• 보존과학연구
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• s.14
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• pp.35-44
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• 1993

The way of prevention for the continuous corrosion progress in iron antiquities after excavation and conservation treatment have been studied. The corrosion occuring have been found the oxidation of ferrous ions in the presence of chloride. The consideration to control the activity of chloride is important of controling relative humidity for the stable environment of the storage. One of the method that keeps archeological iron antiquities recommend the storage of special vinyl film(poly-vinyl alcohol film) with silica gel to control the relative humidity. Although this method is not permanent, it's very well efficiency of economy and convenience at present.

• Journal of the Korean institute of surface engineering
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• v.48 no.6
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• pp.354-359
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• 2015

Stainless steel has poor corrosion resistance in marine environment due to the breakdown of a passive film caused by chloride. It suffers electrochemical corrosion like pitting corrosion, crevice corrosion, and stress corrosion crack (SCC) in marine environment. In general, it indicates that the passive film of $Al_2O_3$ has better corrosion resistance than that of $Cr_2O_3$ in seawater. This paper investigated the damage behavior 304 stainless steel and hot-dip aluminized 304 stainless steel in seawater solution. Various electrochemical experiments were carried out including potential measurement, potentiodynaimic experiment, Tafel analysis and galvanostatic experiment. As a result of anodic polarization experiment, higher pitting damage depth was indicated at 304 stainless steel than hot-dip aluminized 304 stainless steel. In addition, relatively higher corrosion current density was shown at hot-dip aluminized stainless steel as a result of Tafel analysis.

• Journal of the Society of Disaster Information
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• v.11 no.2
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• pp.253-261
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• 2015

Deterioration of reinforced concrete structures in corrosive environment is tend to be accelerated due to ingress of aggressive ion such as chloride ion. Chloride-induced corrosion is affected by various factors such as cover concrete qualities, width of existing cracks, and cover depth of concrete. However, the allowable crack width of RC structure in design code does not consider the concrete material properties and conditions of construction except the cover depth. In this paper, an equation for allowable crack width is proposed to consider the cover concrete quality, crack width, and cover depth. Crack width, cover depth, and water-cement ratio of concrete are selected as influencing factors on corrosion of reinforcement for rapid chloride tests. From test results, the relationships between the factors and corrosion are derived. Finally, the equation for allowable crack width is derived in terms of concrete compressive strength and cover depth. The presented equation is verified by comparative calculations with design code variables.

• Journal of the Korean institute of surface engineering
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• v.53 no.5
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• pp.207-212
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• 2020

Silver is an inexpensive precious metal and is used in various jewelry in Asia. Although silver has high potential, it has corrosion resistance that is vulnerable to boiling sulfuric acid and nitric acid. So, silver research is needed to prevent the corrosion with environment. But silver corrosion is not studied. sulfuric acid make the uniform corrosion and chloride ion make the pitting corrosion. ICCP inhibits the corrosion because it offset electrons. This study used a potential from - 4 V to 4 V to check the effect of potential. Corrosion rate is lowet at -1 V.

• Corrosion Science and Technology
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• v.20 no.5
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• pp.281-288
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• 2021

Due to advancement of the industry, operation of a device in a harsh environment is increasing. Especially, the marine environment contains Cl^- ions which causes localized corrosion such as pitting and crevice corrosion of stainless steel and various metals. In this study, electrochemical corrosion behaviors of austenitic stainless steel (STS 316L) and nickel alloy (Inconel 600) with different seawater concentrations (fresh water, seawater, mixed water) were investigated. The STS 316L and Inconel 600 were etched in 10% oxalic acid and composed of an austenitic phase. Results of Tafel analysis in seawater showed that STS 316L and Inconel 600 presented the highest corrosion current densities of 7.75 × 10^-4 mA/cm² and 1.11 × 10^-4 mA/cm² and the most negative pitting potentials of 0.94 V and 1.06 V, respectively. The maximum damage depths and surface damage ratio by pitting corrosion increased with chloride concentration. The STS 316L had higher PREN than Inconel 600. However, the surface damage and weight loss of Inconel 600 were superior to STS 316L. It was difficult to compare the pitting resistance of STS 316L based on Fe and Inconel 600 based on Ni with PREN simply.

• Journal of the Korea Concrete Institute
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• v.17 no.1 s.85
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• pp.157-166
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• 2005

This article involves architecting prototype-fuzzy expert system for designing the nominal cover thickness by means of fuzzy inference for quantitatively representing the environment affecting factor to reinforced concrete in chloride-induced corrosion environment. In this work, nominal cover thickness to reinforcement in concrete was determined by the sum of minimum cover thickness and tolerance to that defined from skill level, constructability and the significance of member. Several variables defining the quality of concrete and environment affecting factor (EAF) including relative humidity, temperature, cyclic wet and dry, and the distance from coast were treated as fuzzy variables. To qualify EAF the environment conditions of cycle degree of wet-dry, relative humidity, distance from coast and temperature were used as input variables. To determine the nominal cover thickness a qualified EAF, concrete grade, and water-cement ratio were used. The membership functions of each fuzzy variable were generated from the engineering knowledge and intuition based on some references as well as some international codes of practice.

• Proceedings of the Korea Concrete Institute Conference
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• 1996.10a
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• pp.201-206
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• 1996

Recently, to utilize conutry effectively, many concrete structures such as Young Jong Do New Airport. SeoHae Bridege are being constructed. Therefore, Corrosion of steel reinforcement of concrete structures become more and more serious, and prediction of service lives of concrete structures considering steel corrosion is needed much more. The methodologies of predicting service life have been studied for various views, but mathematical modelling based on diffusion theory is generally applied. The purpose of this paper is to investigate current mathematical models, and suggest theoretical basis on estimation of service lives of concrete structures in marine environment. Thus, the procedures for selecting variables such as threshold chloride concentration, diffusion coefficient, etc are suggested, and the service lives calculated through these procedures for various diffusion coefficients and cover depths are presented.

• Proceedings of the Korea Concrete Institute Conference
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• 2008.04a
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• pp.1065-1068
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• 2008

Marine bridges are readily deteriorated due to the exposure to marine environment. The concrete deterioration occurred by corrosion of steel in concrete is mainly relevant to chloride in seawater. Chloride ions penetrate through porous concrete, and then reach to the reinforcing steel, and finally corroded them. The corrosion by-products(rusts) increase the volume as much as 6 to 10 times of origin steel. this creates expanding pressure and tensile stress, which cause the structures cracking and spalling. Sometimes the rebar corrosion is accelerated, and then collapsed catastrophically. In order to prevent corrosion damage, it is important to understand well regarding the reason of concrete corrosion, the quantification of its damage, and protection method/system to stop or to mitigate the corrosion. In this study, slab specimens were fabricated to evaluate the effect of cathodic protection which was simulated to marine bridges, and/or port structures. Zn-mesh sacrificial anode has been applied as a chathodic protection system and accelerated test conditions, i.e. temperature and salt concentration have been used in this study.

• Journal of the Korean institute of surface engineering
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• v.49 no.3
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• pp.274-279
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• 2016

Stainless steel is widely used in various industries due to its excellent anti-corrosion characteristics. However, if the stainless steel is exposed to high speed fluid flow and chloride ion in the marine environment, corrosion and cavitation damage occurred on the surface easily. Therefore, to prevent these problems, stabilzed stainless steel is applied to offshore and shipbuilding industries. In this study, stabilized stainless steel specimen was made by 19%Cr-9%Ni with different Nb contents (0.29%, 0.46% and 0.71%). And then, their cavitation characteristics were investigated. As a result, the characteristics of cavitation resistance of stainless steel could be improved by increasing Nb contents.

• Journal of the Korean Recycled Construction Resources Institute
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• v.4 no.3
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• pp.243-249
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• 2016

The present work is for an evaluation of resistance to corrosion in steel coated with cementitious repair material, so that 3 cases of steel plate(Normal, Welding, Welding & coating case) are subjected to ICM(Impressed Current Method) for acceleration of corrosion for 7days. Tested and estimated corrosion ratio through Faraday's Law are compared, and the related flexural strength are evaluated. In Normal and Welding cases, similar level of corrosion ratio(70%) is evaluated, however only 17% level of corrosion ratio is evaluated in the Welding & coating case, which indicates that cementitious repair material is effective to anti-corrosion due to a block of chloride penetration. The flexural test results are consistent with those in accelerated corrosion test, which shows a significant flexural strength in Welding & coating case by 3.4times greater than the others. The cementitious material repair coating is evaluated to be effective to anti-corrosion in welding of steel plate.