• 제목/요약/키워드: Corrosion rates

검색결과 270건 처리시간 0.021초

농업용 관정의 기계적 처리 이후 성능 개선 효과의 정량적 평가 사례 (Quantitative Evaluation for Improvement Effects of Performance After Mechanical Rehabilitation Treatments on Agricultural Groundwater Well)

  • 송성호;이병선;안중기
    • 한국지하수토양환경학회지:지하수토양환경
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    • 제21권4호
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    • pp.42-49
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    • 2016
  • Step-drawdown pumping tests for identifying the improvement of groundwater well performance after rehabilitation treatments were conducted in three longstanding wells. Three selective mechanical treatment methods including power bubble, high-voltage electric pulse, and air surging were applied to these wells and the applicability of these methods to secure additional groundwater resources were evaluated quantitatively. Commonly, drawdown at final stage of stepdrawdown pumping tests after rehabilitation decreased by as much as 0.61~0.70 meters compared to those before rehabilitation. In addition, final specific drawdown values of three wells increased from 9% to 14% after rehabilitation. Formation loss coefficient and well loss coefficient decreased to 6.1% and 60.6%, respectively, indicating some clogging materials by precipitation/corrosion/microbe within pores of aquifer materials, gravel packs, and screens were effectively removed by applied methods. Decrease of formation loss coefficient was higher in the well applied by the power bubble method meanwhile high-voltage electric pulse method demonstrated the higher decrease of well loss coefficient. Additionally secured groundwater amounts after rehabilitation ranged from 23.3 to 32.1 m3/day, which account for 8~16% of initially developed pumping rates of the wells. From the results of this study, the effective selection of rehabilitation treatments considering aquifer characteristics are expected to contribute to secure groundwater resources for irrigation as well as to plan systematic management program for groundwater resources in rural area.

$UV/TiO_2$ 충진 반응기에서 페놀의 광산화 반응 (Photocatalytic Degradation of Phenol in $UV/TiO_2$ Packed-bed System)

  • 박길순;김종화;이상화
    • 대한환경공학회지
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    • 제27권9호
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    • pp.939-945
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    • 2005
  • 입상형/비드형(직경 = 5 mm) 광촉매가 충진된 고정상 반응기에서 유량별 광산화 반응속도를 고찰한 결과 유량이 400 mL/min 이상에서 페놀의 분해속도가 더 이상 증가하지 않았다. 비드형 광촉매의 경우에는 부식율과 코팅량의 증가에 따른 뚜렷한 광산화 반응속도의 차이가 나타나지 않았다. 광촉매의 종류별 페놀의 분해능을 비교한 결과 Degussa P25가 STS-02(Ishihaha사)와 $TiO_2$(N사)에 비해 높은 광산화 활성을 나타내 주었다. 유체의 전단력에 의한 표면의 마모가 쉽게 일어날 수 있는 입상형 광촉매보다 $TiO_2$가 코팅된 비드형 광촉매를 사용함으로써 광촉매 활성을 오래 동안 유지할 수 있는 광산화 시스템의 개발이 가능하다.

순도가 향상된 금속급 실리콘 제조를 위한 산침출 연구 (A Study of Acid Leaching for Metallurgical Grade Silicon Manufacturing Improved Purity)

  • 엄명헌;하범용
    • 한국산학기술학회논문지
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    • 제18권11호
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    • pp.118-123
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    • 2017
  • 다양한 산업에 사용되고 있는 금속급 실리콘(MG-Si, Metallurgical grade silicon)을 제조하기 위해 실리콘 원료 내 가장 많이 함유하고 있는 불순물인 알루미늄(Al) 및 철(Fe)을 제거하고자 산(Acid) 침출 실험을 수행하였다. 5가지 종류의 산(HCl, HF, H2SO4, HNO3, H3PO4)을 1, 2, 4, 6M로 조제하여 실리콘 원료에 반응시킨 결과, 1M 농도의 HF가 가장 우수한 Al 및 Fe 제거율을 나타내었으며 각각 97.9%와 95.2로 나타났다. 그러나 HF는 실리콘 부식 특성으로 인해 18% 가량의 수율 감소가 발생하였으며 이러한 수율감소를 최소화하기 위해 두 번째로 제거율이 우수하게 나타난 2M HCl과 혼합하여 실리콘 원료에 적용하였다. 혼합용액의 최적조건을 선정하기 위해 실험을 수행하여 $80^{\circ}C$, 2시간의 침출 최적조건으로 결정되었으며 이 혼합용액의 적용 결과 Al 및 Fe 잔류농도가 각각 141 ppmw 및 93ppmw로 나타나 3N급의 순도를 갖는 금속급 실리콘을 제조하기에 매우 용이한 것으로 확인되었다.

ELECTROSLAG STRIP OVERLAY OF PIPE, FITTINGS, AND PRESSURE VESSELS

  • Dan, Capitanescu
    • 대한용접접합학회:학술대회논문집
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    • 대한용접접합학회 2002년도 Proceedings of the International Welding/Joining Conference-Korea
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    • pp.355-360
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    • 2002
  • ElectroSlag Strip Overlaying (ESSO) process has been around since 1970. ESSO process had limited acceptance due to a few problems associated with the use of this process in its very early stage. Limited knowledge and, most significantly, poor quality of the equipment and welding flux gave the ESSO process a bad name. However, this process is well accepted today and used in North America, Europe and Japan. The ESSO process provides low dilution overlays at high deposition rates, excellent and consistent deposit chemistry with excellent surface quality, and virtually no defects. Capitan has taken this process one step further through extensive research and development of the process itself as well as the equipment. The improvement brought to the process warranted the issuance in May 2000 of an US patent. This study demonstrates the feasibility of this process with immediate positive production results. The main achievements of this work are as follows: $\textbullet$ Development of six various strip-flux combinations on three different base materials: carbon steel, $\frac{1}{4}$ Cr/.5 Mo and 2 $\frac{1}{4}$ Cr/l Mo, fully tested with: penetrant, ultrasound, bends, hardness, overlay chemistry, corrosion and hydrogen disbonding. $\textbullet$ 12" dia. 90 hot formed elbows from straight pipe electroslag overlayed with "1 layer" and "2 layer" Alloy 625 $\textbullet$ a very unique development of miniaturized overlaying equipment able to perform overlay in pipe with diameters as low as 10" (254 mm). This development has large applications in the field of offshore, petrochemical, refining, pulp and paper and power generation industries. The aftermath of this development was its immediate acceptance by major end users with the completion of four projects of overlayed pipe in the USA and Far East Asia.

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증기발생기 세관용 Inconel 690 의 프레팅 마찰 및 마멸특성 (Friction and Wear of Inconel 690 for Steam Generator Tube in Fretting)

  • 이영제;임민규;오세두
    • 대한기계학회논문집A
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    • 제27권3호
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    • pp.432-439
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    • 2003
  • Inconel 690 for nuclear steam generator tube has more Chromium than the conventionally used Inconel 600 in order to increase the corrosion resistance. To evaluate the tribological characteristics of Inconel 690 under fretting condition the fretting tests were carried out in air and elevated temperature water. Fretting tests of the cross-cylinder type were done under various vibrating amplitudes and applied normal loads in order to measure the friction forces and wear volumes. From the results of fretting wear tests. the wear of Inconel 690 can be predictable using the work rate model. The amounts of friction forces were proportional to relative movement between two fretting surfaces. The friction coefficients were decreased as increasing the normal loads and deceasing the vibrating amplitudes. Depending on fretting environment, distinctively different wear mechanisms and often drastically different wear rates can occur It was found that the fretting wearfactors in air and water at 2$0^{\circ}C$, 5$0^{\circ}C$, and 8$0^{\circ}C$ were 7.38 $\times$ $10^{-13}$$Pa^{-1}$, 2.12 $\times$$10^{-13}$$Pa^{-1}$, 3.34$\times$$10^{-13}$$Pa^{-1}$and 5.21$\times$$10^{-13}$$Pa^{-1}$, respectively flexibility to model response data with multiple local extreme. In this study, metamodeling techniques are adopted to carry out the shape optimization of a funnel of Cathode Ray Tube, which finds the shape minimizing the local maximum principal stress. Optimum designs using two metamodels are compared and proper metamodel is recommended based on this research.

다구찌 기법을 적용한 섬유금속적층판 접착층의 에너지 해방률 강화에 대한 연구 (Study on Enhancement for Interfacial Energy Release Rate of Adhesive Layer in Fiber Metal Laminates using Taguchi Method)

  • 길민규;박으뜸;송우진;강범수
    • Composites Research
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    • 제29권5호
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    • pp.249-255
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    • 2016
  • 섬유금속적층판은 우수한 피로특성, 내부식성, 충격저항 등으로 인하여 항공우주산업에서 널리 사용되고 있다. 본 논문에서는 다구찌 기법을 사용하여 섬유금속적층판의 내부 에너지 해방률을 향상시킬 수 있는 공정 조건을 도출하는 절차에 대해 실험적 연구가 수행되었다. 내부 접착력 향상을 위한 제조공정을 도출하기 위해서, 표면처리, 접착필름의 용융점 유지시간 및 초기 압력이 서로 다르다는 조건하에서 제작한 시편들에 대해서 Double cantilever beam과 End-notched flexure 시험을 수행하였다. 시험으로부터 모드 I과 모드 II의 에너지 해방률을 측정한 후, 다구찌 기법의 망대특성에 의한 신호 잡음비를 비교하여 효율적인 제조공정을 도출하였다.

Influence of porosity and cement grade on concrete mechanical properties

  • Huang, Jiandong;Alyousef, Rayed;Suhatril, Meldi;Baharom, Shahrizan;Alabduljabbar, Hisham;Alaskar, Abdulaziz;Assilzadeh, Hamid
    • Advances in concrete construction
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    • 제10권5호
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    • pp.393-402
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    • 2020
  • The given research focuses on examining the effect of relatively humidity (RH) and curing temperature on the hydrates as well as the porosity of calcium sulfoaluminate (CSA) cement pastes. Numerous tests, which consist of mercury intrusion porosimetry (MIP), thermosgravi metric (TG) and X-ray diffraction (XRD) were conducted. Various characterization techniques which include, scanning electron microscopy, Fourier transform microscopy along with X-ray diffraction evaluations were conducted on the samples to examine phase formation and crystallinity, morphology and microstructure along with bond formations and functional groups, respectively. During long-term study, the performance of concrete which consisted of limestone and flash-calcined was close to those from standard Portland cement concrete. Traditional classifications and methods of corrosion were widely used for the assessment of steel in concrete which may get employed to concrete which contains LC3 to recalibrate the range of polarization resistance for passitivity condition. For example, there is up to 79.5% and 146% respective flexural and compressive strengths. Moreover, they developed more advance electrical and thermo-mechanical performance with a substantial reduction in absorption of water of close to 400%. These advantages allow this research crucial to evaluate how these methods can be applied. Additionally, the research evaluates developed and more advanced cement preservation and repair techniques. The conclusion suggests concerted efforts by various stakeholders such as policy makers to enable low-carbon rates.

Etching characteristics of Al-Nd alloy thin films using magnetized inductively coupled plasma

  • Lee, Y.J.;Han, H.R.;Yeom, G.Y.
    • 한국표면공학회:학술대회논문집
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    • 한국표면공학회 1999년도 추계학술발표회 초록집
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    • pp.56-56
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    • 1999
  • For advanced TFT-LCD manufacturing processes, dry etching of thin-film layers(a-Si, $SiN_x$, SID & gate electrodes, ITO etc.) is increasingly preferred instead of conventional wet etching processes. To dry etch Al gate electrode which is advantageous for reducing propagation delay time of scan signals, high etch rate, slope angle control, and etch uniformity are required. For the Al gate electrode, some metals such as Ti and Nd are added in Al to prevent hillocks during post-annealing processes in addition to gaining low-resistivity($<10u{\Omega}{\cdot}cm$), high performance to heat tolerance and corrosion tolerance of Al thin films. In the case of AI-Nd alloy films, however, low etch rate and poor selectivity over photoresist are remained as a problem. In this study, to enhance the etch rates together with etch uniformity of AI-Nd alloys, magnetized inductively coupled plasma(MICP) have been used instead of conventional ICP and the effects of various magnets and processes conditions have been studied. MICP was consisted of fourteen pairs of permanent magnets arranged along the inside of chamber wall and also a Helmholtz type axial electromagnets was located outside the chamber. Gas combinations of $Cl_2,{\;}BCl_3$, and HBr were used with pressures between 5mTorr and 30mTorr, rf-bias voltages from -50Vto -200V, and inductive powers from 400W to 800W. In the case of $Cl_2/BCl_3$ plasma chemistry, the etch rate of AI-Nd films and etch selectivity over photoresist increased with $BCl_3$ rich etch chemistries for both with and without the magnets. The highest etch rate of $1,000{\AA}/min$, however, could be obtained with the magnets(both the multi-dipole magnets and the electromagnets). Under an optimized electromagnetic strength, etch uniformity of less than 5% also could be obtained under the above conditions.

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All-ceramic Crown 용 도재의 동적 피로특성 평가 (AN EVALUATION OF DYNAMIC FATIGUE CHARACTERISTICS OF DENTAL CERAMICS FOR ALL-CERAMIC CROWN)

  • 유형우;배태성;송광엽;박찬운
    • 대한치과보철학회지
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    • 제35권4호
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    • pp.781-792
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    • 1997
  • This study was peformed to evaluate the dynamic fatigue characteristics of the dental ceramics for all-ceramic crown. A feldspathic porcelain of VMK68. glass ceramic of IPS-Empress, and glass infiltrated alumina ceramic of In-Ceram were used. Disc specimens were prepared to the final dimensions of 12 mm in diameter and 1 mm in thickness. The biaxial flexure test was conducted using a ball-on-three-ball method. 240 specimens were tested in $37^{\circ}C$ water by testing 20 samples at each of four loading rates:0.05, 0.2, 1, and 5mm/min. 60 specimens were tested in a moisture-free environment by testing 20 samples at 5mm/min. The inert strength of VMK68 was 80.25MPa, and the fatigue parameters were n=29.1, ${\sigma}_{fo}=52.90MPa$. The inert strength of IPS-Empress was 104.76MPa, and the fatigue parameters were n=32.46, ${\sigma}_{fo}=67.52MPa$. The inert strength of In-Ceram was 429.33MPa, and the fatigue parameters were n=31.46, ${\sigma}_{fo}=258.36MPa$. 10-year failure stresses of VMK68, IPS-Empress, and In-Ceram were 20.3MPa, 24.8MPa, and 93.6MPa, respectively. Failure strength and fatigue life showed the highest value in In-Ceram, and then, IPS-Empress and VMK68.

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공동현상을 고려한 커먼레일용 고압 DME 인젝터 노즐의 최적 설계 연구 (Study on the Optimum Design of High Pressure Common-rail DME Injector Nozzle with Consideration of Cavitation)

  • 정수진;박정권;이상인
    • 한국자동차공학회논문집
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    • 제21권1호
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    • pp.99-106
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    • 2013
  • DME (Di-Methyl Ether) is synthetic product that is produced through dehydration of methanol or a direct synthesis from syngas. And it is able to save fossil fuel and reduce pollutants of emission such as PM and $CO_2$. In spite of its advantages it is difficult to design DME fuelled engine system because DME fuel may cause to severely generate cavitation and corrosion in fuel delivery system due to physical properties of DME. Therefore, in this study three-dimensional internal flow characteristics with consideration of cavitation were predicted in the DME injector using diesel and DME fuel. Moving grid technique was employed to describe needle motion and 1-D hydraulic simulation of injector was also simulated to obtain transient needle motion profiles. The results of simulation show that cavitations was generated at the inlet of nozzle near high velocity region both diesel and DME. And mass flow rate of DME is reduced by 4.73% compared to that of diesel at maximum valve lift because cavitation region of DME is much more larger. To increase flow rate of DME injector, internal flow simulation has been conducted to investigate the nozzle hole inner R-cut effect. The flow rates of diesel and DME increase as R-cut increases, and flow coefficient of DME fuel injector was increased by 6.3% on average compared with diesel fuelled injector. Finally, optimum shape of DME injector nozzle is suggested through the comparison of flow coefficient with variation of nozzle hole inner R-cut.