• Proceedings of the KSME Conference
• /
• 2004.04a
• /
• pp.228-233
• /
• 2004

The length of city gas pipeline is increasing with expansion of natural gas transmission rapidly. A lot of the expense was paid for repair and maintenance with increasing of pipeline length and the cost of repair and maintenance by the corrosion was the highest. It is necessary to evaluate integrity in case of thickness reduction by corrosion. There are a lot of assessment criteria for corrosion defect in foreign countries but they are not suitable for application in the country directly. In this work, we performed the burst test and the finite element analysis for city gas pipeline, KS D3507 and KS D3631 for city gas transmission, and developed the assessment method of corrosion defect, which is suitable for domestic condition.

• Corrosion Science and Technology
• /
• v.5 no.5
• /
• pp.153-159
• /
• 2006

Austenitic stainless steels with addition of various amounts of Mo and W were evaluated in terms of corrosion and contact resistance to determine optimum alloy composition of metallic bipolar plate for PEMFC. The corrosion property was evaluated by both acid fume exposure test at $130^{\circ}C$ and by electrochemical polarization tests in $H_3PO_4$ solution at $80^{\circ}C$. Austenitic stainless steel with proper amount of Mo and W demonstrated not only good corrosion resistance but also low contact resistance. Analyses on the passive film show that partial substitution of Mo by W enhances passive film stability and repassivation property. Test results suggest that austenitic stainless steel with 2 wt%Mo and 4 wt%W has optimum composition for metallic bipolar plate used in PEMFC.

• The Transactions of The Korean Institute of Electrical Engineers
• /
• v.60 no.7
• /
• pp.1410-1416
• /
• 2011

A corrosion detecting system for 22.9 kV distribution power line insulation cable, which can travel autonomously along the live line, is proposed. Eddy current test method is employed to detect the corrosion, and the system developed here is capable of detecting internal corrosion of a ACSR-OC. Somewhat details of the electrical and mechanical mechanism of the system and traveling algorithm are introduced. Experimental results applied to the sample cables having artificial corrosion and the operating distribution lines are provided. From the result, we confirmed that the system is useful for detecting internal corrosion of a ACSR, and is expected to be a new non-destructive testing equipment in the area of diagnosis for the distribution power line.

• Journal of Power System Engineering
• /
• v.9 no.1
• /
• pp.50-56
• /
• 2005

The corrosion experiment was performed for 120 hours on the specimens in the natural seawater tank with four steps of the loaded torsional stress. The surface corrosion pattern of SCM440 area was showed global corrosion and narrow pitting, that was cause by galvanic corrosion between friction welded IN713LC and SCM440. But corrosion does not proceeded from IN713LC area. Initially, the average relative electrode potential and corrosion current were decreased suddenly, by and large, it was stabilized gradually tend to decreasing with the elapse of the immersion time. The corrosion rate was decreased by increasing the load stress, but 200 MPa specimen was showed most large value.

• Journal of the Korean Magnetics Society
• /
• v.3 no.3
• /
• pp.221-228
• /
• 1993

The general requirements of recording media include recording performance, environmental stability, runnability on the drive or deck, and manufacturability. CoCrMo thin films were prepared using RF sputtering system for a study on chemical stability. Surface degradation of the CoCrMo thin film was studied by SEM, XPS and AES. Surface degradation was found to be dependent of sputtering condition and Mo content. Addition of Mo to CoCr thin film improved dramatically its surface degradation resistance in dilute sulfuric acid, as indicated by active-passive transition appeared in electrochemical polarization curve. Futhermore, the passive current density was decreased with increasing Mo content. The reduction in a number density of corrosion sites by Mo addition vms observed, after accelerated corrosion test. AES survey indicated that corrosion occured on the site with Cr depletion and highly concentrated chloride ions.

• Corrosion Science and Technology
• /
• v.6 no.1
• /
• pp.18-23
• /
• 2007

DLC coatings have been deposited onto substrate of STS 316L and Ti alloy using r.f. PACVD (plasma-assisted chemical vapor deposition) with a mixture of $C_{6}H_{6}$ and $SiH_{4}$ as the process gases. Corrosion performance of DLC coatings was investigated by electrochemical techniques (potentiodynamic polarization test and electrochemical impedance spectroscopy) and surface analysis (scanning electron microscopy). The electrolyte used in this test was a 0.89% NaCl solution of pH 7.4 at temperature $37^{\circ}C$. The porosity and protective efficiency of DLC coatings were obtained using potentiodynamic polarization test. Moreover, the delamination area and volume fraction of water uptake of DLC coatings as a function of immersion time were calculated using electrochemical impedance spectroscopy. This study provides the reliable and quantitative data for assessment of the effect of substrate on corrosion performance of Si-DLC coatings. The results showed that Si-DLC coating on Ti alloy could improve corrosion resistance more than that on STS 316L in the simulated body fluid environment. This could be attributed to the formation of a dense and low-porosity coating, which impedes the penetration of water and ions.

• Proceedings of the KSME Conference
• /
• 2004.04a
• /
• pp.222-227
• /
• 2004

The failure assessment for corroded pipeline has been considered with the full scale burst test and the finite element analysis. The burst tests were conducted on 762 mm diameter, 17.5 mm wall thickness and API 5L X65 pipe that contained specially manufactured rectangular corrosion defect. The failure pressure for corroded pipeline was measured by burst testing and classified with respect to corrosion sizes and corroded regions - the body, the girth weld and the seam weld of pipe. Finite element analysis was carried out to derive failure criteria of corrosion defect on the pipe. A series of finite element analyses were performed to obtain a limit load solution for corrosion defects on the basis of burst test. As a result, the criteria for failure assessment of corrosion defect within the body, the girth weld and the seam weld of API 5L X65 gas pipeline were proposed.

• Corrosion Science and Technology
• /
• v.5 no.3
• /
• pp.85-89
• /
• 2006

KAERI(Korea Atomic Energy Research Institute) has developed a repassivation rate test system which can be operated at $300^{\circ}C$. It consists of an autoclave, three electrodes for an electrochemical test and a diamond scratch tip. All the electrodes are electrically insulated from the autoclave by using high temperature fittings. Reproducible repassivation curves of alloy 600 at 300 C were obtained. Repassivation rate of alloy 600 at pH 13 was slower than that of pH 10. Stress corrosion cracking test was carried as a function of the pH at a high temperature. At pH 10, alloy 600 showed a severe stress corrosion cracking(SCC), whereas it did not show a SCC at pH 7. From the viewpoint of a relationship between the current density and the charge density, a big difference was observed in the two solutions; the slope of pH 13 was steeper than that of pH 10. So the stress corrosion susceptibility at pH 13 seems to be higher than that of pH 10. The system would be a good tool to evaluate the SCC susceptibility of alloy 600 at a high temperature.

• Steel and Composite Structures
• /
• v.35 no.2
• /
• pp.171-186
• /
• 2020

This paper aims at providing insights on the use of thermosetting liner for the repair of offshore pipelines exposed to corrosion and leakage. The work which covers both experimental and numerical approaches were aspired due to the high cost of repair for pipelines, limitations of thermoplastic material and limited study of reinforced thermosetting liner. The experiment involves a destruction test called the burst test, carried out on an API 5L X42 carbon steel pipe under four case studies, namely (i) intact pipe, (ii) pipe with corrosion defect, (iii) pipe with corrosion defect and repaired with thermosetting liner and (iv) pipe with leakage and repaired with thermosetting liner. The numerical simulation was developed to first validate the experimental results and later to optimize the design of the thermosetting liner in terms of the number of layers required to restore the original strength of the pipe. The burst test shows an improvement in 23% of the burst capacity for the pipe with corrosion defects, after being repaired with a three-layer thermosetting liner. The parametric studies conducted showed that with an addition of thermosetting layers, the burst capacity improves by an average of 1.85 MPa. In conclusions, the improvement in strength can be further increased with increasing thickness of the thermosetting liner. The thermosetting liner was also determined to fail first inside the host pipe.

• Corrosion Science and Technology
• /
• v.20 no.4
• /
• pp.175-182
• /
• 2021

Magnesium alloy is limited in the industrial field because its standard electrode potential is -2.363 V vs. NHE (Normal Hydrogen Electrode) at 25 ℃. This high electrochemical activity causes magnesium to quickly corrode with oxygen in air; chemical conversion coating prevents corrosion but causes surface defects like cracks and pores. We have examined the anti-corrosion effect of sol-gel coating sealed on the defected conversion coating layer. Sol-gel coatings produced higher voltage current and smaller pore than the chemical conversion coating layer. The conversion coating on magnesium alloy AZ31 was prepared using phosphate-permanganate solution. The sol-gel coating was designed using trimethoxymethylsilane (MTMS) and (3-Glycidyloxypropyl) trimethoxysilane (GPTMS) as precursors, and aluminum acetylacetonate as a ring-opening agent. The thermal shock resistance was tested by exposing specimens at 140 ℃ in a convection oven; the results showed changes in the magnesium alloy AZ31 surface, such as oxidization and cracking. Scanning electron microscope (FE-SEM) analysis confirmed a sealed sol-gel coating layer on magnesium alloy AZ31. Electrochemical impedance spectroscopy (EIS) measured the differences in corrosion protection properties by sol-gel and conversion coatings in 0.35 wt% NaCl solution, and the potentiodynamic polarization test and confirmed conversion coating with the sol-gel coating show significantly improved resistance by crack sealing.