• Title/Summary/Keyword: Corrosion damage behavior

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Stress Corrosion Cracking Initiation Behavior of Weldable Structural Steel in $H_2S$ Gas Saturated HCl Solution ($H_2S$ 가스포화 염산수용액에 의한 용접구조용강의 응력부식균열 발생거동)

  • 오세욱;김재철;김광영
    • Journal of Ocean Engineering and Technology
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    • v.4 no.1
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    • pp.88-100
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    • 1990
  • Among the test methods to evaluate stress-corrosion cracking(SCC) on the basis of fracture mechanics, constant displacement(bolt) loading method using modified-WOL specimen is practically convenient. In this test method, compliance formula is generally required to calculate load(consequently $K_{ISCC}$). There are many problems in using the analytic compliance formula to calculate $K_{ISCC}$, so we had proposed the experimental $K_{ISCC}$ evaluation technique in the previous report. This study has employed the slightly altered configuration of modified-WOL specimen made of weldable structural stee(BS360-50D). With these specimens, stress-corrosion tests have been performed in $H_2S$ gas saturated 20% HCl solution. Through the test, the problems as mentioned earlier have been discussed again, and the proposed evaluation technique has been verified. And the stress-corrosion cracks and hydrogen blisters have been investigated in the initiation step with the aids of metallurgical micrographs, SEM fractographs, and EPMA analysis. The inclusions segregated in the mid-thickness region traps hydrogen to produce the hydrogen blistering. The applied or residual stress does not contribute the occurrence of the blister. Hydrogen absorbed into the mid-thickness region is consumed to produce the blistering so that stress-corrosion crack could hardly be detected at that region. The stress-corrosion cracks initiate from the inclusions and propagate in radial pattern. And the initiation site is remote from the crack tip and is inclined from the crack plane, which is assumed to be caused by the triaxial stress and the amount of the absorbed hydrogen.

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An Experimental Study on the Deflection Estimation of RC Flexural Member by Corrosion of Reinforcement (철근 부식에 따른 철근콘크리트 휨 부재의 처짐 산정에 대한 실험적 연구)

  • Kim, Jee-Sang;Moon, Hyeong-Gab
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.9 no.2
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    • pp.143-151
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    • 2021
  • Flexural test of reinforced concrete beam with corroded reinforcement were performed to measure the deflection, curvature and cracking moment for various bar diameter and amounts of corrosion. The amounts of corrosion are varied from 0% to 10% by weight and the bar diameters are chosen as 10mm, 13mm, and 19mm. The changes in reinforcement diameter do not affect the flexural behaviors significantly according to this experiment. If the amounts of corrosion is greater than 2%, the deflection and curvature of the beam increased and the cracking moment decreased. It means that the lower amounts of corrosion does not result structural damage in flexural member significantly as in direct tensile test. A modification factor considering an effect of amounts of corrosion is proposed based on the experiment, which can be used to determine the deflection of reinforced concrete beam with corroded reinforcement.

Effects of Annealing and Post-weld Heat Treatments on Corrosion Behaviors of Super Austenitic Stainless Steel (소둔 및 용접후열처리가 슈퍼 오스테나이트계 스테인리스강의 부식거동에 미치는 영향)

  • Yun, Duck Bin;Park, Jin Sung;Cho, Dong Min;Hong, Seung Gab;Kim, Sung Jin
    • Corrosion Science and Technology
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    • v.20 no.6
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    • pp.426-434
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    • 2021
  • The effect of two different annealing temperatures on the level of the second phase precipitated in the microstructure and the corrosion behaviors of super austenitic stainless steel were examined. The sample annealed at a higher temperature had a significantly lower fraction of the sigma phase enriched with Cr and Mo elements, showing more stable passivity behavior during the potentiodynamic polarization measurement. However, after the welding process with Inconel-type welding material, severe corrosion damage along the interface between the base metal and the weld metal was observed regardless of the annealing temperature. This was closely associated with the precipitation of the fine sigma phase with a high Mo concentration in the unmixed zone (UMZ) during the welding process, leading to the local depletion of Mo concentrations around the sigma phase. On the other hand, the fraction of the newly precipitated fine sigma phase in the UMZ was greatly reduced by post-weld heat treatment (PWHT), and the corrosion resistance was greatly improved. Based on the results, it is proposed that the alloy composition of welding materials and PWHT conditions should be further optimized to ensure the superior corrosion resistance of welded super austenitic stainless steel.

Mechanisms of sulfate ionic diffusion in porous cement based composites

  • Gospodinov, P.;Mironova, M.;Kazandjiev, R.
    • Computers and Concrete
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    • v.4 no.4
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    • pp.273-284
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    • 2007
  • The paper considers a theoretical model for the study of the process of transfer of sulfate ions in saturated porous media - mineral composites. In its turn, the model treats diffusion of sulfate ions into cement based composites, accounting for simultaneous effects such as filling of micro-capillaries with ions and chemical products and liquid push out of them. The proposed numerical algorithm enables one to account for those simultaneous effects, as well as to model the diffusive behavior of separate sections of the considered volume, such as inert fillers. The cases studied illustrate the capabilities of the proposed model and those of the algorithm developed to study diffusion, considering the specimen complex configuration. Computations show that the theoretical assumptions enable one to qualitatively estimate the experimental evidence and the capabilities of the studied composite. The results found can be used to both assess the sulfate corrosion in saturated systems and predict and estimate damage of structures built of cement-based mineral composites.

Investigation on Effect of Distance Between Two Collinear Circumferential Surface Cracks on Primary Water Stress Corrosion Crack Growth in Alloy 600TT Steam Generator Tubes (Alloy 600TT 증기발생기 전열관내 일렬 원주방향 표면 일차수응력 부식균열 성장에 미치는 균열 간격의 영향 고찰)

  • Heo, Eun-Ju;Kim, Jong-Sung;Jeon, Jun-Young;Kim, Yun-Jae
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.39 no.3
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    • pp.269-273
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    • 2015
  • The study investigated the effect of the distance between two collinear circumferential surface cracks on the primary stress corrosion crack (PWSCC) growth in alloy 600TT steam generator tubes using a finite element damage analysis based on the PWSCC initiation model and macroscopic phenomenological damage mechanics approach. The damage analysis method was verified by comparing the results to the previous study results. The verified method was applied to collinear circumferential surface PWSCCs. As a result, it was found that the collinear cracks showed earlier coalescence and penetration times than the a single crack, and the times increased with the distance. In addition, it is expected that penetration may occur before coalescence of two cracks if they are more than a specific distance apart.

Evaluation of Residual Strength of Carbon/Epoxy Laminates Due to Low Velocity Impact Damage (Carbon/Epoxy 적층판의 저속충격손상에 따른 잔류강도 평가)

  • Kang, Min-Sung;Choi, Jung-Hun;Kim, Sang-Young;Koo, Jae-Mean;Seok, Chang-Sung
    • Journal of the Korean Society for Precision Engineering
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    • v.27 no.2
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    • pp.102-108
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    • 2010
  • Recently, carbon fiber reinforced plastic(CFRP) composite materials have been widely used in various fields of engineering because of its advanced properties. Also, CFRP composite materials offer new design flexibilities, corrosion and wear resistance, low thermal conductivity and increased fatigue life. However CFRP composite materials are susceptible to impact damage due to their lack of through-thickness reinforcement and it causes large drops in the load-carrying capacity of a structure. Therefore, the impact damage behavior and subsequently load-carrying capacity of impacted composite materials deserve careful investigation. In this study, the residual strength and impact characteristics of plain-woven CFRP composites with impact damage are investigated under axial tensile test. By using obtained residual strength and Tan-Cheng failure criterion, residual strength of CFRP laminate with arbitrary fiber angle were evaluated.

Corrosion fatigue crack growth behavior of 316LN stainless steel in high-temperature pressurized water

  • Zhang, Ziyu;Tan, Jibo;Wu, Xinqiang;Han, En-Hou;Ke, Wei
    • Nuclear Engineering and Technology
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    • v.53 no.9
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    • pp.2977-2981
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    • 2021
  • Corrosion fatigue crack growth (FCG) behavior of 316LN stainless steel was investigated in high-temperature pressurized water at different temperatures, load ratios (R = Kmax/Kmin) and rise times (tR). The environmental assisted effect on FCG rate was observed when both the R and tR exceeded their critical values. The FCG rate showed a linear relation with stress intensity factor range (ΔK) in double logarithmic coordinate. The environmental assisted effect on FCG rate depended on the ΔK and quantitative relations were proposed. Possible mechanisms of environmental assisted FCG rate under different testing conditions are also discussed.

Fracture Behavior Evaluation of Wall Thinned pipes by Finite Element Analysis (감육배관의 요한요소해석에 의한 파괴거동 평가)

  • AHN SEOK-HWAN;NAM KI-Woo;KIM JIN-WOOK;LEE SOO-SIG;YOON JA-MUN
    • Proceedings of the Korea Committee for Ocean Resources and Engineering Conference
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    • 2004.05a
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    • pp.320-325
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    • 2004
  • Fracture behaviors and strength of pipes with local wall thinning are very important Jar the integrity of energy plants. In pipes of energy plants, sometimes, the local wall thinning may result from severe erosion-corrosion damage. Recently, the effects of local wall thinning on strength and fracture behaviors of piping system have been well studied. In this paper, the elasto-plastic analysis is performed by FE code ANSIS. We evaluated the failure mode, fracture strength and fracture behavior from FE analysis.

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Effect of Anodizing Current Density on Anti-Corrosion Characteristics for Al2O3 Oxide Film (Al2O3 산화 피막의 내식성에 미치는 양극산화 전류밀도의 영향)

  • Lee, Seung-Jun;Jang, Seok-Gi;Kim, Seong-Jong
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2016.11a
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    • pp.153-153
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    • 2016
  • Aluminum alloys have poor corrosion resistance compared to the pure aluminum due to the additive elements. Thus, anodizing technology artificially generating thick oxide films are widely applied nowadays in order to improve corrosion resistance. Anodizing is one of the surface modification techniques, which is commercially applicable to a large surface at a low price. However, most studies up to now have focused on its commercialization with hardly any research on the assessment and improvement of the physical characteristics of the anodized films. Therefore, this study aims to select the optimum temperature of sulfuric electrolyte to perform excellent corrosion resistance in the harsh marine environment through electrochemical experiment in the sea water upon generating porous films by variating the temperatures of sulfuric electrolyte. To fabricate uniform porous film of 5083 aluminum alloy, we conducted electro-polishing under the 25 V at $5^{\circ}C$ condition for three minutes using mixed solution of ethanol (95 %) and perchloric (70 %) acid with volume ratio of 4:1. Afterward, the first step surface modification was performed using sulfuric acid as an electrolyte where the electrolyte concentration was maintained at 10 vol.% by using a jacketed beaker. For anode, 5083 aluminum alloy with thickness of 5 mm and size of $2cm{\times}2cm$ was used, while platinum electrode was used for cathode. The distance between the two was maintained at 3 cm. Afterward, the irregular oxide film that was created in the first step surface modification was removed. For the second step surface modification process (identical to the step 1), etching was performed using mixture of chromic acid (1.8 wt.%) and phosphoric acid (6 wt.%) at $60^{\circ}C$ temperature for 30 minutes. Anodic polarization test was performed at scan rate of 2 mV/s up to +3.0 V vs open circuit potential in natural seawater. Surface morphology was compared using 3D analysis microscope to observe the damage behavior. As a result, the case of surface modification presented a significantly lower corrosion current density than that without modification, indicating excellent corrosion resistance.

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Application of Acoustic Emission for Assessing Deterioration in Reinforced Concrete Beams (철근 콘크리트 빔의 노화도 평가를 위한 음향방출 기술의 응용)

  • Yoon, Dong-Jin;Park, Phi-Lip;Lee, Seung-Seok
    • Journal of the Korean Society for Nondestructive Testing
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    • v.20 no.4
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    • pp.276-284
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    • 2000
  • The acoustic emission (AE) behavior of reinforced concrete beams tested under flexural loading was investigated to characterize and identify the source of damage. This research was aimed at identifying the characteristic AE response associated with micro-crack development, localized crack propagation, corrosion, and debonding of the reinforcing steel. Concrete beams were prepared to isolate the damage mechanisms by using plain, notched-plain, reinforced, and corroded-reinforced specimens. The beams were tested using four-point cyclic step-loading. The AE response was analyzed to obtain key parameters such as the time history of AE events, the total number and rate of AE events, and the characteristic features of the waveform. Initial analysis of the AE signal has shown that a clear difference in the AE response is observed depending on the source of the damage. The Felicity ratio exhibited a correlation with the overall damage level, while the number of AE events during unloading can be an effective criterion to estimate the level of corrosion distress in reinforced concrete structures. Consequently, AE measurement characterization appears to provide a promising approach for estimating the level of deterioration in reinforced concrete structure.

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