• 한국환경과학회:학술대회논문집
• /
• 한국환경과학회 1998년도 봄 학술발표회 프로그램
• /
• pp.122-124
• /
• 1998

• 한국환경과학회:학술대회논문집
• /
• 한국환경과학회 1999년도 정기총회 및 봄 학술발표회 프로그램 The Korean Environmental Sciences Society
• /
• pp.220-223
• /
• 1999

• 한국환경과학회:학술대회논문집
• /
• 한국환경과학회 1999년도 임시총회 및 가을 학술발표회 초록집 The Korean Environmental Sciences Society
• /
• pp.151-153
• /
• 1999

• Environmental Sciences Bulletin of The Korean Environmental Sciences Society
• /
• 제10권S_4호
• /
• pp.181-187
• /
• 2001

This study was carried out to measure the variations of potential and current density with polymers. The results were particularly examined to identify the influences on potential and rate of various factors including temperature and pH. The Tafel slope for anodic dissolution was determined by the polarization effect depending on these conditions. The optimum conditions were established for each case. The second anodic current density peak and maximum current density were designated as the relative polarization sensitivity$(I_r/I_f)$. The mass transfer coefficient value$(\alpha)$ was determined with the Tafel slope for anodic dissolution based on the polarization effect with optimum conditions.

• Journal of Welding and Joining
• /
• 제17권6호
• /
• pp.32-37
• /
• 1999

Since stainless steel plates have good mechanical properties, weldability, appearance and resistance of corrosion, these are traditionally used for vehicles such as the bus and the train. And they are mainly fabricated by spot welding. But fatigue strength of their spot welded joint is considerably influenced by welding conditions as well as geometrical factors. Thus a reasonable and systematic criterion for long life design of spot welded body structure must be established. In this report, strain energy density was analyzed by using 3-dimensional finite element model about the IB-type spot welded lap joint under tension-shear load. Fatigue tests were conducted on them having various thickness, joint angle, lapped length and width. From their results, it was found that fatigue strength of the IB-type spot welded lap joints could be effectively and systematically rearranged by strain energy density at the edge of nugget.

• 한국산학기술학회논문지
• /
• 제12권6호
• /
• pp.2879-2887
• /
• 2011

본 연구는 탄소강 재질의 증기발생기 배관에서 수화학 조건에 따라 발생하는 부식현상의 이해와 부식속도 측정을 위한 것이다. 부식을 최소화하기 위하여 염기 및 환원성 분위기 유지가 중요하나, 계통재질에 따라 pH 및 산화환원 전위가 다르고, pH제어제의 종류에 따라 부식의 정도가 다르게 나타난다. 실험에는 pH제어제로서 ETA 와 전통적 NH3를 사용하였다. 본 연구에서는 pH 8.5~10, 온도 $50\sim250^{\circ}C$의 조건에서 동전위 분극 부식시험(potentiodynamic polarization)을 통해 부식전류밀도(corrosion current density)를 구하여 부식율(corrosion rate)을 계산하였다. 부식시험 결과, $NH_3$ 보다 ETA 용액에서 부식율이 낮고, pH 증가시 부식율이 감소하였으며, $150\sim200^{\circ}C$범위의 온도에서 부식율이 최대로 나타났다.

• Corrosion Science and Technology
• /
• 제8권5호
• /
• pp.203-207
• /
• 2009

Electrochemical methods have been widely used to study the performances and mechanisms for the degradation of organic and inorganic coatings. In this study, EN(Electrochemical noise) measurement was applied to the protective properties and review the parameters analyzed noise signals in the time and in the frequency domain for epoxy resin based coated steels during exposure to hot sea water($40^{\circ}C$) and salt spray for 200 days. It was also found that $R_n$(Noise resistance), $R_{sn}$($f_{min}$)(Spectral noise resistance) and 2H(Hurst exponent) represented the performance of epoxy coated steels. $R_n$ can be determined as the ratio of the standard deviations of potential and current noise signals and is decreased to exposure time. Data qualities can be easily checked by PSD(Power Spectral Density) plot and $V_{psd}$, $I_{psd}$ and $R_{sn}$($f_{min}$) is useful to research the protective performances and mechanisms of coated steels. Hurst exponent represents the degradation of coated steels. But, it is difficult to directly apply the protective criterion to the evaluation of epoxy coated steels used the shipbuilding processes.

• 수산해양교육연구
• /
• 제18권1호
• /
• pp.58-64
• /
• 2006

In order to examine the effect of humidity on hydrogen embrittlement of STS 444 weld zone for boiler with dry and wet welding conditions, this paper was carried out the accelerated hydrogen osmosis test and the electrochemical Tafel polarization test. In 0.5M $H_2SO_4$ + 0.01M $As_20_3$ solution, this test is added to load of $1400kg/cm^2$ together with hydrogen osmosis by current of $50 {mA/cm^2}$ for 60 min.. The electrochemical Tafel polarization test was carried out in 0.5M $H_2SO_4$ + 0.01M $As_20_3$ solution. Therefore, the effect of humidity on hydrogen embrittlement of STS 444 was considered. The main results are as following: On the basis of hydrogen embrittlement mechanism, that is, integrated electrochemical polarization characteristics with the established mechanism of hydrogen embrittlement, the reduction rate of corrosion current density of weld zone in the wet weld condition is larger than in the dry condition. We can nondestructively predict the degree of hydrogen embrittlement of STS 444 weld zone for boiler through the reduction rate of electrochemical corrosion current density.

• 한국진공학회:학술대회논문집
• /
• 한국진공학회 2011년도 제40회 동계학술대회 초록집
• /
• pp.311-311
• /
• 2011

$TiN{\times}$박막은 우수한 내마모성 및 내부식성, 높은 경도 그리고 열적 안정성 등으로 인하여, 절삭공구 및 기계적 부품의 하드코팅, 2차 연료 전지용 확산방지막의 코팅재료로서 광범위하게 사용되어지고 있다. 일반적으로 $TiN{\times}$ 박막은 화학 기상 증착법(CVD)을 이용하였으나, 최근에는 대면적에 균일한 코팅이 가능하고 기판과 박막상의 부착력이 우수하며, 프로세스를 제어하기 쉬운 물리적 기상 증착법(PVD)의 스퍼터링법에 대한 관심이 고조되고 있다. 그러나 스퍼터링법으로 증착된 $TiN{\times}$ 박막의 물성은 주상구조와 국부적 표면결함을 포함하는 박막의 미세구조에 의존하기 때문에 주상구조 사이에 존재하는 Void 와 Pinhole 그리고 crack들이 원인으로 작용하여, 내부식성 및 기계적 특성이 급속도로 저하되는 단점이 있다. 이러한 단점을 보완하기 위해서, 본 연구에서는 기판온도를(RT, $200^{\circ}C$, $400^{\circ}C$)증가시켜 실험 하였다. 이는 온도증가에 따른 박막의 치밀화가 이루어지고 결함이 감소하여 내부식성 특성향상이 기대되어진다. 또한 플라즈마 밀도를 높이기 위해서, 기존 DC 마그네트론 스퍼터링법에 전자기장을 추가로 인가하였다. 이는 플라즈마 밀도증가에 따른 고반응성의 질소 래디컬의 생성율 증가에 기인하여 박막 형성시 질화반응을 촉진시킴으로써 박막의 치밀화 및 내부식성 특성향상이 기대되어진다.

• 한국표면공학회지
• /
• 제51권1호
• /
• pp.1-10
• /
• 2018

Anodic oxidation treatment of metals is one of typical surface finishing methods which has been used for improving surface appearance, bioactivity, adhesion with paints and the resistances to corrosion and/or abrasion. This article provides fundamental principle, type and characteristics of the anodic oxidation treatment methods, including anodizing method and plasma electrolytic oxidation (PEO) method. The anodic oxidation can form thick oxide films on the metal surface by electrochemical reactions under the application of electric current and voltage between the working electrode and auxiliary electrode. The anodic oxide films are classified into two types of barrier type and porous type. The porous anodic oxide films include a porous anodizing film containing regular pores, nanotubes and PEO films containing irregular pores with different sizes and shapes. Thickness and defect density of the anodic oxide films are important factors which affect the corrosion resistance of metals. The anodic oxide film thickness is limited by how fast ions can migrate through the anodic oxide film. Defect density in the anodic oxide film is dependent upon alloying elements and second-phase particles in the alloys. In this article, the principle and mechanisms of formation and growth of anodic oxide films on metals are described.