• International Journal of Concrete Structures and Materials
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• v.9 no.2
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• pp.241-254
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• 2015

A lot of reinforced concrete (RC) structures in Syria went out of service after a few years of construction. This was mainly due to reinforcement corrosion or chemical attack on concrete. The use of blended cements is growing rapidly in the construction industry due to economical, ecological and technical benefits. Syria is relatively rich in scoria. In the study, mortar/concrete specimens were produced with seven types of cement: one plain Portland cement (control) and six blended cements with replacement levels ranging from 10 to 35 %. Rapid chloride penetration test was carried in accordance with ASTM C 1202 after two curing times of 28 and 90 days. The effect on the resistance of concrete against damage caused by corrosion of the embedded steel has been investigated using an accelerated corrosion test by impressing a constant anodic potential. The variation of current with time and time to failure of RC specimens were determined at 28 and 90 days curing. In addition, effects of aggressive acidic environments on mortars were investigated through 100 days of exposure to 5 % $H_2SO_4$, 10 % HCl, 5 % $HNO_3$ and 10 % $CH_3COOH$ solutions. Evaluation of sulfate resistance of mortars was also performed by immersing in 5 % $Na_2SO_4$ solution for 52 weeks. Test results reveal that the resistance to chloride penetration of concrete improves substantially with the increase of replacement level, and the concretes containing scoria based-blended cements, especially CEM II/B-P, exhibited corrosion initiation periods several times longer than the control mix. Further, an increase in scoria addition improves the acid resistance of mortar, especially in the early days of exposure, whereas after a long period of continuous exposure all specimens show the same behavior against the acid attack. According to results of sulfate resistance, CEM II/B-P can be used instead of SRPC in sulfate-bearing environments.

• Journal of ILASS-Korea
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• v.12 no.1
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• pp.18-29
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• 2007

Feedwater heaters of many nuclear power plants have recently experienced severe wall thinning damage, which will increase as operating time progresses. Several nuclear power plants in Korea have experienced wall thinning damage in the area around the impingement baffle - installed downstream of the high pressure turbine extraction steam line - inside number 5A and 5B feedwater heaters. At that point, the extracted steam from the high pressure turbine is two phase fluid at high temperature, high pressure, and high speed. Since it flows in reverse direction after impinging the impingement baffle, the shell wall of the number 5 high pressure feedwater heater may be affected by flow-accelerated corrosion. This paper describes the comparisons between the numerical analysis results using the FLUENT code and the down scale experimental data in an effort to determine root causes of the shell wall thinning of the high pressure feedwater heaters. The numerical analysis and experimental data were also confirmed by actual wall thickness measured by an ultrasonic test.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.31 no.1 s.256
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• pp.1-7
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• 2007

Feedwater heaters of many nuclear power plants have recently experienced severe wall thinning damage, which will increase as operating time progresses. Several nuclear power plants in Korea have experienced wall thinning damage in the area around the impingement baffle - installed downstream of the high pressure turbine extraction steam line - inside number 5A and 5B feedwater heaters. At that point, the extracted steam from the high pressure turbine is two phase fluid at high temperature, high pressure, and high speed. Since it flows in reverse direction after impinging the impingement baffle, the shell wall of the number 5 high pressure feedwater heater may be affected by flow-accelerated corrosion. This paper describes the comparisons between the numerical analysis results using the FLUENT code and the down scale experimental data in an effort to determine root causes of the shell wall thinning of the high pressure feedwater heaters. The numerical analysis and experimental data were also confirmed by actual wall thickness measured by an ultrasonic test.

• Proceedings of the KSME Conference
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• 2004.04a
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• pp.2017-2022
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• 2004

There are multistage preheaters in the power generation plan to improve the thermal efficiency of the plant and to prevent the components from the thermal shock. The energy source of these heaters comes from the extracted two phase fluid of working system. These two-phase fluid can cause the so-called Flow Accelerated Corrosion(FAC) in the extracting piping and the bubble plate of the heater for example, in case of point Beach Nuclear Power Plant and in the Wolsung Nuclear Power Plant. The FAC is due to the mass transport of the thin oxide layer by the convection. FAC is dependent on many parameters such as the operation temperature, void fraction, the fluid velocity and pH of fluid and so on. Therefore, in this paper velocity was calculated by FLUENT code in order to find out the root cause of the wall thinning of the feedwater heaters. It also includeed in the fluid mixing analysis model are around the number 5A feedwater heater shell including the extraction pipeline. To identify the relation between the local velocities and wall thinning, the local velocities according to the analysis results were compared with distribution of the shell wall thicknes by ultrasonic test.

• Journal of ILASS-Korea
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• v.9 no.4
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• pp.24-30
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• 2004

Feedwater flowing tube side of number 5 high pressure feedwatrr heaters was heated by extracting steam from high pressure turbine and draining water from moisture separators and number 6 high pressure feedwater heaters and supplied into steam generators. Because the extracting steam from the high pressure turbine is two phase fluid of high temperature, high pressure, and high speed and flows to inverse direction after impinging to impingement baffle. the shell wall of the number 5 high pressure feedwater heater may be affected by flow accelerated corrosion. On May 14, 1999, Point Beach Nuclear Plant (PBNP) with operating at full power experienced a steam leak from rupture of shell side of number 4B feedwater heater. Also, d domestic nuclear power plant experienced a severe wall thinning of shell side of number 5A and 5B feedwater heaters. This paper describes the fluid mixing analysis study using PHOENICS code in order to get at the root of the shell wall thinning of the feedwater heaters. The sections included in the fluid mixing analysis model are around the number 5h feedwater heater shell including the extracting pipeline. To identify the relation between the local velocities and wall thinning. the local velocities according to the analysis results were compared with the distribution of the shell wall thickness by ultrasonic test.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.26 no.4
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• pp.731-738
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• 2002

To understand failure behavior of pipe thinned by flow accelerated corrosion, in this study, the pipe failure tests were performed on 102mm-Sch.80 carbon steel pipe with various local wall thinning shapes, and the failure mode, load carrying capacity, and deformability were investigated. The tests were conducted under loading conditions of 4-points bending and internal pressure. The experimental results showed that the failure mode of thinned pipe depended on magnitude of internal pressure and thinning length as well as loading direction and thinning depth and angle. The variation in load carrying capacity and deformability of thinned pipe with thinning length was determined by stress type appled to the thinning area and circumferential thinning angle. Also, the effect of internal pressure on failure behavior was dependent on failure mode of thinned pipe, and it promoted crack occurrence and mitigated local buckling at thinned area.

• Journal of the Korean Society for Nondestructive Testing
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• v.33 no.5
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• pp.409-414
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• 2013

In this work, corrosion of 304 stainless steel was evaluated by using acoustic emission(AE) technique. AE measurement system was set for detecting acoustic signal during accelerated corrosion test of the specimen. AE signal started to be detected after the time of pitting corrosion initiation was evaluated by anodic polarization curve. Pitting corrosion damage was confirmed by optical microscopic observation of the surface morphology. AE cumulative counts and amplitude according to corrosion time could be divided into three stages. These trends were discussed in relation with changing pitting corrosion mechanism. Feasibilities of AE technique for evaluation of corrosion damage and mechanism were suggested.

• Corrosion Science and Technology
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• v.6 no.5
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• pp.227-232
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• 2007

The corrosion behavior of carbon steel (N80) in carbon dioxide saturated 1%NaCl solution with and without acetic acid or acetate was investigated by weight-loss test, electrochemical methods (polarization curve, Electrochemical impedance spectroscopy). The major objective is to make clear that the effect of acetic acid and acetate on the corrosion of carbon steel in $Co_2$ environments. The results indicate that either acetic acid or acetate accelerates cathodic reducing reaction, facilitates dissolution of corrosion products on carbon steel, and so promotes the corrosion rate of carbon steel in carbon dioxide saturated NaCl solution. All Nyquist Plots are consisting of a capacitive loop in high frequency region, an inductive loop in medial frequency region and a capacitive arc in low frequency region. The high frequency capacitive loop, medial frequency inductive loop and low frequency capacitive arc are corresponding to the electron transfer reaction, the formation/adsorption of intermediates and dissolution of corrosion products respectively. All arc of the measured impedance reduced with the increase of the concentration of Ac-, especially HAc. However, the same phenomenon is not notable after reducing pH value by adding HCl. HAc is a stronger proton donor and can be reduced directly by electrochemical reaction firstly. Ac- can't participate in electrochemistry reaction directly, but $Ac^-$ an hydrate easily to create HAc in carbon dioxide saturated environments. HAc is as catalyst in $Co_2$ corrosion. As a result, the corrosion rate was accelerated in the presence of acetate ion even pH value of solution increased.

• Nuclear Engineering and Technology
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• v.47 no.4
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• pp.454-460
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• 2015

Acoustic emission (AE) is one of the promising methods for detecting the formation of stress corrosion cracks (SCCs) in laboratory tests. This method has the advantage of online inspection. Some studies have been conducted to investigate the characteristics of AE parameters during SCC propagation. However, it is difficult to classify the distinct features of SCC behavior. Because the previous studies were performed on slow strain rate test or compact tension specimens, it is difficult to make certain correlations between AE signals and actual SCC behavior in real tube-type specimens. In this study, the specimen was a AISI 304 stainless steel tube widely applied in the nuclear industry, and an accelerated test was conducted at high temperature and pressure with a corrosive environmental condition. The study result indicated that intense AE signals were mainly detected in the elastic deformation region, and a good correlation was observed between AE activity and crack growth. By contrast, the behavior of accumulated counts was divided into four regions. According to the waveform analysis, a specific waveform pattern was observed during SCC development. It is suggested that AE can be used to detect and monitor SCC initiation and propagation in actual tubes.

• Journal of the Korean institute of surface engineering
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• v.47 no.3
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• pp.137-146
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• 2014

The important drawback of epoxy electrodeposition(ED) coatings is the lack of the weathering resistance caused by the structure of bisphenol A. To improve this yellowing phenomena, acryl ED coatings have been developed. Compared with the epoxy ED coatings, however, acryl ED coatings are relatively weak in the corrosion resistance and mechanical properties. The purpose of this study is complemented their drawbacks by mixing epoxy and acryl ED paints. The salt spray, accelerated weathering test(QUV) and cupping, bending, impact test were employed to investigate the corrosion resistance, weathering resistance, and mechanical properties of ED coatings. When the ratio of acryl to epoxy resin of ED coating is 0.33, the weathering resistances are appropriately improved in condition maintaining the corrosion resistance. It was shown that the weathering resistance for epoxy ED coating was adjusted by optimally mixing acryl ED paint.