• Title/Summary/Keyword: Corrosion shape

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Bone-like Apatite Formation on Ti-6Al-4V in Solution Containing Mn, Mg, and Si Ions after Plasma Electrolytic Oxidation in the SBF Solution

  • Lim, Sang-Gyu;Choe, Han Cheol
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2017.05a
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    • pp.157-157
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    • 2017
  • Titanium and its alloys that have a good biocompatibility, corrosion resistance, and mechanical properties such as hardness and wear resistance are widely used in dental and orthopedic implant applications. They can directly connect to bone. However, they do not form a chemical bond with bone tissue. Plasma electrolytic oxidation (PEO) that combines the high voltage spark and electrochemical oxidation is a novel method to form ceramic coatings on light metals such as titanium and its alloys. This is an excellent reproducibility and economical, because the size and shape control of the nano-structure is relatively easy. Silicon (Si), manganese (Mn), and magnesium (Mg) has a useful to bone. Particularly, Si has been found to be essential for normal bone, cartilage growth and development. Manganese influences regulation of bone remodeling because its low content in body is connected with the rise of the concentration of calcium, phosphates and phosphatase out of cells. Insufficience of Mn in human body is probably contributing cause of osteoporosis. Pre-studies have shown that Mg plays very important roles in essential for normal growth and metabolism of skeletal tissue in vertebrates and can be detected as minor constituents in teeth and bone. The objective of this work was to study nucleation and growth of bone-like apatite formation on Ti-6Al-4V in solution containing Mn, Mg, and Si ions after plasma electrolytic oxidation. Anodized alloys was prepared at 270V~300V voltages. And bone-like apatite formation was carried out in SBF solution for 1, 3, 5, and 7 days. The morphologies of PEO-treated Ti-6Al-4V alloy in containing Mn, Mg, and Si ions were examined by FE-SEM, EDS, and XRD.

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Development the Technique for Fabrication of the Thermal Fatigue Crack to Enhance the Reliability of Structural Component in NPPs (원자력 구조재 신뢰성 향상을 위한 열피로 균열 시험편 제작 기법 개발)

  • Kim, Yong;Kim, Jae-Sung;Lee, Bo-Young
    • Journal of Welding and Joining
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    • v.26 no.2
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    • pp.43-49
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    • 2008
  • Fatigue cracks due to thermal stratification or corrosion in pipelines of nuclear power plants can cause serious problems on reactor cooling system. Therefore, the development of an integrated technology including fabrication of standard specimens and their practical usage is needed to enhance the reliability of nondestructive testing. The test material was austenitic STS 304, which is used as pipelines in the Reactor Coolant System of a nuclear power plants. The best condition for fabrication of thermal fatigue cracks at the notch plate was selected using the thermal stress analysis of ANSYS. The specimen was installed from the tensile tester and underwent continuos tension loads of 51,000N. Then, after the specimen was heated to $450^{\circ}C$ for 1 minute using HF induction heater, it was cooled to $20^{\circ}C$ in 1 minute using a mixture of dry ice and water. The initial crack was generated at 17,000 cycles, 560 hours later (1cycle/2min.) and the depth of the thermal fatigue crack reached about 40% of the thickness of the specimen at 22,000 cycles. As a results of optical microscope and SEM analysis, it is confirmed that fabricated thermal fatigue cracks have the same characteristics as real fatigue cracks in nuclear power plants. The crack shape and size were identified.

Study on the Optimum Design of High Pressure Common-rail DME Injector Nozzle with Consideration of Cavitation (공동현상을 고려한 커먼레일용 고압 DME 인젝터 노즐의 최적 설계 연구)

  • Jeong, Soo-Jin;Park, Jung-Kwon;Lee, Sang-In
    • Transactions of the Korean Society of Automotive Engineers
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    • v.21 no.1
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    • pp.99-106
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    • 2013
  • DME (Di-Methyl Ether) is synthetic product that is produced through dehydration of methanol or a direct synthesis from syngas. And it is able to save fossil fuel and reduce pollutants of emission such as PM and $CO_2$. In spite of its advantages it is difficult to design DME fuelled engine system because DME fuel may cause to severely generate cavitation and corrosion in fuel delivery system due to physical properties of DME. Therefore, in this study three-dimensional internal flow characteristics with consideration of cavitation were predicted in the DME injector using diesel and DME fuel. Moving grid technique was employed to describe needle motion and 1-D hydraulic simulation of injector was also simulated to obtain transient needle motion profiles. The results of simulation show that cavitations was generated at the inlet of nozzle near high velocity region both diesel and DME. And mass flow rate of DME is reduced by 4.73% compared to that of diesel at maximum valve lift because cavitation region of DME is much more larger. To increase flow rate of DME injector, internal flow simulation has been conducted to investigate the nozzle hole inner R-cut effect. The flow rates of diesel and DME increase as R-cut increases, and flow coefficient of DME fuel injector was increased by 6.3% on average compared with diesel fuelled injector. Finally, optimum shape of DME injector nozzle is suggested through the comparison of flow coefficient with variation of nozzle hole inner R-cut.

Formation of Bioactive Surface by PEO-treatment after 2nd ATO Technique of Ti-6Al-4V Alloy (Ti-6Al-4V 합금에 2nd ATO 처리 후 플라즈마 전해 산화법에 의한 생체활성표면형성)

  • Lim, Sang-Gyu;Cho, Han-Cheol
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2018.06a
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    • pp.74-74
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    • 2018
  • Ti-6Al-4V alloys have been widely used as orthopedic materials because of their excellent corrosion resistance and mechanical properties. However, it does not bind directly to the bone, so it requires a surface modification. This problem can be solved by nanotube and micropore formation. Plasma electrolytic oxidation (PEO) treatment for micropore, which combines high-voltage spark and electrochemical oxidation, is a new way of forming a ceramic coating on light metals such as titanium and its alloys. This method has excellent reproducibility and can easily control the shape and size of the Ti alloy. In this study, formation of bioactive surface by PEO-treatment after $2^{nd}$ ATO technique of Ti-6Al-4V alloy was invesgated by various instrument. Nanotube oxide surface structure was formed on the surface by anodic oxidation treatment in 0.8 wt.% NaF and 1M $H_3PO_4$ electrolytes. After nanotube formation, nanotube layer was removed by ultrasonic cleaning. PEO-treatment was carried out at 280V for 3 minutes in the electrolytic solution containing the bioactive substance (Mg, Zn, Mn, Sr, and Si). The surface of Ti-6Al-4V alloy was observed by field emission scanning electron microscopy (FE-SEM, S-4800 Hitachi, Japan). An energy dispersive X-ray spectrometer (EDS, Inca program, Oxford, UK) was used to analyze the spectra of physiologically active Si, Mn, Mg, Zn, and Sr ions. The PEO film formed on the Ti-6Al-4V alloy surface was characterized using an X-ray diffractometer (TF-XRD, X'pert Philips, Netherlands). It is confirmed that bioactive ions play an essential role in the normal bone growth and metabolism of the human skeletal tissues.

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Study on mechanical behavioral characteristics of the curved FRP-concrete composite member for utilization as a tunnel lining structure (터널 라이닝 구조체로서 활용을 위한 곡면 FRP-콘크리트 복합부재의 역학적 거동특성 분석 연구)

  • Lee, Gyu-Phil;Shin, Hyu-Soung;Kim, Seung-Han
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.13 no.2
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    • pp.149-158
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    • 2011
  • Utilization of the fiber reinforced polymer (FRP) material has been increased as an alternative in a bid to supplement the problems with general construction materials such as long-term problems corrosion, etc. However, there are still many problems in using a linear-shaped FRP material for a tunnel lining structure which has arch-shape in general. In this study, the loading tests for the FRP-concrete composite member was carried out to evaluate their applicability as a tunnel reinforcement material, which are based on the results from preliminary numerical studies for identifying the behavioral characteristics of FRP-concrete composite member. Moreover, numerical analysis under the same condition as applied in the loading tests was again conducted for analysis of mechanical behavior of the composite member. As a result of the load test and numerical analysis, it appears that the FRP-concrete composite member is greatly subject to shear movement caused by bending tension acting on the interface between two constituent members.

Static Performance Test for New Wave Dissipating Block Reinforced with FRP (FRP로 보강된 신형 소파블록의 정적 성능 실험)

  • Paik, In-Yeol;Oh, Young-Min
    • Journal of Korean Society of Coastal and Ocean Engineers
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    • v.23 no.4
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    • pp.285-291
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    • 2011
  • In this study the mechanical performance of the new wave dissipating block is evaluated through experiment and numerical analysis. Also, by selecting adequate reinforcement, the improvement of the structural performance is examined. The reinforcement is designed by predicting the amount of tensile force and the location where the tensile stress develops in the new wave dissipating block through numerical analysis. The new wave dissipating block is reinforced with the ordinary steel bars and the fiber reinforced plastic(FRP) bars which have advantages in ocean environment in terms of corrosion and fatigue. The test result shows that the fracture resistance of the un-reinforced concrete block is 350 kN which is about 6.2 times that of the weight of the block. All the test blocks which are reinforced by either steel of FRP bars show strength capacity of over 900 kN which is the maximum load of the test equipment. Although the single reinforcement with larger-diameter bars has advantage in terms of construction convenience, it is recommended to use multiple number of smaller-diameter bars in order to reduce the crack width.

Effect of Distribution and Shape of Cr-Carbide Precipitates on the Caustic stress Corrosion cracking for Ni-Based Alloy 600 (크롬계 탄화물의 분포와 형태가 니켈계 합금 600의 염기응력부식에 미치는 영향)

  • Kim, Seon-Jae;Choe, Jong-Ho;Seong, Jin-Gyeong;Kim, U-Gon;Park, Sun-Dong;Lee, Chang-Gyu;Jeong, Yong-Hwan;Guk, Il-Hyeon
    • Korean Journal of Materials Research
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    • v.8 no.8
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    • pp.766-774
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    • 1998
  • 32$0^{\circ}C$, 40%NaOH 용액의 autoclave에서 약 300wppm의 탄소를 함유하고 있는 15Cr-9Fe-balanced Ni 합금 판상시편에 대해 응력부식 저항성을 조사하였다. 부식시편은 $700^{\circ}C$, 100시간 동안의 열처리로 합금내부에 석출될 수 있는 가능한 한 많은 양의 크롬계 탄화물을 석출시킨 후, 다시 재용해에 의해 크롬계 탄화물의 형태를 조절하는 $800^{\circ}C$-$950^{\circ}C$범위의 최종열처리를 시행하고 급냉시킨 다음 U-자형으로 응력을 가하여 준비되었다. 최종열처리 온도가 올라감에 따라 시편들의 입계응력부식균열(IGSCC ) 전파속도는 $900^{\circ}C$까지는 거의 직선적으로 증가하다가 $950^{\circ}C$에서는 $700^{\circ}C$에서 얻은 값보다도 더 낮게 감소하였다. 즉, 크롬계 탄화물이 재용해되어 그 밀도가 감소함에 따라 IGSCC저항성이 감소하다가 완전히 재용해된 $950^{\circ}C$ 열처리 조건에서 오히겨 가장 큰 IGSCC 저항성을 나타내었다. 이와같은 최조열처리 온도에 따른 니켈계 합금 600의 부식거동은 입계에 존재하는 크롬계탄화물의 형태변화 때문이 아니라 입계에서 탄소-크롬계 탄화물-크롬간의 상평형에 의해 이루어지는 탄소의 입계편석량이 크롬계탄화물이 존재할 때에는 열처리 온도에 따라 증가하다가 그것이 완전히 재용해 되었을 때 가장 낮아지기 때문인 것으로 생각된다.

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Evaluation of Material Characteristics of Suspension-Type Porcelain Insulators for 154 KV Power Transmission Lines

  • Choi, In-Hyuk;Park, Joon-Young;Kim, Tae-gyun;Yoon, Yong-Beum;Yi, Junsin
    • Transactions on Electrical and Electronic Materials
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    • v.18 no.4
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    • pp.207-210
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    • 2017
  • The suspension arrangement of insulators provides flexibility and assists in power transmission in transmission lines. The performance of the insulator string is strongly influenced by the environmental conditions to which it is exposed, its shape and the inherent material properties of suspension-type insulators. The suspension-type insulators are mostly made from glass, porcelain and ceramic material due to their high resistivity. Irregularity in charge distribution throughout the porcelain insulator may lead to accelerated aging and electrical breakdown. A very high and steep lightning impulse voltage may also cause breakdown of suspension-type insulators. We investigated various material characteristics such as alumina addition, surface morphology, x-ray diffraction pattern and relative density of suspension porcelain insulators manufactured in 1989 (36,000 lbs.), 1995 (36,000 lbs.) and 2001 (36,000 lbs.) by the KRI Company for use in 154 kV high power transmission lines. We compared the material characteristics of these porcelain insulators with that of the top-of-the-line porcelain insulators (36,000 lbs.) manufactured by the NGK Company in 2000. These suspension-type porcelain insulators were exposed to arc and flashover tests to examine their electrical and mechanical strength. It was noted that alumina addition (17 wt.%) for K-2001 was one of the major contributors to the enhancement of the performance of the porcelain insulators and to their ability to withstand very high current generation during the arc test. The porcelain insulators manufactured during 2001 also showed the highest relative density of 95.8% as compared to the other insulators manufactured in 1989 and 1995 respectively 94.2% and 91.5%. We also discuss reports of various failure modes of suspension-type porcelain insulators.

Experimental and numerical investigation of strengthened deficient steel SHS columns under axial compressive loads

  • Shahraki, Mehdi;Sohrabi, Mohammad Reza;Azizyan, Gholam Reza;Narmashiri, Kambiz
    • Structural Engineering and Mechanics
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    • v.67 no.2
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    • pp.207-217
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    • 2018
  • In past years, numerous problems have vexed engineers with regard to buckling, corrosion, bending, and overloading in damaged steel structures. This article sets out to investigate the possible effects of carbon fiber reinforced polymer (CFRP) and steel plates for retrofitting deficient steel square hollow section (SHS) columns. The effects of axial loading, stiffness, axial displacement, the position and shape of deficient region on the length of steel SHS columns, and slenderness ratio are examined through a detailed parametric study. A total of 14 specimens was tested for failure under axial compression in a laboratory and simulated using finite element (FE) analysis based on a numerical approach. The results indicate that the application of CFRP sheets and steel plates also caused a reduction in stress in the damaged region and prevented or retarded local deformation around the deficiency. The findings showed that a deficiency leads to reduced load-carrying capacity of steel SHS columns and the retrofitting method is responsible for the increase in the load-bearing capacity of the steel columns. Finally, this research showed that the CFRP performed better than steel plates in compensating the axial force caused by the cross-section reduction due to the problems associated with the use of steel plates, such as in welding, increased weight, thermal stress around the welding location, and the possibility of creating another deficiency by welding.

A study on minimum weight design of vertical corrugated bulkheads for chemical tankers

  • Shin, Sang-Hoon;Ko, Dae-Eun
    • International Journal of Naval Architecture and Ocean Engineering
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    • v.10 no.2
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    • pp.180-187
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    • 2018
  • Corrugated bulkhead has been adopted for cargo tank bulkheads of commercial vessels such as bulk carriers, product oil carriers and chemical tankers. It is considered that corrugated bulkhead is a preferred structural solution, compared to the flat stiffened bulkhead, due to several advantages such as lower mass, easier maintenance and smaller corrosion problems. Many researches to find the optimum shape of corrugated bulkhead have been mostly carried out for bulk carriers. Compared to corrugated bulkheads of bulk carriers, ones of chemical tankers are more complicated since they are composed of transverse and longitudinal bulkheads, and they are made of higher priced materials. The purpose of this study is the development of minimum weight design method for corrugated bulkhead of chemical tankers. Evolution strategy is applied as an optimization technique. It has been verified from many researches that evolution strategy searches global optimum point prominently by using multi-individual searching technique. Multi-individual searching methods need excessive time if they connect to 3-D finite element model for repetitive structural analyses. In order to resolve this issue, 2-D beam element connected to deck and lower stool is substituted for a corrugated structure in this study. To verify the reliability of the structural responses by idealized 2-D beam model, they have been compared with ones by 3-D finite element model. In this study, optimum design for corrugated bulkhead of 30 K chemical tanker has been carried out, and the results by developed optimum design program have been compared with design data of existing ship. It is found out that optimum design is about 9% lighter than one of existing ship.