• 제목/요약/키워드: Corrosion and wear

검색결과 407건 처리시간 0.026초

Duplex Surface Modification with Micro-arc Discharge Oxidation and Magnetron Sputtering for Aluminum Alloys

  • Tong, Honghui;Jin, Fanya;He, Heng
    • 한국진공학회지
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    • 제12권S1호
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    • pp.21-27
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    • 2003
  • Micro-arc discharge oxidation (MDO) is a cost-effective plasma electrolytic process which can be used to improve the wear and corrosion resistance of Al-alloy parts by forming a alumina coating on the component surface. However, the MDO coated Al-alloy components often exhibit relatively high friction coefficients and low wear resistance fitted with many counterface materials, additionally, the pitting corrosion for the MDO coated AI-alloy components, especially for a thinner alumina coating, often occurs in atmosphere circumstance due to the porous alumina coats. Therefore, a duplex treatment, combining a MDO coated ahumina thin layer with a TiN coating, prepared by magnetron sputtering (MS), has been investigated. The Vicker's microhardness, pin-on-disc, electrochemical measurement, salt spray, XRD and SEM tests were used to characterize and analyze the treated samples. The work demonstrates that the MDO/MS coated samples have a combination of a very low friction coefficient and good wear resistance as well as corrosion since the micro-holes on alumina coating are partly or fully covered by TiN material.

5% 황산용액에서 배기밸브 보수 용접부의 부식 특성에 미치는 용접방법과 용접봉의 영향-1 (Effect of Welding method and Welding Material to Corrosion Property of Repair Weld Zone for Exhaust Valve in 5% H2SO4 Solution -1)

  • 김진경;조황래;이명훈;김윤해;문경만
    • Journal of Advanced Marine Engineering and Technology
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    • 제31권6호
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    • pp.744-752
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    • 2007
  • Recently a fuel oil of the diesel engine in the ship is being changed with low quality as the oil price is higher more and more. Therefore the wear and corrosion in all parts of the engine like cylinder liner ring groove of piston crown, spindle and seat ring of exhaust valve are increased with using of heavy oil of low quality In particular the degree of wear and corrosion in between valve spindle and seat ring are more serious compared to the other parts of the engine due to operating in severe environment such as the high temperature of exhaust gas and repeating impact. Thus the repair weld to the valve spindle and seat ring is a unique method to prolong the life of the exhaust valve in an economical point of view In this study. corrosion property of both weld metal zone and base metal was investigated with some electrochemical methods such as measurement of corrosion potential, cathodic and anodic polarization curves, cyclic voltammogram and polarization resistance etc. in 5% $H_2SO_4$ solution. in the case of being welded with some welding methods and welding materials to the exhaust valve specimen as the base metal. In all cases. the values of hardness of the weld metal zone were more high than that of the base metal. And their corrosion resistance were also superior to the base metal. The weld metal of A2F(AC SMAW: 2 pass welding with foreign electrode) showed a relatively good results to the corrosion resistance as well as the hardness compared to the ether welding methods and welding materials. Moreover it indicated that hardness of the weld metal by the domestic electrode was considerably high compared to that of the foreign electrode.

질소이온주입된 초내식성 스테인리스강의 마모부식 특성 (Wear Corrosion Behaviour of Nitrogen Ion Implanted Super Stainless Steel)

  • 강선화;김철생
    • 대한의용생체공학회:학술대회논문집
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    • 대한의용생체공학회 1994년도 추계학술대회
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    • pp.175-177
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    • 1994
  • The wear corrosion behaviour of a nitrogen ion implanted super stainless steel (S.S.S, 22Cr - 20Ni - 6Mo - 0.25N) was compared with those of S.S.S, 316L SS and TiN coated 316L SS. The Cr and Ni amounts won out from the materials were investigated using an electrothermal atomic absorption spectrometry. We observed that the Cr dissolution rate of the S.S.S was similar to that of 316L SS, however, the Ni release of the S.S.S was feater than 316L SS. The metal ions released from the nitrogen ion implanted S.S.S surface were significantly reduced. The wear corrosion behaviour of the stainless steels was not correlated with the results shown by a static metal ion release test.

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Corrosion and Wear Properties of Cold Rolled 0.087% Gd Lean Duplex Stainless Steels for Neutron Absorbing Material

  • Choi, Yong;Baik, Youl;Moon, Byung-Moon;Sohn, Dong-Seong
    • Nuclear Engineering and Technology
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    • 제48권1호
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    • pp.164-168
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    • 2016
  • Lean duplex stainless steels with 0.087 wt.% gadolinium (Gd) were inert arc-melted and cast in molds of size $10mm{\times}10mm{\times}20mm$. The micro-hardnesses of the rolling direction (RD), transverse direction (TD) and short transverse (ST) direction were $258.5H_V$, $292.3H_V$, and $314.7H_V$, respectively. A 33% cold rolled specimen had the crystallographic texture that (100) pole was mainly concentrated to the normal direction (ND) and (110) pole was concentrated in the center of ND and RD. The corrosion potential and corrosion rate in artificial seawater and $0.1M\;H_2SO_4$ solution were in the range of $105.6-221.6mV_{SHE}$, $0.59-1.06mA/cm^2$, and $4.75-8.25mV_{SHE}$, $0.69-1.68mA/cm^2$, respectively. The friction coefficient and wear loss of the 0.087 w/o Gd-lean duplex stainless steels in artificial seawater were about 67% and 65% lower than in air, whereas the wear efficiency was 22% higher. The corrosion and wear behaviors of the 0.087 w/o Gd-lean duplex stainless steels significantly depended on the Gd phases.

플라즈마 전해 산화처리한 시효경화 Mg-Al 합금 피막의 기계적 및 전기화학적 특성 (Mechanical and Electrochemical Properties of Plasma Electrolytic Oxide Coatings on Aged Mg-Al alloy)

  • 장시영;김예림;김양도
    • 한국재료학회지
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    • 제17권12호
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    • pp.648-653
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    • 2007
  • Plasma electrolytic oxidation (PEO) treatment was performed on cast Mg-6 wt%Al alloy solution-treated at 693K for 16h and aged at 498K. The surface roughness, thickness, micro-hardness, wear and corrosion properties of coatings on solution-treated and aged Mg-6 wt%Al alloy were investigated. The coatings on aged Mg-6 wt%Al alloy had thinner layer and lower micro-hardness and wear resistance than the solution-treated Mg-6 wt%Al alloy. As the aging time increased, the thickness of coatings decreased while the surface roughness was almost no changed. In addition, the micro-hardness and wear property of coatings decreased with increasing the aging time unlike the uncoated Mg-6 wt%Al alloy showing the peak micro-hardness and the best wear property after aging for 16 h. However, the coatings on Mg-6 wt%Al alloy peak-aged for 16h revealed the best corrosion resistance in 3.5% NaCl solution, which was explained based on the microstructural characteristics.

Tribological and Corrosion Behavior of Multilayered $WC-Ti_{1-x}Al_xN$ Coatings Deposited by Cathodic Arc Deposition Process on High Speed Steel

  • S.H. Ahn;J.H. Yoo;Park, Y.S.;Kim, J.G.;Lee, H.Y.;J.G. Han
    • 한국표면공학회:학술대회논문집
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    • 한국표면공학회 2001년도 추계학술발표회 초록집
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    • pp.31-32
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    • 2001
  • Recently, many of the current development in surface modification engineering are focused on multilayered coatings. Multilayered coatings have the potential to improve the tribological and corrosion properties of tools and components. By using cathodic arc deposition, $WC-Ti_{1-x}Al_xN$ multilayers were deposited on steel substrates. Wear tests of four multiplayer coatings were performed using a ball-on-disc configuration with a linear sliding speed of 0.1m/s, 5N load. The tests were carried out at room temperature in airby employing AISI 52100 steel ball ($H_v=848N$) of 11mm in diameter. Electrochemical tests were performed using the potentiodynamic and electrochemical impedance spectroscopy (EIS) measurements. The surface morphology and topography of the wear scars of tribo-element and the corroded specimen have been determined by using scanning electron spectroscopy (SEM). Also, wear mechanism was determined by using SEM coupled with EDS. Results have showed an improved wear resistance and corrosion resistance of the $WC-Ti_{1-x}Al_xN$ coatings.

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PTA법에 의한 스텔라이트 12 합금 육성층의 특성에 미치는 전류의 영향 (The Effect of Current on Characteristics of Stellite 12 Alloy Overlayer by PTA Process)

  • 정병호;김무길;안용식;김민영;이성열
    • 동력기계공학회지
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    • 제5권3호
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    • pp.88-94
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    • 2001
  • Stellite 12 alloy-powders were overlaid on 410 stainless steel valve seat using plasma transferred arc(PTA) process. Variation of the microstructure, hardness, wear and corrosion of overlaid deposit with current change was investigated. The deposit showed hypoeutectic microstructure, which was consisted of primary cobalt dendrite and networked $M_7C_3$ type eutectic carbides. As current increased, the amount of eutectic carbide decreased and its dendritic secondary arm spacing increased. Hardness of the deposit was decreased with increase of current. Stress relief heat treatment at $600^{\circ}C$ for two hours resulted in slight increase of hardness in the deposit and showed uniform hardness distribution in base metal without any hardened layer in HAZ. Specific wear decreased with increase of sliding distance. The deposit of high hardness with a lot of eutectic carbide showed relatively low specific wear. Initial corrosion current density of the deposit in 0.1N sulfuric acid was lower than those of 410 stainless steel, and showed a little variation with PTA current.

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A STUDY ON WEAR AND CORROSION RESISTANCE OF CrN$_{x}$ FILMS BY CATHODIC ARC ION PLATING PROCESS

  • Han, Jeon-G.;Kim, Hyung-J.;Kim, Sang-S.
    • 한국표면공학회지
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    • 제29권5호
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    • pp.545-548
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    • 1996
  • $CrN_x$ films were deposited on SKD61 and S45C by cathodic arc ion plating process. In this study, the microstructure, microhardness, a hesion, wear and corrosion properties of the CrNx films were studied for various nitrogen partial pressures and the results were compared with those from the electroplated hard Cr. The crystal structure of the films was characterized by X-ray diffraction. Wear tests were performed under no lubricant condition at atmosphere by ball-on-disc type tribotester. Corrosion resistance of the films were studied by electrochemical corrosion test, measuring current demsity-potential curves. The results indicated that the $CrN_x$ films formed using ion plation method showed higer hardness and lower current density, friction coefficient than electroplated hard Cr. Consequently, the application of the CrNx coationgs by ion plating which is free of environmental pollution, is expected to improve lifetime of components in industrial practice.

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프렛팅 마모에 의한 커넥터 단자의 접촉불량 재현 (Reappearance of the Electrical Poor Contact in Connectors by Fretting Wear)

  • 김성우;정원욱;위신환;김형민;박성배;이동훈
    • 대한기계학회:학술대회논문집
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    • 대한기계학회 2008년도 추계학술대회A
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    • pp.1361-1366
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    • 2008
  • Failure mechanism of the poor contact is analyzed on the basis of used connectors and this poor contact of connectors is reappeared by the new forced fretting wear method. As the result of failure analysis and reappearance, fretting wear and corrosion of the contact interface causes the contact resistance degradation and the poor contact of connectors. The amount of degradation depends on the fretting stroke. Changes in contact resistance of static contacts are likely to be small and gradual, while motions of contact interface may result in larger and discontinuous changes in resistance and voltage. This voltage drop by fretting motions is large enough to cause the distortion of sensor signal and mis-working of electric components.

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해수 중에서 STS304강의 프레팅 마멸특성 (Fretting Wear Characteristics of STS304 Steel in Seawater)

  • 김은구;김태형;김석삼
    • Tribology and Lubricants
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    • 제16권4호
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    • pp.302-307
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    • 2000
  • The fretting wear characteristics of STS304 steel in seawater were investigated experimentally. A fretting wear tester was designed to be suitable for this fretting test. This study was focused on the effects due to the combination of normal load, slip amplitude and number of cycles and corrosive environment as the main factors of fretting. The results of this study showed that the wear volume increased abruptly at slip amplitude between 70 $\mu\textrm{m}$∼100 $\mu\textrm{m}$ by fracture of oxide layers but above that slip amplitude the wear volume increased steadily.