• 제목/요약/키워드: Corrosion index

검색결과 108건 처리시간 0.021초

정수처리에서 pH 저감에 의한 응집효율향상에 관한 연구 (Improving Coagulation Performance with pH Preadjustment in Drinking Water Treatment)

  • 이환;이철효;정창규;이윤진
    • 한국환경보건학회지
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    • 제29권2호
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    • pp.1-6
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    • 2003
  • This paper reports on a pilot scale comparison of PACS coagulation with and without pH preadjustment. The pH of the water was adjusted with carbon dioxide and sulfuric acid. Process performance was assessed on the basis of total organic carbon(TOC), UV absorbance, turbidity and disinfection by-product(DBP) precursors. Coagulation pH appeared to be a determining factor for maximum NOM removal. The optimum coagulation pH in order to decrease TOC and turbidity were pH 7. Preadjustment of pH 7 increased TOC removal to as much as 43, 47 percent with sulfuric acid and carbon dioxide. Moreover, coagulation at pH 7 caused a reduction in UV$_{254}$, THMFP and HAAFP compared to the baseline coagulation. For preadjustment of pH 7 with carbon dioxide, the percentage of TOC, UV$_{254}$, THMFP and HAAFP shows the reduction rate of 3.8, 0.5, 4.8, 9.4% comparing to the coagulation rendition using sulfuric acid. Acid addition to depress pH during coagulation decrease Langelier Saturation Index(LSI), potentially causing increase corrosion in water distribution systems. LSI for carbon dioxide and sulfuric acid at pH 6 was -2.3, -3.3. Therefore, carbon dioxide was more effective at controlling corrosion than sulfuric acid.

Zn-Flash 코팅 처리가 전기아연도금 시 초고강도 강재의 수소 발생, 유입 및 취화 거동에 미치는 영향 (Effects of Zn-Flash Coating on Hydrogen Evolution, Infusion, and Embrittlement of Advanced-High-Strength Steel During Electro-Galvanizing)

  • 방혜린;김상헌;김성진
    • Corrosion Science and Technology
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    • 제22권5호
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    • pp.341-350
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    • 2023
  • In the present study, effects of a thin Zn-flash coating on hydrogen evolution, infusion, and embrittlement of advanced high strength steel during electro-galvanizing were examined. The electrochemical permeation technique in conjunction with impedance spectroscopy was employed under applied cathodic polarization. Moreover, a slow-strain rate test was conducted to evaluate loss of elongation (i.e., indicative of hydrogen embrittlement (HE)) and examine fracture surfaces. Results showed that the presence of a thin Zn-flash coating, even when it was not distributed uniformly, reduced hydrogen evolution rate and substantially impeded infusion of hydrogen into the steel substrate. This was primarily due to a hydrogen overvoltage on Zn coating and trapping of hydrogen at the interface of Zn coating/flash coating/steel substrate. Consequently, the sample with flash coating had a smaller HE index than the sample without flash coating. These results suggest that a thin Zn-flash coating could be an effective technical strategy for mitigating HE in advanced high-strength steels.

석탄 보일러에서 회분 부착성향 예측 접근 방법에 대한 고찰 (Consideration on the Prediction Approach of Ash Deposition Propensity in Coal-fired Boilers)

  • 김대희;최상민;김정래
    • 한국연소학회지
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    • 제22권4호
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    • pp.27-34
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    • 2017
  • Various approaches have been proposed to predict the ash deposition (slagging and fouling) propensity of coal, which is essential in maintaining high efficiency and preventing corrosion/damage of a coal-fired boiler. The common method is to establish an index of the ash deposition propensity based on elementary coal composition and advanced characterization of ash properties, which is readily applicable to design, operation and maintenance of coal-fired boilers. Although many indexes have been developed for this purpose, their validity is still not satisfactory in actual applications to particular coal types or operating conditions. This paper reviews the status of predictive approaches for the ash deposition propensity, and assesses the performance of existing indexes by comparing the results for selected coals. This work will contribute to the development of a comprehensive and practical method for prediction of the ash deposition propensity.

교량구조물의 유지관리를 위한 신뢰성 해석 모델 (Reliability Analysis Models for Maintenance of bridge structures)

  • 김종길;손용우;이증빈;안영기
    • 한국구조물진단유지관리공학회 논문집
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    • 제8권3호
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    • pp.251-261
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    • 2004
  • 최근에 교량구조물의 부식과 노회에 대한 관심이 모아지고 있는 상황에서 부식된 철근의 불확실성은 교량구조물의 안전성 뿐만 아니라 철근콘크리트 부재의 휨강도에 영향을 미치고 있다. 이 논문에서는 이들 불확실성을 고려한 신뢰성 뼈대구조물의 거동과 최적유지관리 시나리오에 대한 검증을 제시하고 있으며, 이들 과정은 부죄된 구조물의 생애주기를 고려한 프로그램에 의해 산출한 값이며 부식구조물의 신뢰성지수 프로파일에 의한 여러 형태의 구조물에 대한 영향을 고려하여 유지관리 효과에 대해 연구 하였다.

수도관 내부부식방지를 위한 CCPP 조절시 정수공정내에서의 수질변화 (Water Quality Variation on the Unit Operation of Water Treatment Process When CCPP Index was Controlled for Internal Corrosion of Water Pipes)

  • 이재인;김도환;이지형;김동윤;홍순헌;신판세
    • 대한환경공학회지
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    • 제27권4호
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    • pp.362-368
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    • 2005
  • 본 연구에서는 수도관부식방지를 위해 정수공정에 탄산가스와 소석회, 소다회를 주입함으로 pH, 알칼리도, 칼슘경도와 같이 부식에 영향을 미치는 수질을 조절하여 운전하였다. 탄산가스와 소석회는 정수공정 중 응집제주입 이전에, 소다회는 정수공정의 마지막 단계인 BAC 처리 후에 주입하여 정수공정 내의 수질변화에 미치는 영향을 고찰하였다. pH와 알칼리도는 응집조에서 감소한 후 침전이후 BAC 공정까지 일정하게 되었으며, 칼슘경도는 응집조에서 증가한 후 BAC 공정까지 큰 변화 없이 일정하였다. 연구기간동안 탄산가스와 소석회주입으로 탁도 발생과 DOC 제거율에 미치는 영향은 거의 없었다. 최종처리수의 평균수질은 pH 8.39, 알칼리도 $61.4\;mg/L$ as $CaCO_3$, 칼슘경도 59.4 mg/L as $CaCO_3$였고, CCPP 지수는 BAC 처리수보다 평균 29.5 mg/L 상승시켜 CCPP $\geq$ 0으로 조절하여 수도관내 부식방지효과를 기대할 수 있었다.

상수도관 부식방지를 위한 CCPP(Calcium Carbonate Precipitation Potential) 산정 프로그램 개발 (Development of CCPP(Calcium Carbonate Precipitation Potential) calculating program for corrosion control of drinking water distribution system)

  • 황병기
    • 한국산학기술학회논문지
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    • 제9권1호
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    • pp.170-175
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    • 2008
  • 본 연구에서는 상수도관의 부식방지를 위해 관망 내부에서 탄산칼슘의 침전 및 용해 여부를 판단할 수 있는 지표인 CCPP를 산정할 수 있는 프로그램을 개발하였다. CCPP 산정은 9단계 절차를 통하여 이루어지며, 평형상태의 pH를 가정하고 결정 식의 왼쪽 항의 합과 오른 쪽 항의 합이 오차의 범위에서 유사한 값을 주도록 반복계산을 수행하고, 다음 단계에서 초기 및 평형상태의 알칼리도를 대입하여 CCPP를 구한다. 프로그램 개발은 계산을 위해 포트란 언어를, 결과 값을 그래프로 표현하여 쉽게 판단할 수 있도록 비쥬얼베이직 언어를 사용하였다. 개발된 프로그램을 적용하여 한강 수계 Y정수사업소의 수질을 평가한 결과, 탄산칼슘의 불포화 상태가 심한 수질로 판명되어 부식성이 높은 것으로 평가되었다.

Assessment of Semi-Quantitative Health Risks of Exposure to Harmful Chemical Agents in the Context of Carcinogenesis in the Latex Glove Manufacturing Industry

  • Yari, Saeed;Asadi, Ayda Fallah;Varmazyar, Sakineh
    • Asian Pacific Journal of Cancer Prevention
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    • 제17권sup3호
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    • pp.205-211
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    • 2016
  • Excessive exposure to chemicals in the workplace can cause poisoning and various diseases. Thus, for the protection of labor, it is necessary to examine the exposure of people to chemicals and risks from these materials. The purpose of this study is to evaluate semi-quantitative health risks of exposure to harmful chemical agents in the context of carcinogenesis in a latex glove manufacturing industry. In this cross-sectional study, semi-quantitative risk assessment methods provided by the Department of Occupational Health of Singapore were used and index of LD50, carcinogenesis (ACGIH and IARC) and corrosion capacity were applied to calculate the hazard rate and the biggest index was placed as the basis of risk. To calculate the exposure rate, two exposure index methods and the actual level of exposure were employed. After identifying risks, group H (high) and E (very high) classified as high-risk were considered. Of the total of 271 only 39 (15%) were at a high risk level and 3% were very high (E). These risks only was relevant to 7 materials with only sulfuric acid placed in group E and 6 other materials in group H, including nitric acid (48.3%), chromic acid (6.9%), hydrochloric acid (10.3%), ammonia (3.4%), potassium hydroxide (20.7%) and chlorine (10.3%). Overall, the average hazard rate level was estimated to be 4 and average exposure rate to be 3.5. Health risks identified in this study showed that the manufacturing industry for latex gloves has a high level of risk because of carcinogens, acids and strong alkalisand dangerous drugs. Also according to the average level of risk impact, it is better that the safety design strategy for latex gloves production industry be placed on the agenda.

Predictive model for the shear strength of concrete beams reinforced with longitudinal FRP bars

  • Alzabeebee, Saif;Dhahir, Moahmmed K.;Keawsawasvong, Suraparb
    • Structural Engineering and Mechanics
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    • 제84권2호
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    • pp.143-154
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    • 2022
  • Corrosion of steel reinforcement is considered as the main cause of concrete structures deterioration, especially those under humid environmental conditions. Hence, fiber reinforced polymer (FRP) bars are being increasingly used as a replacement for conventional steel owing to their non-corrodible characteristics. However, predicting the shear strength of beams reinforced with FRP bars still challenging due to the lack of robust shear theory. Thus, this paper aims to develop an explicit data driven based model to predict the shear strength of FRP reinforced beams using multi-objective evolutionary polynomial regression analysis (MOGA-EPR) as data driven models learn the behavior from the input data without the need to employee a theory that aid the derivation, and thus they have an enhanced accuracy. This study also evaluates the accuracy of predictive models of shear strength of FRP reinforced concrete beams employed by different design codes by calculating and comparing the values of the mean absolute error (MAE), root mean square error (RMSE), mean (𝜇), standard deviation of the mean (𝜎), coefficient of determination (R2), and percentage of prediction within error range of ±20% (a20-index). Experimental database has been developed and employed in the model learning, validation, and accuracy examination. The statistical analysis illustrated the robustness of the developed model with MAE, RMSE, 𝜇, 𝜎, R2, and a20-index of 14.6, 20.8, 1.05, 0.27, 0.85, and 0.61, respectively for training data and 10.4, 14.1, 0.98, 0.25, 0.94, and 0.60, respectively for validation data. Furthermore, the developed model achieved much better predictions than the standard predictive models as it scored lower MAE, RMSE, and 𝜎, and higher R2 and a20-index. The new model can be used in future with confidence in optimized designs as its accuracy is higher than standard predictive models.

몰리브덴광 부유선별 공정 최적화를 위한 기초 선광 특성 평가 (Evaluation of Basic Beneficiation Characteristics for Optimizing Molybdenum Ore Flotation Process)

  • 한성수;서주범
    • 자원리싸이클링
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    • 제33권2호
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    • pp.37-45
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    • 2024
  • 몰리브덴은 높은 내열성, 내부식성에 의해 다양한 산업에 적용되어, 우리나라의 핵심광물로 선정된 중요한 금속이다. 그러나 최근 몰리브덴 광맥의 저품위화로 인해 생산에 어려움을 겪고 있어, 몰리브덴 선광 공정에 대한 효율 향상이 필요하다. 본 연구에서는 국내 몰리브덴광 선광 공정의 효율 향상을 위한 기초 선광 특성 평가 연구를 수행하였다. 기초 선광 특성은 광물학적 분석, 분쇄일지수, 부유선별 속도 분석으로 평가되었다. 분석 결과, 단체분리가 가능한 몰리브덴광의 입자 크기는 ~100 ㎛였으며, 분쇄 일지수는 14.57 kWh/t로 산출되었다. 또한 부유선별 속도 분석을 통해, 부유선별 단위 공정 각각의 최적 부유선별 시간을 제공함으로써 최적화를 위한 운영 조건을 확립하였다. 마지막으로 본 연구에서 제공한 몰리브덴광 기초 선광 특성 정보는 향후 산업 규모의 몰리브덴 선광 플랜트의 분쇄 및 부유선별 공정을 진단하는 데 활용될 예정이다.

Analysis of Arc Tube Properties by Degradation in Ceramic Metal Halide Lamp

  • Yang, Jong-Kyung;Jang, Hyeok-Jin;Park, Dae-Hee
    • Journal of Electrical Engineering and Technology
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    • 제6권1호
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    • pp.123-127
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    • 2011
  • To clarify the relations of optical properties to the main factors responsible for the loss and damage of luminous efficacy, a 20 min turn-on/turn-off test for 2,000 h for a ceramic metal halide lamp is conducted. The corrosion rates of the arc tube wall and electrode are estimated based on thermal stress. Wall blackening is attributed to the tungsten being transported from the hot electrode tips to the relatively cold arc tube wall. Furthermore, the grain boundaries of the arc tube are changed by the degradation. Distortion of the electrode is observed, and the ignition and the driving voltage of the load both increase. Finally, the color rendering index and the color coordinates are changed after the degradation. The luminous flux and the intensity of the luminous distribution are decreased significantly.