• v.23 no.1
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• pp.72-81
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• 2024

The Ti-6Al-4V alloy is widely used as an implant material due to its higher fatigue strength and strengthto-weight ratio compared to pure titanium, excellent corrosion resistance, and bone-like properties that promote osseointegration. For rapid osseointegration, the adhesion between the titanium surface and cellular biomolecules is crucial because adhesion, morphology, function, and proliferation are influenced by surface characteristics. Polymeric peptides and similar coating technologies have limited effectiveness, prompting a demand for alternative materials. There is growing interest in 2D nanomaterials, such as MoS₂, for good corrosion resistance and antibacterial, and bioactive properties. However, to coat MoS₂ thin films onto titanium, typically a low-temperature hydrothermal synthesis method is required, resulting in the synthesis of films with a toxic 1T@2H crystalline structure. In this study, through high-temperature annealing, we transformed them into a non-toxic 2H structure. The implant coating technique proposed in this study has good corrosion resistance and biocompatibility, and antibacterial properties.

• Journal of Electrochemical Science and Technology
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• v.4 no.2
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• pp.61-70
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• 2013

Corrosion inhibition of carbon steel in 2M HCl by some benzohydrazide derivatives (I-III) was studied using weight loss, potentiodynamic polarization, and electrochemical impedance spectroscopy (EIS) techniques at $30^{\circ}C$. Polarization studies showed that all the investigated compounds are of mixed type inhibitors. Temperature studies revealed a decrease in efficiency with rise in temperature and corrosion activation energies increased in the presence of the hydrazide derivatives, probably implying that physical adsorption of cationic species may be responsible for the observed inhibition behavior. Electrochemical impedance studies showed that the presence of benzohydrazide derivatives decreases the double layer capacitance and increases the charge transfer resistance. The adsorption of these compounds on carbon steel surface was found to obey Temkin's adsorption isotherm. Synergistic effects increased the inhibition efficiency in the presence of halide additives namely KI and KBr. An inhibition mechanism was proposed in terms of strongly adsorption of inhibitor molecules on carbon steel surface.

• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2016.11a
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• pp.194.2-194.2
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• 2016

Magnesium has many desirable properties of which the high strength/weight ratio makes it extremely valuable in automobile and aerospace industry. However, the high corrosion susceptibility of magnesium and its alloys has greatly limited their large scale use for various applications. Organic coating is one of the most effective ways to prevent magnesium alloys from corrosion. An organic coating is normally used in the final stage of a coating process. It can enhance corrosion resistance of magnesium and its alloys. Organic coating involves a variety of process such as painting, powder coating, cathodic electrocoating (E-painting) and the application of lacquers, enamel and varnishes.

• Tribology and Lubricants
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• v.11 no.1
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• pp.58-65
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• 1995

When marine lubricating oil began to be emulsified and oxidized through ingressive water that have leaked from cooling pump seal systems, cooler, purifier system and piping system, the cavitation erosion-corrosion in alloy metals of bearings remains to the various troublesome problem at effective engine performance. Therefore, applied the cathodic protection to the control test of cavitation erosion-corrosion, and appointed the marine system oil containing 3% sea water as test environments, with different conductibility. Also, used the piezoelectric vibrator with 20 KHz, 24 $\mu$m as the cavity generation apparatus, and examined the weight loss, potential value, current density etc. in specimens with those condition. According to this testing data, investigated influence of cathodic protection on the control characteristics of cavitation erosion-corrosion, and will serve those as an elementary design data of marine bearing.

• Proceedings of the Korea Concrete Institute Conference
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• 2006.05b
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• pp.73-76
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• 2006

Sewage facilities mainly consisted of concrete structures are being deteriorated seriously by biodeterioration originated from sulfur-oxidizing bacteria. To prevent biochemical corrosion of the sewage concrete, antibiotics which prevent growth of sulfur-oxidizing bacteria were developed. Recently, to evaluate biochemical corrosion properties of concrete, antimicrobial performance and resistance to sulfuric acid were investigated respectively. But, in this study, to evaluate it complexly, concrete specimen covered with antibiotics were exposed in the actual sewage environment and were investigated about corrosion properties after three months. As a result, weight change ratio, nature potential and sulfuric ratio of concrete covered with antibiotics were less than plain concrete.

• Proceedings of the KSME Conference
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• 2001.06a
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• pp.256-261
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• 2001

Corrosion and tensile properties of zircaloy-4 cladding tube having a laser welding part in elevated temperature are studied to present the criterion of quality evaluation in nuclear reactor and to found the scientific basis of SCC, with laser welding method using by coupling up cladding tube to end cap. In the result of tensile test($400^{\circ}C$), the fracture is not happened in the welding part but base metal and the result of corrosion test($400^{\circ}C$ 1500psi steam), corrosion rate of the molten zone and PMZ is a little higher than the other zone.

• Nuclear Engineering and Technology
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• v.30 no.5
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• pp.396-402
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• 1998

Experiments on the steamside corrosion and hydrogen pick-up of Zircaloy-4 under high pressure up to 10.3MPa are carried out to estimate the pressure effects on the kinetics. Temperature and reaction time are determined to be 37$0^{\circ}C$ and 72hours for the pre-transition test and $700^{\circ}C$ and 210minutes for the post-transition test, respectively. Results show that under 10.3MPa pressure the oxidation reaction is 50% and 100% enhanced in the pre-and the post-transition regime, respectively. Total amount of hydrogen uptake in the reaction is proportionally increased as corrosion weight gain is elevated. However, pick-up fraction is not affected by the high pressure. The fraction is almost twice greater than that in the waterside corrosion. Edges in the specimens play a certain role in the enhancement, especially in the post-transition regime. To identify physical property changes of oxide film such as micro-cracks or micro-pores, careful and thorough examination must be needed with some special techniques.

• Journal of the Korean Chemical Society
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• v.58 no.1
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• pp.25-32
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• 2014

Corrosion inhibition of 304 stainless steel (SS) in 1 M HCl by aqueous extract of coriander seeds was studied using weight loss, potentiodynamic polarization, electrochemical impedance spectroscopy (EIS) and electrochemical frequency modulation (EFM) techniques. Values of inhibition efficiency obtained are dependent upon the concentration of extract and temperature. Generally, inhibition was found to increase with inhibitor concentration, but decrease with temperature. Physical adsorption mechanism has been proposed for the inhibition with Langmuir adsorption isotherm obeyed. Values of activation energy of the inhibited corrosion reaction of 304 SS are greater than the value obtained for the blank. Thermodynamic consideration reveals that adsorption of aqueous extract of coriander seeds 304 SS surface is spontaneous.

• Structural Engineering and Mechanics
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• v.63 no.5
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• pp.607-615
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• 2017

This study presents optimum design of plane steel bridges considering corrosion effect by using teaching-learning based optimization (TLBO) method. Optimum solutions of three different bridge problems are linearly carried out including and excluding corrosion effect. The member cross sections are selected from a pre-specified list of 128 W profiles taken from American Institute of Steel Construction (AISC). A computer program is coded in MATLAB to carry out optimum design interacting with SAP2000 using OAPI (Open Application Programming Interface). The stress constraints are incorporated as indicated in AISC Allowable Stress Design (ASD) specifications and also displacement constraints are applied in optimum design. The results obtained from analysis show that the corrosion effect on steel profile surfaces causes a crucial increase on the minimum steel weight of bridges. Moreover, the results show that the method proposed is applicable and robust to reach the destination even for complex problems.